Iron Sulphate Heptahydrate Product Code: PC Department: chemical products C.A.S.:

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1 Material Safety Data Sheet Iron Sulphate Heptahydrate Product Code: PC Department: chemical products C.A.S.: Section: 1 Identification Product name : Iron(II) sulfate heptahydrate Form solid Colour Section: 2 Hazard Identification Emergency Overview Target Organs WHMIS Classification Gastro-intestinal system, LiverGastro-intestinal system, Liver D2B Toxic Material Causing Other Toxic Effects. Moderate skin irritant. Moderate eye irritant HMIS Classification Health hazard: 1 Flammability: 0 Physical hazards: 0 Potential Health Effects Inhalation May be harmful if inhaled. May cause respiratory tract irritation. Skin Harmful if absorbed through skin. May cause skin irritation. Eyes May cause eye irritation. Ingestion Harmful if swallowed. SGH Label Elements Product: kama pigments PC , Iron Sulphate Heptahydrate page 1 of 6

2 Signal Word attention GHS Classification Acute toxicity, Oral (Category 4) Skin corrosion/irritation (Category 2) Serious eye damage/eye irritation (Category 2A) Precautionary Statements P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Hazard Statements H302 Harmful if swallowed. H315 Causes skin irritation. H319 Causes serious eye irritation. Section: 3 Composition / Information on Ingredients Synonyms : Ferrous sulfateheptahydrate Formula : FeO4S 7H2O Molecular weight : g/mol Ferrous sulfate heptahydrate CAS-No. EC-No. Index-No. Concentration <=100% Section: 4 First-Aid Measures General advice If inhaled In case of skin contact In case of eye contact If swallowed Move out of dangerous area.consult a physician. Show this safety data sheet to the doctor in attendance. If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. Wash off with soap and plenty of water. Consult a physician. Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. Section: 5 Fire-Fighting Measures Conditions of flammability Suitable extinguishing media Special protective equipment for firefighters Hazardous combustion products Explosion data - sensitivity to mechanical impact Explosion data - sensitivity to static discharge Not flammable or combustible. Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus for firefighting if necessary. Hazardous decomposition products formed under fire conditions. - Sulphur oxides, Iron oxides Section: 6 Accidental Release Measures Personal precautions Environmental precautions Methods and materials for containment and cleaning up Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Avoid breathing dust. Do not let product enter drains. Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal. Product: kama pigments PC , Iron Sulphate Heptahydrate page 2 of 6

3 Section: 7 Handling And Storage Precautions for safe handling Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed. Conditions for safe storage Keep container tightly closed in a dry and well-ventilated place. Air sensitive. Store under inert gas. hygroscopic Section: 8 Exposure Control/Personal Protection Components with workplace control parameters Components CAS-No. Value Control parameters Basis Ferrous sulfate Heptahydrate TWA 1.0 mg/m3 Canada. Alberta, Occupational Health and Safety Code (table 2: OEL) Remarks Occupational exposure limit is based on irritation effects and its adjustment to compensate for unusual work schedules is not required TWAEV 1.0 mg/m3 Québec. Regulation respecting occupational health and safety, Schedule 1, Part 1: Permissible exposure values for airborne contaminants TWAEV 1.0 mg/m3 Canada. Ontario OELs TWA 1.0 mg/m3 Canada. British Columbia OEL STEL 2.0 mg/m3 Canada. British Columbia OEL TWA 1 mg/m3 Canada. Alberta, Occupational Health and Safety Code (table 2: OEL) Occupational exposure limit is based on irritation effects and its adjustment to compensate for unusual work schedules is not required TWAEV 1 mg/m3 Québec. Regulation respecting occupational health and safety, Schedule 1, Part 1: Permissible exposure values for airborne contaminants TWA 1 mg/m3 Canada. British Columbia OEL STEL 2 mg/m3 Canada. British Columbia OEL TWA 1 mg/m3 USA. ACGIH Threshold Limit Values (TLV) Personal protective equipment Respiratory protection Hand protection For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.for higher level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Full contact Material: Nitrile rubber Minimum layer thickness: 0.11 mm Break through time: 480 min Material tested:dermatril (KCL 740 / Aldrich Z677272, Size M) Splash contact Material: Nitrile rubber Minimum layer thickness: 0.11 mm Break through time: 480 min Material tested:dermatril (KCL 740 / Aldrich Z677272, Size M) Product: kama pigments PC , Iron Sulphate Heptahydrate page 3 of 6

