SAFETY DATA SHEET. according to Regulation (EC) No. 453/2010

Transcription

1 SAFETY DATA SHEET according to Regulation (EC) No. 453/2010 MIDA ACTISEPT Page: 1/5 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Chemical type Trade name Product code : Mixture : MIDA ACTISEPT : MIDA ACTISEPT 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Description/Application Uses advised against No uses adviced against Details of the supplier of the safety data sheet CHRISTEYNS s.r.o. Vítovská 453/ Odry T Emergency telephone number National Poisons Information Service worldwide: SECTION 2: Hazards identification 2.1. Classification of the substance or mixture : Liquid detergent. For professional use only Classification according to Regulation (EC) No. 1272/2008 [CLP] Acute Tox 4 Eye Dam. 1 Skin Corr. 1A H302 Harmful if swallowed. H312 Harmful in contact with skin. H332 Harmful if inhaled. H319 Causes serious eye irritation. H315 Causes skin irritation Adverse physicochemical, human health and environmental effects Mixture was classified as irritating for skin and eyes Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) : CLP Signal word : Danger Hazardous ingredients : Polyoxyethylated decylalcohol, Dodecylbispropylentriamin, Butylglycol Hazard statements (CLP) : H302 Harmful if swallowed. H312 Harmful in contact with skin. H315 Dráždí kůži. Causes skin irritation. H319 Causes serious eye irritation. H332 Harmful if inhaled. Precautionary statements (CLP) : P261 Avoid breathing vapours. P264 Wash the hands thoroughly after handling. P270 Do no eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing/eye protection/face protection. P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P304+P341 IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove

2 Page: 2/ Other hazards Substance meets the criteria for PBT according to regulation (EG) n. 1907/2006, annex XIII : Not applicable P : no B : no T : no Substance meets the criteria for vpbt according to regualtion (EG) n. 1907/2006, annex XIII : vp : not vb : not SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention. P363 Wash contaminated clothing before reuse. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Polyoxyethylated decylalcohol (CAS-no) (Einecs nr) / (EG annex nr) / Tetrasodium Ethylene Diamine Tetraacetate (EDTA) (CAS-no) (Einecs nr) (EG annex nr) (REACH-no) Butyldiglycol (CAS-no) (Einecs nr) (EG annex nr) Bis (3-aminopropyl) dodecylamine (CAS-no) (Einecs nr) / (EG annex nr) / Butylglycol/2-butoxyethanol (CAS-no) (Einecs nr) (EG annex nr) (REACH-no) Full text of H- and EUH-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures General advice Inhalation Skin contact Eye contact Ingestion 4.2. Most important symptoms and effects, both acute and delayed Acute effects inhalation : /. Acute effects skin Acute effects eyes Acute effects oral route 5-15 Acute Tox. 4 (Oral), H302 Eye Dam. 1, H318 Eye Dam. 1, H318 < 5 Eye Irrit. 2, H319 Skin Corr. 1B, H314 STOT RE 2, H373 Aquatic Acute 1, H400 Acute Tox. 4 (Dermal), H312 Acute Tox. 4 (Inhalation), H332 Skin Irrit. 2, H315 Eye Irrit. 2, H319 : In case of doubt or persistent symptoms, consult always a physician. For symptom description, see item 11. : Take victim to fresh air, in a quiet place and if necessary take medical advice. : Wash off with plenty of water. In case of faintness or symptoms of skin irritation appear, take medical advice. : Rinse thoroughly and plentifully with water, also under the eyelids. If eye irritation persists, take medical advice. : Rinse mouth, drink a lot of water, keep quiet, and go immediately to hospital or to a doctor. : Irritant effect to skin. : Risk of serious eye damage. : May be burn of the upper digestive and respiratory tracts Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media suitable extinguishing media : In fire case not far from, any kind of extinguisher can be used: foam, sand, carbon dioxyde (CO2), water Special hazards arising from the substance or mixture 5.3. Advice for firefighters

