Product Safety Data Sheet

Transcription

1 Page 1 of 15 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture Battery. The battery may only be charged with chargers specified in the operating instructions (charger by Nokia). Uses advised against Use only for the intended purpose Details of the supplier of the safety data sheet Company name: Street: Oskar-Messter-Straße Place: D Ismaning Telephone: +49 (089) Internet: info@pruftechnik.com Emergency telephone number: (24/7) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Lithium batteries are sealed gas-tight and harmless if the manufacturer s instructions are followed in use and handling Label elements Hazardous components which must be listed on the label 2.3. Other hazards The product is not subject to labeling. The product must not be short-circuited. Short-circuiting (even with metallic jewellery or tools) can cause a fire or burns due to high currents. Mechanical damage can lead to internal short-circuits. The high current flow causes the battery to heat up. Plastic housings can melt and catch fire. Under certain circumstances a mechanical defect may not be immediately recognizable. There may still be an internal short-circuit even a long time after the mechanical defect. The electrolyte is flammable. In case of electrolyte leakage, put the battery out of fire range immediately. If a battery burns, the vapors can irritate eyes, skin and the respiratory tract.

2 Page 2 of 15 SECTION 3: Composition/information on ingredients 3.2. Mixtures Chemical characterization No data available. Further Information The chemicals are contained in sealed cans, so they cannot leak when properly used. Under normal conditions of use, risk of exposure occurs only if the battery is mechanically abused. Note: Lithium batteries are articles. Under normal conditions no substances are released from lithium batteries. SECTION 4: First aid measures 4.1. Description of first aid measures General information First-aider: Pay attention to self-protection! After inhalation Escaping gases can cause respiratory irritation. Provide fresh air. Seek medical attention if problems persist. After contact with skin Skin contact may cause skin irritation. Wash skin with soap and water. After contact with eyes If product gets into the eye, keep eyelid open and rinse immediately with large quantities of water, for at least 5 minutes. Subsequently consult an ophthalmologist. After ingestion If electrolyte is swallowed, consult a doctor immediately Most important symptoms and effects, both acute and delayed Escaped electrolyte fluid can cause skin irritation, thermal and chemical burns Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing Dry chemical extinguishers fire classification D (dry powder). Fires involving lithium batteries in use can generally be fought with water; this should only be carried out by trained personnel with sufficient volumes of water, however.

3 Extinguishing media which must not be used for safety reasons High power water jet Special hazards arising from the substance or mixture When burned, hazardous fumes might arise. Page 3 of Advice for firefighters In case of fire: Wear self-contained breathing apparatus. Keep away from unprotected people. Keep upwind. Remove rechargeable batteries from the area of the fire if safe to do so. Additional information Extinguishing materials should be selected according to the surrounding area. Contaminated fire-fighting water must be collected separately. Remove according to the regulations. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Provide adequate ventilation Environmental precautions Preferably prevent the material from infiltrating the canalization or water courses. Do not contaminate surface waters Methods and material for containment and cleaning up Electrolyte can leak if the battery housing is damaged. Batteries must be hermetically sealed in a plastic bag and dry sand, chalk powder (CaCO 3 ) or vermiculite has to be added. Traces of electrolyte can be soaked up with dry sanitary paper. Direct contact with the skin must be avoided by wearing protective gloves. Skin must be rinsed with copious water Reference to other sections For waste disposal see section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Advice on safe handling Do not open, crush, disassemble, drop or solder the battery. Store the battery out of the reach of children. Advice on protection against fire and explosion Wrong handling can cause fire or explosion. Further information on handling Charge within temperature range of 0 C to +45 C. Discharge within temperature range of -20 C to +60 C Conditions for safe storage, including any incompatibilities Requirements for storage and vessels Storage temperature: Cool storage location preferably below 30 C. Relative room humidity: 0%-80% Maintaining optimum functionality: 10 C-20 C Advice on storage compatibility Keep in a cool place away from metals.