4 If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario. Eye protection Skin and body protection Hygiene measures Specific engineering controls Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Use mechanical exhaust or laboratory fumehood to avoid exposure. Section: 9 Physical and Chemical Properties Safety data ph Melting point/range: Boiling point Flash point Ignition temperature Auto-ignition temperature Lower explosion limit Upper explosion limit Vapour pressure Density Water solubility Partition coefficient: Relative vapour density Odour Odour Evaporation rate at 50 g/l at 25 C (77 F) 64 C (147 F) Not applicable 14.6 hpa (11.0 mmhg) at 25 C (77 F) g/cm3 at 25 C (77 F) n-octanol/water Threshold Section: 10 Stability And Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Materials to avoid Hazardous decomposition products Other decomposition products Stable under recommended storage conditions. Strong oxidizing agents Hazardous decomposition products formed under fire conditions. - Sulphur oxides, Iron oxides Product: kama pigments PC , Iron Sulphate Heptahydrate page 4 of 6

5 Section: 11 Toxicological Information Acute toxicity Oral LD50 LD50 Oral - Mouse - 1,520 mg/kg Inhalation LC50 Dermal LD50 Other information on acute toxicity LD50 Intraperitoneal - Mouse mg/kg LD50 Intravenous - Mouse - 51 mg/kg Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. Reproductive toxicity Teratogenicity Specific target organ toxicity single exposure (Globally Harmonized System) repeated exposure (Globally Harmonized System) Aspiration hazard Potential health effects Inhalation May be harmful if inhaled. May cause respiratory tract irritation. Ingestion Harmful if swallowed. Skin Harmful if absorbed through skin. May cause skin irritation. Eyes May cause eye irritation. Signs and Symptoms of Exposure To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Synergistic effects Section: 12 Ecological Information Toxicity Persistence and degradability Bioaccumulative potential Mobility in soil PBT and vpvb assessment Other adverse effects Section: 13 Disposal Considerations Product Contaminated packaging Offer surplus and non-recyclable solutions to a licensed disposal company. Dispose of as unused product. Product: kama pigments PC , Iron Sulphate Heptahydrate page 5 of 6

6 Section: 14 Transport Information DOT (US) UN number: 3077 Class: 9 Packing group: III Proper shipping name: Environmentally hazardous substances, solid, n.o.s. (Ferrous sulfate heptahydrate) Reportable Quantity (RQ): 1000 lbs Marine pollutant: No Poison Inhalation Hazard: No IMDG Not dangerous goods IATA Not dangerous goods Section: 15 Regulatory Information WHMIS Classification D2B Toxic Material Causing Other Toxic Effects. Moderate skin irritant. Moderate eye irritant This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. Section: 16 Other Information reference prepared by manufacturer's material safety data sheet Kama pigments Disclaimer: Kama pigments, expressly disclaims all express or implied warranties of merchantability and fitness for a particular purpose, with respect to the product or information provided herein, and shall under no circumstances be liable for incidental or consequential damages. Do not use ingredient information and/or ingredient percentages in this MSDS as a product specification. For product specification information, refer to a Product Specification Sheet and/or a Certificate of Analysis. These can be obtained from your local Kama pigments Sales Office. All information appearing herein is based upon data obtained from the manufacturer and/or recognized technical sources. While the information is believed to be accurate, Kama pigments makes no representations as to its accuracy or sufficiency. Conditions of use are beyond Kama pigments control and therefore users are responsible to verify this data under their own operating conditions to determine whether the product is suitable for their particular purposes and they assume all risks of their use, handling, and disposal of the product, or from the publication or use of, or reliance upon, information contained herein. This information relates only to the product designated herein, and does not relate to its use in combination with any other material or in any other process. Last revision: Product: kama pigments PC , Iron Sulphate Heptahydrate page 6 of 6