- Stainless Steel. - Titanium. Your Partner for

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1 - Alloy steel - Stainless Steel - Nickel and Nickel Alloys - Titanium Your Partner for Piping Systems

2 TPS-Technitube Röhrenwerke GmbH a privat owned company with head office, production and stock in Daun / Germany is a worldwide renowed, reliable and competent partner in piping, tubing, fitting, flanges, plates and bars. We are in the market with competence and uncompromising commitment to quality since more than 35 years. Our closest price calculation puts our customers in the front of their competition. TPS-Technitube Röhrenwerke GmbH your flexible partner for pipes, fittings, flanges, plates and bars and other accessories for chemical and petrochemical industry, energy- and offshore technology, paper and pharma industry. With this catalogue we like to introduce you a part of our possibilities for: Stainless Steel, Nickel and Nickel Alloys and Titanium: - to ASTM or ASME - in accordance to DIN/EN - or other international standards on request Products: - seamless and welded tubes and pipes - forged and buttweld fittings - flanges and special forged parts acc. to your design - plates and bars in size range from 1/4 OD 72 NB Our service: - a well assorted stock - just in time logistics - mill production Head office Technical advisory service: - qualified personal - quality management system Material testing and documentation: - acc. to EN 10204/2.1, EN 10204/2.2, EN 10204/3.1 and EN 10204/3.2 Please sent your enquiries to: TPS-Technitube Röhrenwerke GmbH Tel.: (+49) Julius Saxler Str. 7 Fax: (+49) Daun service@tpsd.de Germany Internet: Partview of our store Partial view of the Technitube pipe mill

3 Stainless Steels Alloy steel Chemical composition and mechanical properties Grade DIN/EN %C %Mn %P %S %SI %Cr %Mo Others max. max. P1 15Mo P5 12 CrMo 19 5 V 0.15 max max P9 X 12 CrMo max P11 13 CrMo P22 10 CrMo max P91 X 10 CrMoVNb V = N = Ni = 0.40 max. Al = 0.02 max. Cb = Ti = 0.01 max. Zr = 0.01 max. P max V = N = Ni = 0.40 max. Al = 0.02 max. Cb = max. W = B = Ti = 0.01 max. Zr =0.01 max. Grade DIN/EN Heat Treat Type Tensile Strength Yield Strength Elongation min. min. (4D) % min. Longitudinal Transverse P1 15Mo3 Full or isothermal anneal 55 ksi 30 ksi normalize & temper (380 MPa) (205 MPa) subcritical anneal P5 12 CrMo 19 5 V Full or isothermal anneal 60 ksi 30 ksi normalize & temper (415 Mpa) (205 MPa) P9 X 12 CrMo 9 1 Full or isothermal anneal 60 ksi 30 ksi normalize & temper (415 Mpa) (205 MPa) P11 13 CrMo 4 4 Full or isothermal anneal 60 ksi 30 ksi normalize & temper (415 Mpa) (205 MPa) P22 10 CrMo 9 10 Full or isothermal anneal 60 ksi 30 ksi normalize & temper (415 Mpa) (205 MPa) P91 X 10 CrMoVNb 9 1 normalize & temper 85 ksi 60 ksi quench & temper (585 MPA) (415 Mpa) P92 normalize & temper 90 ksi 64 ksi (620 Mpa) (440 Mpa) 3

