Product Safety Data Sheet

Transcription

1 Print date: Page 1 of 10 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier VIBTOOL PDA VIB EX 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture This product is used in the device VIB EX. To charge the battery only specified chargers may be used. Uses advised against Only use for the intended purpose Details of the supplier of the safety data sheet Company name: Street: Oskar-Messter-Straße Place: D Ismaning Telephone: +49 (089) Internet: info@pruftechnik.com Telephone number for additional information: SECTION 2: Hazards identification Classification of the substance or mixture Lithium batteries are sealed gas-tight and harmless if the manufacturer s instructions are followed in use and handling Label elements Hazardous components which must be listed on the label 2.3. Other hazards The product is not subject to labeling. The product, like other rechargeable batteries, must not be short-circuited. Short-circuiting (even with metallic jewelry or tools) can cause a fire or burns due to high currents. Mechanical damage can lead to internal short-circuits. The high current flow causes the battery to heat up. Plastic housings can melt and catch fire. Under certain circumstances a mechanical defect may not be immediately recognizable. There may still be an internal short-circuit even a long time after the mechanical defect. Lithium polymer batteries are mechanically, electrically and thermally sensitive: damage, overcharging, over-discharging, excessive currents, operating at too high (over 60 C) or low temperatures (below 0 C) and long storage in a discharged state damage or destroy the cell, in most cases. If a battery burns, the vapors can irritate eyes, skin and the respiratory tract.

2 Print date: Page 2 of 10 SECTION 3: Composition/information on ingredients 3.2. Mixtures Chemical characterization Polymer-Lithium Battery 50% Lithium Manganese Oxide, 10% Graphite, 5% Polypropylene, 2% Poly (vinylidene fluoride), 5% Polythene, 0,5% Sodium carboxymethylcellulose, 5% Lithium hexafluorophosphate, 5% Ethylene Carbonate, 5% Dimethyl Carbonate, 2,5% Nickel, 5% Copper, 5% Aluminium Further Information The chemicals are contained in sealed cans, so they cannot leak when properly used. Under normal conditions of use, risk of exposure occurs only if the battery is mechanically abused. Note: Lithium batteries are articles. Under normal conditions no substances are released from lithium batteries. SECTION 4: First aid measures 4.1. Description of first aid measures General information First-aider: Pay attention to self-protection! After inhalation Escaping gases can cause respiratory irritation. Provide fresh air. Seek medical attention if problems persist. After contact with skin Skin contact may cause skin irritation. Wash skin with soap and water. After contact with eyes If product gets into the eye, keep eyelid open and rinse immediately with large quantities of water, for at least 5 minutes. Subsequently consult an ophthalmologist. After ingestion If any parts of the product are swallowed, consult a doctor immediately Most important symptoms and effects, both acute and delayed Combustion products may cause irritation Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing Dry chemical extinguishers fire classification D (dry powder). Sand. Fires involving lithium batteries in use can generally be fought with water; this should only be carried out by trained personnel with sufficient volumes of water, however.

3 Print date: Page 3 of 10 Extinguishing media which must not be used for safety reasons High power water jet Special hazards arising from the substance or mixture When burned, hazardous fumes might arise Advice for firefighters In case of fire: Wear self-contained breathing apparatus. Keep away from unprotected people. Keep upwind. Remove rechargeable batteries from the area of the fire if safe to do so. Additional information Extinguishing materials should be selected according to the surrounding area. Contaminated fire-fighting water must be collected separately. Remove according to the regulations. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Provide adequate ventilation Environmental precautions Preferably prevent the material from infiltrating the canalization or water courses. Do not contaminate surface waters Methods and material for containment and cleaning up Batteries must be hermetically sealed in a plastic Reference to other sections For waste disposal see section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Advice on safe handling Do not open, crush, disassemble, drop or solder the battery. Store the battery out of the reach of children. Advice on protection against fire and explosion Wrong handling can cause fire or explosion. Further information on handling For long-time storage, the battery must be kept under 40-60% state of charge. Transport under 10-50% state of charge. Charge within a temperature range of 0 C to +40 C. Discharge within temperature range of -20 C to +60 C Conditions for safe storage, including any incompatibilities Requirements for storage and vessels Storage temperature: Cool storage location preferably below 30 C. Relative room humidity (%): 0%-80% Maintaining optimum functionality: 10 C-20 C Advice on storage compatibility Keep in a cool place away from metals.

4 Print date: Page 4 of 10 SECTION 8: Exposure controls/personal protection 8.1. Control parameters Additional information on exposure limits Lithium batteries are articles. Under normal conditions no substances are released from lithium batteries Exposure controls Appropriate engineering controls Ensure adequate ventilation. Protective and hygiene measures When using do not eat, drink or smoke. Respiratory protection In the event of a major escape of electrolyte fluid, wear gas masks against organic gases. Hand protection Wear chemically resistant gloves. Eye protection Use protective goggles. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state: Colour: Odour: ph-value: Changes in the physical state Melting point: Boiling point: Flash point: Flammability Solid: Explosive properties No data available Oxidizing properties No data available Vapour pressure: Solubility in other solvents: 9.2. Other information Net weight: Nominal voltage: Nominal energy: 47 g 3,7 V 1,85 Wh two lithium-ion polymer cells, together with electronics encapsulated in PU block Test method

