No. 45 Corrosion Inhibitor

Transcription

1 Page 1 of 7 MATERIAL SAFETY DATA SHEET No. 45 Corrosion Inhibitor Section 01 - Chemical And Product And Company Information Product Identifier... No. 45 Corrosion Inhibitor Product Use... Supplier Name... ClearTech Industries Inc Quebec Avenue Saskatoon, SK. Canada S7K 1V7 Used for protecting steam condensate lines in food and industrial plants against rust, pitting and corrosion. Prepared By ClearTech Industries Inc. Technical Department Phone: 1 (800) Hour Emergency Phone... 1 (800) Section 02 - Composition / Information on Ingredients Hazardous Ingredients Cyclohexylamine Morpholine CAS Number Cyclohexylamine Morpholine 7-13% 3-7% Synonym (s)......

2 Page 2 of 7 Section 03 - Hazard Identification Inhalation Mist can cause irritation of respiratory tract and inflammation of lungs. Skin Contact / Absorption.... Causes irritation. May cause burns. Morpholine may be absorbed through intact skin causing liver, kidney, CNS depression and blood system damage. Eye Contact Causes severe irritation to the mucous membranes of the eyes. May cause ulceration of the eye. Ingestion..... Burning in mouth and esophagus; nausea, vomiting, abdominal pain and diarrhea, edema (swelling) of larynx and subsequent suffocation. Perforation of gastrointestinal tract can occur. May cause liver, kidney, central nervous system depression and blood system damage. Exposure Limits... ACGIH/TLV: 10 ppm (Cyclohexylamine) PEL-TWA: 10 ppm (Cyclohexylamine) TLV-TWA: 10 ppm (Cyclohexylamine) ACGIH/TLV (skin): 20 ppm (Morpholine) TLV-TWA (skin): 20 ppm (Morpholine) PEL-TWA (skin): 20 ppm (Morpholine) PEL-STEL (skin): 20 ppm (Morpholine) Section 04 - First Aid Measures Inhalation Remove victim to fresh air. Give artificial respiration only if breathing has stopped. If breathing is difficult, give oxygen. Seek medical attention if difficulties persist. Skin Contact / Absorption... Remove contaminated clothing. Wash affected area with soap and water. Seek medical attention if irritation occurs or persists. Eye Contact Flush immediately with water for at least 20 minutes. Forcibly hold eyelids apart to ensure complete irrigation of eye tissue. Seek medical attention if symptoms persist. Ingestion..... Do not induce vomiting. Drink large quantities of water or milk to dilute the chemical. Seek immediate medical attention. Additional Information......

3 Page 3 of 7 Conditions of Flammability... Flammable liquid Section 05 - Fire Fighting Means of Extinction Carbon dioxide and dry chemical extinguishers. Use water spray to disperse vapours. Flash Point o C Auto-ignition Temperature.. Upper Flammable Limit... Lower Flammable Limit Hazardous Combustible Products... Nitrogen oxides Special Fire Fighting Procedures... Wear NIOSH-approved self-contained breathing apparatus and protective clothing. Explosion Hazards... Vapours are heavier than air and may "travel" to source of ignition causing fire and explosion. Section 06 - Accidental Release Measures Leak / Spill Wear appropriate personal protective equipment if required. Ventilate area. Stop or reduce leak if safe to do so. Prevent material from entering sewers or water ways. Flush with water to remove any residue. Neutralize minor spills with dilute acid before washing away with plenty of water. Deactivating Materials Neutralize with dilute acid. Section 07 - Handling and Storage Handling Procedures Use proper equipment for lifting and transporting all containers. Use sensible industrial hygiene and housekeeping practices. Wash thoroughly after handling. Avoid all situations that could lead to harmful exposure. Storage Requirements Store in cool area above freezing point away from incompatible materials.

4 Page 4 of 7 Protective Equipment Eyes..... Respiratory... Section 08 - Personal Protection and Exposure Controls Chemical goggles, full-face shield, or a full-face respirator is to be worn at all times when product is handled. Contact lenses should not be worn; they may contribute to severe eye injury. Approved respiratory protection should be used if chance of mist will be formed. Gloves... Clothing..... Footwear... Impervious gloves of chemically resistant material should be worn at all times. Wash contaminated clothing and dry thoroughly before reuse. Body suits, aprons, and/or coveralls of chemical resistant material should be worn at all times. Wash contaminated clothing and dry thoroughly before reuse. Impervious boots of chemically resistant material should be worn. Engineering Controls Ventilation Requirements... Mechanical ventilation (dilution or local exhaust), process or personnel enclosure and control of process conditions should be provided. Supply sufficient replacement air to make up for air removed by exhaust systems. Other... Keep an eye wash fountain and safety shower available and in close proximity to work area. Section 09 - Physical and Chemical Properties Physical State Liquid Odor and Appearance..... Pale liquid with amine type odour. Odor Threshold Specific Gravity (Water=1) Vapor Pressure (mm Hg, 20 o C)... Vapor Density (Air=1)..... Evaporation Rate Boiling Point