4 Stainless Steels Austenitic, Ferritic and Martensitic Stainless Steel Austenitic Stainless Steel Material Standard: Tubes and Pipes: ASTM A 213 / 249 / 269 / 312 / 358 / 688 Fittings: ASTM A 403 Flanges: ASTM A 182 Grade UNSNo C Si Mn P S TP 304 S max 0.75 max 2.00 max max max TP 304 H S max 2.00 max max max TP 304 N S max 0.75 max 2.00 max max max TP 304 LN S max 0.75 max 2.00 max max max TP 304 L S max 0.75 max 2.00 max max max TP 309 S S max 0.75 max 2.00 max max max TP 310 S S max 0.75 max 2.00 max max max TP 316 S max 0.75 max 2.00 max max max TP 316 H S max 2.00 max max max TP 316 L S max 0.75 max 2.00 max max max TP 316 N S max 0.75 max 2.00 max max max TP 316 LN S max 0.75 max 2.00 max max max TP 317 S max 0.75 max 2.00 max max max TP 317 L S max 0.75 max 2.00 max max max TP 321 S max 0.75 max 2.00 max max max TP 321 H S max 2.00 max max max TP 347 S max 0.75 max 2.00 max max max TP 347 H S max 2.00 max max max TP 904 L N max 1.00 max 2.00 max max max Ferritic and Martensitic Stainless Steel Material Standard: Tubes and Pipes: ASTM A 268 / 312 / 358 Fittings: ASTM A 403 / 815 Flanges: ASTM A 182 Grade UNSNo C Si Mn P S TP 405 S max 0.75 max 1.00 max max max TP 410 S max 0.75 max 1.00 max max max TP 429 S max 0.75 max 1.00 max max max TP 430 S max 0.75 max 1.00 max max max TP S max 0.75 max 1.50 max max max TP S max 0.75 max 1.50 max max max TP 409 S max 1.00 max 1.00 max max max TP 430 TI S max 1.00 max 1.00 max max max Ferritic and Martensitic Stainless Steel Material Standard Tubes and Pipes: ASTM A 789 / 790 Fittings: ASTM A 403 / 815 Flanges: ASTM A 182 Manufacturing Process Seamless or welded UNSNo C Si Mn P S Ni Cr Mo S max 1.00 max 2.00 max max max S max max max S ,04 max 1.00 max 1.50 max max max S max 1.00 max 2.00 max max max S max 0.75 max 1.00 max max max S max 1.00 max 2.50 max max max OD 1 in [25mm] and Under OD over 1 in. [25 mm] S max 0.80 max 1.20 max max max S max 1.00 max 1.00 max max max Not mentioned grades on request. 4

5 Stainless Steels Chemical composition and mechanical properties Plates: ASTM A 167 / 240 Bars: ASTM A 276 / 479 Ni Cr Mo Others YS min TS min El.* KSI [MPa] KSI [MPa] min [205] 75[515] [205] 75[515] N [240] 80[550] N [205] 75[515] [170] 70[485] [205] 75[515] max 30[205] 75[515] [205] 75[515] [205] 75[515] [170] 70[485] N [240] 80[550] N [205] 75[515] [205] 75[515] [205] 75[515] Ti Ž 5xC, max 0.60% 30[205] 75[515] Ti Ž 4xC, max 0.60% 30[205] 75[515] (Cu + Ta) Ž 10xC, max 1.00% 30[205] 75[515] (Cu + Ta) Ž 8xC, max 1.00% 30[205] 75[515] Cu [215] 71[490] 35 Plates: ASTM A 240 Bars: ASTM A 276 / 479 Ni Cr Mo Others YS min TS min El.* KSI [MPa] KSI [MPa] min 0.50 max Al [205] 60[415] max [215] 60[415] max [240] 60[415] max [240] 60[415] max N [275] 70[485] max N [275] 65[450] max Ti 6xC min; 0.75 max 30[205] 55[380] max Ti 5xC min; 0.75 max 35[240] 60[415] 20 Plates: ASTM A 240 Bars: ASTM A 276 / 479 N Cu Others YS TS El* Brinell Rockwell KSI [MPa] KSI [MPa] min max C max [450] 90[620] [440] 92[630] [550] 110[760] [450] 100[690] W [450] 100[690] [450] 100[690] [400] 87[600] max... 80[550] 116[800] W [550] [ ] Mechanical properties all at roomtemperature *Elongation in 2 in or 50 mm, (or 4D), min, % 5

