SAFETY DATA SHEET. 1. Identification. 2. Hazard(s) identification. Version: 1.0 Revision Date: 07/28/2015

Transcription

1 1. Identification SAFETY DATA SHEET Material name: POWERPLY STANDARD FR - BLACK GRANULE Material: 036BSTDFR601 Recommended use and restriction on use Recommended use: Article Restrictions on use: Not known. Manufacturer/Importer/Supplier/Distributor Information Tremco U.S. Roofing 3735 Green Road Cleveland OH US Contact person: EH&S Department Telephone: Emergency telephone number: (US); (Canada) 2. Hazard(s) identification Hazard Classification Health Hazards Carcinogenicity Category 1A Unknown toxicity - Health Acute toxicity, oral % Acute toxicity, dermal % Acute toxicity, inhalation, vapor 100 % Acute toxicity, inhalation, dust or mist 100 % Unknown toxicity - Environment Acute hazards to the aquatic environment Chronic hazards to the aquatic environment % 100 % Label Elements Hazard Symbol: Signal Word: Hazard Statement: Danger May cause cancer. Precautionary Statement: 1/16

2 Prevention: Response: Storage: Disposal: Other hazards which do not result in GHS classification: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. If exposed or concerned: Get medical advice/attention. Store locked up. Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. None. 3. Composition/information on ingredients Mixtures Chemical Identity CAS number Content in percent (%)* Calcium Carbonate (Limestone) % Asphalt % Crystalline Silica (Quartz)/ Silica Sand % Magnesite % Fibrous Glass % Titanium dioxide % Clay % Carbon Black % Iron oxide % * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. 4. First-aid measures Ingestion: Inhalation: Skin Contact: Eye contact: Rinse mouth thoroughly. Move to fresh air. Remove contaminated clothing and wash the skin thoroughly with soap and water after work. Rinse immediately with plenty of water. Most important symptoms/effects, acute and delayed Symptoms: May cause skin and eye irritation. Indication of immediate medical attention and special treatment needed Treatment: Symptoms may be delayed. 5. Fire-fighting measures 2/16

3 General Fire Hazards: No unusual fire or explosion hazards noted. Suitable (and unsuitable) extinguishing media Suitable extinguishing media: Unsuitable extinguishing media: Specific hazards arising from the chemical: Use fire-extinguishing media appropriate for surrounding materials. Do not use water jet as an extinguisher, as this will spread the fire. During fire, gases hazardous to health may be formed. Special protective equipment and precautions for firefighters Special fire fighting procedures: Special protective equipment for fire-fighters: Self-contained breathing apparatus and full protective clothing must be worn in case of fire. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures: Methods and material for containment and cleaning up: Notification Procedures: Environmental Precautions: Collect spillage in containers, seal securely and deliver for disposal according to local regulations. In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water sources or sewer. Environmental manager must be informed of all major spillages. 7. Handling and storage Precautions for safe handling: Do not handle until all safety precautions have been read and understood. Obtain special instructions before use. Use personal protective equipment as required. Ventilate well, avoid breathing vapors. Use approved respirator if air contamination is above accepted level. Use mechanical ventilation in case of handling which causes formation of dust. Conditions for safe storage, including any incompatibilities: Store locked up. 8. Exposure controls/personal protection Control Parameters 3/16

