Appendix 1 LIST OF DANGEROUS GOODS WITH THEIR UNITED NATIONS NUMBER, DANGEROUS GOODS CLASS AND TOPS COMMODITY CODE Contents

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1 LIST OF DANGEROUS GOODS WITH THEIR UNITED NATIONS NUMBER, DANGEROUS GOODS CLASS AND TOPS COMMODITY CODE Contents Page Latest Issue Contents App 1.1 Dec 2018 List of with their App 1.2 Dec 2018 United Nations Number, and TOPS This issue contains changes published in the Periodical Operating Notice (PON) on 01/12/2018 Handling and Carriage of Page App1.1

2 1.1 es 2 9 This list, applicable to freight train carriage, is for reference purposes only. It must not be used to allocate United Nations numbers, dangerous goods classifications, subsidiary hazards or packing groups. More than one class or packing group is shown against some substances and in these instances the actual class or packing group, which should be declared by the consignor, will depend upon the properties of the actual substances consigned Acetylene, dissolved Air, compressed Air, refrigerated liquid Ammonia, anhydrous , Argon, compressed Boron trifluoride , Bromotrifluoromethane (R 13B1) Butadienes, stabilized Butane Butylene Carbon dioxide Carbon monoxide, compressed , Chlorine , 8 535, Chlorodifluoromethane (R 22) Chloropentafluoroethane (R 115) Chloro-1,2,2,2-tetrafluoroethane (R 124) Chlorotrifluoromethane (R 13) Coal gas, compressed , Cyanogen , Cyclopropane Dichlorodifluoromethane (R 12) Dichlorofluoromethane (R 21) ,1-Difluoroethane (R 152a) Dimethylamine, anhydrous Dimethyl ether Ethane Ethylamine Ethyl chloride Ethylene, refrigerated liquid Ethyl methyl ether Ethylene oxide or ethylene oxide with nitrogen , Ethylene oxide and carbon dioxide mixture Fertilizer ammoniating solution with free ammonia Fire extinguishers with compressed or liquefied gas Fluorine, compressed , Helium, compressed Hydrogen bromide, anhydrous , Hydrogen, compressed Handling and Carriage of Page App1.2

3 1050 Hydrogen chloride, anhydrous , Hydrogen cyanide, stabilized I Hydrogen fluoride, anhydrous I Hydrogen sulphide , Isobutylene Krypton Lighters or lighter refills (cigarettes), containing flammable gas 1058 Liquefied gases, non-flammable, charged with nitrogen, carbon dioxide or air 1060 Methylacetylene and propadiene mixture, stabilized Methylamine, anhydrous Methyl bromide with not more than 2% chloropicrin , Methyl chloride (R 40) Methylmercaptan , Neon, compressed Nitrogen, compressed Dinitrogen tetroxide (Nitrogen dioxide) , 8 535, Nitrosyl chloride Nitrous oxide Oil gas, compressed , Oxygen, compressed Oxygen, refrigerated liquid Petroleum gases, liquefied Phosgene , Propylene Refrigerant gas Sulphur dioxide , Sulphur hexafluoride Tetrafluoroethylene, stabilized Trifluorochloroethylene, stabilized (Refrigerant , 547 gas R1113) 1083 Trimethylamine, anhydrous Vinyl bromide, stabilized Vinyl chloride, stabilized Vinyl methyl ether, stabilized Acetal 3 II Acetaldehyde 3 I Acetone 3 II Acetone oils 3 II Acrolein, stabilized I Acrylonitrile, stabilized I Allyl alcohol I Allyl bromide I Allyl chloride I Amyl acetates 3 III Pentanols 3 II, III 526, Amylamine 3 8 II, III 529, Amyl chloride 3 II Pentene (n-amylene) 3 I Amyl formates 3 III n-amyl methyl ketone 3 III Amyl mercaptan 3 II 596 Handling and Carriage of Page App1.3

4 1112 Amyl nitrate 3 III Amyl nitrite 3 II Benzene 3 II Butanols 3 II, III 526, Butyl acetates 3 II, III 529, Butylamine, normal 3 8 II Bromobutane 3 II Chlorobutanes 3 II n-butyl formate 3 II Butyraldehyde 3 II Camphor oil 3 III Carbon disulphide I Adhesives containing flammable liquid 3 I, II, III 596, Chlorobenzene 3 III Ethylene chlorohydrin I Coal tar distillates 3 II, III 502, Coating solution 3 I, II, III 505, Crotonaldehyde or Crotonaldehyde stabilized I Crotonylene 3 I Cyclohexane 3 II Cyclopentane 3 II Decahydro-naphthalene 3 III Diacetone alcohol 3 II, III 526, Dibutyl ethers 3 III ,2-Dichloroethylene 3 II Dichloropentanes 3 III Ethylene glycol diethyl ether 3 II, III 529, Diethylamine 3 8 II Diethyl ether (Ethyl ether) 3 I Diethyl ketone 3 II Diisobutyl ketone 3 III Diisopropylamine 3 8 II Diisopropyl ether 3 II Dimethylamine, aqueous solution 3 8 II Dimethyl carbonate 3 II Dimethyldichlorosilane 3 8 II Dimethylhydrazine, unsymmetrical I Dimethyl sulphide 3 II Dioxane 3 II Dioxolane 3 II Divinyl ether, stabilized 3 I Extracts, aromatic, liquid 3 II, III 596, Ethanol (Ethyl alcohol or its solutions 3 II, III 526, Ethylene glycol monoethyl ether 3 III Ethylene glycol monoethyl ether acetate 3 III Ethyl acetate 3 II Ethylbenzene 3 II Ethyl borate 3 II Ethylbutyl acetate 3 III Ethylbutyraldehyde 3 II Ethyl butyl ether 3 II Ethyl butyrate 3 III Ethyl chloroacetate II 531 Handling and Carriage of Page App1.4

