: Ad Bac 4227 Disinfectant

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1 Revision date: 04/15/2015 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product name : Mixture Product code : : Ad Bac 4227 Disinfectant 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Disinfectant 1.3. Details of the supplier of the safety data sheet CSI Group Int'l Inc.-DBA Concrete Services Int'l 575 Route 73 North, Unit C-4 West Berlin, NJ T (856) Emergency telephone number SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Skin Irrit. 2 H315 Eye Dam. 1 H318 Full text of H-phrases: see section Label elements GHS-US labeling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) : Danger GHS05 : H315 - Causes skin irritation H318 - Causes serious eye damage : P264 - Wash hands and forearms thoroughly after handling P280 - Wear protective gloves/eye protection/face protection P302+P352 - If on skin: Wash with plenty of soap and water P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a poison center/doctor P321 - Specific treatment (see First aid measures on this label) P332+P313 - If skin irritation occurs: Get medical advice/attention P362 - Take off contaminated clothing and wash it before reuse 2.3. Other hazards 2.4. Unknown acute toxicity (GHS-US) SECTION 3: Composition/information on ingredients 3.1. Substance 3.2. Mixture 05/15/2015 EN (English US) Page 1

2 Name Product identifier % Classification (GHS-US) Sodium carbonate (CAS No) Skin Corr. 1A, H314 Eye Irrit. 2A, H319 Aquatic Acute 3, H402 Full text of H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Allow victim to breathe fresh air. Allow the victim to rest. : Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. Specific treatment (see First aid measures on this label). : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center or doctor/physician. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed Symptoms/injuries after skin contact : Causes skin irritation. Symptoms/injuries after eye contact : Causes serious eye damage Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream Special hazards arising from the substance or mixture 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. : Wash hands and forearms thoroughly after handling. 05/15/2015 EN (English US) 2/6

3 7.2. Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials 7.3. Specific end use(s) : Keep only in the original container in a cool, well ventilated place away from heat, hot surfaces, sparks, open flame and other ignition sources. No smoking. Keep container closed when not in use. : Strong bases. Strong acids. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Ad Bac 4227 Disinfectant ACGIH OSHA : Sources of ignition. Direct sunlight. ACGIH OSHA 8.2. Exposure controls Personal protective equipment : Avoid all unnecessary exposure. Hand protection Eye protection Skin and body protection Respiratory protection : Wear protective gloves/eye protection/face protection protective gloves. : Chemical goggles or safety glasses. : Wear suitable protective clothing. : Wear appropriate mask. : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Color Odor Odor threshold : Liquid : Yellow : lemon odor ph : Melting point Freezing point Boiling point : F Flash point : 200 F Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) Explosion limits Explosive properties Oxidizing properties Vapor pressure Relative density : 1.06 Relative vapor density at 20 C Solubility Log Pow Log Kow Auto-ignition temperature Decomposition temperature : Same as water : Soluble in water. Water: Solubility in water of component(s) of the mixture : : 22 g/100ml : : 103 g/100ml : 42 g/100ml : 66 g/100ml 05/15/2015 EN (English US) 3/6

4 Viscosity Viscosity, kinematic Viscosity, dynamic 9.2. SECTION 10: Stability and reactivity Reactivity Chemical stability Stable under normal conditions. Not established Possibility of hazardous reactions Not established Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids. Strong bases Hazardous decomposition products Fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 oral rat LD50 dermal rabbit ATE US (oral) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential Adverse human health effects and symptoms Symptoms/injuries after skin contact Symptoms/injuries after eye contact 2800 mg/kg (Rat; Experimental value) > 2000 mg/kg (Rabbit; Experimental value) mg/kg body weight : Causes skin irritation. ph: : Causes serious eye damage. ph: : Based on available data, the classification criteria are not met. : Causes skin irritation. : Causes serious eye damage. SECTION 12: Ecological information Toxicity LC50 fish 1 EC50 Daphnia 1 EC50 other aquatic organisms mg/l (96 h; Lepomis macrochirus) 424 mg/l (48 h; Daphnia magna) 14 mg/l (168 h; Plankton) 05/15/2015 EN (English US) 4/6

5 LC50 fish 2 EC50 Daphnia 2 TLM fish 1 TLM other aquatic organisms 1 Threshold limit algae mg/l (96 h; Gambusia affinis) 265 mg/l (48 h; Daphnia magna) 300 ppm (96 h; Lepomis macrochirus) 500 ppm (96 h; Daphnia magna) 242 mg/l (5 days; Algae) Persistence and degradability Ad Bac 4227 Disinfectant Persistence and degradability Persistence and degradability ThOD Not established. Biodegradability: not applicable. Low potential for adsorption in soil. (inorganic) Bioaccumulative potential Ad Bac 4227 Disinfectant Bioaccumulative potential Not established. Log Pow (Estimated value) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4) Mobility in soil Other adverse effects Effect on the global warming : No known ecological damage caused by this product. : Avoid release to the environment. SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Not regulated for transport Additional information : No supplementary information available. ADR Transport by sea Air transport SECTION 15: Regulatory information US Federal regulations Listed on the United States TSCA (Toxic Substances Control Act) inventory International regulations CANADA 05/15/2015 EN (English US) 5/6

6 EU-Regulations Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Not classified National regulations US State regulations SECTION 16: Revision date : 04/15/2015 : None. Full text of H-phrases: Aquatic Acute 3 Hazardous to the aquatic environment - Acute Hazard Category Eye Dam. 1 Serious eye damage/eye irritation Category Eye Irrit. 2A Serious eye damage/eye irritation Category 2A Skin Corr. 1A Skin corrosion/irritation Category 1A Skin Irrit. 2 Skin corrosion/irritation Category H314 Causes severe skin burns and eye damage H315 Causes skin irritation H318 Causes serious eye damage H319 Causes serious eye irritation H402 Harmful to aquatic life HMIS III Rating Health Flammability Physical Personal Protection : 3 Serious Hazard - Major injury likely unless prompt action is taken and medical treatment is given : 0 Minimal Hazard - Materials that will not burn : 0 Minimal Hazard - Materials that are normally stable, even under fire conditions, and will NOT react with water, polymerize, decompose, condense, or self-react. Non-Explosives. : B B - Safety glasses, Gloves SDS US (GHS HazCom 2012) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 05/15/2015 EN (English US) 6/6