1. Substance/preparation and manufacturer/supplier identification. Dispex Ultra FA 4483 (old Hydropalat 7003)

Transcription

1 Safety data sheet Page: 1/9 1. Substance/preparation and manufacturer/supplier identification Dispex Ultra FA 4483 (old Hydropalat 7003) Use: wetting agent Manufacturer/supplier: PT BASF Indonesia Plaza GRI, 10th & 11th Floor Jl. H.R. Rasuna Said Blok X-2 No.1 Jakarta Selatan 12950, P.O. Box 2431 Gbr., Jakarta 10024, INDONESIA Telephone: / Telefax number: / Emergency information: International emergency number: Telephone: Hazard identification Classification of the substance and mixture: Skin corrosion/irritation: Cat. 2 Serious eye damage/eye irritation: Cat. 1 Hazardous to the aquatic environment - acute: Cat. 3 Label elements and precautionary statement: Pictogram: Signal Word:

2 Page: 2/9 Danger Hazard Statement: Causes serious eye damage. Causes skin irritation. Harmful to aquatic life. Precautionary Statements (Prevention): Wear protective gloves and eye/face protection. Avoid release to the environment. Wash with plenty of water and soap thoroughly after handling. Precautionary Statements (Response): IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (on hair): Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Precautionary Statements (Disposal): Dispose of contents/container to hazardous or special waste collection point. Other hazards which do not result in classification: No specific dangers known, if the regulations/notes for storage and handling are considered. 3. Composition/information on ingredients Chemical nature Aqueous solution based on: phosphoric ester, fatty alcohol Hazardous ingredients Poly(oxy-1,2-ethanediyl),.alpha.-hydro-.omega.-hydroxy-, mono-c12-14-alkyl ethers, phosphates Content (W/W): >= 25 % - < 50 % Skin Corr./Irrit.: Cat. 2 CAS Number: Eye Dam./Irrit.: Cat. 1 Aquatic Acute: Cat First-Aid Measures General advice: Immediately remove contaminated clothing. If inhaled: If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical attention. On skin contact: Wash thoroughly with soap and water. On contact with eyes: Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist. On ingestion: Rinse mouth immediately and then drink plenty of water, seek medical attention.

3 Page: 3/9 Note to physician: Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further important symptoms and effects are so far not known. Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. 5. Fire-Fighting Measures Suitable extinguishing media: water spray, dry powder, foam Specific hazards: harmful vapours Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire. Special protective equipment: Wear a self-contained breathing apparatus. Further information: The degree of risk is governed by the burning substance and the fire conditions. Contaminated extinguishing water must be disposed of in accordance with official regulations. 6. Accidental Release Measures Personal precautions: Use personal protective clothing. Environmental precautions: Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater. Methods for cleaning up or taking up: For small amounts: Pick up with suitable appliance and dispose of. For large amounts: Pick up with suitable appliance and dispose of. 7. Handling and Storage Handling No special measures necessary provided product is used correctly. Protection against fire and explosion: No special precautions necessary. Storage

4 Page: 4/9 Suitable materials for containers: Corrosion-resistant containers and collecting zones., High density polyethylene (HDPE) Unsuitable materials for containers: Do not use containers susceptible to corrosion. Further information on storage conditions: Keep container tightly closed and dry; store in a cool place. Protect from temperatures below: 5 C Protect from temperatures above: 35 C 8. Exposure controls and personal protection Components with occupational exposure limits No occupational exposure limits known. Personal protective equipment Respiratory protection: Respiratory protection not required. Hand protection: Chemical resistant protective gloves Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): nitrile rubber (NBR) mm coating thickness Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing. Manufacturer's directions for use should be observed because of great diversity of types. Eye protection: Tightly fitting safety goggles (cage goggles) (e.g. EN 166) and face shield. Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN in case of splashes or EN ISO in case of dust). General safety and hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is required additionally to the stated personal protection equipment. 9. Physical and Chemical Properties Form: Colour: Odour: Odour threshold: liquid colourless to yellow characteristic Not determined due to potential health hazard by inhalation.