5 1182 Ethyl chloroformate 6.1 3, 8 I Ethyldichlorosilane 4.3 3, 8 I Ethylene dichloride II Ethyleneimine, stabilized I Ethylene glycol monomethyl ether 3 III Ethylene glycol monomethyl ether acetate 3 III Ethyl formate 3 II Octyl aldehydes 3 III Ethyl lactate 3 III Ethyl methyl ketone (Methyl ethyl ketone) 3 II Ethyl nitrite solution I Ethyl propionate 3 II Ethyltrichlorosilane 3 8 II Extracts, flavouring, liquid 3 II, III 596, Formaldehyde solution, flammable 3 8 III Furaldehydes II Fusel oil 3 II, III 526, Diesel fuel or gas oil or heating oil (light) 3 III 721 or Motor spirit or gasoline or petrol 3 II 716 or Nitroglycerin solution in alcohol 3 II Heptanes 3 II Hexaldehyde 3 III Hexanes 3 II Printing ink or related material, flammable 3 I, II, III 596, Isobutanol (Isobutyl alcohol) 3 III Isobutyl acetate 3 II Isobutylamine 3 8 II Isooctene 3 II Isoprene, stabilized 3 I Isopropanol (Isopropyl alcohol) 3 II Isopropyl acetate 3 II Isopropylamine 3 8 I Isopropyl nitrate 3 II Kerosene 3 III 712, 713, Ketones, liquid 3 II, III 529, Mercaptans or mercaptan mixture, liquid II, III 596, Mesityl oxide 3 III Methanol II Methyl acetate 3 II Methylamyl acetate 3 III Methylal 3 II Methylamine, aqueous solution 3 8 II Methyl butyrate 3 II Methyl chloroformate 6.1 3, 8 I Methyl chloromethyl ether I Methyldichlorosilane 4.3 3, 8 I Methyl formate 3 I Methylhydrazine 6.1 3, 8 I Methyl isobutyl ketone 3 II Methyl isopropenyl ketone, stabilized 3 II 529 Handling and Carriage of Page App1.5

6 1247 Methyl methacrylate monomer, stabilized 3 II Methyl propionate 3 II Methyl propyl ketone 3 II Methyltrichlorosilane 3 8 II Methyl vinyl ketone, stabilized 6.1 3, 8 I Nickel carbonyl I Nitromethane 3 II Octanes 3 II Paint or Paint related material 3 I, II, III 505, Paraldehyde 3 III Pentanes, liquid 3 I, II Perfumery products with flammable solvents 3 II, III 596 or Petroleum crude oil 3 I, II, III 730, Petroleum distillates or petroleum products 3 I, II, III 708, 709, 735, 736 or 734ø 1272 Pine oil 3 III n-propanol (Propyl alcohol, normal) 3 II, III 526, Propionaldehyde 3 II n-propyl acetate 3 II Propylamine 3 8 II Chloropropane 3 II ,2-Dichloropropane 3 II Propylene oxide 3 I Propyl formates 3 II Pyridine 3 II Rosin oil 3 II, III 520, Rubber solution 3 II, III 520, Shale oil 3 II, III 730, Sodium methylate solution in alcohol 3 8 II, III 526, Tetraethyl silicate 3 III Tinctures, medicinal 3 II, III Toluene 3 II Trichlorosilane 4.3 3, 8 I Triethylamine 3 8 II Trimethylamine, aqueous solution 3 8 I, II, III 520, Trimethylchlorosilane 3 8 II Turpentine 3 III Turpentine substitute 3 II, III Vinyl acetate, stabilized 3 II Vinyl ethyl ether, stabilized 3 I Vinylidene chloride, stabilized 3 I Vinyl isobutyl ether, stabilized 3 II Vinyltrichlorosilane 3 8 II Wood preservatives, liquid 3 II, III 502, Xylenes 3 II, III 529, 530, 735 or Zirconium suspended in a flammable liquid 3 I, II, III 596, Aluminium powder, coated 4.1 II, III Ammonium picrate, wetted 4.1 I Borneol 4.1 III 528 Handling and Carriage of Page App1.6

7 1313 Calcium resinate 4.1 III Calcium resinate, fused 4.1 III Cobalt resinate, precipitated 4.1 III Dinitrophenol, wetted I Dinitrophenolates, wetted I Dinitroresorcinol, wetted 4.1 I Ferrocerium 4.1 II Films, nitrocellulose base, gelatin coated 4.1 III 598 (scrap excluded) 1325 Flammable solid, organic 4.1 II, III Hafnium powder, wetted 4.1 II Hay, straw or bhusa Hexamethylenetetramine 4.1 III Manganese resinate 4.1 III Matches, "strike anywhere" 4.1 III Metaldehyde 4.1 III Cerium 4.1 II Naphthalene, crude or refined 4.1 III Nitroguanidine (Picrite), wetted 4.1 I Nitrostarch, wetted 4.1 I Phosphorus, amorphous 4.1 III Phosphorus heptasulphide 4.1 II Phosphorus pentasulphide II Phosphorus sesquisulphide 4.1 II Phosphorus trisulphide 4.1 II Trinitrophenol (Picric Acid), wetted 4.1 I Rubber scrap or Rubber shoddy 4.1 II Silicon powder, amorphous 4.1 III Silver picrate, wetted 4.1 I Sodium dinitro-o-cresolate, wetted I Sodium picramate, wetted 4.1 I Sulphur 4.1 III Titanium powder, wetted 4.1 II Fibres or fabrics impregnated with weakly 4.1 III 598 nitrated nitrocellulose 1354 Trinitrobenzene, wetted 4.1 I Trinitrobenzoic acid, wetted 4.1 I Trinitrotoluene (TNT), wetted 4.1 I Urea nitrate, wetted 4.1 I Zirconium powders, wetted 4.1 II Calcium phosphide I Carbon, animal or vegetable origin 4.2 II, III Carbon, activated 4.2 III Copra 4.2 III Cotton waste, oily 4.2 III Cotton, wet 4.2 III p-nitrosodimethylaniline 4.2 II Fibres, animal or fibres, vegetable burnt, wet or damp 1373 Fibres or fabrics, animal or vegetable or 4.2 III 598 synthetic, with oil 1374 Fish meal (Fish scrap), unstabilized 4.2 II Iron oxide, spent, or iron sponge, spent 4.2 III 598 Handling and Carriage of Page App1.7