4 Page 4 of 15 SECTION 8: Exposure controls/personal protection 8.1. Control parameters Additional information on exposure limits Lithium batteries are articles. Under normal conditions no substances are released from lithium batteries Exposure controls Appropriate engineering controls Ensure adequate ventilation. Protective and hygiene measures When using do not eat, drink or smoke. Respiratory protection In the event of a major escape of electrolyte fluid, wear gas masks against organic gases. Hand protection Wear chemically resistant gloves. Eye protection Use protective goggles. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state: Colour: Odour: ph-value: Changes in the physical state Melting point: Boiling point: Flash point: Flammability Solid: Explosive properties No data available Oxidizing properties No data available Rechargeable battery, fixed not applicable not applicable Test method not applicable not applicable not applicable not applicable No data available Other information Net weight: Nominal voltage: Nominal energy: 22 g 3,7 V <10 Wh

5 Page 5 of 15 SECTION 10: Stability and reactivity Reactivity The product is not reactive if handled and stored in a proper manner Chemical stability The product is stable when stored and handled appropriately Possibility of hazardous reactions When properly used, no hazardous reactions are expected Conditions to avoid Protect from short-circuiting, fire and direct sunlight Incompatible materials Do not store with metal objects Hazardous decomposition products Thermal decomposition can lead to harmful gases and vapors. Further information If stored for long durations, the capacity of the battery is reduced and the expected functional life is shortened. The housing can be damaged by leaking electrolyte. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity With proper use of the product no toxic effects are expected. Irritation and corrosivity Escaped electrolyte fluid can cause skin irritation, thermal and chemical burns. Sensitising effects Based on available data, the classification criteria are not met. STOT single exposure Based on available data, the classification criteria are not met. Severe effects after repeated or prolonged exposure Based on available data, the classification criteria are not met. Carcinogenic/ mutagenic/ toxic effects for reproduction Based on available data, the classification criteria are not met. Aspiration hazard Based on available data, the classification criteria are not met. Specific effects in experiment on an animal No test data available. SECTION 12: Ecological information Toxicity With proper handling no dangers to humans or the environment is to be expected from the product Persistence and degradability No data available Bioaccumulative potential No data available Mobility in soil No data available Results of PBT and vpvb assessment The product does not meet the PBT or vpvb criteria in Annex XIII of the REACH Regulation Other adverse effects No data available.

6 Page 6 of 15 SECTION 13: Disposal considerations Waste treatment methods Advice on disposal The battery must never be disposed of as residual waste. A battery is hazardous waste and must only be disposed of by a collection system. Disposal according to official regulations. In order to prevent short-circuits and the accompanying heating, lithium batteries must never be stored or transported unprotected in bulk. The product is registered under the number: in accordance with the German Battery Act. SECTION 14: Transport information General Requirements The following requirements apply to all lithium-ion batteries: (a) Each cell and battery is of the type proven to meet the requirements of each test in the UN Manual of Tests and Criteria, Part III, subsection However, batteries and cells manufactured before 1 January 2014 conforming to a design type tested according to the requirements of the 5th revised edition of the UN Manual of Tests and Criteria, Part III, subsection 38.3 may continue to be transported. (b) Cells and batteries must be manufactured under a quality management program. (c) Cells and batteries identified by the manufacturer as being defective for safety reasons, or that have been damaged, that have the potential of producing a dangerous evolution of heat, fire or short circuit are forbidden for transport (e.g. those being returned to the manufacturer for safety reasons). Do not send damaged, defective or inoperative batteries! (d) Cells and batteries must be protected so as to prevent short circuits. This includes protection against contact with conductive materials within the same packaging that could lead to a short circuit.

7 Page 7 of 15 Land transport (ADR/RID) UN number: UN UN proper shipping name: Lithium-ion battery Transport hazard class(es): Packing group: II Hazard label: 9 Classification code: M4 Special Provisions: Packing P903 P903a P903b Limited quantity: 0 Transport category: 2 Tunnel restriction code: E Other applicable information (land transport) Excepted Quantity: E0 Simplified scheme according to special provision 188 for Lithium-ion batteries <100 Wh Tare weight: gross weight 30 kg Packing: Packaging that meets the test requirements for packing group II (see SP 188) an indication that the package shall be handled with care and that a flammability hazard exists if the package is damaged; information that special procedures shall be followed if the package is damaged and that inspection and possible repackaging is necessary, and

