Document id : Issue date : 05/05/2004 Version : 8.00 Supersedes date : 05/28/2001

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1 3M Canada Company Post Office Box 5757 London, Ontario N6A 4T1 Medical Emergency Telephone: (519) , Ext Transportation Emergency Telephone (CANUTEC): (613) ======================================================================= Material Safety Data Sheet ======================================================================= Document id : Issue date : 05/05/2004 Version : 8.00 Supersedes date : 05/28/2001 Copyright, 1997, 3M Canada Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Prepared by: Environmental Health and Safety Services Department, 3M Canada Company Telephone: (519) , Fax: (519) , Web Site: 1 Product Identification Tradename: 6360, 6262, 6363, 6364, 6365, 6366, 6368 TEMP Product ID: Intended Use of Product: Dental Product Division: DENTAL PRODUCTS 2 Composition/Information on Ingredients Ingredient Name CAS Number Percentage QUARTZ SILICA POLYESTER ACRYLIC OLIGOMER Trade Secret POLY(CAPROLACTONE) BENZOTRIAZOLYL-4-METHYLPHENOL NOTE: POLYESTER ACRYLIC OLIGOMER is a Trade Secret material. 6360, 6262, 6363, 6364, 6365, 6366, 6368 TEMP Page 2 of 7 Page 1

2 MAT-0007 (ENG) RUBAN 3M 3 Hazards Identification Critical Hazards: See Sections 7 and 11 for further information. 4 First Aid Measures Instructions for Eye Contact: Immediately flush eyes with large amounts of water. Get immediate medical attention. Instructions for Skin Contact: Wash affected area with soap and water. Instructions for Inhalation: If signs/symptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician. Instructions for Ingestion: No need for first aid is anticipated. 5 Fire Fighting Measures Flash point: >93.3 C Lower Explosive Limit (%): Not available Upper Explosive Limit (%): Not available Autoignition temperature: Not available Suitable Extinguishing Media: Water spray; Carbon Dioxide; Dry chemical; Foam; Exposure Hazards during Fire: Combustion Products from Fire: Fire Fighting Procedures: Special Instructions:. 6360, 6262, 6363, 6364, 6365, 6366, 6368 TEMP Page 3 of 7 6 Accidental Release Measures Personal Precautions: Spill Response: Place in a closed container approved for transportation by appropriate authorities. Page 2

3 Methods for Disposal: Dispose of waste product in a sanitary landfill. 7 Handling and Storage Storage Requirements: Store at room temperature. Incompatible Materials: Ventilation: Fire Prevention:. Use Instructions: Please see package insert for additional precautionary warnings. 8 Exposure Controls/Personal Protection Personal Protection Eye Protection: Avoid eye contact. Skin Protection: Avoid skin contact. Respiratory Protection: Avoid breathing of airborne material. Ingestion (Prevention): Wash hands after handling and before eating. Recommended Ventilation:. Ingredient Exposure Data QUARTZ SILICA ( ) LD50 (rat, oral) 6360, 6262, 6363, 6364, 6365, 6366, 6368 TEMP Page 4 of 7 : : Exposure Limits: ACGIH: TWA 0.05 mg/m3 (Respirable) (Table A2) POLYESTER ACRYLIC OLIGOMER (Trade Secret) Specific Ingredient Data: LD50 (rat, oral) : : Exposure Limits : POLY(CAPROLACTONE) ( ) Specific Ingredient Data: Page 3

4 LD50 (rat, oral) : : Exposure Limits : 2-BENZOTRIAZOLYL-4-METHYLPHENOL ( ) Specific Ingredient Data: LD50 (rat, oral): >2000 mg/kg : Exposure Limits : 9 Physical and Chemical Properties Physical form,color,odour: Solid; Waxy solid; pale yellow; White; slight acrylate odour; Odour Threshold: ph: Boiling point/boiling range: >93.3 C Melting point/melting range: >57 C Vapour pressure: <0.1 Air=1 Water Solubility: Nil Partition coefficient (K o/w): Specific gravity: 3.0 Water=1 Vapour density: Volatile organic compounds: Evaporation rate: Viscosity: 6360, 6262, 6363, 6364, 6365, 6366, 6368 TEMP Page 5 of 7 10 Stability and Reactivity Conditions to Avoid: Materials to Avoid: Hazardous Decomposition: None known Stability and Reactivity: Stable. Hazardous polymerization will not occur. 11 Toxicological Information Effects from Eye Contact: Mechanical eye irritation: Signs/symptoms can include pain, redness, tearing and corneal abrasion. Effects from Skin Contact: Mechanical skin irritation: Signs/symptoms can include abrasion, Page 4

5 redness, pain,and itching. Effects from Inhalation: No health effects are expected. The product contains quartz silica known to cause silicosis of the lungs under prolonged and repeated inhalation exposure. If grinding is part of the preparation and dust is produced at levels above the recommended guidelines, a half-mask dust respirator should be worn. Effects from Ingestion: No health effects are expected. Sensitization Information: Carcinogenicity: Mutagenicity: Reproductive Effects: Component Based Information: Product Based Information: 6360, 6262, 6363, 6364, 6365, 6366, 6368 TEMP Page 6 of 7 12 Ecological Information Environmental Data: Ecotoxicity Data: Ecofate Data: Other Effects and Information: 13 Disposal Considerations Product as Sold: Product Packaging: Special Instructions: Since regulations vary, consult applicable regulations or authorities before disposal. 14 Transportation Information Transportation of Dangerous Goods TDG Classification: Non-Regulated Material International Dangerous Goods Classification Page 5

6 MAT-0007 (ENG) RUBAN 3M 15 Regulatory Information WHMIS Classification: Exempt (Dental Product) NOTE: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. 6360, 6262, 6363, 6364, 6365, 6366, 6368 TEMP Page 7 of 7 16 Other Information Reason for Reissue: The following Sections and topics have been updated or revised: Update Tradename (Obsolete product) The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, STATUTORY OR OTHERWISE, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OR CONDITION OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. ---End--- Page 6

Page 2 of 6 signs/symptoms continue, call a physician. Instructions for Ingestion: No need for first aid is anticipated. 5 Fire Fighting Measures Flas

Page 2 of 6 signs/symptoms continue, call a physician. Instructions for Ingestion: No need for first aid is anticipated. 5 Fire Fighting Measures Flas Page 1 of 6 3M Canada Company Post Office Box 5757 London, Ontario N6A 4T1 Medical Emergency Telephone: (519)451-2500, Ext. 2222 =======================================================================

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