3 SECTION 6: Accidental release measures MIDA ACTISEPT 6.1. Personal precautions, protective equipment and emergency procedures Page: 3/ For non-emergency personnel Concerning personal protective equipment to use, see item For emergency responders 6.2. Environmental precautions Stop leak without risks if possible Methods and material for containment and cleaning up Absorb spilled material with sand or earth. Sweep up, shovel or vacuum Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not eat, drink and do not smoke in areas where product is used. Do not use compressed air to fill, handle or work up. No special handling advice required Conditions for safe storage, including any incompatibilities Only store product in original container. Keep out of frost Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters No additional information available 8.2. Exposure controls Hand protection : Chemical resistant PVC gloves (to European standard EN 374 or equivalent). Eye protection : Safety glasses with side-shields (EN 166). Protective equipment : Wear suitable protective clothing (EN 14605). Respiratory protection SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Physical state/form Colour : /. Odour Odour threshold : Not necessary with sufficient ventilation. : Liquid : Liquid. : Characteristic. ph : 11,0 ± 0,5 (100%); 9,7 ± 0,5 (1%) Melting point/range : < 0 C Freezing point Boiling point/boiling range : / Flash point Relative evaporation rate (butylacetate=1) Flammability (solid, gas) Explosive limits Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Autoignition temperature Decomposition temperature Viscosity : Not applicable. : 1013 ± 25 g/lt : Water: Soluble 9.2. Other information

4 Page: 4/5 SECTION 10: Stability and reactivity Reactivity Chemical stability The product is stable at normal handling- and storage conditions Possibility of hazardous reactions Conditions to avoid Incompatible materials Never mix with other materials Hazardous decomposition products Hazardous decomposition products may be released during prolonged heating like smokes, carbon monoxide and dioxide. SECTION 11: Toxicological information Information on toxicological effects Irritation : Risk of serious damage to eyes. Laureth-7 ( ) LD50 oral rat 2000 mg/kg 2000 mg/kg Bis (3- aminopropyl) dodecylamine ( ) LD50 oral rat 871 LD50 dermal rat ,00000 mg/kg Butylglycol/2-butoxyethanol ( ) ATE (dermal) 500,00000 mg/kg 1100,00000 mg/kg SECTION 12: Ecological information Toxicity Bis (3- aminopropyl) dodecylamine ( ) LC50 fish 1 LC50 other aquatic organisms 1 EC50 Daphnia Persistence and degradability 0,68 mg/l 0,45 mg/l 0,073 mg/l The surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the Member States and will be made available to them, at their direct request or at the request of a detergent manufacturer Bioaccumulative potential No bioaccumulation Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Waste / unused products SECTION 14: Transport information No dangerous good in sense of transport regulations (ADR, RID, IMDG, IATA). SECTION 15: Regulatory information : Collect all waste in suitable and labelled containers and dispose according to local legislation Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations INGREDIENT DECLARATION ACCORDING TO 648/2004/EEG

5 <5% EDTA and salts. 5-15% Nonionic surfactants. OTHER Desinfectant agent National regulations No chemical safety report for the product available. Page: 5/ Chemical safety assessment SECTION 16: Other information It is recommended to pass the information of this safety data sheet in an appropriate form to the users. Such information is actually the best of our knowledge and believes accurate as reliable. This information relates to the specific material designated and may not be valid in combination with other products. This safety data sheet is in compliance with 1907/2006/EEC. It is user's liabilities to take all necessary measures to meet local required laws and regulations. The producer is not responsable for any damage and loss due to the use of information mentioned in this safety data sheet. HISTORY PREVIOUS REVISION DATE : REVIEW CHAPTER(S) N : 2,3,16 Full text of H-, P- and EUH-phrases: Acute Tox. 4 (Dermal) Acute toxicity (dermal) Category Acute Tox. 4 Acute toxicity (inhalation) Category 4 (Inhalation) Acute Tox. 4 (Oral) Acute toxicity (oral) Category Aquatic Acute 1 Hazardous to the aquatic environment - Acute Hazard Category Eye Dam. 1 Serious eye damage/eye irritation Category Eye Irrit. 2 Serious eye damage/eye irritation Category Skin Corr. 1B skin corrosion/irritation Category 1B Skin Irrit. 2 skin corrosion/irritation Category STOT RE 2 Specific target organ toxicity (repeated exposure) Category H302 Harmful if swallowed H312 Harmful in contact with skin H314 Causes severe skin burns and eye damage H315 Causes skin irritation H318 Causes serious eye damage H319 Causes serious eye irritation H332 Harmful if inhaled H373 May cause damage to organs through prolonged or repeated exposure H400 Very toxic to aquatic life P261 Avoid breathing vapours P264 Wash the hands thoroughly after handling P270 Do no eat, drink or smoke using this product P271 Use only outdoors or in a well-ventilated area P280 Wear protective gloves/protective clothing/eye protection/face protection P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell P302+P352 IF ON SKIN: Wash with plenty of soap and water P304+P341 IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337+P313 If eye irritation persists: Get medical advice/attention P363 Wash contaminated clothing before reuse P501 Dispose of contents/container in accordance with local/regional/national/international regulations.