Item No: Item Desc: Shared SDS s (Item No): SDS Origin. Note: This SDS cover page should accompany all printed copies of actual Safety Data Sheets

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1 Item No: Item Desc: Note: This SDS cover page should accompany all printed copies of actual Safety Data Sheets Shared SDS s (Item No): SDS Origin Manufacturer: Mfg. Code No: SDS No: Phone: Print Date: Revised Date: Hazardous Ingredients Note: Ingredient CAS No Carcinogen Male Toxin If all Shared SDS boxes above are filled then all shared part numbers may not be represented. Those potentially not shown above are however, available individually from this website. Proposition 65 Items Female Toxin Repro Toxin

2 Revision date: 21/01/2013 : Version:1.0 SECTION 1: Identification of the product and of the company/undertaking 1.1. Product identifier Trade name : Steel with cobalt 1.2. Relevant identified uses of the product Relevant identified uses Use of the product : Production of metallic articles 1.3. Details of the supplier of the safety data sheet Erasteel Tour Maine Montparnasse PARIS CEDEX 15 - France T +33 (0) F +33 (0) erasteel.info@eramet-erasteel.com - SECTION 2: Hazards identification In case of melting, grinding, sieving or any other method of manufacturing creating dust, smoke, or oxide, follow the recommandations of paragraph 8. Upon heating, toxic fumes may be formed. SECTION 3: Composition/information on ingredients Name Product identifier % Classification according to Directive 67/548/EEC Cobalt (CAS No.) (EC no) (EC index no) Chromium (CAS No.) (EC no) Nickel (n CAS) (Numéro CE) (Numéro index) Cat.Repr.3; R62 Xn; R42 Xi; R43 R53 < 5 Not classified < 1 Cat.Carc.3; R40 T; R48/23 R43 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Cobalt (CAS No.) (EC no) (EC index no) Chromium (CAS No.) (EC no) Nickel (n CAS) (Numéro CE) (Numéro index) Full text of R-, H- and EUH-phrases: see section Resp. Sens. 1B, H334 Skin Sens. 1, H317 Repr. 2, H361f Aquatic Chronic 4, H413 < 5 Not classified < 1 Skin Sens. 1, H317 Carc. 2, H351 STOT RE 1, H372 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after skin contact : In all cases of doubt, or when symptoms persist, seek medical advice. : After contact with skin, wash immediately with plenty of water and soap. In case of skin irritation, consult a physician Most important symptoms and effects, both acute and delayed Symptoms/injuries : Allergic reactions Indication of any immediate medical attention and special treatment needed In case of doubt or persistent symptoms, consult always a physician. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Co-ordinate fire-fighting measures to the fire surroundings Special hazards arising from the product Fire hazard : The product itself does not burn Advice for firefighters Protection during firefighting Other information : In case of fire: Wear self-contained breathing apparatus. : Do not allow run-off from fire-fighting to enter drains or water courses. 01M 1/4

3 SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : See protective measures under point 7 and For non-emergency personnel Protective equipment : Use personal protective equipment as required For emergency responders Protective equipment 6.2. Environmental precautions Do not allow to enter into surface water or drains Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections : Use personal protective equipment as required. : Avoid generation of dust. Treat the recovered material as prescribed in the section on waste disposal. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed Precautions for safe handling Hygiene measures : Persons with a history of asthma, allergies, chronic or recurrent respiratory disease should not be exposed to any process in which this product is used. : Avoid generation of dust Conditions for safe storage, including any incompatibilities Prohibitions on mixed storage 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters Cobalt ( ) : Contaminated work clothing should not be allowed out of the workplace. : Do not store together with: Acidic. oxidation agents and reductor agents. USA ACGIH ACGIH TWA (mg/m³) 0,02 mg/m³ USA NIOSH NIOSH REL (TWA) (mg/m3) 0,05 mg/m³ USA OSHA OSHA PEL (TWA) (mg/m3) 0,1 mg/m³ Nickel ( ) USA ACGIH ACGIH TWA (mg/m³) 1,5 mg/m³ Chromium ( ) USA ACGIH ACGIH TWA (mg/m³) 0,5 mg/m³ 8.2. Exposure controls Appropriate engineering controls : Technical measures and the application of suitable work processes have priority over personal protection equipment. Personal protective equipment : Gloves. Dust production: dust mask with filter type P3. Hand protection : EN-norms: EN 374. Respiratory protection : Filtering Half-face mask (EN 149). SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Colour : Steel. Odour : odourless. Melting point : C Relative density : 7-8 Explosive properties : not explosive. Oxidising properties : Not oxidizing. 01M 2/4

4 SECTION 10: Stability and reactivity Reactivity Chemical stability Stable under normal conditions Possibility of hazardous reactions Conditions to avoid The product in the delivered form is not dust explosion capable; the build-up of fine dust however leads to the danger of dust explosion Incompatible materials Acidic. oxidation agents and reductor agents Hazardous decomposition products metallic oxide. SECTION 11: Disposal considerations Waste treatment methods Waste treatment methods Ecology - waste materials SECTION 12: Transport information No dangerous good in sense of transport regulations. SECTION 13: Regulatory information EU-Regulations : Material recycling possible. : Do not dispose of waste into sewer. Dispose according to legislation. For an article, according to the REACH 1907/2006/EC Regulation, there is no legal obligation to provide a safety data sheet. However, to be able to provide information typically included in a safety data sheet also for articles, the present safety information sheet for articles has been worked out. This article does not contain substances on the Candidate List SECTION 14: Other information Abbreviations and acronyms : ACGIH American Conference of Governmental Industrial Hygienists CAS Chemical Abstract Service EINECS European Inventory of Existing Commercial Chemical Substances OSHA Occupational Safety and Health Administration NOHSC National Occupational Health & Safety Commission. Other information : The above information describes exclusively the safety requirements of the product and is based on our present-day knowledge. The information is intended to give you advice about the safe handling of the product named in this safety information sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the case of mixing the product with other products or in the case of processing, the information on this safety information sheet is not necessarily valid for the new made-up material. Full text of R-, H- and EUH-phrases:: Aquatic Chronic 3 Hazardous to the aquatic environment - Chronic Hazard Category Aquatic Chronic 4 Hazardous to the aquatic environment - Chronic Hazard Category Carc. 2 Carcinogenicity Category Eye Irrit. 2 Serious eye damage/eye irritation Category Repr. 2 Reproductive toxicity Category Resp. Sens. 1 Respiratory sensitisation Category Skin Sens. 1 Skin sensitisation Category STOT RE 1 Specific target organ toxicity (repeated exposure) Category H317 May cause an allergic skin reaction H319 Causes serious eye irritation H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled H351 Suspected of causing cancer H361f Suspected of damaging fertility H372 Causes damage to organs through prolonged or repeated exposure H413 May cause long lasting harmful effects to aquatic life R36 Irritating to eyes R40 Limited evidence of a carcinogenic effect R42 May cause sensitization by inhalation R43 May cause sensitisation by skin contact R48/23 Toxic: danger of serious damage to health by prolonged exposure through inhalation R53 May cause long-term adverse effects in the aquatic environment. 01M 3/4

5 R62 Possible risk of impaired fertility T Toxic Xi Irritant Xn Harmful This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. 01M 4/4