8 1378 Metal catalyst, wetted 4.2 II Paper, unsaturated oil treated, incompletely dried 4.2 III 598 (includes carbon paper) 1380 Pentaborane I Phosphorus, white or yellow I Potassium sulphide, anhydrous 4.2 II Pyrophoric metal or alloy 4.2 I Sodium dithionite (Sodium hydrosulphite) 4.2 II Sodium sulphide, anhydrous 4.2 II Seed cake 4.2 III Wool waste, wet Alkali metal amalgam, liquid 4.3 I Alkali metal amides 4.3 II Alkali metal or alkaline earth metal dispersion 4.3 I Alkaline earth metal amalgam, liquid 4.3 I Alkaline earth metal alloy 4.3 II Aluminium carbide 4.3 II Aluminium ferrosilicon powder II Aluminium powder, uncoated 4.3 II, III Aluminium phosphide I Aluminium silicon powder, uncoated 4.3 III Barium 4.3 II Calcium 4.3 II Calcium carbide 4.3 I, II Calcium cyanamide 4.3 III Calcium hydride 4.3 I Calcium silicide 4.3 II, III Caesium 4.3 I Ferrosilicon III Metal hydrides, water-reactive 4.3 I, II Lithium aluminium hydride 4.3 I Lithium aluminium hydride, ethereal I Lithium borohydride 4.3 I Lithium hydride 4.3 I Lithium 4.3 I Lithium silicon 4.3 II Magnesium or magnesium alloys, powder I, II, III Magnesium aluminium phosphide I Potassium metal alloys, liquid 4.3 I Alkali metal alloy, liquid 4.3 I Potassium sodium alloys, liquid 4.3 I Rubidium 4.3 I Sodium borohydride 4.3 I Sodium hydride 4.3 I Sodium 4.3 I Sodium methylate II Sodium phosphide I Stannic phosphides I Zinc ashes 4.3 III Zinc, powder or dust I, II, III Zirconium hydride 4.1 II Aluminium nitrate 5.1 III Ammonium dichromate 5.1 II 598 Handling and Carriage of Page App1.8

9 1442 Ammonium perchlorate 5.1 II Ammonium persulphate 5.1 III Barium chlorate, solid II Barium nitrate II Barium perchlorate, solid II Barium permanganate II Barium peroxide II Bromates, inorganic 5.1 II Caesium nitrate 5.1 III Calcium chlorate 5.1 II Calcium chlorite 5.1 II Calcium nitrate 5.1 III Calcium perchlorate 5.1 II Calcium permanganate 5.1 II Calcium peroxide 5.1 II Chlorate and borate mixture 5.1 II, III Chlorate and magnesium chloride mixture, solid 5.1 II, III Chlorates, inorganic 5.1 II Chlorites, inorganic 5.1 II Chromium trioxide, anhydrous , 8 II Didymium nitrate 5.1 III Ferric nitrate 5.1 III Guanidine nitrate 5.1 III Lead nitrate II Lead perchlorate, solid II Lithium hypochlorite, dry or mixture 5.1 II,III Lithium peroxide 5.1 II Magnesium bromate 5.1 II Magnesium nitrate 5.1 III Magnesium perchlorate 5.1 II Magnesium peroxide 5.1 II Nitrates, inorganic 5.1 II, III Oxidizing solid 5.1 I, II, III Perchlorates, inorganic 5.1 II, III Permanganates, inorganic 5.1 II, III Peroxides, inorganic 5.1 II, III Potassium bromate 5.1 II Potassium chlorate 5.1 II Potassium nitrate 5.1 III Potassium nitrate and sodium nitrite mixture 5.1 II Potassium nitrite 5.1 II Potassium perchlorate 5.1 II Potassium permanganate 5.1 II Potassium peroxide 5.1 I Potassium persulphate 5.1 III Silver nitrate 5.1 II Sodium bromate 5.1 II Sodium chlorate 5.1 II Sodium chlorite 5.1 II Sodium nitrate 5.1 III Sodium nitrate and potassium nitrate mixture 5.1 III Sodium nitrite III Sodium perchlorate 5.1 II 594 Handling and Carriage of Page App1.9

10 1503 Sodium permanganate 5.1 II Sodium peroxide 5.1 I Sodium persulphate 5.1 III Strontium chlorate 5.1 II Strontium nitrate 5.1 III Strontium perchlorate 5.1 II Strontium peroxide 5.1 II Tetranitromethane I Urea hydrogen peroxide III Zinc ammonium nitrite 5.1 II Zinc chlorate 5.1 II Zinc nitrate 5.1 II Zinc permanganate 5.1 II Zinc peroxide 5.1 II Zirconium picramate, wetted 4.1 I Acetone cyanohydrin, stabilized 6.1 I Alkaloids, toxic, or their salts, solid 6.1 I, II, III Allyl isothiocyanate, stabilized II Ammonium arsenate 6.1 II Aniline 6.1 II Aniline hydrochloride 6.1 III Antimony compound, inorganic, solid 6.1 III Antimony lactate 6.1 III Antimony potassium tartrate 6.1 III Arsenic acid, liquid 6.1 I Arsenic acid, solid 6.1 II Arsenic bromide 6.1 II Arsenic compound, liquid 6.1 I, II, III Arsenic compound, solid 6.1 I, II, III Arsenic 6.1 II Arsenic pentoxide 6.1 II Arsenic trichloride 6.1 I Arsenic trioxide 6.1 II Arsenical dust 6.1 II Barium compound 6.1 II, III Barium cyanide 6.1 I Beryllium compound 6.1 II, III Beryllium, powder II Bromoacetone II Brucine 6.1 I Barium azide, wetted I Cacodylic acid 6.1 II Calcium arsenate 6.1 II Calcium arsenate and calcium arsenite mixture, solid 6.1 II Calcium cyanide 6.1 I Chlorodinitrobenzenes, liquid 6.1 II Chloronitrobenzenes, solid 6.1 II Chloro-toluidine hydrochloride, solid 6.1 III Chloropicrin 6.1 I Chloropicrin and methyl bromide mixture with , 550 more than 2% chloropicrin 1582 Chloropicrin and methyl chloride mixture , Chloropicrin mixture 6.1 I, II, III 598 Handling and Carriage of Page App1.10

