Safety Data Sheet (SDS)

Transcription

1 Safety Data Sheet (SDS) Part # Z12450 Issuing Date 01-Jan-2014 Revision Number 0 Product Name 1. PRODUCT AND COMPANY IDENTIFICATION #62512, #62517,#11, #22, BX6478 Brown Tripoli General Purpose Buffing Wheel Compound Recommended Use Supplier Address Formax Manufacturing Corporation 168 Wealthy St. SW, Grand Rapids, Michigan, US Phone: Fax: Contact: Andrew Johnston Contact Phone: Emergency Phone: Metal finishing. Metal polish. Proper Shipping Name: NMFC Scouring Compound (Cake, Paste or Liquid form N.O.I.) / Polishing Wheels /clc-70 Additional Hazard Classes (As Applicable): ne Listed --- Shipping t Regulated by D.O.T. Chemical Family: Organic / Inorganic Mixture Reportable Quantities: ne Formula: Proprietary Formula Abrasive/Grease Mixture Company Emergency Phone Number HAZARDS IDENTIFICATION CAUTION! Emergency Overview May cause skin and eye irritation Appearance Red brown, Brown Physical State Solid. Odor Fatty odor Potential Health Effects Principle Routes of Exposure Acute Toxicity Eyes Skin Inhalation Ingestion Chronic Effects Aggravated Medical Conditions Environmental Hazard Eye contact. Skin contact. May cause irritation. May cause irritation. Repeated exposure may cause skin dryness or cracking. t an expected route of exposure. hazard from product as supplied. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. This product contains carbon black in a non-respirable form. Inhalation of carbon black is unlikely to occur from exposure to this product. Carbon black has been classified by the International Agency for Research on Cancer (IARC) as possibly carcinogenic to humans (Group 2B) by inhalation. This product contains crystalline silica (quartz) in a non-respirable form. Inhalation of crystalline silica is unlikely to occur from exposure to this product. Preexisting eye disorders. Skin disorders. See Section 12 for additional Ecological Information. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS- Weight % Silica-tripoli Page 1 / 7

2 Stearic acid Petrolatum Quartz Carbon black FIRST AID MEASURES Eye Contact Skin Contact Inhalation Ingestion tes to Physician Rinse thoroughly with plenty of water, also under the eyelids. If symptoms persist, call a physician. Wash skin with soap and water. In the case of skin irritation or allergic reactions see a physician. Move to fresh air. If symptoms persist, call a physician. Do NOT induce vomiting. Drink plenty of water. If symptoms persist, call a physician. Treat symptomatically. 5. FIRE-FIGHTING MEASURES Flammable Properties Flash Point Suitable Extinguishing Media Uniform Fire Code Hazardous Combustion Products Explosion Data Sensitivity to Mechanical Impact Sensitivity to Static Discharge t flammable. t determined. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Irritant: Liquid Carbon oxides... Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA Health Hazard 1 Flammability 0 Stability 0 Physical and Chemical Hazards - 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Avoid contact with eyes. Environmental Precautions Refer to protective measures listed in Sections 7 and 8. Methods for Containment Methods for Cleaning Up Prevent further leakage or spillage if safe to do so. Use personal protective equipment. Soak up with inert absorbent material. Pick up and transfer to properly labeled containers. 7. HANDLING AND STORAGE Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes and clothing. Storage Keep container tightly closed. Page 2 / 7

