Safety Data Sheet according to (EC) No 1907/ ISO

Transcription

1 Safety Data Sheet according to (EC) No 1907/ ISO Page 1 of 1 Brush Alocrom 1200A sds no. : Revision: printing date: Identification of the substance/preparation and of the company/undertaking Trade name: Brush Alocrom 1200A Intended use: Product for the conversion treatment of metals Company name: Henkel Limited Technologies House Wood Lane End HP2 4RQ Hemel Hempstead Great Britain Phone: +44 (0) Fax-no.: +44 (0) address of person responsible for Safety Data Sheet: ua-productsafety.uk@uk.henkel.com Emergency information: 24 Hours Emergency Tel: +44 (0) Hazards identification The product is classified as hazardous within the meaning of the valid (EU) preparation directive. R23 Toxic by inhalation. R45 May cause cancer. R46 May cause heritable genetic damage. R60 May impair fertility. R61 May cause harm to the unborn child. R22 Harmful if swallowed. R35 Causes severe burns. R42/43 May cause sensitization by inhalation and skin contact. R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Base substances of preparation: inorganic acids Organic salts 3. Composition / information on ingredients Declaration of ingredients according to (EC) No 1907/2006:

2 Brush Alocrom 1200A Page 2 of 2 Hazardous components CAS-No. Potassium dichromate Sodium dichromate Tetrafluoroboric acid Dihydrogen hexafluorozirconate(2-) EINECS ELINCS content Classification ,1-1 % Xn - Harmful; R21 C - Corrosive; R34 R42/43 N - Dangerous for the environment; R50, R53 Mutagen category 2.; R46 Toxic for reproduction - category 2.; R60, R61 T+ - Very toxic; R26 T - Toxic; R25, R48/23 O - Oxidizing; R8 carcinogenic, category 2; R % N - Dangerous for the environment; R50, R53 Toxic for reproduction - category 2.; R60, R61 T+ - Very toxic; R26 carcinogenic, category 2; R45 O - Oxidizing; R8 Mutagen category 2.; R46 T - Toxic; R25, R48/23 Xn - Harmful; R21 C - Corrosive; R34 R42/ % C - Corrosive; R ,1-1 % T - Toxic; R23/24/25 C - Corrosive; R34 For full text of the R-Phrases indicated by codes see section 16 'Other Information'. Substances without classification may have community workplace exposure limits available. 4. First aid measures Inhalation: Move to fresh air, administer oxygen, keep warm ; hospitalise. Skin contact: Immediately rinse with copious amounts of running water (for 10 minutes). Remove contaminated clothes. Put on a bandage with sterile gauze, seek medical attention in hospital. Eye contact: Immediately flush eyes with water (for 10 minutes), put on a bandage with sterile gauze, see an oculist. Ingestion: Rinse out mouth, drink 1-2 glasses of water, do not induce vomiting. Immediate medical treatment necessary. 5. Fire fighting measures Combustion behaviour: Non-flammable (aqueous solution). In case of fire toxic gases can proceed after evaporation of water and further heating of the product. Suitable extinguishing media: All common extinguishing agents are suitable. Extinguishing media which must not be used for safety reasons: None known Special protection equipment for firefighters: Wear protective equipment. Wear self-contained breathing apparatus. Additional information: In case of fire, keep containers cool with water spray. 6. Accidental release measures

3 Brush Alocrom 1200A Page 3 of 3 Personal precautions: Avoid contact with skin and eyes. Wear protective equipment. Keep unprotected persons away. See advice in chapter 8 Environmental precautions: Do not empty into drains / surface water / ground water. Clean-up methods: Neutralize with acid-binding material (e.g. powdered limestone). Take up with liquid-absorbing material (sand). Do not use any organic materials (e.g. sawmill waste). Dispose of contaminated material as waste according to item Handling and storage Handling: Avoid spraying/aerosol generation. Avoid skin and eye contact. When diluting, always stir slowly the product into standing water. Storage: Store in sealed original container. Store in a dry place. Keep container in a well ventilated place. Do not store together with food or other consumables (coffee, tea, tobacco, etc.). Do not store together with substances which can be oxidized. 8. Exposure controls / personal protection Components with specific control parameters for workplace: Valid for Great Britain Basis UK s Ingredient ppm mg/m3 Type Category Remarks CHROMIUM (VI) COMPOUNDS (AS CR) 0,05 Time Weighted Average CHROMIUM (VI) COMPOUNDS (AS CR) 0,05 Time Weighted Average ZIRCONIUM COMPOUNDS (AS ZR) 5 Time Weighted Average ZIRCONIUM COMPOUNDS (AS ZR) 10 Short Term Exposure Limit (STEL): FLOURIDE (INORGANIC, AS F) 2,5 Time Weighted Average FLUORIDES, INORGANIC 2,5 Time Weighted Average ECTLV FLOURIDE (INORGANIC, AS F) 2,5 Time Weighted Average FLUORIDES, INORGANIC ,5 Time Weighted Average ECTLV Engineering controls: Ensure good ventilation/suction at the workplace. Respiratory protection: if there is atomisation

