Phosphorescent Pigment Green

Transcription

1 Revised edition: Version: 7 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Phosphorescent Pigment Green Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Mapping of thermoplastics (industrial use) Use of coatings, paints and inks (industrial, professional and consumer use). Calendering / extrusion, industrial spraying, Masterbatch additive (industrial use) Uses advised against: Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr , Aichstetten, Germany Tel./Fax.: Tel , Fax Internet: info@kremer-pigmente.de Importer: -- Emergency No. Emergency No.: (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) Classification according to Directive No. 67/548/EC or No. 1999/45/EC This product does not require classification and labelling as hazardous according to CLP/GHS. The material is not subject to classification according to EC lists Safety Phrases: Possible Environmental Effects: Label Elements Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) Hazard designation: Signal word: See Section 12. This product does not require classification and labelling as hazardous according to CLP/GHS. Hazard designation: 2

2 Safety designation: Page Hazardous components for labelling: Other Hazards Composition/Information on Ingredients Substance Mixture Chemical Characterization: Information on Components / Hazardous Ingredients: Zinc sulfide (ZnS), Copper chloride-doped; REACH Reg. No % CAS-Nr: EINECS-Nr: EC-Nr: Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Remove contaminated clothes immediately. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Give artificial respiration in case breathing is not regular or if it has stopped. In case of complaints consult a physician. Wash off with plenty of water and soap. Consult a physician if irritation persists. Do not use solvents or thinners. Remove contact lens. Rinse open eyes with plenty of water (10-15 min). Consult physician After ingestion: Most important Symptoms and Effects, both Acute and Delayed Immediately get medical help. Never give anything by mouth to an unconscious person. Do not induce vomiting. Symptoms: No further information available Effects: No further information available. Indication of any Immediate Medical Attention and special Treatment needed Treatment: Never give anything by mouth to an unconscious person. 3

3 Page Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: Unsuitable extinguishing media: Carbon dioxide (CO2), extinguishing powder. Use extinguishing media for surrounding fire. Fight larger fire with water jet or alcohol resistant foam. Water with full jet Special Hazards arising from the Substance or Mixture Special hazards: In case of fire: formation of carbon oxides and smoke Advice for Firefighters Protective equipment: Further information: Wear self-contained respiratory protective device. Contaminated extinguishing water and debris should be disposed of according to local regulations. Cool exposed containers with water spray Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Personal precautions: Do not inhale dust. Ensure adequate ventilation Environmental Precautions Environmental precautions: Prevent contamination of soil, drains and surface waters Methods and Material for Containment and Cleaning Up Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Hygienic measures: Take up mechanically and collect in suitable containers for disposal. Avoid dust formation. Protective clothing, see Section 8. See Section 13 for information on disposal. Avoid contact with eyes, skin and clothing. Avoid formation of dust. Do not eat or drink during work. Do not smoke. Keep away from foodstuffs and drinks. Do not eat, drink or smoke 4

4 7. 2. Conditions for Safe Storage, including any Incompatibilities Page 4 during work. Wash hands before breaks and at the end of work. Storage conditions: Requirements for storage areas and containers: Information on fire and explosion protection: Store in tightly sealed containers in a cool and well ventilated location. Do not store together with food stuff and animal feed. Store the product in the original container. Keep away from sources of ignition - do not smoke Storage class (VCI): Further Information: Specific End Use(s) Storage temperature: 5-35 C Further information: No further information available. Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): none known Parameters to be controlled: Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): 5 mg/m3 (worker, inhalation, long-term exposition - systemic effects) 0.83 mg/kg bw/day (consumer, swallowing, long-term exposition - systemic effects) 83 mg/kg bw/d (Consumer, skin contakt, long-term exposition - systemic effects) 2.5 mg/kg (consumer, inhalation, long-term exposition - systemic effects) Fresh water: 20.6 µg/l Fresh water sediment: mg/kg Seawater: 6.1 µg/l Seawater sediment: 56.5 mg/kg Soil: 35.6 mg/kg Sewage treatment system (STP): 52 µg/l Additional Information: Exposure Controls Technical protective measures: Adequate ventilation. 5

