Material Safety Data Sheet

Transcription

1 Conforms to ANSI Z Standard (United States, Canada, Mexico).. Material Safety Data Sheet Product and company identification Common name Material uses Supplier/Manufacturer Uncured rubber compound. Fenner Dunlop 46 South Westwood P. O. Box 44 Toledo, OH Tel (49) ext. 324 Fax (49) In case of emergency CHEMTREC, U.S. (800) International (703) MSDS authored by Kemika XXI Inc /5/ Physical state Odor Color Hazard status Hazards identification Routes of entry Potential acute health effects Eyes Skin Ingestion Potential chronic health effects Solid. (Rubber.) Aromatic. (Slight.) Black. This material is classified hazardous under OSHA regulations in the United States, the WHMIS Controlled Product Regulation in Canada and the NOM-08-STPS-2000 in Mexico. Emergency overview WARNING! CAUSES RESPIRATORY TRACT, EYE AND SKIN IRRITATION. CONTAINS MATERIAL WHICH CAUSES DAMAGE TO THE FOLLOWING ORGANS LUNGS, RESPIRATORY TRACT, EYE, LENS OR CORNEA. Avoid contact with skin and clothing. Avoid breathing dust. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Dermal contact. Eye contact.. Ingestion. Irritating to eyes. Irritating to skin. Irritating to respiratory system. No known significant effects or critical hazards. Carcinogenic effects Classified + (Proven.) by NIOSH [Carbon Black]. Classified 2B (Possible for humans.) by IARC [Carbon Black]. Classified A4 (Not classifiable for humans or animals.) by ACGIH [Carbon Black]. Classified 2B (Possible for humans.) by IARC [Extracts (petroleum), heavy paraffinic distillate solvent]. Classified 2 (Reasonably anticipated to be human carcinogens.) by NTP, 2 (Suspected for humans.) by European Union [Extracts (petroleum), heavy paraffinic distillate solvent]. Classified A4 (Not classifiable for humans or animals.) by ACGIH [Zinc oxide]. Mutagenic effects Not available. Teratogenic effects Not available. Carbon black and Extracts (petroleum), heavy paraffinic distillate solvent contained in this material are totally bounded, so cannot be inhaled under any normal circumstances of uses. Date of issue 09/5/2006 Page /7

2 Medical conditions aggravated by overexposure See toxicological information (section ) 3. Name Repeated skin exposure can produce local skin destruction or dermatitis. Repeated exposure of the eyes to a low level of dust can produce eye irritation. Repeated or prolonged exposure to the substance can produce target organ damage. Composition/information on ingredients United States Canada Name CAS number % Carbon Black Extracts (petroleum), heavy paraffinic distillate solvent Mexico CAS number Carbon Black Extracts (petroleum), heavy paraffinic distillate solvent Classification Name UN number IDLH H F R Special CAS number % Carbon Black Not 750 mg/m regulated. Extracts (petroleum), heavy Not paraffinic distillate solvent regulated. Zinc oxide UN mg/m Eye contact Skin contact First aid measures Check for and remove any contact lenses. In case of contact with eyes, rinse immediately with plenty of water. Get medical attention if symptoms occur. Wash with soap and water. Get medical attention if symptoms occur. % Ingestion Notes to physician If inhaled, remove to fresh air. If not breathing, give artificial respiration. Get medical attention if symptoms appear. Do not induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention if symptoms appear. No specific antidote. Medical staff must contact Poison Control Center. 5. Fire-fighting measures Flammability of the product Products of combustion Extinguishing media Suitable Not suitable Special exposure hazards Special protective equipment for fire-fighters May be combustible at high temperature. These products are carbon oxides. Some metallic oxides. Use an extinguishing agent suitable for the surrounding fire. None known. No specific hazard. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Date of issue 09/5/2006 Page 2/7