5 Page 5 of 7 Freeze/Melting Point ph Strong base Water/Oil Distribution Coefficient... Bulk Density % Volatiles by Volume..... Solubility in Water Molecular Formula Molecular Weight Completely soluble Section 10 - Stability and Reactivity Stability Stable under normal conditions. Incompatibility Oxidizing materials, acids, copper, copper alloys, lead Hazardous Products of Decomposition... Nitrogen oxides Polymerization Section 11 - Toxicological Information Irritancy Severe irritant to the eyes. Sensitization Chronic/Acute Effects No other adverse effects expected other than those mentioned above in section 3. Synergistic Materials Animal Toxicity Data LD 50(oral, rat): 156 mg/kg (Cyclohexylamine) LD 50(dermal, rat): 320 mg/kg (Cyclohexylamine) LC 50(mouse): <493 ppm LD 50(oral, rat): 1050 mg/kg (Morpholine) LD 50(inhalation, rat): 4000 ppm (Morpholine) LC 50(male mouse 4 hour exposire): 1450 ppm (Morpholine) LC 50(female mouse 4 hour exposure): 1900 ppm (Morpholine)

6 Page 6 of 7 Carcinogenicity Reproductive Toxicity Teratogenicity Mutagenicity Fish Toxicity Section 12 - Ecological Information Biodegradability Environmental Effects.. Section 13 - Disposal Consideration Waste Disposal Dispose in accordance with all federal, provincial, and/or local regulations including the Canadian Environmental Protection Act. TDG Classification Class (3) Group II PIN Number UN 2920 Other... Section 14 - Transportation Information Secure containers (full and/or empty) with suitable hold down devises during shipment. WHMIS Classification......B, D1, E Section 15 - Regulatory Information NOTE: THE PRODUCT LISTED ON THIS MSDS HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF THE CANADIAN CONTROLLED PRODUCTS REGULATIONS. THIS MSDS CONTAINS ALL INFORMATION REQUIRED BY THOSE REGULATIONS.

7 Page 7 of 7 Section 16 - Other Information Preparation Date March 9, 2011 Revision Date... February 20, 2014 March 18, 2014 Note: The responsibility to provide a safe workplace remains with the user. The user should consider the health hazards and safety information contained herein as a guide and should take those precautions required in an individual operation to instruct employees and develop work practice procedures for a safe work environment. The information contained herein is, to the best of our knowledge and belief, accurate. However, since the conditions of handling and use are beyond our control, we make no guarantee of results, and assume no liability for damages incurred by the use of this material. It is the responsibility of the user to comply with all applicable laws and regulations. Attention: Receiver of the chemical goods / MSDS coordinator As part of our commitment to the Canadian Association of Chemical Distributors (CACD) Responsible Distribution initiative, ClearTech Industries Inc. and its associated companies require, as a condition of sale, that you forward the attached Material Safety Data Sheet(s) to all affected employees, customers, and end-users. ClearTech will send any available supplementary handling, health, and safety information to you at your request. If you have any questions or concerns please call our customer service or technical service department. ClearTech Industries Inc. - Locations Corporate Head Office: 1500 Quebec Avenue, Saskatoon, SK, S7K 1V7 Phone: 1 (800) Fax: 1 (888) Location Address Postal Code Phone Number Fax Number Richmond, B.C Horseshoe Way V7A 4X6 1 (800) (888) Port Coquitlam, B.C 2023 Kingsway Ave V3C 1S9 1 (800) (888) Calgary, AB. 5516E - 40 th St. S.E. T2C 2A1 1 (800) (888) Edmonton, AB th Street T5S 1N7 1 (800) (888) Saskatoon, SK Hanselman Avenue S7L 5Z3 1 (800) (888) Regina, SK. 555 Henderson Drive S42 5X2 1 (800) (888) Winnipeg, MB. 340 Saulteaux Crescent R3J 3T2 1 (800) (888) Mississauga, ON Bath Road L4T 1L2 1 (800) (888) Hour Emergency Number - All Locations 1 (800)