11 1585 Copper acetoarsenite 6.1 II Copper arsenite 6.1 II Copper cyanide 6.1 II Cyanides, inorganic, solid 6.1 I, II, III Cyanogen chloride, stabilized Dichloroanilines, liquid 6.1 II o-dichlorobenzene 6.1 III Dichloromethane 6.1 III Diethyl sulphate 6.1 II Dimethyl sulphate I Dinitroanilines 6.1 II Dinitrobenzenes, liquid 6.1 II, III Dinitro-o-cresol 6.1 II Dinitrophenol solution 6.1 II, III Dinitrotoluenes, molten 6.1 II Disinfectant, solid, toxic 6.1 I, II, III Dye, liquid, toxic or dye intermediate, liquid, toxic 6.1 I, II, III Ethyl bromoacetate II Ethylenediamine 8 3 II Ethylene dibromide (1,2-Dibromoethane) 6.1 I Ferric arsenate 6.1 II Ferric arsenite 6.1 II Ferrous arsenate 6.1 II Hexaethyl tetraphosphate 6.1 II Hexaethyl tetraphosphate and compressed , 550 gas mixture 1613 Hydrocyanic acid, aqueous solution I 553 (Hydrogen cyanide, aqueous solution) 1614 Hydrogen cyanide, stabilized I Lead acetate 6.1 III Lead arsenates 6.1 II Lead arsenites 6.1 II Lead cyanide 6.1 II London Purple 6.1 II Magnesium arsenate 6.1 II Mercuric arsenate 6.1 II Mercuric chloride 6.1 II Mercuric nitrate 6.1 II Mercuric potassium cyanide 6.1 I Mercurous nitrate 6.1 II Mercury acetate 6.1 II Mercury ammonium chloride 6.1 II Mercury benzoate 6.1 II Mercury bromides 6.1 II Mercury cyanide 6.1 II Mercury gluconate 6.1 II Mercury iodide 6.1 II Mercury nucleate 6.1 II Mercury oleate 6.1 II Mercury oxide 6.1 II Mercury oxycyanide, desensitized 6.1 II Mercury potassium iodide 6.1 II Mercury salicylate 6.1 II 594 Handling and Carriage of Page App1.11

12 1645 Mercury sulphate 6.1 II Mercury thiocyanate 6.1 II Methyl bromide and ethylene dibromide 6.1 I 576 mixture, liquid 1648 Acetonitrile 3 II Motor fuel anti-knock mixture 6.1 I beta-napthylamine, solid 6.1 II Naphthylthiourea 6.1 II Naphthylurea 6.1 II Nickel cyanide 6.1 II Nicotine 6.1 II Nicotine compounds or preparations thereof, solid 6.1 I, II, III Nicotine hydrochloride, liquid or solution 6.1 II, III Nicotine salicylate 6.1 II Nicotine sulphate solution 6.1 II, III Nicotine tartrate 6.1 II Nitric oxide, compressed , Nitroanilines 6.1 II Nitrobenzene 6.1 II Nitrophenols 6.1 III Nitrotoluenes, liquid 6.1 II Nitroxylenes, liquid 6.1 II Pentachloroethane 6.1 II Perchloromethylmercaptan 6.1 I Phenol, solid 6.1 II Phenylcarbylamine chloride 6.1 I Phenylenediamines 6.1 III Phenylmercuric acetate 6.1 II Potassium arsenate 6.1 II Potassium arsenite 6.1 II Potassium cuprocyanide 6.1 II Potassium cyanide, solid 6.1 I Silver arsenite 6.1 II Silver cyanide 6.1 II Sodium arsenate 6.1 II Sodium arsenite, aqueous solution 6.1 II, III Sodium azide 6.1 II Sodium cacodylate 6.1 II Sodium cyanide, solid 6.1 I Sodium fluoride, solid 6.1 III Strontium arsenite 6.1 II Strychnine or salts thereof 6.1 I Tear gas substance, liquid 6.1 I, II Bromobenzyl cyanides, liquid 6.1 I Chloroacetone, stabilized 6.1 3, 8 I Chloroacetophenone, solid 6.1 II Diphenylaminechloroarsine 6.1 I Diphenylchloroarsine, liquid 6.1 I Tear-gas candles Xylyl bromide, liquid 6.1 II ,1,2,2-Tetrachloroethane 6.1 II Tetraethyl dithiopyrophosphate 6.1 II Thallium compounds 6.1 II 594 Handling and Carriage of Page App1.12

13 1708 Toluidines, liquid 6.1 II ,4-Toluylenediamine, solid 6.1 III Trichloroethylene 6.1 III Xylidines, liquid 6.1 II Zinc arsenate and zinc arsenite or mixture thereof 6.1 II Zinc cyanide 6.1 I Zinc phosphide I Acetic anhydride 8 3 II Acetyl bromide 8 II Acetyl chloride 3 8 II Butyl acid phosphate 8 III Caustic alkali liquids 8 II, III Allyl chloroformate 6.1 3, 8 I Allyl iodide 3 8 II Allyl trichlorosilane, stabilized 8 3 II Aluminium bromide, anhydrous 8 II Aluminium chloride, anhydrous 8 II Ammonium hydrogendifluoride, solid 8 II Amyltrichlorosilane 8 II Anisoyl chloride 8 II Antimony pentachloride, liquid 8 II Antimony pentachloride, solution 8 II, III Antimony pentafluoride II Antimony trichloride 8 II Benzoyl chloride 8 I Benzyl bromide II Benzyl chloride II Benzyl chloroformate 8 I Hydrogendifluorides, solid 8 II, III Boron trichloride , Boron trifluoride acetic acid complex, liquid 8 II Boron trifluoride propionic acid complex, liquid 8 II Bromine or bromine solution I Bromine pentafluoride , 8 I Bromine trifluoride , 8 I Butyltrichlorosilane 8 3 II Calcium hypochlorite, dry or Calcium hypochlorite 5.1 II, III 598 mixture, dry 1749 Chlorine trifluoride , 8 535, Chloroacetic acid, solution II Chloroacetic acid, solid II Chloroacetyl chloride I Chlorophenyl trichlorosilane 8 II Chlorosulphonic acid 8 I Chromic acid solution 8 II, III Chromic fluoride, solid 8 II Chromic fluoride, solution 8 II, III Chromium oxychloride 8 I Corrosive solid 8 I, II, III Corrosive liquid 8 I, II, III Cupriethylenediamine solution II, III Cyclohexenyltrichlorosilane 8 II Cyclohexyltrichlorosilane 8 II 522 Handling and Carriage of Page App1.13