5 Print date: Page 5 of 10 SECTION 10: Stability and reactivity Reactivity The product is not reactive if handled and stored in a proper manner Chemical stability The product is stable when stored and handled appropriately Possibility of hazardous reactions When properly used, no hazardous reactions are expected Conditions to avoid Protect from short-circuiting, fire and direct sunlight Incompatible materials Do not store with metal objects Hazardous decomposition products Thermal decomposition can lead to harmful gases and vapors. Further information If stored for long durations, the capacity of the battery is reduced and the expected functional life is shortened. The housing can be damaged by leaking electrolyte. SECTION 11: Toxicological information Information on toxicological effects Toxicological tests Acute toxicity With proper use of the product no toxic effects are expected. Specific effects in experiment on an animal no test data Irritation and corrosivity Combustion products may cause irritation. SECTION 12: Ecological information Toxicity With proper handling no dangers to humans or the environment is to be expected from the product Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment The product does not meet the PBT or vpvb criteria in Annex XIII of the REACH Regulation Other adverse effects

6 Print date: Page 6 of 10 SECTION 13: Disposal considerations Waste treatment methods Advice on disposal The battery must never be disposed of as residual waste. A battery is hazardous waste and must only be disposed of by a collection system. Disposal according to official regulations. In order to prevent short-circuits and the accompanying heating, lithium batteries must never be stored or transported unprotected in bulk. The product is registered under the number: in accordance with the German Battery Act.

7 Print date: Page 7 of 10 SECTION 14: Transport information Land transport (ADR/RID) UN number: UN UN proper shipping name: Lithium-ion batteries in equipment or lithium-ion batteries packed with equipment Transport hazard class(es): Packing group: II Hazard label: 9 Classification code: M4 Special Provisions: Packing Instructions: P903 P903a P903b Limited quantity: 0 Transport category: 2 Tunnel restriction code: E Other applicable information (land transport) Excepted Quantity: E0 Simplified scheme according to special provision 188 for Lithium-ion batteries < 100 Wh Labeling / accompanying document at > 2 batteries Tare weight: Packing: Labeling: gross weight 30 kg Packaging that meets the test requirements for packing group II; Batteries, expect when installed inside equipment, shall be packed in strong outer and inner packagings that completely enclose the battery and protect the battery from short circuit. Batteries installed inside equipment shall be protected from damage and short circuit. Accidental activation must be prevented. Instructions: Each package shall be accompanied by a document containing the following information: an indication that the package contains "Lithium-ion batteries"; an indication that the package shall be handled with care and that a flammability hazard exists if the package is damaged; information that special procedures shall be followed if the package is damaged and that inspection and possible repackaging is necessary, and a telephone number for more information

8 Print date: Page 8 of 10 Marine transport UN number: UN UN proper shipping name: Lithium-ion batteries in equipment or lithium-ion batteries packed with equipment Transport hazard class(es): Packing group: II Hazard label: 9 Special Provisions: Packing Instructions: P903 Limited quantity: 0 EmS: F-A, S-I Other applicable information (marine transport) Excepted Quantity: E0 Simplified scheme according to special provision 188 for Lithium-ion batteries < 100 Wh Labeling / accompanying document at > 2 batteries Tare weight: Packing: Labeling: gross weight 30 kg Packaging that meets the test requirements for packing group II; Batteries, expect when installed inside equipment, shall be packed in strong outer and inner packagings that completely enclose the battery and protect the battery from short circuit. Batteries installed inside equipment shall be protected from damage and short circuit. Accidental activation must be prevented. Instructions: Each package shall be accompanied by a document containing the following information: an indication that the package contains "Lithium-ion batteries"; an indication that the package shall be handled with care and that a flammability hazard exists if the package is damaged; information that special procedures shall be followed if the package is damaged and that inspection and possible repackaging is necessary, and a telephone number for more information

9 Print date: Page 9 of 10 Air transport UN number: UN UN proper shipping name: Lithium-ion batteries in equipment or lithium-ion batteries packed with equipment Transport hazard class(es): Packing group: II Hazard label: 9 Net weight without equipment: Passenger 5kg / Cargo 35 kg Special Provisions: A48 (967) A88 (966) A99 A154 A164 A181 A182 A183 IATA-packing instructions Passenger: 966, 967 IATA- packing instructions Cargo: 966, 967 Other applicable information (Air transport) Excepted Quantity: E0 Passenger-LQ: E0 Simplified scheme according to IATA PI 966, 967 part II for Lithium-ion batteries < 100 Wh Labeling / accompanying document at > 2 batteries Packing: Labeling: Packaging that meets the test requirements for packing group II; Batteries, expect when installed inside equipment, shall be packed in strong outer and inner packagings that completely enclose the battery and protect the battery from short circuit. Batteries installed inside equipment shall be protected from damage and short circuit. Accidental activation must be prevented. Instructions: Each package shall be accompanied by a document containing the following information: an indication that the package contains "Lithium-ion batteries"; an indication that the package shall be handled with care and that a flammability hazard exists if the package is damaged; information that special procedures shall be followed if the package is damaged and that inspection and possible repackaging is necessary, and a telephone number for more information The hints Lithium ion batteries, not restricted und PI 965 must be noted in the Additional Handling Information (Field for additional handling information) on the air waybill, if one is used.

10 Print date: Page 10 of 10 Other applicable information Do not send damaged, defective or inoperative batteries! Batteries are tested in accordance with UN SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture This product safety data sheet was prepared based on a safety data sheet according to Regulation (EC) No 1907/2006. The relevant regulations have to be considered. SECTION 16: Other information Changes Further Information Version 1,00 - First Creation The information in this safety data sheet should describe the product with regard to the required safety precautions. It does not serve to guarantee any particular properties and is based on our current state of knowledge. The safety data sheet was produced on the basis of information from sub-suppliers. We accept no liability for loss or damage arising from the use of the information contained in this product safety sheet. (The data for the hazardous ingredients were taken respectively from the last information of the sub-contractor.)