4 Occupational Exposure Limits Chemical Identity type Exposure Limit Values Source Calcium Carbonate (Limestone)- Total dust. Calcium Carbonate (Limestone)- Respirable fraction. Asphalt - Inhalable fraction. - as benzene solubles Crystalline Silica (Quartz)/ Silica Sand - Respirable fraction. Crystalline Silica (Quartz)/ Silica Sand - Respirable. PEL PEL mg/m3 2.4 millions of particles per cubic foot of air Crystalline Silica (Quartz)/ Silica Sand - Total dust. Magnesite - Total dust. PEL Magnesite - Respirable fraction. PEL Fibrous Glass - Inhalable fraction. Fibrous Glass - Fiber. 1 fibers/cm3 Clay - Respirable fraction. 15 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) 5 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) 0.5 mg/m3 US. ACGIH Threshold Limit Values (2011) US. ACGIH Threshold Limit Values (2011) US. OSHA Table Z-3 (29 CFR ) (2000) 0.1 mg/m3 US. OSHA Table Z-3 (29 CFR ) (2000) 0.3 mg/m3 US. OSHA Table Z-3 (29 CFR ) (2000) 15 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) 5 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) 5 mg/m3 US. ACGIH Threshold Limit Values (032014) US. ACGIH Threshold Limit Values (032014) 1 US. ACGIH Threshold Limit Values fibers/cm3 (032014) 1 US. ACGIH Threshold Limit Values fibers/cm3 (032014) 1 US. ACGIH Threshold Limit Values fibers/cm3 (032014) 1 US. ACGIH Threshold Limit Values fibers/cm3 (032014) 0.2 US. ACGIH Threshold Limit Values fibers/cm3 (032014) 2 mg/m3 US. ACGIH Threshold Limit Values (2011) PEL 5 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) Clay - Total dust. PEL 15 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) Titanium dioxide 10 mg/m3 US. ACGIH Threshold Limit Values (2011) Titanium dioxide - Total PEL 15 mg/m3 US. OSHA Table Z-1 Limits for Air 4/16

5 dust. Contaminants (29 CFR ) Iron oxide - Respirable 5 mg/m3 US. ACGIH Threshold Limit Values fraction. (2011) Iron oxide - Fume. PEL 10 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) Carbon Black - Inhalable fraction. 3 mg/m3 US. ACGIH Threshold Limit Values (2011) Carbon Black PEL 3.5 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) Chemical name type Exposure Limit Values Source Calcium Carbonate (Limestone) - Total dust. STEL 20 mg/m3 Canada. British Columbia OELs. 10 mg/m3 Canada. British Columbia OELs. 5/16

6 Calcium Carbonate (Limestone) - Respirable fraction. Calcium Carbonate (Limestone) - Total dust. Asphalt - Aerosol, inhalable. - as benzene solubles Asphalt - Inhalable fraction. - as benzene solubles EV 3 mg/m3 Canada. British Columbia OELs. 10 mg/m3 Canada. Quebec OELs. (Ministry of 0.5 mg/m3 Canada. British Columbia OELs. 0.5 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) (112010) Asphalt - Fume. 5 mg/m3 Canada. Quebec OELs. (Ministry of Crystalline Silica (Quartz)/ Silica Sand - Respirable fraction. Crystalline Silica (Quartz)/ Silica Sand - Respirable. Crystalline Silica (Quartz)/ Silica Sand - Respirable dust mg/m3 EV 0.10 mg/m3 Magnesite - Total dust. EV Magnesite - Total dust. Fibrous Glass - Fiber. 0.2 fibers/cm3 1 fibers/cm3 Canada. British Columbia OELs. Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) (112010) 0.1 mg/m3 Canada. Quebec OELs. (Ministry of 10 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) (112010) 10 mg/m3 Canada. Quebec OELs. (Ministry of Canada. British Columbia OELs. Canada. British Columbia OELs. 6/16

7 Fibrous Glass - Inhalable fibers. Fibrous Glass - Inhalable Fibrous Glass - Respirable fibers. EV EV 1 fibers/ml Fibrous Glass - Fiber. EV 0.2 fibers/ml Fibrous Glass - Total dust. Fibrous Glass - Fiber. 1 fibres/cm3 (nonasbestos fibres) -- size restriction s apply 2 fibres/cm3 (nonasbestos fibres) -- size restriction s apply 5 mg/m3 Canada. British Columbia OELs. 5 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) (112010) Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) (112010) Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) (112010) 10 mg/m3 Canada. Quebec OELs. (Ministry of Canada. Quebec OELs. (Ministry of Canada. Quebec OELs. (Ministry of 7/16

8 Titanium dioxide - Total dust. Titanium dioxide - Respirable fraction. 10 mg/m3 Canada. British Columbia OELs. 3 mg/m3 Canada. British Columbia OELs. Titanium dioxide EV 10 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) (112010) Titanium dioxide - Total dust. Carbon Black - Inhalable 10 mg/m3 Canada. Quebec OELs. (Ministry of 3 mg/m3 Canada. British Columbia OELs. as amended) (092011) Carbon Black EV 3.5 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) (112010) Carbon Black 3.5 mg/m3 Canada. Quebec OELs. (Ministry of Appropriate Engineering Controls Mechanical ventilation or local exhaust ventilation may be required. Observe good industrial hygiene practices. Observe occupational exposure limits and minimize the risk of inhalation of dust. Individual protection measures, such as personal protective equipment General information: Eye/face protection: Skin Protection Hand Protection: Other: Respiratory Protection: Hygiene measures: Use personal protective equipment as required. Wear goggles/face shield. Use suitable protective gloves if risk of skin contact. In case of inadequate ventilation use suitable respirator. Seek advice from local supervisor. Observe good industrial hygiene practices. Wash hands before breaks and immediately after handling the product. 9. Physical and chemical properties 8/16