14 ember 1764 Dichloroacetic acid 8 II Dichloroacetyl chloride 8 II Dichlorophenyltrichlorosilane 8 II Diethyldichlorosilane 8 3 II Difluorophosphoric acid, anhydrous 8 II Diphenyldichlorosilane 8 II Diphenylmethyl bromide 8 II Dodecyltrichlorosilane 8 II Ferric chloride, anhydrous 8 III Fire extinguisher charges, corrosive liquid 8 II Fluoroboric acid 8 II Fluorophosphoric acid, anhydrous 8 II Fluorosulphonic acid 8 I Fluorosilicic acid 8 II Formic acid with more than 85% acid 8 3 II Fumaryl chloride 8 II Hexadecyltrichlorosilane 8 II Hexafluorophosphoric acid 8 II Hexamethylenediamine solution 8 III Hexyltrichlorosilane 8 II Hydrofluoric acid and sulphuric acid mixture I Hydriodic acid 8 II, III Hydrobromic acid 8 III Hydrochloric acid 8 II, III Hydrofluoric acid I, II Hypochlorite solution 8 II, III Iodine monochloride solid 8 II Isopropyl acid phosphate 8 III Lead sulphate 8 II Nitrating acid mixture I Nitrating acid mixture 8 II Nitrohydrochloric acid 8 CARRIAGE PROHIBITED 1799 Nonyltrichlorosilane 8 II Octadecyltrichlorosilane 8 II Octyltrichlorosilane 8 II Perchloric acid, not more than 50% II Phenolsulphonic acid, liquid 8 II Phenyltrichlorosilane 8 II Phosphoric acid solution 8 III Phosphorus pentachloride 8 II Phosphorus pentoxide 8 II Phosphorus tribromide 8 II Phosphorus trichloride I Phosphorus oxychloride I Potassium hydrogendifluoride solid II Potassium fluoride, solid 6.1 III Potassium hydroxide, solid 8 II Potassium hydroxide solution 8 II, III Propionyl chloride 3 8 II Propyltrichlorosilane 8 3 II Pyrosulphuryl chloride 8 II Silicon tetrachloride 8 II Sodium aluminate solution 8 II, III 557 Handling and Carriage of Page App1.14

15 1823 Sodium hydroxide, solid 8 II Sodium hydroxide solution 8 II, III Sodium monoxide 8 II Nitrating acid mixture, spent I Stannic chloride, anhydrous 8 II Sulphur chlorides 8 I Sulphur trioxide, stabilized 8 I Sulphuric acid with more than 51% acid 8 II Sulphuric acid, fuming Oleum I Sulphuric acid, spent 8 II Sulphurous acid 8 II Sulphuryl chloride I Tetramethylammonium hydroxide solution 8 II, III Thionyl chloride 8 I Thiophosphoryl chloride 8 II Titanium tetrachloride I Trichloroacetic acid 8 II Zinc chloride, solution 8 III Acetaldehyde ammonia 9 III Ammonium dinitro-o-creosolate, solid 6.1 II 598 $1845 Carbon dioxide, solid (Dry Ice) Carbon tetrachloride 6.1 II Potassium sulphide, hydrated 8 II Propionic acid with less than 90% acid 8 III Sodium sulphide, hydrated 8 II Medicine, liquid, toxic 6.1 II Barium alloys, pyrophoric 4.2 III Calcium or calcium alloys, pyrophoric 4.2 I Rags, oily - I Textile waste, wet Hexafluoropropylene (R 1216) Silicon tetrafluoride , Vinyl fluoride, stabilized Ethyl crotonate 3 II Fuel, aviation, turbine engine 3 I, II, III 717, n-propyl nitrate 3 II Resin solution 3 I, II, III 520, Decaborane II Magnesium or magnesium alloys 4.1 III Potassium borohydride 4.3 I Titanium hydride 4.1 II Lead dioxide III Perchloric acid, more than 50% I Barium oxide 6.1 III Benzidine 6.1 II Benzylidene chloride 6.1 II Bromochloromethane 6.1 III Chloroform 6.1 III Cyanogen bromide I Ethyl bromide (Bromoethane) 6.1 II Ethyldichloroarsine 6.1 I Phenylmercuric hydroxide 6.1 II Phenylmercuric nitrate 6.1 II 579 Handling and Carriage of Page App1.15

16 1897 Tetrachloroethylene (Perchloroethylene) 6.1 III Acetyl iodide 8 II Diisooctyl acid phosphate 8 III Disinfectant, liquid, corrosive 8 I, II, III Selenic acid 8 I Sludge acid 8 II Soda lime with more than 4% sodium hydroxide 8 III Chlorite solution 8 II, III Calcium oxide Diborane Methyl chloride and methylene chloride mixture Neon, refrigerated liquid Butyl propionates 3 III Cyclohexanone 3 III ,2 -Dichlorodiethyl ether II Ethyl acrylate, stabilized 3 II Isopropylbenzene 3 III Methyl acrylate, stabilized 3 II Nonanes 3 III Propyleneimine, stabilized I Pyrrolidine 3 8 II Calcium dithionite (Calcium hydrosulphite) 4.2 II Methyl magnesium bromide in ethyl ether I Potassium dithionite (Potassium hydrosulphite) 4.2 II Zinc dithionite (Zinc hydrosulphite) 9 III Zirconium scrap 4.2 III Cyanide solution 6.1 I, II, III Bromoacetic acid solution 8 II, III Phosphorus oxybromide 8 II Thioglycolic acid 8 II Dibromodifluoromethane 9 III Ammonium nitrate 5.1 III Matches, safety 4.1 III Matches, wax ''Vesta 4.1 III Aerosols 2.1, , 543, , Argon, refrigerated liquid Ethylene oxide and carbon dioxide mixture Compressed gas, toxic, flammable , Compressed gas, flammable, Compressed gas, toxic , Compressed gas, non-flammable, non-toxic Deuterium, compressed ,2-Dichloro-1,1,2,2-tetrafluoroethane (R 114) ,1-Difluoroethylene (R 1132a) Ethane, refrigerated liquid Ethylene Helium, refrigerated liquid Hydrocarbon gas mixture, compressed Hydrocarbon gas mixture, liquefied Hydrogen, refrigerated liquid Insecticide gas, toxic , Insecticide gas, non-toxic Handling and Carriage of Page App1.16

