Peosta, IA HAZARDOUS IDENTIFICATION Classification: Flammable Liquid 2 Acute Toxicity Oral 4 Acute Toxicity Inhalation 4 Skin Corrosion 1B

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1 IBI SCIENTIFIC 9861 Kapp Court Peosta, IA Tele: (563) Fax: (563) Web: Issuing Date: 26-Dec-1997 Revision Date: 22-Dec-2011 Rev IDENTIFICATION OF THE SUBSTANCE/ MIXTURE AND THE COMPANY/UNDERTAKING Product Name: Product Code: Recommend Use: Synonyms: Company: TEMED IB70120 For further manufacturing use only Not for human or animal drug use High purity, protease-free product used to identify and quantify proteins in their various forms 1,2-BIS-(DIMETHYLAMINO)ETHANE * 1,2-DI-(DIMETHYLAMINO) ETHANE (DOT) * 1,2-ETHANEDIAMINE, N,N,N,N -TETRAMETHYL-(9Cl) * PROPAMINE D * TEMED * TETRAMEEN * N,N,N,N -TETRAMETHYL-1,2-DIAMINOETHANE * N,N,N,N -TETRAMETHYLETHANEDIAMINE * N,N,N,N -TETRAMETHYL- 1,2-ETHANEDIAMINE * TETRAMETHYL ETHYLENE DIAMINE * N,N,N,N - TETRAMETHYLETHYLENEDIAMINE * TMEDA * UN2372 (DOT) * IBI SCIENTIFIC 9861 Kapp Court Peosta, IA Emergency Tele. Number: 3E Company (Acct# 9027) / (001) Company Tele. Number: / (001) Address: info@ibisci.com 2. HAZARDOUS IDENTIFICATION GHS Classification Classification: Signal Word: Flammable Liquid 2 Acute Toxicity Oral 4 Acute Toxicity Inhalation 4 Skin Corrosion 1B Danger Hazard Statements: Precautionary Statements: H225-Highly flammable liquid and vapor * H301 Toxic if swallowed * H331-Toxic in inhaled * H314-Causes severe skin burns and eye damage P210-Keep away from heat/sparks/open flames/hot surfaces. No smoking * P261-Avoid breathing dust/fume/gas/mist/vapors/spray * P280-Wear protective gloves/protective clothing/eye protection/face protection * P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing * P310-Immediately call a Poison Center or doctor/physician Page 1 of 6

2 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name: 1,2-Bis(dimethylamino)ethane EC No.: EEC No REACH Reg. No.: Not Available CAS No.: Weight %: Classification: F; R11, Xn;R20/22, C;R34 4. FIRST AID MEASURES Eye Contact: Skin Contact: Inhalation: Ingestion: Notes to Physician: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Wash off immediately with soap and plenty of water, removing all contaminated clothes and shoes. Move to fresh air. Clean mouth with water and afterwards drink plenty of water. Treat symptomatically. 5. FIRE FIGHTING MEASURES Flammable Properties: Flammable liquid Flash Point: 20 C / 68 F Suitable Extinguishing Media: Dry chemical, CO 2, appropriate foam Unsuitable Extinguishing Media: Vapor may travel considerable distance to source of ignition and flash back Hazardous Combustion Products: Carbon oxides, Nitrogen oxides (NOx) Explosion Data Sensitivity to Mechanical Impact: Not sensitive Sensitivity to Static Discharge: Not sensitive Protective Equip. & Precautions for Firefighters: As in any fire, wear self-contaimed breathing apparatus pressure-demand, MSHA/NIOSH (approved or equiv.) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Methods for Containment: Methods for Cleaning Up: Avoid contact with skin, eyes, and clothing. Use personal protective equipment. Ensure adequate ventilation. Prevent further leakage or spillage, if safe to do so. Cover with dry lime or soda ash. Use non-sparking tools and equipment. Pick up and transfer to properly labeled containers. Ventilate area and wash spill site after material pickup is complete. 7. HANDLING AND STORAGE Handling: Storage: Incompatible Products: Handle in accordance with good industrial hygiene and safety practice. Hygroscopic. Protect from moisture. Keep container tightly closed in a dry, cool, and well-ventilated place. Protect from moisture. Hygroscopic. Acids, Acid chlorides, Anhydrides, Strong oxidizing agents, Carbon dioxide, Copper, Copper alloys. Page 2 of 6