9 Appearance Physical state: solid Form: solid Color: Black Odor: Slight Odor threshold: ph: Melting point/freezing point: Initial boiling point and boiling range: Flash Point: Evaporation rate: Flammability (solid, gas): No Upper/lower limit on flammability or explosive limits Flammability limit - upper (%): Flammability limit - lower (%): Explosive limit - upper (%): Explosive limit - lower (%): Vapor pressure: Vapor density: Relative density: 1.0 Solubility(ies) Solubility in water: Insoluble in water Solubility (other): Partition coefficient (n-octanol/water): Auto-ignition temperature: Decomposition temperature: Viscosity: 10. Stability and reactivity Reactivity: Chemical Stability: Possibility of Hazardous Reactions: Conditions to Avoid: Incompatible Materials: Hazardous Decomposition Products: Material is stable under normal conditions. Avoid heat or contamination. Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapors. 11. Toxicological information Information on likely routes of exposure Ingestion: May be ingested by accident. Ingestion may cause irritation and malaise. 9/16

10 Inhalation: Skin Contact: Eye contact: In high concentrations, vapors, fumes or mists may irritate nose, throat and mucus membranes. Moderately irritating to skin with prolonged exposure. Eye contact is possible and should be avoided. Information on toxicological effects Acute toxicity (list all possible routes of exposure) Oral Dermal Inhalation Specified substance(s): Asphalt ATEmix: 30, mg/kg ATEmix: 5, mg/kg LC 50 (Rat): > 94.4 mg/m3 Titanium dioxide LC 50 (Rat, 4 h): > 6.82 mg/l Carbon Black LC 0 (Rat, 4 h): > 10 mg/m3 Iron oxide LC 0 (Rat): > 210 mg/m3 Repeated dose toxicity Skin Corrosion/Irritation Serious Eye Damage/Eye Irritation Specified substance(s): Asphalt Magnesite Titanium dioxide Carbon Black Iron oxide in vivo (Rabbit, 24 hrs): Not irritating In vitro (Reconstituted Corneal Epithelium model, 10 min): Not irritating in vivo (Rabbit, hrs): Not irritating in vivo (Rabbit, hrs): Not irritating in vivo (Rabbit, 1-72 hrs): Not irritating Respiratory or Skin Sensitization 10/16

11 Carcinogenicity IARC Monographs on the Evaluation of Carcinogenic Risks to Humans: Asphalt Crystalline Silica (Quartz)/ Silica Sand Fibrous Glass Titanium dioxide Carbon Black Overall evaluation: Possibly carcinogenic to humans. Overall evaluation: Carcinogenic to humans. Overall evaluation: Not classifiable as to carcinogenicity to humans. Overall evaluation: Not classifiable as to carcinogenicity to humans. Overall evaluation: Possibly carcinogenic to humans. Overall evaluation: Possibly carcinogenic to humans. Overall evaluation: Possibly carcinogenic to humans. Overall evaluation: Possibly carcinogenic to humans. US. National Toxicology Program (NTP) Report on Carcinogens: Crystalline Silica Known To Be Human Carcinogen. (Quartz)/ Silica Sand Fibrous Glass Reasonably Anticipated to be a Human Carcinogen. Reasonably Anticipated to be a Human Carcinogen. US. OSHA Specifically Regulated Substances (29 CFR ): No carcinogenic components identified Germ Cell Mutagenicity In vitro In vivo Reproductive toxicity Specific Target Organ Toxicity - Single Exposure Specific Target Organ Toxicity - Repeated Exposure Aspiration Hazard 11/16