17 1969 Isobutane Krypton, refrigerated liquid Methane or natural gas, compressed Methane or natural gas, refrigerated liquid Chlorodifluoromethane and chloropentafluoroethane mixture (R 502) 1974 Chlorodifluorobromomethane (R12B1) Nitric oxide and nitrogen dioxide mixture , Octafluorocyclobutane (RC 318) Nitrogen, refrigerated liquid Propane Tetrafluoromethane (R 14) Chloro-2,2,2-trifluoroethane (R 133a) Trifluoromethane (R 23) Alcohols, flammable, toxic I, II, III 526, Alcohols 3 II, III 526, Aldehydes, flammable, toxic I, II, III 529, Aldehydes 3 I, II, III 529, Benzaldehyde 9 III Chloroprene, stabilized I Flammable liquid, toxic I, II, III 596, Flammable liquid, non-toxic 3 I, II, III 596, Iron pentacarbonyl I Tars, liquid, including road asphalt and oils, 3 II, III 500, 733, bitumen and cut-backs 735 or Celluloid, in block, rods, rolls, sheets, tubes, etc., 4.1 III 598 except scrap excluded) 2001 Cobalt naphthenates, powder 4.1 III Celluloid, scrap 4.2 III Magnesium diamide 4.2 II Plastics, nitrocellulose-based, self-heating 4.2 III Zirconium powder, dry 4.2 I, II, III Zirconium, dry, finished sheets, strip or coiled wire 4.2 III Magnesium hydride 4.3 I Magnesium phosphide I Potassium phosphide I Strontium phosphide I Hydrogen peroxide, aqueous solution with not less II 574 than 20% but not more than 60% hydrogen peroxide 2015 Hydrogen peroxide, stabilized or hydrogen peroxide, I 574 aqueous solution, stabilized with more than 60% hydrogen peroxide 2016 Ammunition, toxic, non-explosive Ammunition, tear-producing, non-explosive Chloroanilines, solid 6.1 II Chloroanilines, liquid 6.1 II Chlorophenols, solid 6.1 III Chlorophenols, liquid 6.1 III Cresylic acid II Epichlorohydrin II Mercury compound, liquid 6.1 I, II, III Mercury compound, solid 6.1 I, II, III 594 Handling and Carriage of Page App1.17

18 2026 Phenylmercuric compound 6.1 I, II, III Sodium arsenite, solid 6.1 II Bombs, smoke, non-explosive with corrosive liquid 8 II Hydrazine, anhydrous 8 3, 6.1 I Hydrazine aqueous solution, with more than 37% I, II, III 557 hydrazine 2031 Nitric acid, with more than 70% nitric acid I Nitric acid, with at least 65%, but not more II 554 than 70% nitric acid 2031 Nitric acid, with less than 65% nitric acid 8 II Nitric acid, red fuming 8 5.1, 6.1 I Potassium monoxide 8 II Hydrogen and methane mixture, compressed ,1,1-Trifluoroethane (R 143a) Xenon Receptacles, small, containing gas (gas cartridges) 2.1, , 8 543, Dinitrotoluenes, liquid 6.1 II ,2-Dimethylpropane Isobutyraldehyde (Isobutyl aldehyde) 3 II Cymenes 3 III Dichloropropenes 3 II, III Dicyclopentadiene 3 III Diethylbenzene 3 III Di-isobutylene, isomeric compounds 3 II Dimethylaminoethanol 8 3 II Dipentene 3 III Methyl isobutyl carbinol 3 III Morpholine 8 3 I Styrene monomer, stabilized 3 III Tetrahydrofuran 3 II Tripropylene 3 II, III 596, Valeraldehyde 3 II Nitrocellulose solution, flammable 3 I, II, III 505, Ammonium nitrate based fertilizer 5.1 III Ammonium nitrate based fertilizer Ammonia solution with more than 35% ammonia Acrylamide, solid 6.1 III Chloral, anhydrous, stabilized 6.1 II Cresols, liquid II alpha-naphthylamine 6.1 III Toluene diisocyanate 6.1 II Diethylenetriamine 8 II Hydrogen chloride, refrigerated liquid 2 CARRIAGE PROHIBITED 2187 Carbon dioxide, refrigerated liquid Arsine Dichlorosilane , 8 535, Oxygen difluoride, compressed , Sulphuryl fluoride , Germane , Hexafluoroethane (R 116) Selenium hexafluoride Handling and Carriage of Page App1.18

19 2195 Tellurium hexafluoride Tungsten hexafluoride Hydrogen iodide, anhydrous , Phosphorus pentafluoride Phosphine Propadiene, stabilized Nitrous oxide, refrigerated liquid Hydrogen selenide, anhydrous Silane Carbonyl sulphide , Adiponitrile 6.1 III Isocyanates, toxic or isocyanate solution, toxic 6.1 II, III Calcium hypochlorite mixture, dry 5.1 III Formaldehyde solution 8 III Maneb or maneb preparation III Polymeric beads, expandable 9 III Asbestos, amphibole (amosite, tremolite, actinolite 9 II 959 anthophyllite, crocidolite) 2213 Paraformaldehyde 4.1 III Phthalic anhydride with more than 0 05% 8 III 522 maleic anhydride 2215 Maleic anhydride or maleic anhydride, molten 8 III Fish meal (fish scrap), stabilized Seed cake 4.2 III Acrylic acid, stabilized 8 3 II Allyl glycidyl ether 3 III Anisole 3 III Benzonitrile 6.1 II Benzenesulphonyl chloride 8 III Benzotrichloride 8 II n-butyl methacrylate, stabilized 3 III Chloroethanal 6.1 I Chloroanisidines 6.1 III Chlorobenzotrifluorides 3 III Chlorobenzyl chlorides, liquid 6.1 III Chloro-4-methylphenyl isocyanate, liquid 6.1 II Chloronitroanilines 6.1 III Chlorotoluenes 3 III Chlorotoluidines, solid 6.1 III Chromosulphuric acid 8 I Cycloheptane 3 II Cycloheptene 3 II Cyclohexyl acetate 3 III Cyclopentanol 3 III Cyclopentanone 3 III Cyclopentene 3 II n-decane 3 III Di-n-butylamine 8 3 II Dichlorodimethyl ether 6.1 CARRIAGE PROHIBITED 2250 Dichlorophenyl isocyanates 6.1 II Bicyclo[2,2,1]hepta-2,5-diene, stabilized 3 II 596 (2,5-Norbornadiene, stabilized) ,2-Dimethoxyethane 3 II 529 Handling and Carriage of Page App1.19

