Issue Date: 14-Jul-2014 Revision Date: 18-Jul-2014 Version 1 1. IDENTIFICATION 2. HAZARDS IDENTIFICATION

Transcription

1 Safety Data Sheet Issue Date: 14-Jul-2014 Version 1 Product Identifier Product Name Pecan Kicker IDENTIFICATION Other means of identification SDS # CAG-050 Recommended use of the chemical and restrictions on use Recommended Use Plant Nutrients. Details of the supplier of the safety data sheet Supplier Address Triangle Chemical P.O. Box 4528 Macon, GA Cardinal Chemical P.O. Box 368 Kinston, NC Emergency Telephone Number Company Phone Number Triangle Chemical: (478) Cardinal Chemical: (252) Emergency Telephone (24 hr) Chemtrec (North America) (International) 2. HAZARDS IDENTIFICATION Appearance Light brown liquid Physical State Liquid Odor Odorless Classification Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2 Hazards Not Otherwise Classified (HNOC) May be harmful if swallowed Signal Word Warning Hazard Statements Causes skin irritation Causes serious eye irritation Page 1 / 7

2 Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Precautionary Statements - Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF ON SKIN: Wash with plenty of soap and water If skin irritation occurs: Get medical advice/attention Take off contaminated clothing and wash it before reuse 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% Potassium Carbonate **If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.** First Aid Measures 4. FIRST-AID MEASURES Eye Contact Skin Contact Inhalation Ingestion IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/ attention. Take off contaminated clothing and wash it before reuse. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a poison center or doctor/physician. IF SWALLOWED: rinse mouth. Do NOT induce vomiting. If conscious, give water or milk. Immediately call a poison center or doctor/physician. Most important symptoms and effects Symptoms Causes skin irritation. Causes serious eye irritation. Ingestion may cause irritation of the gastrointestinal tract, cramps, vomiting, convulsions, or diarrhea. May cause irritation of the respiratory tract. Chronic ingestion may cause damage to heart, liver, and blood-forming tissues. Ingestion of large quantities may cause headache, mental impairment, dizziness, and may be fatal. Existing skin and lung disorders may be aggravated by overexposure. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media. Specific Hazards Arising from the Chemical Product is not flammable. Hazardous Combustion Products Nitrogen oxides (NOx). Metal oxide/oxides. Oxides of sulfur. Page 2 / 7

3 Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Environmental Precautions Use personal protective equipment as required. Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information. See Section 13: DISPOSAL CONSIDERATIONS. Methods and material for containment and cleaning up Methods for Containment Methods for Clean-Up Prevent further leakage or spillage if safe to do so. Contained materials may be salvaged for use if uncontaminated. For small spills, absorb with sand, clay, or other inert absorbent. For large spills, dike far ahead of spill for later disposal. Do not release into sewers or waterways. Dispose of in accordance with federal, state and local regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Wear protective gloves/protective clothing and eye/face protection. Wash face, hands, and any exposed skin thoroughly after handling. Use in accordance with product label instructions. Conditions for safe storage, including any incompatibilities Storage Conditions Incompatible Materials Keep container tightly closed and store in a cool, dry and well-ventilated place. Keep in properly labeled containers. Store in compatible containers. Keep away from children, pets, domestic animals, and wildlife. Strong bases. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies Appropriate engineering controls Engineering Controls Ensure adequate ventilation, especially in confined areas. Eyewash stations. Showers. Page 3 / 7

4 Individual protection measures, such as personal protective equipment Eye/Face Protection Skin and Body Protection Respiratory Protection Chemical safety goggles/faceshield. Chemical resistant protective gloves. Suitable protective clothing. Respiratory protection may be needed if airborne mists are created. Seek professional advice prior to respirator selection and use. Follow OSHA respirator regulations (29 CFR ) and, if necessary, wear a NIOSH-approved respirator. Select respirator based on its suitability to provide adequate worker protection for given working conditions, level of airborne contamination, and presence of oxygen. Warning: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres. If respirators are required, OSHA requires a written respiratory protection program that includes at least: medical certification, training, fit-testing, periodic environmental monitoring, maintenance, inspection, cleaning, and convenient, sanitary storage areas. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Information on basic physical and chemical properties 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Liquid Appearance Light brown liquid Odor Odorless Color light brown Odor Threshold Property Values Remarks Method ph Melting Point/Freezing Point Below 0 C / Below 32 F freezing point Boiling Point/Boiling Range 92 C / 198 F Flash Point Evaporation Rate Flammability (Solid, Gas) Liquid-Not Applicable Upper Flammability Limits Lower Flammability Limit Vapor Pressure Vapor Density Specific Gravity (Water = 1) Water Solubility Freely Soluble Solubility in other solvents Partition Coefficient Auto-ignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity Explosive Properties Oxidizing Properties Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization 10. STABILITY AND REACTIVITY Hazardous polymerization does not occur. Page 4 / 7

5 Conditions to Avoid Contact with incompatible materials. Avoid evaporating to dryness. Keep out of reach of children. Incompatible Materials Strong bases. Hazardous Decomposition Products Nitrogen oxides (NOx). Metal oxides. Sulfur oxides. Information on likely routes of exposure Product Information 11. TOXICOLOGICAL INFORMATION Eye Contact Skin Contact Inhalation Ingestion Causes serious eye irritation. Causes skin irritation. Avoid breathing mists. May be harmful if swallowed. Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Potassium Carbonate = 1870 mg/kg ( Rat ) Urea = 8471 mg/kg ( Rat ) - - Information on physical, chemical and toxicological effects Symptoms Please see section 4 of this SDS for symptoms. Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity This product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP. Numerical measures of toxicity 12. ECOLOGICAL INFORMATION Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Component Information Chemical Name Algae/aquatic plants Fish Toxicity to microorganisms Urea : 96 h Poecilia reticulata mg/l LC50 Crustacea 10000: 24 h Daphnia magna Straus mg/l EC : 48 h Daphnia magna mg/l EC50 Static Page 5 / 7

6 Persistence/Degradability. Bioaccumulation. Mobility Other Adverse Effects Waste Treatment Methods 13. DISPOSAL CONSIDERATIONS Disposal of Wastes Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. Disposal should be in accordance with applicable regional, national and local laws and regulations. 14. TRANSPORT INFORMATION Note DOT IATA IMDG Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. Not regulated Not regulated Not regulated 15. REGULATORY INFORMATION International Inventories US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR and 40 CFR ) US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations This product does not contain any substances regulated under applicable state right-to-know regulations Page 6 / 7

7 16. OTHER INFORMATION NFPA HMIS Health Hazards Health Hazards Flammability Flammability Instability Physical Hazards Special Hazards Personal Protection Issue Date: Revision Date: Revision Note: 14-Jul Jul-2014 New format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 7 / 7