12 Other effects: 12. Ecological information Ecotoxicity: Acute hazards to the aquatic environment: Fish Specified substance(s): Titanium dioxide Aquatic Invertebrates Specified substance(s): Titanium dioxide LC 50 (Mummichog(Fundulus heteroclitus), 96 h): > 1,000 mg/l Mortality EC 50 (Water flea (Daphnia magna), 48 h): > 1,000 mg/l Intoxication Chronic hazards to the aquatic environment: Fish Specified substance(s): Asphalt Titanium dioxide Carbon Black Iron oxide Aquatic Invertebrates NOAEL (Oncorhynchus mykiss, 28 d): >= 1,000 mg/l interpreted LC 0 (Coregonus autumnalis migratorius G., 30 d): 3 mg/l experimental result NOAEL (Salmo sp., 30 d): 17 mg/l QSAR LOAEL (Pimephales promelas, 33 d): 1.6 mg/l experimental result Toxicity to Aquatic Plants Persistence and Degradability Biodegradation BOD/COD Ratio Bioaccumulative Potential 12/16

13 Bioconcentration Factor (BCF) Partition Coefficient n-octanol / water (log Kow) Mobility in Soil: Other Adverse Effects: 13. Disposal considerations Disposal instructions: Contaminated Packaging: Dispose of waste at an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. 14. Transport information TDG: Not Regulated CFR / DOT: Not Regulated IMDG: Not Regulated 15. Regulatory information US Federal Regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) None present or none present in regulated quantities. 13/16

14 US. OSHA Specifically Regulated Substances (29 CFR ) Chemical Identity Formaldehyde OSHA hazard(s) Acute toxicity Skin irritation Skin sensitization Flammability respiratory tract irritation Respiratory sensitization Cancer Eye irritation CERCLA Hazardous Substance List (40 CFR 302.4): Chemical Identity Asphalt Formaldehyde Reportable quantity 100 lbs. 100 lbs. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Delayed (Chronic) Health Hazard SARA 302 Extremely Hazardous Substance Reportable Chemical Identity quantity Threshold Planning Quantity Formaldehyde 100 lbs. 500 lbs. SARA 304 Emergency Release Notification Chemical Identity Reportable quantity Asphalt 100 lbs. Formaldehyde 100 lbs. SARA 311/312 Hazardous Chemical Chemical Identity Threshold Planning Quantity Formaldehyde 500lbs Calcium Carbonate 500 lbs (Limestone) Asphalt 500 lbs Crystalline Silica (Quartz)/ 500 lbs Silica Sand Magnesite 500 lbs Fibrous Glass 500 lbs Titanium dioxide 500 lbs Clay 500 lbs Carbon Black 500 lbs Iron oxide 500 lbs SARA 313 (TRI Reporting) None present or none present in regulated quantities. Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3) None present or none present in regulated quantities. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ): Chemical Identity Reportable quantity 14/16

15 Formaldehyde lbs US State Regulations US. California Proposition 65 This product contains chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm. US. New Jersey Worker and Community Right-to-Know Act Chemical Identity Calcium Carbonate (Limestone) Asphalt Crystalline Silica (Quartz)/ Silica Sand Magnesite Fibrous Glass US. Massachusetts RTK - Substance List Chemical Identity Calcium Carbonate (Limestone) Asphalt Crystalline Silica (Quartz)/ Silica Sand Magnesite Fibrous Glass Formaldehyde US. Pennsylvania RTK - Hazardous Substances Chemical Identity Calcium Carbonate (Limestone) Asphalt Crystalline Silica (Quartz)/ Silica Sand Fibrous Glass US. Rhode Island RTK No ingredient regulated by RI Right-to-Know Law present. Other Regulations: Inventory Status: Australia AICS: Canada DSL Inventory List: All components in this product are listed on or exempt from the Inventory. EINECS, ELINCS or NLP: Japan (ENCS) List: China Inv. Existing Chemical Substances: 15/16

16 Korea Existing Chemicals Inv. (KECI): Canada NDSL Inventory: Philippines PICCS: US TSCA Inventory: New Zealand Inventory of Chemicals: Japan ISHL Listing: Japan Pharmacopoeia Listing: All components in this product are listed on or exempt from the Inventory. 16.Other information, including date of preparation or last revision Version #: 1.0 Further Information: Disclaimer: For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the consideration of the user, subject to their own investigation of compliance with applicable regulations, including the safe use of the product under every foreseeable condition. 16/16