3 6. Accidental release measures Personal precautions Immediately contact emergency personnel. Keep unnecessary personnel away. Use suitable protective equipment. Environmental precautions Avoid dispersal of spilled material, runoff and contact with soil, waterways, drains and sewers. Methods for cleaning up If emergency personnel are unavailable, vacuum or carefully scoop up spilled material and place in an appropriate container for disposal by incineration. Avoid creating dusty conditions and prevent wind dispersal. 7. Handling Storage 8. Handling and storage Avoid contact with eyes, skin and clothing. Keep container closed. Use only with adequate ventilation. Avoid breathing dust. Wash thoroughly after handling. Keep container tightly closed. Keep material in a cool well ventilated area. Exposure controls/personal protection United States Product name Exposure limits Carbon Black ACGIH TLV (United States, /2005). TWA 3.5 mg/m 3 8 hour(s). Form All forms. NIOSH REL (United States, 2/200). TWA 3.5 mg/m 3 0 hour(s). Form All forms. OSHA PEL (United States, 8/997). TWA 3.5 mg/m 3 8 hour(s). Form All forms. Zinc oxide ACGIH TLV (United States, /2005). STEL 0 mg/m 3 5 minute(s). Form All forms. TWA 2 mg/m 3 8 hour(s). Form All forms. NIOSH REL (United States, 2/200). CEIL 5 mg/m 3 Form Dust STEL 0 mg/m 3 5 minute(s). Form Fume TWA 5 mg/m 3 0 hour(s). Form Dust and fumes OSHA PEL (United States, 8/997). TWA 5 mg/m 3 8 hour(s). Form Fume TWA 5 mg/m 3 8 hour(s). Form Respirable fraction TWA 5 mg/m 3 8 hour(s). Form Total dust Canada Product name Exposure limits Carbon Black ACGIH TLV (United States, /2005). TWA 3.5 mg/m 3 8 hour(s). Form All forms. Zinc oxide ACGIH TLV (United States, /2005). STEL 0 mg/m 3 5 minute(s). Form All forms. TWA 2 mg/m 3 8 hour(s). Form All forms. Mexico Product name Exposure limits Carbon Black NOM-00-STPS (Mexico, 9/2000). CCT 7 mg/m 3 5 minute(s). Form Smoke CPT 3.5 mg/m 3 8 hour(s). Form Smoke Zinc oxide NOM-00-STPS (Mexico, 9/2000). CCT 0 mg/m 3 5 minute(s). Form Smoke CPT 0 mg/m 3 8 hour(s). Form Powder CPT 5 mg/m 3 8 hour(s). Form Smoke Date of issue 09/5/2006 Page 3/7

4 Engineering measures Personal protection Eyes Skin Respiratory Hands Use only with adequate ventilation. If user operations generate dust, fumes, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Safety glasses. Lab coat. A respirator is not needed under normal and intended conditions of use. Natural rubber (latex). HMIS Code/Personal B protective equipment Personal protection in case Safety glasses, goggles or face shield. Impervious gloves. Full suit. Boots. Wear NIOSHapproved of a large spill Hygiene measures self-contained breathing apparatus or equivalent and full protective gear. Wash hands, forearms and face thoroughly after handling compounds and before eating, smoking and using the lavatory and at the end of the day. Follow good industrial hygiene practice. 9. Physical state Physical and chemical properties Auto-ignition temperature Color Odor ph Relative density Solubility 0. Solid. (Rubber.) >246 C (474.8 F) Black. Aromatic. (Slight.) Stability and reactivity Stability and reactivity Incompatibility with various substances Hazardous polymerization Conditions of reactivity. Neutral..448 (Water = ) Insoluble in cold water, hot water. The product is stable. Reactive with oxidizing materials. Will not occur. Not available. Toxicological information Toxicity data Product/ingredient name Test Result Route Species Carbon Black LD50 >5400 mg/kg Oral Rat Zinc oxide LD50 LC mg/kg 2500 mg/m 3 (4 hour(s)) Oral Mouse Mouse Acute Effects Eyes Skin Ingestion Irritating to eyes. Irritating to skin. Irritating to respiratory system. No known significant effects or critical hazards. Date of issue 09/5/2006 Page 4/7

5 Potential chronic health effects Carcinogenic effects Classified + (Proven.) by NIOSH [Carbon Black]. Classified 2B (Possible for humans.) by IARC [Carbon Black]. Classified A4 (Not classifiable for humans or animals.) by ACGIH [Carbon Black]. Classified 2B (Possible for humans.) by IARC [Extracts (petroleum), heavy paraffinic distillate solvent]. Classified 2 (Reasonably anticipated to be human carcinogens.) by NTP, 2 (Suspected for humans.) by European Union [Extracts (petroleum), heavy paraffinic distillate solvent]. Classified A4 (Not classifiable for humans or animals.) by ACGIH [Zinc oxide]. Mutagenic effects Not available. Teratogenic effects Not available. Carbon black and Extracts (petroleum), heavy paraffinic distillate solvent contained in this material are totally bounded, so cannot be inhaled under any normal circumstances of uses. Target organs Contains material which causes damage to the following organs lungs, upper respiratory tract, eye, lens or cornea. 2. Ecological information Product/ingredient name Zinc oxide Environmental precautions Ecotoxicity data Species Period Result Daphnia magna (EC50) Oncorhynchus mykiss (LC50) Lepomis macrochirus (LC50) Pimephales promelas (LC50) 48 hour(s) 96 hour(s) 96 hour(s) 96 hour(s) This material is not expected to be harmful to aquatic organisms. >000 mg/l. mg/l >320 mg/l 2246 mg/l Products of degradation Zinc oxide contained in this material is totally bounded, so cannot be release in the environment under any normalcircumstances of uses. These products are carbon oxides. Some metallic oxides. 3. Disposal considerations Waste disposal The generation of waste should be avoided or minimized wherever possible. Avoid dispersal of spilled material, runoff and contact with soil, waterways, drains and sewers. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional and local authority requirements. 4. Transport information Regulatory information UN/ IMDG/ IATA DOT/ TDG Not regulated. Zinc oxide contained in this material is totally bounded, so cannot be release in the environment under any normalcircumstances of uses. 5. Regulatory information United States HCS Classification U.S. Federal regulations Irritating material Target organ effects TSCA All components listed. Date of issue 09/5/2006 Page 5/7

