Material Safety Data Sheet Isagum BV 1304 stabilizer

Transcription

1 Material Safety Data Sheet Isagum BV 1304 stabilizer SDS # : B FMC BioPolymer This MSDS has been prepared to meet U.S. OSHA Hazard Communication Standard 29 CFR andcanada sworkplacehazardousmaterialsinformationsystem (WHMIS)requirements. 1. PRODUCT AND COMPANY IDENTIFICATION Product name Synyms Isagum BV 1304 stabilizer Sodium Carboxymethylcellulose: NaCMC, CMC, SCMC, Carboxymethyl ether, Sodium CMC, Sodium salt, Cellulose gum; Gellan gum; : CI 77220; Carbonic acid, calcium salt (1:1); Pigment white 18; Precipitated chalk Recommended use Manufacturer FMC BioPolymer 1735 Market Street Philadelphia, PA (800) msdsinfo@fmc.com Foodstuff application. Emergency telephone number Medical Emergencies: (800) (U.S.A. & Canada) +1 (651) (All Other Countries - Collect) For leak, fire, spill or accident emergencies, call: / (CHEMTREC - U.S.A.) / (CHEMTREC - Collect - All Other Countries) 2. Hazards identification Emergency Overview Powder becomes slippery when wet. Dry or powdered ingredients are combustible. Dispersal of finely divided dust from products into air may form mixtures that are ignitable and explosive. Minimize airborne dust generation and eliminate sources of ignition. Appearance Physical state Odor Eyes Skin Inhalation Ingestion Chronic effects free flowing powder solid odorless May cause slight irritation. Prolonged or repeated contact may dry skin and cause irritation. May cause irritation of respiratory tract. Ingestion may cause gastrointestinal discomfort including nausea, vomiting and diarrhea if large amounts are ingested. No kwn effect based on information supplied. Page 1 / 7

2 3. Composition/information on ingredients Non-Hazardous CAS-No Sodium carboxymethylcellulose Gellan Gum First aid measures Eye contact Skin contact Inhalation Ingestion Notes to physician Protection of first-aiders In case of contact, immediately flush eyes with plenty of water. Get medical attention immediately if symptoms occur. Wash with water and soap as a precaution. Move to fresh air. If breathing is irregular or stopped, administer artificial respiration. Consult a physician. Never give anything by mouth to an unconscious person. Drink plenty of water. Get medical attention immediately if symptoms occur. Treat symptomatically. This product has low oral toxicity and it may be irritating to the eyes. Ingestion of large quantities of alginates may cause intestinal obstruction. Aspiration or inhalation of alginates could cause chemical pneumonitis. Use personal protective equipment. 5. Fire-fighting measures Suitable extinguishing media Specific hazards arising from the chemical Protective equipment and precautions for firefighters Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Dry or powdered ingredients are combustible. Dispersal of finely divided dust from products into air may form mixtures that are ignitable and explosive. Minimize airborne dust generation and eliminate sources of ignition. As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA Health Hazard 0 Flammability 1 Stability 0 Special Hazards - 6. Accidental release measures Personal precautions Methods for containment Methods for cleaning up Powder becomes slippery when wet. For personal protection see section 8. Avoid dust formation. Avoid breathing dust. Maintain good housekeeping practices to avoid accumulation of settled dust, especially on overhead surfaces. Sweep up and shovel into suitable containers for disposal. Page 2 / 7

3 7. Handling and storage Handling Storage Avoid dust formation in confined areas. Wear personal protective equipment. In case of insufficient ventilation, wear suitable respiratory equipment. Refer to Section 8. Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from heat. 8. Exposure controls/personal protection Exposure guidelines ACGIH TLV OSHA PEL NIOSH Mexico - TWA: 15 mg/m 3 TWA: 5 TWA: 10 mg/m 3 TWA: 5 Mexico: TWA 10 mg/m 3 mg/m 3 mg/m 3 Mexico: STEL 20 mg/m 3 British Columbia Quebec Ontario TWAEV Alberta TWA: 10 mg/m 3 TWA: 3 TWA: 10 mg/m 3 - TWA: 10 mg/m 3 mg/m 3 STEL: 20 mg/m 3 Occupational exposure controls Engineering measures Apply technical measures to comply with the occupational exposure limits. When working in confined spaces (tanks, containers, etc.), ensure that there is a supply of air suitable for breathing and wear the recommended equipment. Personal Protective Equipment General Information Respiratory protection Eye/face protection Skin and body protection Hand protection If the product is used in mixtures, it is recommended that you contact the appropriate protective equipment suppliers. These recommendations apply to the product as supplied. In case of insufficient ventilation wear suitable respiratory equipment. Safety glasses. No special precautions required. No special precautions required. Hygiene measures When using, do t eat, drink or smoke. Wear suitable gloves and eye/face protection. Wash hands before breaks and at the end of workday. Page 3 / 7