8 Page 8 of 15 Land transport (ADR/RID) UN number: UN UN proper shipping name: Lithium-ion batteries in equipment or lithium-ion batteries packed with equipment Transport hazard class(es): Packing group: II Hazard label: 9 Classification code: M4 Special Provisions: Packing P903 P903a P903b Limited quantity: 0 Transport category: 2 Tunnel restriction code: E Other applicable information (land transport) Excepted Quantity: E0 Simplified scheme according to special provision 188 for Lithium-ion batteries <100 Wh (Only for batteries packed in equipment: Labelling/instruction only for more than 2 batteries per package) Packing: Packaging that meets the test requirements for packing group II (see SP 188) an indication that the package shall be handled with care and that a flammability hazard exists if the package is damaged; information that special procedures shall be followed if the package is damaged and that inspection and possible repackaging is necessary, and

9 Page 9 of 15 Marine transport (IMDG) UN number: UN UN proper shipping name: Lithium-ion batteries Transport hazard class(es): Packing group: II Hazard label: 9 Special Provisions: Packing P903 Limited quantity: 0 EmS: F-A, S-I Other applicable information (marine transport) Excepted Quantity: E0 Simplified scheme according to special provision 188 for Lithium-ion batteries <100 Wh Tare weight: gross weight 30 kg Packing: Packaging that meets the test requirements for packing group II (see SP 188) an indication that the package shall be handled with care and that a flammability hazard exists if the package is damaged; information that special procedures shall be followed if the package is damaged and that inspection and possible repackaging is necessary, and

10 Page 10 of 15 Marine transport (IMDG) UN number: UN UN proper shipping name: Lithium-ion batteries in equipment or lithium-ion batteries packed with equipment Transport hazard class(es): Packing group: II Hazard label: 9 Special Provisions: Packing P903 Limited quantity: 0 EmS: F-A, S-I Other applicable information (marine transport) Excepted Quantity: E0 Simplified scheme according to special provision 188 for Lithium-ion batteries <100 Wh (Only for batteries packed in equipment: Labelling/instruction only for more than 2 batteries per package) Packing: Packaging that meets the test requirements for packing group II (see SP 188) an indication that the package shall be handled with care and that a flammability hazard exists if the package is damaged; information that special procedures shall be followed if the package is damaged and that inspection and possible repackaging is necessary, and

11 Page 11 of 15 Air transport (ICAO) UN number: UN UN proper shipping name: Lithium-ion batteries Transport hazard class(es): Packing group: II Hazard label: 9 Gross weight: Passenger 5kg / Cargo 35 kg Special Provisions: A51 A88 A99 A154 A164 A183 IATA-packing instructions Passenger / Cargo: 965 Other applicable information (Air transport) Excepted Quantity: E0 Passenger-LQ: forbidden Simplified scheme according to PI 965 for Lithium-ion batteries 100 Wh / more than 2 batteries Packing: Cells and batteries must be packed in inner packaging that completely enclose the cell or battery and then placed in a strong outer packaging (PI 965 Section IB). Quantity per package: Passenger aircraft (PAX) = 10 kg G Cargo Aircraft Only (CAO) = 10 kg G an indication that the package shall be handled with care and that a flammability hazard exists if the package is damaged; information that special procedures shall be followed if the package is damaged and that inspection and possible repackaging is necessary, and

12 Page 12 of 15 The following information must be contained on the air waybill when used, or in the appropriate location on alternative transport documentation. The information required by 2., 3. and 4. below must be shown in the Nature and Quantity of Goods box of the air waybill. The information required is as follows and should be shown in the following order: 1. name and address of the shipper and consignee 2. UN Lithium ion batteries, PI 965, IB 4. number of packages and the gross weight of each package Simplified scheme according to PI 965 section II for Lithium-ion batteries >2,7 Wh and max. 100 Wh / max. 2 batteries Packing: Cells and batteries must be packed in inner packaging that completely enclose the cell or battery then placed in a strong outer packaging (PI 965 Section II). an indication that the package shall be handled with care and that a flammability hazard exists if the package is damaged; information that special procedures shall be followed if the package is damaged and that inspection and possible repackaging is necessary, and The words Lithium ion batteries in compliance with Section II of PI 965 must be included on the air waybill, when an air waybill is used. The information should be shown in the Nature and Quantity of Goods box of the air waybill. Any person preparing or offering cells or batteries for transport must receive adequate instruction on these requirements commensurate with their responsibilities.