5 Personal Protection Page 5 General protective measures: Respiratory protection: Hand protection: Protective glove material: Eye protection: Body protection: The usual precautionary measures are to be adhered to when handling chemicals. Do not inhale dust. Do not eat, drink or smoke while working. Wash hands before breaks and at the end of work. Dust mask recommended when very dusty: with particle filter P2. Protective gloves Polyvinyl chloride (> 480 min, 0.35 mm) Safety glasses with protective shields (EN 166). Protective clothing. Safety shoes (EN-ISO 13287, EN 20347) Environmental precautions: Physical and Chemical Properties Information on Basic Physical and Chemical Properties Form: powder Color: yellowish-green Odor: odorless Odor threshold: ph-value: Melting temperature: > C Boiling temperature: Flash point: not flammable Evaporation rate: Flammability (solid, gas): not flammable Upper explosion limit: not determined Lower explosion limit: not determined 6

6 Vapor pressure: Page 6 Vapor density: Density: Solubility in water: Coefficient of variation (n- Octanol/Water): 1.78 g/cm3 (20 C) 1002.e-3 g/l (zinc compound) not determined Auto-ignition temperature: > 400 C Decomposition temperature: Viscosity, dynamic: Explosive properties: Oxidizing properties: Bulk density: Further Information Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: Particle size: Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: No data available. Product does not present an explosion hazard. not determined No further information. Stable if used according to specifications. Stable if used according to specifications. Reacts with acids: development of hydrogen sulfide. Thermal decomposition: 7

7 Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Avoid heat. Page 7 Keep away from strong alkalies, acids and propellants. Thermal decomposition may evolve zinc oxide, sulphur dioxide. Irritating fumes/vapors. Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: Zinc Sulfid (ZnS), Copper chloride-doped ( ): > 2000 mg/kg (rat) > 2000 mg/kg (rat) 5.41 mg/m3 (rat) Primary effects Irritant effect on skin: Irritant effect on eyes: Inhalation: Ingestion: Sensitization: Mutagenicity: Reproductive toxicity: Carcinogenicity: Teratogenicity: Specific target organ toxicity (STOT): Non irritating Non-irritating to eyes No information available No sensitizing effects known. Not mutagenic. LOAEL: 50 mg/kg bw/day (rat, oral, development toxicity) NOAEL: 20 mg/kg bw/day (rat, oral, fertility) No relevant data found. Repeated exposure: Subchronic toxicity (oral): NOAEL: 13.3 mg/kg; Subacute toxicity (inhalative) NOAEC: 2.7 mg/m3 (rat) Additional toxicological information: 12. Ecological Information 8

8 Aquatic Toxicity No toxicity expected. Page Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Mobility Results of PBT- und vpvp Assessment Other Adverse Effects Water hazard class: Behaviour in sewage systems: Further ecological effects: AOX Value: Disposal Considerations Waste Treatment Methods Product: European Waste Code (EWC): Uncleaned packaging: Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name ADR/RID: Inorganic product, not very soluble in water. Not applicable. No ecological data available. Dispose of according to official national and local regulations Solid salts and solutions other than those mentioned in and Uncontaminated packaging may be recycled. Packaging may be disposed of in the same manner as the product. No hazardous goods according to ADR (land transportation). IMDG/IATA: No hazardous goods according to IMDG. 9

9 Transport Hazard Classes Page 9 ADR Class: Hazard no.: Classification code: Tunnel restriction code: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: Hazard no.: Packaging Group ADR/RID: IMDG: IATA: Environmental Hazards Not classified as environmentally hazardous. Special Precautions for User none known Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Not classified as a dangerous good under transport regulations. Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: Local regulations on chemical accidents: 2, hazardous for water (German Regulation) Seveso III Directive: under Directive 2012/18/EC. Employment restrictions: Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information Not applicable. A Chemical Safety Assessment has not been carried out for this product. Regulation (EC) 1005/ Substances that Deplete next the page: Ozone 10

10 16. Other Information Page 10 Layer: not regulated / Regulation (EC) 649/2012 concerning the export and import of dangerous chemicals: Not applicable This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.