6 SARA 33 Form R - Reporting requirements Supplier notification Canada WHMIS (Canada) SARA 302/304/3/32 extremely hazardous substances No products were found. SARA 302/304 emergency planning and notification No products were found. SARA 302/304/3/32 hazardous chemicals Carbon Black; Zinc oxide SARA 3/32 MSDS distribution - chemical inventory - hazard identification Carbon Black Immediate (acute) health hazard, Delayed (chronic) health hazard; Zinc oxide Immediate (acute) health hazard, Delayed (chronic) health hazard Clean Water Act (CWA) 307 Zinc oxide Clean Water Act (CWA) 3 No products were found. Clean Air Act (CAA) 2 accidental release prevention No products were found. Clean Air Act (CAA) 2 regulated flammable substances No products were found. Clean Air Act (CAA) 2 regulated toxic substances No products were found. Product name CAS number Concentration SARA 33 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed. State regulations Pennsylvania RTK Carbon Black (generic environmental hazard); Zinc oxide (environmental hazard, generic environmental hazard) Massachusetts RTK Carbon Black; Extracts (petroleum), heavy paraffinic distillate solvent; Zinc oxide New Jersey Carbon Black; Zinc oxide California prop. 65 No products were found. Ingredient name Cancer Reproductive No significant risk level Maximum acceptable dosage level Carbon Black Yes. No. No. No. When bonded in the material, carbon black is exempted from California proposition 65 warning statement. Class D-2B Material causing other toxic effects (Toxic). Mexico Classification DSL All components listed. This product has been classified in accordance with the hazard criteria of the Canadian CPR, the United States OSHA and the Mexican NOM -08-STPS This MSDS contains all the information required by the CPR, OSHA, the American National Standard Institute (ANSI) Z400. and NOM -08-STPS Health Flammability 0 Reactivity Special HAZARD RATINGS 4- Extreme 3- Serious 2- Moderate - Slight 0- Minimal International lists This product, (and its ingredients) is (are) listed on national inventories, or is (are) exempted from being listed, Australia (AICS), in Europe (EINECS/ELINCS), in Korea (TCCL), in Japan (METI), in the Philippines (RA6969). Date of issue 09/5/2006 Page 6/7

7 6. Other information Label requirements (U.S.A.) CAUSES RESPIRATORY TRACT, EYE AND SKIN IRRITATION. CONTAINS MATERIAL WHICH CAUSES DAMAGE TO THE FOLLOWING ORGANS LUNGS, RESPIRATORY TRACT, EYE, LENS OR CORNEA. Hazardous Material Information System (U.S.A.) HMIS RATING Health * Fire hazard Physical Hazard 0 Personal protection B HAZARD RATINGS 4- Extreme 3- Serious 2- Moderate - Slight 0- Minimal See section 8 for more detailed information on personal protection. National Fire Protection Association (U.S.A.) Health 0 Flammability Reactivity Special References Date of issue Version ANSI Z400., MSDS Standard, Manufacturer's Material Safety Data Sheet. - 29CFR Part OSHA MSDS Requirements. - 49CFR Table List of Hazardous Materials, UN#, Proper Shipping Names, PG. - Canada Gazette Part II, Vol. 22, No. 2. Registration SOR/88-64, 3 December 987. Hazardous Products Act "Ingredient Disclosure List" - Canadian Transport of Dangerous Goods, Regulations and Schedules, Clear Language version Official Mexican Standards NOM-08-STPS-2000 and NOM-004-SCT /5/2006 Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Date of issue 09/5/2006 Page 7/7