SAFETY DATA SHEET HCS 2012 (29 CFR ) PVDC - DIOFAN A 063

Transcription

1 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION 1.1. Identification of the substance or mixture Product name : Product grade(s) : This product meets the requirements of 21 CFR For FDA Use Only 1.2. Use of the Substance/Mixture Recommended use : - Packaging - Pharmaceuticals - Adhesives and/or sealants 1.3. Company/Undertaking Identification Address : SOLVAY SPECIALTY POLYMERS USA, LLC 4500 McGINNIS FERRY ROAD ALPHARETTA GA USA 1.4. Emergency and contact telephone numbers Emergency telephone number : 1 (800) CHEMTREC (USA & Canada) (MEX. REPUBLIC) Contact telephone number (product information): : US: (Product information) US: (Product information) SECTION 2. HAZARDS IDENTIFICATION Although OSHA has not adopted the environmental portion of the GHS regulations, this document may include information on environmental classification/labeling Classification of the substance or mixture Not classified according to Label elements No labelling Page 1 of 10

2 2.3. Other hazards which do not result in classification In case of decomposition, releases hydrochloric acid. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substances Not applicable, this product is a mixture 3.2 Mixtures Chemical Name Identification number Concentration [%] Polymer based on: 1,1-dichloroethylene / methyl acrylate /nitrile acrylate / hydroxyethyl acrylate CAS-No.: - ca. 50 % The specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret. SECTION 4. FIRST AID MEASURES 4.1. Inhalation - none 4.2. Eye contact - Flush eyes with running water for several minutes, while keeping the eyelids wide open. - If eye irritation persists, consult a specialist Skin contact - Wash off with soap and water. - Wash contaminated clothing before re-use. - If symptoms persist, call a physician Ingestion - Consult a physician. If victim is conscious: - If swallowed, rinse mouth with water (only if the person is conscious). - Do NOT induce vomiting. If victim is unconscious but breathing: - not applicable 4.5. Notes to physician Exposure to decomposition products : - Indication of immediate medical attention and special treatment needed, if necessary Page 2 of 10

3 SECTION 5. FIREFIGHTING MEASURES 5.1. Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment Extinguishing media which shall not be used for safety reasons None Special exposure hazards in a fire The product is not flammable. Product resists ignition and does not promote flame spread. Hazardous decomposition products formed under fire conditions. Gaseous hydrogen chloride (HCl) Hazardous decomposition products hydrochloric acid Carbon monoxide Particulates of carbon 5.5. Special protective equipment for firefighters In the event of fire, wear self-contained breathing apparatus. Wear chemical resistant oversuit Clean contaminated surface thoroughly. Fire fighters must wear fire resistant personnel protective equipment Other information After the fire, proceed rapidly with cleaning of surfaces exposed to the fumes in order to limit equipment damage. Keep product and empty container away from heat and sources of ignition. SECTION 6. ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Advice for non-emergency personnel - none Advice for emergency responders - Use personal protective equipment Environmental precautions - Should not be released into the environment. - The product should not be allowed to enter drains, water courses or the soil. - In case of accidental release or spill, immediately notify the appropriate authorities if required by Federal, State/Provincial and local laws and regulations. Page 3 of 10

4 6.3. Methods and materials for containment and cleaning up - If possible, dam up the resulting liquid phase with sand or earth. - Treat recovered material as described in the section "Disposal considerations". - Flush with plenty of water Reference to other sections - Refer to protective measures listed in sections 7 and 8. SECTION 7. HANDLING AND STORAGE 7.1. Handling - To avoid thermal decomposition, do not overheat. - Use only equipment and materials which are compatible with the product Storage - none 7.3. Packaging material - Stainless steel - Steel coated. - Approved grades of HDPE. - Polypropylene - PVC 7.4. Other information - Do not freeze. - Provide tight electrical equipment well protected against corrosion. - For personal protection see section 8. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Exposure Limit Values Polymer based on: 1,1-dichloroethylene / methyl acrylate /nitrile acrylate / hydroxyethyl acrylate - US. ACGIH Threshold Limit Values Remarks: none established 8.2. Engineering controls - Ensure adequate ventilation. - Provide local ventilation appropriate to the product decomposition risk (see section 10) Personal protective equipment Respiratory protection - Use only respiratory protection that conforms to international/ national standards. - Use NIOSH approved respiratory protection. - Respirator with combination filter for vapour/particulate (EN 141). Page 4 of 10

5 - When workers are facing concentrations above the exposure limit they must use appropriate certified respirators Hand protection - Wear suitable gloves. - Suitable material: PVC, Neoprene, Natural Rubber Eye protection - If splashes are likely to occur, wear: Face-shield Skin and body protection - Wear suitable protective clothing Hygiene measures - Ensure that eyewash stations and safety showers are close to the workstation location. - Handle in accordance with good industrial hygiene and safety practice. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1. General Information Appearance Colour Odour : aqueous dispersion : white : characteristic 9.2. Important health safety and environmental information ph : 1-4 Boiling point/boiling range : ca. 100 C ( 212 F ) Flash point Flammability Explosive properties Oxidizing properties : Remarks: not applicable : Lower explosion limit: Remarks: not applicable Remarks: The product is not flammable. : Explosion danger: Remarks: Not explosive : Remarks: Non oxidizer Relative density / Density : Bulk density Solubility(ies) Partition coefficient: : Remarks: not applicable : Remarks: No data available : Remarks: not applicable Page 5 of 10

