Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet Revision Number: Issue date: 08/17/ PRODUCT AND COMPANY IDENTIFICATION Product name: DB EPOXY ADH E-60HP 400ML RESIN IDH number: Product type: Epoxy resin Item number: 29321_ Region: United States Company address: Contact information: Henkel Corporation Telephone: One Henkel Way MEDICAL EMERGENCY Phone: Poison Control Center Rocky Hill, Connecticut (toll free) or TRANSPORT EMERGENCY Phone: CHEMTREC (toll free) or Internet: 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW HMIS: Physical state: Liquid HEALTH: 2 Color: Pale yellow, to, Off white FLAMMABILITY: 1 Odor: Faint, Epoxy PHYSICAL HAZARD: 0 Personal Protection: See MSDS Section 8 WARNING: MAY CAUSE ALLERGIC SKIN REACTION. MAY CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION. Relevant routes of exposure: Skin, Inhalation, Eyes Potential Health Effects Inhalation: Skin contact: Eye contact: Ingestion: Existing conditions aggravated by exposure: May cause respiratory tract irritation. May cause allergic skin reaction. May cause skin irritation. This product may cause irritation to the eyes. Ingestion of this product is unlikely. However, ingestion of product may produce gastrointestinal irritation and disturbances. Vomiting. Eye, skin and respiratory disorders. This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR ). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous components CAS NUMBER % Epoxy resin Proprietary Acrylic polymers Unknown FIRST AID MEASURES Inhalation: Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. If symptoms develop and persist, get medical attention. IDH number: Page 1 of 5 Product name: DB EPOXY ADH E-60HP 400ML RESIN

2 Skin contact: Eye contact: Ingestion: Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothing and footwear. If symptoms develop and persist, get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. Immediately flush eyes with plenty of water for at least 15 minutes. If symptoms develop and persist, get medical attention. DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention. 5. FIRE FIGHTING MEASURES Flash point: Autoignition temperature: Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Extinguishing media: Special firefighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: C (205 F) Setaflash Closed Cup Water spray (fog), foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Personnel in vicinity and downwind should be evacuated. Burning produces obnoxious and toxic fumes. In case of fire, keep containers cool with water spray. Closed containers may rupture (due to build up of pressure) when exposed to extreme heat. Oxides of carbon. Oxides of nitrogen. Aldehydes. Formaldehyde. Acids. Acrylic monomers. Toxic fumes. Irritating vapors. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Clean-up methods: Do not allow product to enter sewer or waterways. Ensure adequate ventilation. Wear appropriate personal protective equipment. Refer to Section 8 "Exposure Controls / Personal Protection" prior to clean up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Scrape up spilled material and place in a closed container for disposal. 7. HANDLING AND STORAGE Handling: Storage: Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Use only with adequate ventilation. Keep container closed. Keep container tightly closed and in a cool, well-ventilated place away from incompatible materials. Keep away from heat, spark and flame. For information on product shelf life contact Henkel Customer Service at (800) EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. IDH number: Page 2 of 5 Product name: DB EPOXY ADH E-60HP 400ML RESIN

3 Hazardous components ACGIH TLV OSHA PEL AIHA WEEL OTHER Epoxy resin None None None None Acrylic polymers None None None None Engineering controls: Respiratory protection: Eye/face protection: Skin protection: Use local exhaust ventilation if the potential for airborne exposure exists. Use a NIOSH approved respirator if ventilation is inadequate. Safety goggles or safety glasses with side shields. Use chemical resistant, impermeable clothing including gloves and either an apron or body suit to prevent skin contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid Color: Pale yellow, to, Off white Odor: Faint, Epoxy Odor threshold: ph: Vapor pressure: Boiling point/range: Melting point/ range: Specific gravity: 1.10 Vapor density: Flash point: C (205 F) Setaflash Closed Cup Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Autoignition temperature: Evaporation rate: Solubility in water: Partition coefficient (n-octanol/water): VOC content: 0.0 % California SCAQMD Method 316B 10. STABILITY AND REACTIVITY Stability: Hazardous reactions: Hazardous decomposition products: Incompatible materials: Conditions to avoid: Stable under normal conditions of storage and use. Reaction with some curing agents may produce an exothermic reaction which in large masses could cause runaway polymerization. Oxides of carbon. Oxides of nitrogen. Aldehydes. Formaldehyde. Acids. Acrylic monomers. Toxic fumes. Irritating vapors. Acids. Bases. Oxidizing agents. Amines. Keep away from heat, ignition sources and incompatible materials. 11. TOXICOLOGICAL INFORMATION Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) Epoxy resin No No No Acrylic polymers No No No Hazardous components Epoxy resin Acrylic polymers Health Effects/Target Organs Allergen, Irritant No Data 12. ECOLOGICAL INFORMATION Ecological information: IDH number: Page 3 of 5 Product name: DB EPOXY ADH E-60HP 400ML RESIN