20 2253 N,N-Dimethylaniline 6.1 II Matches, fusee 4.1 III Cyclohexene 3 II Potassium 4.3 I , 2-Propylenediamine 8 3 II Triethylenetetramine 8 II Tripropylamine 3 8 III Xylenols, solid 6.1 II Dimethylcarbamoyl chloride 8 II Dimethylcyclohexanes 3 II N,N-Dimethylcyclohexylamine 8 3 II N,N-Dimethylformamide 3 III Dimethyl-N-propylamine 3 8 II Dimethyl thiophosphoryl chloride II ,3'-Iminodipropylamine 8 III Ethylamine, 50-70% aqueous solution 3 8 II Ethyl amyl ketone 3 III N-Ethylaniline 6.1 III Ethylaniline 6.1 III N-Ethyl-N-benzylaniline 6.1 III Ethylbutanol 3 III Ethylhexylamine 3 8 III Ethyl methacrylate, stabilized 3 II n-heptene 3 II Hexachlorobutadiene 6.1 III Hexamethylenediamine, solid 8 III Hexamethylene diisocyanate 6.1 II Hexanols 3 III Isobutyl methacrylate, stabilized 3 III Isobutyronitrile II Isocyanatobenzotrifluorides II Pentamethylheptane 3 III Isoheptene 3 II Isohexene 3 II Isophoronediamine 8 III Isophorone diisocyanate 6.1 III Lead compound, soluble 6.1 III Methoxy-4-methylpentan-2-one 3 III N-Methylaniline 6.1 III Methyl chloroacetate I Methylcyclohexane 3 II Methylcyclohexanone 3 III Methylcyclopentane 3 II Methyl dichloroacetate 6.1 III Methyl-5-ethylpyridine 6.1 III Methylfuran 3 II Methylhexan-2-one 3 III Isopropenylbenzene 3 III Naphthalene, molten 4.1 III Nitrobenzenesulphonic acid 8 II Nitrobenzotrifluorides, liquid 6.1 II Nitro-4-chlorobenzotrifluoride 6.1 II Nitrosylsulphuric acid, liquid 8 II 557 Handling and Carriage of Page App1.20

21 2309 Octadienes 3 II Pentane-2,4-dione III Phenetidines 6.1 III Phenol, molten 6.1 II Picolines 3 III Polychlorinated biphenyls, liquid 9 II Sodium cuprocyanide, solid 6.1 I Sodium cuprocyanide solution 6.1 I Sodium hydrosulphide 4.2 II Terpene hydrocarbons 3 III Tetraethylenepentamine 8 III Trichlorobenzenes, liquid 6.1 III Trichlorobutene 6.1 II Triethyl phosphite 3 III Triisobutylene 3 III ,3,5-Trimethylbenzene 3 III Trimethylcyclohexylamine 8 III Trimethylhexamethylenediamines 8 III Trimethylhexamethylene diisocyanate 6.1 III Trimethyl phosphite 3 III Undecane 3 III Zinc chloride, anhydrous 8 III Acetaldehyde oxime 3 III Allyl acetate II Allylamine I Allyl ethyl ether II Allyl formate I Phenyl mercaptan I Benzotrifluoride 3 II Bromobutane 3 II Bromoethyl ethyl ether 3 II Bromo-3-methylbutane 3 III Bromomethylpropanes 3 II Bromopentane 3 II Bromopropanes 3 II, III Bromopropyne 3 II Butanedione 3 II Butyl mercaptan 3 II Butyl acrylates, stabilized 3 III Butyl methyl ether 3 II Butyl nitrites 3 II, III 596, Butyl vinyl ether, stabilized 3 II Butyryl chloride 3 8 II Chloromethyl ethyl ether II Chloropropane 3 I Cyclohexylamine 8 3 II Cyclooctatetraene 3 II Diallylamine 3 6.1, 8 II Diallylether II Diisobutylamine 3 8 III , 1-Dichloroethane 3 II Ethyl mercaptan 3 I n-propylbenzene 3 III 597 Handling and Carriage of Page App1.21

22 2366 Diethyl carbonate 3 III alpha-methyl valeraldehyde 3 II alpha-pinene 3 III Hexene 3 II Isopentenes 3 I ,2-Di-(dimethylamino) ethane 3 II Diethoxymethane 3 II ,3-Diethoxypropene 3 II Diethyl sulphide 3 II ,3-Dihydropyran 3 II ,1-Dimethoxyethane 3 II Dimethylaminoacetonitrile II ,3-Dimethylbutylamine 3 8 II Dimethyldiethoxysilane 3 II Dimethyl disulphide II Dimethylhydrazine, symmetrical I Dipropylamine 3 8 II Di-n-propyl ether 3 II Ethyl isobutyrate 3 II Ethylpiperidine 3 8 II Fluorobenzene 3 II Fluorotoluenes 3 II Furan 3 I Iodobutane 3 II Iodomethylpropanes 3 II Iodopropanes 3 III Isobutyl formate 3 II Isobutyl propionate 3 III Isobutyryl chloride 3 8 II Methacrylaldehyde, stabilized II Methylbutan-2-one 3 II Methyl tert-butyl ether 3 II Methylpiperidine 3 8 II Methyl isovalerate 3 II Piperidine 8 3 I Propanethiols 3 II Isopropenyl acetate 3 II Propionitrile II Isopropyl butyrate 3 III Isopropyl isobutyrate 3 II Isopropyl chloroformate 6.1 3, 8 I Isopropyl propionate 3 II ,2,3,6-Tetrahydropyridine 3 II Butyronitrile II Tetrahydrothiophene 3 II Tetrapropyl orthotitanate 3 III Thiophene 3 II Trimethyl borate 3 II Carbonyl fluoride , Sulphur tetrafluoride Bromotrifluorethylene Hexafluoroacetone , Nitrogen trioxide 2 CARRIAGE PROHIBITED Handling and Carriage of Page App1.22