6 Nickel and Nickel Alloys Grades Chemical Composition Grade C max. Si max. Mn max. P max. S max. Cr Ni UNSN ,150 0,35 0,35-0,010-99,0 min UNSN ,020 0,35 0,35-0,010-99,0 min UNSN ,300 0,50 2,00-0,024-63,0 min UNSN ,150 0,50 1,00-0,015 14,0-17,0 72,0 min UNSN ,100 0,50 1,50-0,015 21,0-25,0 58,0-63,0 UNSN ,100 0,50 0,50 0,015 0,015 20,0-23,0 58,0 min UNSN ,100 1,00 1,50 0,030 0,015 19,0-23,0 30,0-35,0 UNSN ,750 1,00 1,50 0,030 0,015 19,0-23,0 30,0-35,0 UNSN ,750 1,00 1,50 0,030 0,015 19,0-23,0 30,0-35,0 UNSN ,050 0,50 1,00-0,030 19,5-23,5 38,0-46,0 UNSN ,070 1,00 2,00 0,045 0,035 19,0-21,0 32,0-38,0 UNSN ,010 0,08 1,00 0,040 0,030 14,5-16,5 remainder UNSN ,015 0,08 0,500 0,020 0,020 20,0-22,5 remainder UNSN ,020 0,10 1,000 0,040 0,030 1,00 max remainder Not mentioned grades on request. 6

7 Nickel and Nickel Alloys Grades PHYSICAL PROPERTIES TS min. YS min. EL min.* Mo Ti Others KSi (MPa) KSi (MPa) - - Cu 0,25 max, Fe 0,40 max 55 (380) 15 (105) Cu 0,25 max, Fe 0,40 max 50 (345) 12 (80) Cu 28,0-34,0;Fe 2,5 max. 70 (483) 25 (172) Cu 0,5 max; Fe 6,0-10,0 80 (552) 35 (241) Cu 1,0 max, Fe remainder 80 (550) AL 1,0-1,70 30 (205) 30 8,0-10,0 0,40 max. CB + Ta 3,15-4,15, Fe max 5,0; AL max 0,40; Ti max 0, (827) 60 (414) 30-0,15-0,60 Cu 0,75 max;ai 0,15-0,6:Fe 39,5 min 75 (517) 30 (207) 30-0,15-0,60 Cu 0,75 max;ai 0,15-0,6:Fe 39,5 min 65 (172) 25 (172) 30-0,15-0,60 Cu 0,75 max;ai 0,15-0,6:Fe 39,5 min 65 (172) 25 (172) 30 2,5-3,5 0,60-1,20 Cu 1,5-3,0; AI 0,2 max, Fe min 22,0; Ti 0,6-1,2 85 (586) 35 (241) 30 2,0-3,0 - Cu 3-4;NB+Ta 8xC max. 1,0; Fe remainder 80 (551) 35 (241) 30 15,0-17,0 - W 3,0-4,5, Fe 4,0-7,0, Cu 2,5 max, V 0,35 max 100 (690) 41 (283) 40 12,5-14,5 - Fe 2,0-6,0, V 0,35 max Cu 2,5 max 100 (690) 45 (310) 45 26,0-30,0 - Fe 2,0 max 110 (760) 51 (350) 40 a. m. values are for annealed condition and for indication only (values may change depending on size required) * Elongation in 2 IW or 50 mm(or 4D), % 7