13 Page 13 of 15 Air transport (ICAO) UN number: UN UN proper shipping name: Lithium-ion batteries packed in equipment Transport hazard class(es): Packing group: II Hazard label: 9 Net weight without equipment: Passenger 5kg / Cargo 35 kg Special Provisions: A88 A99 A154 A164 A183 IATA-packing instructions Passenger / Cargo: 967 Other applicable information (Air transport) Excepted Quantity: E0 Passenger-LQ: forbidden Simplified scheme according to PI 967 section II for Lithium-ion batteries with 100 Wh (Labelling and instruction only for packages with more than 2 batteries contained in equipment) Packing: The equipment must be packed in strong outer packaging constructed of suitable material of adequate strength and design in relation to the packaging's capacity and its intended use unless the cell or battery is afforded equivalent protection by the equipment in which it is contained (PI 967 section II). Net quantity per package: Passenger aircraft (PAX) = 5 kg net Cargo Aircraft Only (CAO) = 5 kg net an indication that the package shall be handled with care and that a flammability hazard exists if the package is damaged; information that special procedures shall be followed if the package is damaged and that inspection and possible repackaging is necessary, and

14 Page 14 of 15 Where a consignment includes packages bearing the lithium battery handling label, the words Lithium ion batteries in compliance with Section II of PI 967 must be included on the air waybill, when an air waybill is used. The information should be shown in the Nature and Quantity of Goods box of the air waybill. Any person preparing or offering cells or batteries for transport must receive adequate instruction on these requirements commensurate with their responsibilities. Air transport (ICAO) UN-number: UN UN proper shipping name: Lithium-ion batteries packed with equipment Transport hazard class(es): Packing group: II Hazard label: 9 Net weight without equipment: Passenger 5kg / Cargo 35 kg Special Provisions: A88 A99 A154 A164 A181 A185 IATA- packing instructions Passenger / Cargo: 966 Other applicable information (Air transport) Excepted Quantity: E0 Passenger-LQ: forbidden Simplified scheme according to PI 966 section II for Lithium-ion batteries; 100 Wh (The maximum number of batteries in each package must be the minimum number required to power the equipment plus two spares.) Packing: Lithium ion cells and batteries must be placed in inner packaging that completely enclose the cell or battery then placed in a strong outer packaging; or be placed in inner packaging that completely enclose the cell or battery, then placed with equipment in a strong outer packaging. The equipment must be secured against movement within the outer packaging and must be equipped with an effective means of preventing accidental activation. (PI 966 section II).

15 Page 15 of 15 Net quantity per package: Passenger aircraft (PAX) = 5 kg Cargo Aircraft Only (CAO) = 5 kg an indication that the package shall be handled with care and that a flammability hazard exists if the package is damaged; information that special procedures shall be followed if the package is damaged and that inspection and possible repackaging is necessary, and The words Lithium ion batteries in compliance with Section II of PI 966 must be included on the air waybill, when an air waybill is used. The information should be shown in the Nature and Quantity of Goods box of the air waybill. Any person preparing or offering cells or batteries for transport must receive adequate instruction on these requirements commensurate with their responsibilities Environmental hazards DANGEROUS TO THE ENVIRONMENT: no Special precautions for the user See instruction Transport in bulk regarding to Annex II of MARPOL 73/78 and the IBC Code not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture This product safety data sheet was prepared based on a safety data sheet according to Regulation (EC) No 1907/2006. The relevant regulations have to be considered. SECTION 16: Other information Changes Further Information Version 1,00 First Creation Version 1,10 General Revision The information in this safety data sheet should describe the product with regard to the required safety precautions. It does not serve to guarantee any particular properties and is based on our current state of knowledge. The safety data sheet was produced on the basis of information from sub-suppliers. We accept no liability for loss or damage arising from the use of the information contained in this product safety sheet. (The data for the hazardous ingredients were taken respectively from the last information of the sub-contractor.)