4 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Hazardous waste number: Follow all local, state, federal and provincial regulations for disposal. Not a RCRA hazardous waste. U.S. Department of Transportation Ground (49 CFR) Not regulated Hazard class or division: None Identification number: None None 14. TRANSPORT INFORMATION International Air Transportation (ICAO/IATA) Environmentally hazardous substance, liquid, n.o.s. (epoxy resin) Hazard class or division: 9 Identification number: UN 3082 III Water Transportation (IMO/IMDG) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (epoxy resin) Hazard class or division: 9 Identification number: UN 3082 III Marine pollutant: epoxy resin United States Regulatory Information 15. REGULATORY INFORMATION TSCA 8 (b) Inventory Status: TSCA 12(b) Export Notification: CERCLA/SARA Section 302 EHS: CERCLA/SARA Section 311/312: CERCLA/SARA 313: California Proposition 65: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. None above reporting de minimus None above reporting de minimus Immediate Health None above reporting de minimus This product contains a chemical known in the State of California to cause cancer. This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Canada Regulatory Information CEPA DSL/NDSL Status: WHMIS hazard class: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. D.2.B 16. OTHER INFORMATION This material safety data sheet contains changes from the previous version in sections: First issue. Prepared by: Rena Petrides, Regulatory Affairs Specialist IDH number: Page 4 of 5 Product name: DB EPOXY ADH E-60HP 400ML RESIN

5 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of any kind, including lost profits. IDH number: Page 5 of 5 Product name: DB EPOXY ADH E-60HP 400ML RESIN

6 Material Safety Data Sheet Revision Number: Issue date: 02/04/ PRODUCT AND COMPANY IDENTIFICATION Product name: DB EPOXY ADH E-60HP 400 ML HARD IDH number: Product type: Epoxy Hardener Item number: 29321_ Region: United States Company address: Contact information: Henkel Corporation Telephone: One Henkel Way MEDICAL EMERGENCY Phone: Poison Control Center Rocky Hill, Connecticut (toll free) or TRANSPORT EMERGENCY Phone: CHEMTREC (toll free) or Internet: 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW HMIS: Physical state: Liquid HEALTH: 3 Color: Yellow FLAMMABILITY: 1 Odor: Mild PHYSICAL HAZARD: 0 Personal Protection: See MSDS Section 8 DANGER: CAUSES EYE, SKIN AND RESPIRATORY TRACT BURNS. HARMFUL IF INHALED. MAY CAUSE ALLERGIC SKIN REACTION. Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion Potential Health Effects Inhalation: Skin contact: Eye contact: Ingestion: Existing conditions aggravated by exposure: Harmful if inhaled and may cause delayed lung injury. Inhalation of aerosol may cause irritation to the upper respiratory tract. Risk of serious damage to the lungs (by inhalation). May cause nose, throat and lung irritation. Can cause respiratory tract burns. Causes skin burns. May cause allergic skin reaction. Causes eye burns. Burns of the eye may cause blindness. Exposure to vapor may cause tearing of the eyes, irritation and burning sensation. If ingested, severe burns of the mouth and throat may occur, as well as perforation of the esophagus and the stomach. Asthma. Eye, skin, and respiratory disorders. This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR ). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous components CAS NUMBER % Substituted polyamine Proprietary ,3'-Oxybis(ethyleneoxy)bis(propylamine) Amorphous fumed silica IDH number: Page 1 of 5 Product name: DB EPOXY ADH E-60HP 400 ML HARD

7 4. FIRST AID MEASURES Inhalation: Skin contact: Eye contact: Ingestion: Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Remove contaminated clothing and footwear. Immediately flush skin with plenty of water (using soap, if available). Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention. DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention. If vomiting occurs, prevent aspiration by keeping the patient's head below the knees. 5. FIRE FIGHTING MEASURES Flash point: Autoignition temperature: Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Extinguishing media: Special firefighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: > 93 C (> F) Setaflash Closed Cup... Foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Personnel in vicinity and downwind should be evacuated. Burning produces obnoxious and toxic fumes. Do not allow run-off from fire fighting to enter drains or water courses. Use of water may result in the formation of very toxic aqueous solutions. Ammonia. Oxides of carbon. Oxides of nitrogen. Nitric acid. Toxic fumes. Irritating vapors. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Clean-up methods: Do not allow product to enter sewer or waterways. Remove all sources of ignition. Ensure adequate ventilation. Wear appropriate personal protective equipment. Refer to Section 8 "Exposure Controls / Personal Protection" prior to clean up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Scrape up spilled material and place in a closed container for disposal. 7. HANDLING AND STORAGE Handling: Storage: Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Use only with adequate ventilation. Keep container closed. Keep container tightly closed and in a cool, well-ventilated place away from incompatible materials. Keep away from heat, spark and flame. Do not store in reactive metal containers. For information on product shelf life contact Henkel Customer Service at (800) IDH number: Page 2 of 5 Product name: DB EPOXY ADH E-60HP 400 ML HARD