8 NICKEL AND NICKEL ALLOYS THE STANDARDS UNS-GRADE TUBES PIPES FITTINGS FLANGES PLATES BARS UNSNO 2200/2201 ASTM B 161 ASTM B 161 ASTM B 366 ASTM B 564 ASTM B 162 ASTM B 160 ASTM B 163 ASTM B 725 ASTM B 730 ASTM B 775 ASTM B 751 ASTM B 829 UNSNO 4400 ASTM B 163 ASTM B 165 ASTM B 366 ASTM B 564 ASTM B 127 ASTM B 164 ASTM B 165 ASTM B 725 ASTM B 730 ASTM B 775 ASTM B 751 ASTM B 829 UNSNO 6600 ASTM B 163 ASTM B 167 ASTM B 366 ASTM B 564 ASTM B 168 ASTM B 166 ASTM B 516 ASTM B 517 ASTM B 751 ASTM B 775 ASTM B 829 UNSNO 6601 ASTM B 163 ASTM B 167 ASTM B 366 ASTM B 564 ASTM B 168 ASTM B 166 ASTM B 167 ASTM B 829 ASTM B 751 ASTM B 775 UNSNO 6625 ASTM B 444 ASTM B 444 ASTM B 366 ASTM B 564 ASTM B 443 ASTM B 446 ASTM B 705 ASTM B 704 ASTM B 775 ASTM B 775 ASTM B 829 ASTM B 829 UNSNO 8800 ASTM B 407 ASTM B 407 ASTM B 366 ASTM B 564 ASTM B 409 ASTM B 408 UNSNO 8810 ASTM B 515 ASTM B 514 UNSNO 8811 ASTM B 751 ASTM B 775 ASTM B 829 ASTM B 829 UNSNO 8825 ASTM B 163 ASTM B 423 ASTM B 366 ASTM B 564 ASTM B 424 ASTM B 425 ASTM B 704 ASTM B 705 ASTM B 751 ASTM B 775 ASTM B 829 UNSN10276 ASTM B 757 ASTM B 619 ASTM B 366 ASTM B 564 ASTM B 575 ASTM B 574 ASTM B 622 ASTM B 622 ASTM B 626 ASTM B 829 ASTM B 775 UNSN06022 ASTM B 516 ASTM B 619 ASTM B 366 ASTM B 564 ASTM B 575 ASTM B 574 ASTM B 622 ASTM B 622 ASTM B 626 ASTM B 775 ASTM B 751 ASTM B 829 UNSN10665 ASTM B 622 ASTM B 619 ASTM B 366 ASTM B 564 ASTM B 333 ASTM B 335 ASTM B 626 ASTM B 622 UNSNO 8020 ASTM B 468 ASTM B 464 ASTM B 366 ASTM B 462 ASTM B 464 ASTM B 473 ASTM B 729 ASTM B 729 ASTM B 751 ASTM B 829 Not mentioned grades on request. 8

9 ASA Pipe Schedule acc. to. ANSI B OD STD XS mm 5s 5 10s s s XXS 1/ / / / / / / / / = Wall thickness in mm 0.81 = kg/m Identical with STD and 40s Identical with XS and 80s 9

10 Titanium and Titanium Alloys Chemical composition, mechanical properties and heat treatment Materialstandard: Tubes and Pipes: ASTM B 337 / 338 / 861 / 862 Fittings: ASTM B 363 Flanges: ASTM B 348 Chemical Composition Titanium Grades N C H Fe O Al V Pa Mo Ni % max % max % max % max % max % max % max Grade 1 0,03 0,08 0,015 0,20 0, ,05 0,06 0,013* 0,15 0, Grade 2 0,03 0,08 0,015 0,30 0, ,05 0,06 0,013* 0,20 0, Grade 3 0,05 0,08 0,015 0,30 0, ,05 0,06 0,013* 0,25 0, Grade 7 0,03 0,08 0,015 0,30 0, ,12-0, ,05 0,06 0,013* 0,20 0, ,05-0, Grade 9 0,02 0,08 0,015 0,25 0,15 2,5-3,5 2,0-3, Grade 11 0,03 0,08 0,015 0,20 0, ,12-0, ,05 0,06 0,013* 0,20 0, ,15-0, Grade 12 0,03 0,08 0,015 0,30 0, ,2-0,4 0,6-0, ,04 0,05 0,015 0,30 0,12 2,5-3,5 2,0-3, * In case wallthickness is under 2 mm, the Hydrogen content up to 0,015% is allowed. 10