3 8. EXPOSURE CONTROLS / PERSONAL PROTECTION ACGIH TLV: - OSHA PEL: - NIOSH IDLH: - Engineering Measures: Showers, Eyewash Stations, Ventilation Systems Personal Protective Equipment Eye/Face Protection: Tight fitting safety goggles. Skin & Body Protection: Wear protective gloves/clothing. Respiratory Protection: If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. Hygiene Measures: Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Clear liquid Odor: Amine-like Odor Threshold: Decomposition Temp. C: Freezing Point: Initial Boiling Point: Physical State: Liquid ph: Flash Point: 20 C / 68 F Flammable Properties Flammable liquid Autoignition Temp. C: Boiling Point/Range: C Melting Point/Range: -55 C Flammability Limits (Air): Upper-9.08% * Lower-0.98% Explosive Properties: Oxidizing Properties: Evaporation Rate: 37.8 C: Vapor Density: Specific Gravity: Density: 4.0 Solubility: Water Solubility: Soluble in water Partition Coefficient (n-octanol/water): Viscosity: 10. STABILITY AND REACTIVITY Stability: Incompatible Products: Conditions to Avoid: Hazardous Decomposition Products: Hazardous Polymerization: Stable under recommended storage conditions Acids, Acid chlorides, Anhydrides, Strong oxidizing agents, Carbon dioxide, Copper, Copper alloys Protect from moisture. Hygroscopic. Carbon oxides, Nitrogen oxides (NOx) Hazardous polymerization does not occur. Page 3 of 6

4 11. TOXICOLOGICAL INFORMATION MATERIAL SAFETY DATA SHEET Acute Toxicity Product Information: Toxic by inihalation and if swallowed, corrosive to eye, skin, and respiratory system. LD50 Oral: 268mg/kg (Rat) LD50 Dermal: 5390mg/kg (Rabbit) LC50 Inhalation: 1318mg/kg (Rat) 4h Chronic Toxicity Target Organ Effects: None known. 12. ECOLOGICAL INFORMATION Ecotoxicity: 13. DISPOSAL CONSIDERATIONS Water Disposal Method: Contaminated Packaging: 14. TRANSPORT INFORMATION The environmental impact of this product has not been fully investigated. Dispose of material in accordance with all federal, state, and local regulations. Dispose of in accordance with all federal, state, and local regulations. IATA UN# UN2372 Proper Shipping Name 1,2-DI-(DIMETHYLAMINO) ETHANE Hazardous Class 3 Packing Group II US DOT UN# UN2372 Proper Shipping Name 1,2-DI-(DIMETHYLAMINO) ETHANE Hazardous Class 3 Packing Group II 15. TOXICOLOGICAL INFORMATION REACH Title VII Restrictions Dangerous Substances: Organic Solvents: Harmful Substances Whose Names are to be indicated on the Label: Pollution Release and Transfer Registry (Class II): Pollution Release and Transfer Registry (Class I): Poison and Deleterious Substances Control Law: ISHA Harmful Substances Prohibited for Manufacturing, Importing, Transferring, or Supplying: ISHA Harmful Substances Requiring Permission: Toxic Chemical Classification Listing (TCCL): Toxic Release Inventory (TRI) Group I: Toxic Release Inventory (TRI) Group II: International Inventories TSCA: DSL: EINECS/ELINCS: ENCS: IECSC: KECL PICCS AICS Page 4 of 6

5 U.S. Federal Regulations SARA 313 Section 313 of Title III of the superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain a chemical/chemicals which are subject to the reporting requirements of the Act & Title 40 of the Code of Federal Regulations, part 372. SARA 311/312 Hazard Categories Acute Health Hazard Yes Chronic Health Hazard No Fire Hazard Yes Sudden Release of Pressure Hazard No Reactive Hazard No Clean Water Act This product does not contain any substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR and 40 CFR ). Clean Air Act Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61). This product contains the following substances regulated as hazardous air pollutants (HAPs)under Section 112 of the Clean Air Act Amendments of Weight (%): HAPs Data: - VOC Chemicals: Group V Class 1 Ozone Depletors: - Class 2 Ozone Depletors: - CERCLA U.S. State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. State Massachusetts - New Jersey X Pennsylvania - Illinois - Rhode Island - International Regulations Mexico Canada Page 5 of 6

6 WHMIS Hazard Class E Corrosive material D2B Toxic materials B2 Flammable liquid 16. OTHER INFORMATION Issuing Date: Revision Date: Revision Note: Recommended Restrictions: Disclaimer: 26-Dec Dec-2011 Update to GHS Standard The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal, and release; and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the test. End of MSDS Page 6 of 6