23 2422 Octafluorobut-2-ene (R 1318) Octafluoropropane (R 218) Ammonium nitrate, liquid (hot concentrated solution) Potassium chlorate, aqueous solution 5.1 II, III Sodium chlorate, aqueous solution 5.1 II, III Calcium chlorate, aqueous solution 5.1 II, III Alkylphenols, solid 8 I, II, III Anisidines 6.1 III N, N-Diethylaniline 6.1 III Chloronitrotoluenes, liquid 6.1 III Dibenzyldichlorosilane 8 II Ethyl phenyl dichlorosilane 8 II Thioacetic acid 3 II Methylphenyldichlorosilane 8 II Trimethylacetyl chloride 6.1 3, 8 I Sodium hydrogendifluoride 8 II Stannic chloride pentahydrate 8 III Titanium trichloride, pyrophoric or titanium I 598 trichloride mixture, pyrophoric 2442 Trichloroacetyl chloride 8 II Vanadium oxytrichloride 8 II Vanadium tetrachloride 8 I Nitrocresols, solid 6.1 III Phosphorus, white, molten I Sulphur, molten 4.1 III Nitrogen trifluoride Ethylacetylene, stabilized Ethyl fluoride (R 161) Methyl fluoride (R 41) Methyl nitrite 2 CARRIAGE PROHIBITED Chloropropene 3 I ,3-Dimethylbutane 3 II Hexadienes 3 II Methyl-1-butene 3 I Methyl-2-butene 3 II Methylpentadiene 3 II Aluminium hydride 4.3 I Beryllium nitrate II Dichloroisocyanuric acid dry or its salts 5.1 II Potassium superoxide 5.1 I Trichloroisocyanuric acid, dry 5.1 II Zinc bromate 5.1 III Phenylacetonitrile, liquid 6.1 III Osmium tetroxide 6.1 I Sodium arsanilate 6.1 III Thiophosgene 6.1 I Vanadium trichloride 8 III Methyl isothiocyanate I Isocyanates, flammable, toxic or isocyanate II, III 520, 521 solution, flammable, toxic 2480 Methyl isocyanate I Ethyl isocyanate I n-propyl isocyanate I 522 Handling and Carriage of Page App1.23

24 2483 Isopropyl isocyanate I tert-butyl isocyanate I n-butyl isocyanate I Isobutyl isocyanate I Phenyl isocyanate I Cyclohexyl isocyanate I Dichloroisopropyl ether 6.1 II Ethanolamine or ethanolamine solution 8 III Hexamethyleneimine 3 8 II Iodine pentafluoride , 8 I Propionic anhydride 8 III ,2,3,6-Tetrahydro-benzaldehyde 3 III Tris-(1-aziridinyl) phosphine oxide solution 6.1 II, III Valeryl chloride 8 3 II Zirconium tetrachloride 8 III Tetrabromoethane 6.1 III Ammonium fluoride 6.1 III Ammonium hydrogen sulphate 8 II Chloroplatinic acid, solid 8 III Molybdenum pentachloride 8 III Potassium hydrogen sulphate 8 II Chloropropionic acid 8 III Aminophenols 6.1 III Bromoacetyl bromide 8 II Bromobenzene 3 III Bromoform 6.1 III Carbon tetrabromide 6.1 III Chloro-1,1-difluoroethane (R 142b) ,5,9-Cyclododecatriene 6.1 III Cyclooctadienes 3 III Diketene, stabilized I Dimethylaminoethyl methacrylate 6.1 II Ethyl orthoformate 3 III Ethyl oxalate 6.1 III Furfurylamine 3 8 III Isobutyl acrylate, stabilized 3 III Isobutyl isobutyrate 3 III Isobutyric acid 3 8 III Methacrylic acid, stabilized 8 II Methyl trichloroacetate 6.1 III Methylchlorosilane , 8 535, Methylmorpholine (N-Methylmorpholine) 3 8 II Methyltetrahydrofuran 3 II Nitronaphthalene 4.1 III Terpinolene 3 III Tributylamine 6.1 II Hafnium powder, dry 4.2 I, II, III Titanium powder, dry 4.2 I, II, III Sodium superoxide 5.1 I Chlorine pentafluoride , Hexafluoroacetone hydrate, liquid 6.1 II Methylallyl chloride 3 II Nitrocellulose with water 4.1 II 507 Handling and Carriage of Page App1.24

25 2556 Nitrocellulose with alcohol 4.1 II Nitrocellulose mixture with or without plasticizer 4.1 II 507 or pigment 2558 Epibromohydrin I Methylpentan-2-ol 3 III Methyl-1-butene 3 I Trichloroacetic acid solution 8 II, III Dicyclohexylamine 8 III Sodium pentachlorophenate 6.1 II Cadmium compound 6.1 I, II, III Alkylsulphuric acids 8 II Phenylhydrazine 6.1 II Thallium chlorate II Tricresyl phosphate 6.1 II Phosphorus oxybromide, molten 8 II Phenylacetyl chloride 8 II Phosphorus trioxide 8 III Piperazine 8 III Aluminium bromide solution 8 III Aluminium chloride solution 8 III Ferric chloride solution 8 III Alkyl or aryl sulphonic acids, solid, with more than 8 II 557 5% free sulphuric acid 2584 Alkyl or aryl sulphonic acids, liquid, with more than 8 II 557 5% free sulphuric acid 2585 Alkyl or aryl sulphonic acids, solid, with not more 8 III 557 than 5% free sulphuric acid 2586 Alkyl or aryl sulphonic acids, liquid, with not more 8 III 557 than 5% free sulphuric acid 2587 Benzoquinone 6.1 II Pesticide, solid, toxic 6.1 I, II, III Vinyl chloroacetate II Asbestos, chrysotile 9 III Xenon, refrigerated liquid Chlorotrifluoromethane and trifluoromethane azeotropic mixture (R 503) 2601 Cyclobutane Dichlorodifluoromethane and 1,1-difluoroethane azeotropic mixture (R 500) 2603 Cycloheptatriene II Boron trifluoride diethyl etherate 8 3 I Methoxymethyl isocyanate I Methyl orthosilicate I Acrolein dimer, stabilized 3 III Nitropropanes 3 III Triallyl borate 6.1 III Triallylamine 3 8 III Propylene chlorohydrin II Methyl propyl ether 3 II Methallyl alcohol 3 III Ethyl propyl ether 3 II Triisopropyl borate 3 II, III 596, Methylcyclohexanols, flammable 3 III 527 Handling and Carriage of Page App1.25