5 Page: 5/9 ph value: (water, 20 C) (DIN EN 1262) Freezing point: Boiling point: > 100 C contains water Flash point: > 100 C Aqueous preparation Evaporation rate: Flammability (solid/gas): not flammable Lower explosion limit: For liquids not relevant for classification and labelling., The lower explosion point may be 5-15 C below the flash point. Upper explosion limit: For liquids not relevant for classification and labelling. Ignition temperature: Based on the water content the product does not ignite. Thermal decomposition: Self ignition: not self-igniting Test type: Spontaneous selfignition at room-temperature. Explosion hazard: not explosive Fire promoting properties: not fire-propagating Vapour pressure: Density: approx g/cm3 (20 C) Relative density: approx (20 C) Relative vapour density (air): (DIN 51757) Solubility in water: soluble (20 C) Hygroscopy: Non-hygroscopic Partitioning coefficient n-octanol/water (log Pow): not applicable for mixtures Surface tension: Viscosity, dynamic: 500-3,000 mpa*s (25.0 C) (DIN EN ISO 2555)

6 Page: 6/9 10. Stability and Reactivity Conditions to avoid: See MSDS section 7 - Handling and storage. Thermal decomposition: Substances to avoid: strong bases, strong oxidizing agents Hazardous reactions: No hazardous reactions when stored and handled according to instructions. Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. 11. Toxicological Information Acute toxicity Assessment of acute toxicity: Virtually nontoxic after a single ingestion. Experimental/calculated data: LD50 rat (oral): > 2,000 mg/kg LC50 rat (by inhalation): 4 h LD50 rat (dermal): Irritation Experimental/calculated data: Skin corrosion/irritation rabbit: Irritant. Serious eye damage/irritation rabbit: irreversible damage Respiratory/Skin sensitization Experimental/calculated data:

7 Page: 7/9 Germ cell mutagenicity Assessment of mutagenicity: No data available concerning mutagenic effects. Carcinogenicity Assessment of carcinogenicity: Reproductive toxicity Assessment of reproduction toxicity: Developmental toxicity Assessment of teratogenicity: Specific target organ toxicity (single exposure): Remarks: Repeated dose toxicity and Specific target organ toxicity (repeated exposure) Assessment of repeated dose toxicity: Aspiration hazard No aspiration hazard expected. 12. Ecological Information Ecotoxicity Toxicity to fish: LC50 (48 h) mg/l, Fish Aquatic invertebrates: LC50 (24 h) mg/l, daphnia Aquatic plants: EC50 (72 h), algae Microorganisms/Effect on activated sludge:

8 Page: 8/9 EC0 (0.5 h) > 100 mg/l, bacteria (OECD Guideline 209) Chronic toxicity to fish: Chronic toxicity to aquatic invertebrates: Assessment of terrestrial toxicity: No data available concerning terrestrial toxicity. Mobility Assessment transport between environmental compartments: Persistence and degradability Assessment biodegradation and elimination (H2O): Readily biodegradable (according to OECD criteria). The product has not been tested. The statement has been derived from the properties of the Bioaccumulation potential Assessment bioaccumulation potential: The product has not been tested. Additional information Add. remarks environm. fate & pathway: Treatment in biological waste water treatment plants has to be performed according to local and administrative regulations. 13. Disposal Considerations Must be disposed of or incinerated in accordance with local regulations. Contaminated packaging: Uncontaminated packaging can be re-used. Packs that cannot be cleaned should be disposed of in the same manner as the contents. 14. Transport Information Domestic transport: Not classified as a dangerous good under transport regulations Sea transport IMDG

9 Page: 9/9 Not classified as a dangerous good under transport regulations Air transport IATA/ICAO Not classified as a dangerous good under transport regulations 15. Regulatory Information Regulations of the European union (Labelling) EEC Directives: Hazard symbol(s) Xi R-phrase(s) R38 R41 S-phrase(s) S37 S39 S26 Irritant. Irritating to skin. Risk of serious damage to eyes. Wear suitable gloves. Wear eye/face protection. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Hazard determining component(s) for labelling: Poly(oxy-1,2-ethanediyl),.alpha.-hydro-.omega.- hydroxy-, mono-c12-14-alkyl ethers, phosphates Other regulations 16. Other Information Vertical lines in the left hand margin indicate an amendment from the previous version. The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. The data do not describe the product's properties (product specification). Neither should any agreed property nor the suitability of the product for any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.