11 Titanium and Titanium Alloys Plates: ASTM B 265 Bars: B 348 Mechanical properties and heat treatment Residuals Residuals Titanium Rp 0,2 N/mm 2 Rp 1,0 N/mm 2 Rm N/mm 2 A5 % Heat Treatment Each max Total max min. max. min. min. max. min. 0,1 0,4 Rem min. 24 annealed 0,1 0,4 Rem soft annealed 0,1 0,4 Rem min. 20 annealed 0,1 0,4 Rem soft annealed 0,1 0,4 Rem min. 18 annealed 0,1 0,4 Rem soft annealed 0,1 0,4 Rem min. 20 annealed 0,1 0,4 Rem soft annealed 0,1 0,4 Rem annealed 0,1 0,4 Rem annealed 0,1 0,4 Rem soft annealed 0,1 0,4 Rem annealed 0,1 0,4 Rem min. 15* soft annealed * Wall thickness under 1 mm 12% View of pilger process area 11

12 Fittings Buttweld fittings, either seamless or welded, acc. to ANSI B 16.9 or MSS SP 43 or DIN in size range 1 / 2 NB 60 NB - Elbows, 45, 90 and 180, long or short radius - Tees, equal and unequal - Reducers, concentric and eccentric - Caps or acc. to your special design Forged fittings acc. to ANSI B 16.11, in size range from 1 / 4 NB 12 NB, in 3000 LBS, 6000 LBS and 9000 LBS - socket weld - threaded (NPT) - butt weld 12

13 Dimensional Tolerances for buttweld Fittings Elbows L.R. or S.R. 180 return bends Caps T O.D. T O.D. 45 m A 90 T O.D. Equal or reducing Tees Stub ends Eccentric & concentric reducers O.D. T 2 O.D. 2 T O.D. 2 O.D. 2 T 2 T 2 M T 1 F H H O.D. 1 R C ANSI B16-9 C G T O.D. 1 T 1 O.D. 1 T 1 All Fittings 90 and 45 Elbows and Tees Reducers and Lap Joint Stub Ends Caps 180 Returns Lap-Joint Stub Ends Nominal Pipe Size Outside Diameter at Bevel Inside Diameter at End Wall Thickness Center-to End Dimension A B C M Overall Length F H Overall Length E Center-to Centre Dimension P Back-to- Alignment Face of End Dimension K U Outside Diameter of Lap G Thickness of Lap T Fillet Radius of Lap R 1/2 to 21/ ±0.76 ±1.52 ±1.52 ±3.05 ±6.35 ±6.35 ± to 3 1/2 ±1.52 ±1.52 ±1.52 ±1.52 ±3.05 ±6.35 ±6.35 ± ±1.52 ±1.52 ±1.52 ±3.05 ±6.35 ±6.35 ± to ±1.52 Not less ±1.52 ±1.52 ±6.35 ±6.35 ±6.35 ± than to ± % of ±2.29 ±2.29 ±6.35 ±9.65 ±6.35 ± nominal to ±4.83 thickness ±2.29 ±2.29 ±6.35 ±9.65 ±6.35 ± to ±4.83 ±3.05 ±4.83 ± to ±4.83 ±4.83 ±4.83 ±

14 Flanges Production range WEDLING-NECK Size: 1/4 NB to 72 NB. Pressure Ratings: ANSI B 16.5: 150 lb. to 2500 lb. DIN: PN 10 - PN 100 SLIP-ON BLIND Dimensional Standards: ANSI B 16.5, BS 1560, API 605, BS 3293 BS 10, BS 4504, MSS SP44, DIN/EN, API 6A, AWWA Types: WeldingNeck, Slip-On, Socket-Weld, Blind, Spectacle, Spades, Spacers, Slip-Blinds, TEMA, Nozzle Flanges, Long Welding-Necks, Orifice, Swivel-ring, Anchor Flanges, `SPECIAL` to customers drawings. SOCKET-WELD THREADED LAP-JOINT SPECIAL EXECUTIONS ON REQUEST 14