3 Exposure Guidelines 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Carbon black TWA: 3.5 mg/m 3 TWA: 3.5 mg/m 3 (vacated) TWA: 3.5 mg/m 3 IDLH: 1750 mg/m 3 TWA: 0.1 mg/m 3 TWA: 3.5 mg/m 3 Silica-tripoli TWA: mg/m 3 (vacated) TWA: 0.1 mg/m 3 IDLH: 50 mg/m Quartz NIOSH IDLH: Immediately Dangerous to Life or Health TWA: 0.05 mg/m 3 TWA: mg/m 3 (vacated) TWA: 0.1 mg/m 3 IDLH: 50 mg/m 3 TWA: 0.05 mg/m 3 Other Exposure Guidelines Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Engineering Measures Personal Protective Equipment Eye/Face Protection Skin and Body Protection Respiratory Protection Hygiene Measures Showers Eyewash stations Ventilation systems special protective equipment required. Protective gloves. protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required. Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Red brown, Brown. Odor Fatty odor. Odor Threshold information available Physical State Solid ph information available Flash Point t determined. Autoignition Temperature information available Decomposition Temperature information available Boiling Point/Range information available Melting Point/Range information available Flammability Limits in Air information available Explosion Limits information available Water Solubility Negligible Solubility information available Evaporation Rate information available Vapor Pressure data available Vapor Density data available VOC Content(%) t applicable Partition Coefficient: n- octanol/water 10. STABILITY AND REACTIVITY Stability Incompatible Products Conditions to Avoid Stable under recommended storage conditions. ne known. ne known. Hazardous Decomposition Products Carbon oxides. Hazardous Polymerization Hazardous polymerization does not occur. Page 3 / 7

4 Acute Toxicity Product Information 11. TOXICOLOGICAL INFORMATION Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation Carbon black mg/kg ( Rat ) 3 g/kg ( Rabbit ) - Petrolatum mg/kg ( Rabbit ) - Quartz 500 mg/kg ( Rat ) - - Chronic Toxicity Chronic Toxicity Carcinogenicity This product contains carbon black in a non-respirable form. Inhalation of carbon black is unlikely to occur from exposure to this product. Carbon black has been classified by the International Agency for Research on Cancer (IARC) as possibly carcinogenic to humans (Group 2B) by inhalation. This product contains crystalline silica (quartz) in a non-respirable form. Inhalation of crystalline silica is unlikely to occur from exposure to this product. The table below indicates whether each agency has listed any ingredient as a carcinogen. This product contains carbon black which is classified as a possible carcinogen when present as respirable dust. This is not relevant for this product since it is not in a respirable form. This product contains crystalline silica (quartz) in a non-respirable form. Inhalation of crystalline silica is unlikely to occur from exposure to this product. Chemical Name ACGIH IARC NTP OSHA Carbon black Group 2B X Quartz Group 1 Known X IARC: (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans Group 2B - Possibly Carcinogenic to Humans NTP: (National Toxicity Program) Known - Known Carcinogen OSHA: (Occupational Safety & Health Administration) X - Present Target Organ Effects Eyes. Respiratory system. Skin. Ecotoxicity 12. ECOLOGICAL INFORMATION The environmental impact of this product has not been fully investigated. Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to Microorganisms Daphnia Magna (Water Flea) Carbon black EC50 24 h Daphnia magna >5600 mg/l Page 4 / 7

5 13. DISPOSAL CONSIDERATIONS Waste Disposal Methods Contaminated Packaging This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261). This material could become a hazardous waste if it is mixed with or otherwise comes in contact with a hazardous waste, if chemical additions are made to this material, or if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether the altered material is a hazardous waste. Consult the appropriate state, regional, or local regulations for additional requirements. Dispose of in accordance with local regulations. 14. TRANSPORT INFORMATION DOT TDG MEX ICAO IATA IMDG/IMO RID ADR ADN Page 5 / 7

6 International Inventories 15. REGULATORY INFORMATION TSCA DSL EINECS/ELINCS ENCS IECSC KECL PICCS AICS Exempt U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Yes Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR and 40 CFR ). Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act Amendments of CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material. U.S. State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals: Chemical Name CAS- California Prop. 65 Carbon black Carcinogen Quartz Carcinogen U.S. State Right-to-Know Regulations Chemical Name Massachusetts New Jersey Pennsylvania Illinois Rhode Island Carbon black X X X X X Silica-tripoli X X X X Quartz X X X X International Regulations Page 6 / 7

7 Mexico - Grade Slight risk, Grade 1 Chemical Name Carcinogen Status Exposure Limits Carbon black Mexico: TWA= 3.5 mg/m 3 Mexico: STEL= 7 mg/m 3 Silica-tripoli Mexico: TWA= 0.1 mg/m 3 Quartz Mexico: TWA= 0.1 mg/m 3 Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class D2B Toxic materials 16. OTHER INFORMATION Issuing Date 01-JAN-2014 Revision te information available Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of Safety Data Sheet Page 7 / 7