6 n-octanol/water Viscosity : < 40 mpa.s 9.3. Other data Freezing point: : ca. 0 C ( 32 F ) Decomposition temperature Remarks : > 100 C ( 212 F ) : No data available SECTION 10. STABILITY AND REACTIVITY Stability - Corrosive in contact with metals Conditions to avoid - To avoid thermal decomposition, do not overheat Materials to avoid - Metallic ions (cations) Hazardous decomposition products - hydrochloric acid, Carbon monoxide, Particulates of carbon SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity Skin corrosion/irritation - rabbit, slight irritation Serious eye damage/eye irritation - rabbit, Mild eye irritation Sensitisation Page 6 of 10

7 11.5. Mutagenicity Carcinogenicity Toxicity for reproduction Repeated dose toxicity SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity effects Acute toxicity - Remarks: No data available Mobility - Remarks: No data available Persistence and degradability Abiotic degradation - Remarks: No data available Biodegradation - Remarks: No data available Bioaccumulative potential - Remarks: No data available Other adverse effects Remarks - Product is non-degradable. SECTION 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products - Refer to manufacturer/supplier for information on recovery/recycling. - Must be incinerated in a suitable incineration plant holding a permit delivered by the competent authorities. - In accordance with local and national regulations. Page 7 of 10

8 13.2. Packaging treatment - Must be incinerated in a suitable incineration plant holding a permit delivered by the competent authorities. SECTION 14. TRANSPORT INFORMATION - not regulated SECTION 15. REGULATORY INFORMATION Inventory Information USA. Toxic Substances Control Act (TSCA) Australia. Inventory of Chemical Substances (AICS) Canada. Domestic Substances List (DSL) Korea. Existing Chemicals Inventory (KECI(KR)) EU list of existing chemical substances (EINECS) Japan. Inventory of Existing & New Chemical Substances (ENCS) Inventory of Existing Chemical Substances (China)(IECS) Philippine. Inventory of Chemicals and Chemical Substances (PICCS) New Zealand. Inventory of Chemicals (NZIOC) : - In compliance with inventory Other regulations US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III Section 302 Extremely Hazardous Substance (40 CFR 355, Appendix A) Components CAS-No. Acrylonitrile Reportable quantity: 100 lbs Threshold Planning Quantity:: lbs US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III Section 313 Toxic Chemicals (40 CFR ) - Supplier Notification Required - not regulated. Page 8 of 10

9 US. EPA CERCLA Hazardous Substances (40 CFR 302) This product is reportable under 40 CFR Part because it contains the following substance(s): : Components CAS-No. Acrylonitrile Reportable quantity: 100 lbs US. California Safe Drinking Water & Toxic Enforcement Act (Proposition 65) This product contains a chemical known in the State of California to cause cancer and/or to cause birth defects or other reproductive harm. : Components CAS-No. Concentration Acrylonitrile <= 6.0 PPM SECTION 16. OTHER INFORMATION Further information - Update This data sheet contains changes from the previous version in section(s): LOGO - Distribute new edition to clients - Date prepared 07/16/2014 Material Safety Data Sheets contain country specific regulatory information; therefore, the MSDS's provided are for use only by customers of the company mentioned in section 1 in North America. If you are located in a country other than Canada, Mexico or the United States, please contact the Solvay Group company in your country for MSDS information applicable to your location. The previous information is based upon our current knowledge and experience of our product and is not exhaustive. It applies to the product as defined by the specifications. In case of combinations or mixtures, one must confirm that no new hazards are likely to exist. In any case, the user is not exempt from observing all legal, administrative and regulatory procedures relating to the product, personal hygiene, and integrity of the work environment. (Unless noted to the contrary, the technical information applies only to pure product). To our actual knowledge, the information contained herein is accurate as of the date of this document. However, neither the company mentioned in section 1 nor any of its affiliates makes any warranty, express or implied, including merchantability or fitness for use, or accepts any liability in connection with this information or its use. This information is for use by technically skilled persons at their own discretion and risk and does not relate to the use of this product in combination with any other substance or any other process. This is not a license under any patent or other proprietary right. The user alone must finally determine suitability of any information or material for any contemplated use in compliance with applicable law, the manner of use and whether any patents are infringed. This information gives typical properties only and is not to be used for specification purposes. The company mentioned in section 1 reserves the right to make additions, deletions or modifications to the information at any time without prior notification. Page 9 of 10

10 Trademarks and/or other products of the company mentioned in section 1 referenced herein are either trademarks or registered trademarks of the company mentioned in section 1 or its affiliates, unless otherwise indicated. Copyright 2014, Company mentioned in Section 1. All Rights Reserved. Page 10 of 10