15 TPS complete delivery programme Stainless Steel & Nickel Alloy Tubes Seamless Coldfinished Stainless Steel and Nickel Alloy Tubes; Welded Stainless Steel Tubes with Cold Worked Seam; Welded, Colddrawn and Heattreated Stainless Steel Tubes; Seamless and Welded Heatexchanger Tubes in Stainless Steel and Nickel Alloy Grades. Size Range 6-60,3 mm Outside Diameter, also U-bended. Grades Stainless Steel: AISI 304 (1.4301), 304L (1.4306), 321 (1.4541), 316 (1.4401/1.4436), 316 L (1.4404/1.4435), 316 Ti (1.4571); Special Ferritic Grades like AISI 405 (1.4002), 410 (1.4006), 430 (1.4016) Special Grades: TECHNICHROMO 904 L UNS N 08904, TECHNIDUPLEX 2205 UNS S 31803, DUPLINOS 1905 UNS S 31500, TECRONIMO , etc.; Nickel Alloys like TECHALLOY 200, 400, 600, 800, 825, 8020; Heat resisting Grades such as AISI 310/S and AISI 347. Titanium Heat Exchanger Tubes in lengths up to 21 m - U-Tubes -OCTG PRODUCT & DELIVERY PROGRAMME: Tubing and Casing from new production or ex stock with Multiseal gastight Premium Two-Step Integral Joint Connections: -Multiseal-TS 4 / TS 4 TR -Multiseal-TS 6 / TS 6 TR -Multiseal TS 8 / TS 8 TR -Multiseal-Flush-Joint Techniseal Premium Coupling Connection Optiflow High Performance Coupling Connection API Connections as per API Spec. 5B Tubing and Casing available in all Sizes and Grades according to API 5CT and also -Special Grades. Pup Joints, Cross-Overs, Couplings, Blast Joints and Accessories in all Grades and Sizes according to Specification. Drill-Pipe as per API Standard 5D in all grades & sizes up to 5 1/2" incl. Heatexchanger & Condenser Tubes ex stock Carbon steel: A 179, A 214, ST 35.8 I, Alloy steel: A 213/A 199, T 5, T 9 Stainless steel: ASTM A 213 TP, 304/L, 321, 316/L, 316Ti Non Ferrous: Aluminium brass, AL 687, Admiralty brass AL 443, Copper Nickel 90/10, AL 706, Copper Nickel 90/30, AL 715 Seamless Stainless Steel Pipes, Fittings and Flanges ex Stock and from new production Stock Material Grades: TP 304/1.4301, TP 304L/1.4306, TP 321/1.4541, TP 316/1.4401, TP 316L/1.4404, TP 316Ti/ Stock Sizes: O.D.: 1/2" NB - 12" NB; W.T.: Sch 10S, Sch 40S, 80S, 160 O.D.: 21,3 mm - 323,9 mm; W.T.: 2,11-33,32 mm Fittings in Special Grades for your Piping Systems Specification/Standards according to ASTM, DIN/EN, BS and other international documentation; in form of: Seamless and Welded Buttweld Fittings, Forged Fittings, Flanges, Forgings, Fittings as per drawing and components according to your design. Specification: ASTM A 403, ASTM B 366, ASTM A 815, ASTM B 363, ASTM A 420, ASTM A 182, ASTM A 350, ASTM A 234. Seamless Stainless Steel Tubes -Multiseal-TS-8 Pin End Fittings & Flanges Heatexchanger- and Condenser Tubes in NON - FERROUS Grades Thinwalled Seamless Coldfinished Stainless Steel Tubes Complete 'Piping Packages' in Stainless Steel Special Grades, e.g. TECHNICROMO 904 L UNS N 08904, TECHNIDUPLEX 2205 UNS S and in Nickel Alloys. The quality management system of according to ISO production, stock holding and trade is certified Finned Tubes 15

16 TPS App View our catalogues on your mobile device! Julius-Saxler-Straße Daun/Germany P.O. Box Daun/Germany Tel.: (+49) Fax: (+49) service@tpsd.de /2015