4 9. Physical and chemical properties Appearance Color Physical state Odor Odor Threshold ph Melting Point/Range Freezing point Boiling Point/Range Flash Point Evaporation rate Autoignition Temperature Vapor pressure Vapor density Density Specific Gravity Bulk density Water solubility Percent volatile Partition coefficient: Viscosity Oxidizing properties free flowing powder Yellowish to white solid odorless t determined. 10. Stability and reactivity Stability Conditions to avoid Stable. Excessive heat. Humid air. Hazardous decomposition products None kwn. Hazardous polymerization Hazardous polymerization does t occur. Page 4 / 7

5 11. Toxicological information Acute Toxicity There are data available for this product. Skin contact Eye contact Inhalation Ingestion May cause irritation. Contact with eyes may cause irritation. May cause irritation of respiratory tract. Ingestion may cause gastrointestinal discomfort including nausea, vomiting and diarrhea if large amounts are ingested. Component Information Component Information LD50 Oral LD50 Dermal LC50 Inhalation Sodium carboxymethylcellulose mg/kg ( Rat ) >2 g/kg ( Rabbit ) >5800 mg/m 3 ( Rat ) 4 h 6450 mg/kg ( Rat ) Gellan Gum 5000 mg/kg ( Rat ) Chronic Toxicity Chronic Toxicity Carcigenicity No kwn effect based on information supplied. Contains ingredient listed as a carcigen. Sensitization Mutagenicity Reproductive toxicity Target Organ Effects Not expected to be sensitizing based on the components... None kwn. 12. Ecological information Ecotoxicity The environmental impact of this product has t been fully investigated. Carrageenan is an extract of seaweeds of the class Rhodophycaea (red seaweeds). Persistence and degradability Bioaccumulation Mobility Other adverse effects No product level data available. Microcrystalline cellulose is inherently biodegradable in soil. Microcrystalline cellulose biodegrades in soil at a rate comparable to corn starch. Bioaccumulation is unlikely.. None kwn 13. Disposal considerations Waste disposal methods This material, as supplied, is t a hazardous waste according to Federal regulations (40 CFR 261). This material could become a hazardous waste if it is mixed with or otherwise comes in contact with a hazardous waste, if chemical additions are made to this material, or if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether the altered material is a hazardous waste. Consult the appropriate state, regional, or local regulations for additional requirements. Contaminated packaging Dispose of in accordance with local regulations. 14. Transport information Page 5 / 7

6 DOT TDG ICAO/IATA IMDG/IMO t regulated t regulated t regulated t regulated 15. Regulatory information International Inventories Sodium carboxymethylcellulose Gellan Gum Legend: TSCA Inventory (United States of America) DSL (Canada) - - Listed EINECS/E LINCS (Europe) ENCS (Japan) - IECSC (China) KECL (Korea) PICCS (Philippines ) AICS (Australia) NZIoC (New Zealand) U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does t contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard CERCLA This material, as supplied, does t contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material. U.S. - TSCA (Toxic Substances Control Act) - Section 8(a) - Chemical-Specific Reporting and Recordkeeping Partially exempt chemical substance under 40 CFR (b)(2) International Regulations Mexico - Grade Slight risk, Grade 1 Carcigen Status Mexico Mexico: TWA 10 mg/m 3 Mexico: STEL 20 mg/m 3 Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class Non-controlled Page 6 / 7

7 16. Other information HMIS Health Hazard 0 Flammability 1 Stability 0 Special precautions - NFPA/HMIS Ratings Legend Severe = 4; Serious = 3; Moderate = 2; Slight = 1; Minimal = 0 Reason for revision: (M)SDS sections updated. Disclaimer FMC Corporation believes that the information and recommendations contained herein (including data and statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EPRESSED OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided herein relates only to the specified product designated and may t be applicable where such product is used in combination with any other materials or in any process. Further, since the conditions and methods of use are beyond the control of FMC Corporation, FMC corporation expressly disclaims any and all liability as to any results obtained or arising from any use of the products or reliance on such information. Prepared By Isagum and FMC BioPolymer Logo - Trademarks of FMC Corporation 2012 FMC Corporation. All Rights Reserved. End of Material Safety Data Sheet Page 7 / 7