8 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous components ACGIH TLV OSHA PEL AIHA WEEL OTHER Substituted polyamine None None None None 3,3'-Oxybis(ethyleneoxy)bis(propylamine) None None None None Amorphous fumed silica None None None None Engineering controls: Respiratory protection: Eye/face protection: Skin protection: Local exhaust ventilation is recommended when general ventilation is not sufficient to control airborne contamination below occupational exposure limits. Use a NIOSH approved respirator if ventilation is inadequate. Safety goggles or safety glasses with side shields. Full face protection should be used if the potential for splashing or spraying of product exists. Use chemical resistant, impermeable clothing including gloves and either an apron or body suit to prevent skin contact. Neoprene, Butyl-rubber, or nitrilerubber gloves. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Color: Odor: Odor threshold: ph: Vapor pressure: Boiling point/range: Melting point/ range: Vapor density: Flash point: Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Autoignition temperature: Evaporation rate: Solubility in water: Partition coefficient (n-octanol/water): VOC content: Liquid Yellow Mild > 93 C (> F) Setaflash Closed Cup.... Partially soluble. < 1 %; < 10 g/l Estimated 10. STABILITY AND REACTIVITY Stability: Hazardous reactions: Hazardous decomposition products: Incompatible materials: Conditions to avoid: Stable under normal conditions of storage and use. None under normal processing. Ammonia. Oxides of carbon. Oxides of nitrogen. Nitric acid. Toxic fumes. Irritating vapors. Sodium hypochlorite. Organic acids. Mineral acids. This product slowly corrodes copper, aluminum, zinc and galvanized surfaces. Peroxides. Oxidizing agents. Keep away from heat, ignition sources and incompatible materials. IDH number: Page 3 of 5 Product name: DB EPOXY ADH E-60HP 400 ML HARD

9 11. TOXICOLOGICAL INFORMATION Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) Substituted polyamine No No No 3,3'-Oxybis(ethyleneoxy)bis(propylamine) No No No Amorphous fumed silica No No No Hazardous components Substituted polyamine 3,3'-Oxybis(ethyleneoxy)bis(propylamine) Amorphous fumed silica Health Effects/Target Organs No Records Corrosive No Target Organs 12. ECOLOGICAL INFORMATION Ecological information:. 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Hazardous waste number: Follow all local, state, federal and provincial regulations for disposal. Not a RCRA hazardous waste. 14. TRANSPORT INFORMATION The shipping classifications in this sections are for non-bulk packaging only (unless otherwise specified). Shipping classification may be different for bulk packaging. U.S. Department of Transportation Ground (49 CFR) Amines, liquid, corrosive, n.o.s. (Polyglycol diamine) Hazard class or division: 8 Identification number: UN 2735 II International Air Transportation (ICAO/IATA) Amines, liquid, corrosive, n.o.s. (Polyglycol diamine) Hazard class or division: 8 Identification number: UN 2735 II Water Transportation (IMO/IMDG) AMINES, LIQUID, CORROSIVE, N.O.S. (Polyglycol diamine) Hazard class or division: 8 Identification number: UN 2735 II United States Regulatory Information 15. REGULATORY INFORMATION TSCA 8 (b) Inventory Status: TSCA 12(b) Export Notification: CERCLA/SARA Section 302 EHS: CERCLA/SARA Section 311/312: CERCLA/SARA 313: California Proposition 65: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. None above reporting de minimus None above reporting de minimis Immediate Health None above reporting de minimis This product contains a chemical known in the State of California to cause cancer. IDH number: Page 4 of 5 Product name: DB EPOXY ADH E-60HP 400 ML HARD

10 Canada Regulatory Information CEPA DSL/NDSL Status: WHMIS hazard class: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. D.2.B, E 16. OTHER INFORMATION This material safety data sheet contains changes from the previous version in sections: 1,5,6,7,8,10,14 Prepared by: Rena Petrides, Regulatory Affairs Specialist DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates ( Henkel ) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user s responsibility to determine the suitability of Henkel s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. IDH number: Page 5 of 5 Product name: DB EPOXY ADH E-60HP 400 ML HARD