4 Brush Alocrom 1200A Page 4 of 4 Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): Polychloroprene (CR; >= 1 mm thickness) or natural rubber (NR; >=1 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): Polychloroprene (CR; >= 1 mm thickness) or natural rubber (NR; >=1 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced. Eye protection: Goggles which can be tightly sealed. Skin protection: Wear protective equipment. General protection and hygiene measures: Do not eat, drink or smoke while working. Wash hands before work breaks and after finishing work. 9. Physical and chemical properties General characteristics: Appearance Odor: liquid clear yellow orange Odorless Phys./chem. properties: ph-value (; Conc.: 1 Weight%; Solvent: Water) Flash point Vapor pressure Density (20 C (68 F)) Solubility (qualitative) VOC content (1999/13/EC) 2,0 No flash point up to 100 C. Aqueous preparation. (aqueous solution) 1,005-1,065 g/cm3 fully miscible 0,0 % Conditions to avoid: No decomposition if used according to specifications. Materials to avoid: None if used for intended purpose. Reacts with alkalis: Heat generated. Can attack glass and vitreous materials. Hazardous decomposition products: None if used for intended purpose. 10. Stability and reactivity

5 Brush Alocrom 1200A Page 5 of Toxicological information General toxicological information: May cause cancer. May cause harm to the unborn child. May impair fertility. May cause heritable genetic damage. The classification as corrosive is due to the extreme ph. Oral toxicity: Harmful if swallowed. Inhalative toxicity: Danger of serious damage to health by prolonged exposure by inhalation. Toxic by inhalation. Dermal toxicity: The product causes corrosion on skin and mucous membranes. Eye irritation: very corrosive Sensitizing: May cause sensitization by inhalation and skin contact. 12. Ecological information Ecotoxicity: Toxic to aquatic organisms May cause long-term adverse effects in the aquatic environment. General ecological information: Inorganic product: Decomposition not affected. Other remarks: The product contains wastewater-relevant heavy metals. Officially determined threshold values for wastewater (also for partial flows, if applicable) and local discharge guidelines must be observed. If acidic or alkaline products are discharged into wastewater installations care must be taken that the discharged wastewater has a ph in the range ph 6-10, as ph variations could cause disorders in wastewater channels and biological sewage treatment plants. The local discharge regulations take precedence. 13. Disposal considerations Product disposal: In consultation with the responsible local authority, must be subjected to special treatment: Removal of heavy metals Waste code(ewc ): The valid EWC waste code numbers are source-related. The manufacturer is therefore unable to specify EWC waste codes for the articles or products used in the various sectors. The EWC codes listed are intended as a recommendation for users. We will be happy to advise you

6 Brush Alocrom 1200A Page 6 of Transport information Road transport ADR: Classification code: C1 Hazard ident. number: 80 Technical name: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (Chromic acid,sodium dichromate) Tunnelcode: (E) Additional substance property: Environmentally Hazardous Railroad transport RID: Classification code: C1 Hazard ident. number: 80 Technical name: Tunnelcode: Additional substance property: Inland water transport ADN: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (Chromic acid,sodium dichromate) Environmentally Hazardous Classification code: C1 Hazard ident. number: Technical name: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (Chromic acid,sodium dichromate) Additional substance property: Environmentally Hazardous Marine transport IMDG: EmS: F-A,S-B Seawater pollutant: Marine pollutant Proper shipping name: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (Chromic acid,sodium dichromate) Air transport IATA: Packaging instructions (passenger) 808 Packaging instructions (cargo) 812 Proper shipping name: Corrosive liquid, acidic, inorganic, n.o.s. (Chromic acid,sodium dichromate)

7 Brush Alocrom 1200A Page 7 of Regulations - classification and identification Indication of danger: T - Toxic N - Dangerous for the environment Contains Potassium dichromate, Sodium dichromate Risk phrases: R23 Toxic by inhalation. R45 May cause cancer. R46 May cause heritable genetic damage. R60 May impair fertility. R61 May cause harm to the unborn child. R22 Harmful if swallowed. R35 Causes severe burns. R42/43 May cause sensitization by inhalation and skin contact. R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Safety phrases: S23 Do not breathe spray. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S53 Avoid exposure - obtain special instructions before use. Additional labeling: Restricted to professional users. Can attack glass and vitreous materials. National regulations/information (Great Britain): Remarks Control of Substances Hazardous to Health Regulations (COSHH), and related guidance, e.g COSHH Essentials. EH40 Occupational Exposure Limits Chemicals (Hazard Information & Packaging for Supply) Regulations. The Personnel Protective Equipment at Work Regulations. The Carriage of Dangerous Goods by Road Regulations. The Health & Safety at Work Act (Note: Use latest editions/amendments of above referenced documents.)

8 Brush Alocrom 1200A Page 8 of Other information The labelling of the product is indicated in Section 15. The full text of the R-phrases indicted by codes in this safety data sheet are as follows: R21 Harmful in contact with skin. R23/24/25 Toxic by inhalation, in contact with skin and if swallowed. R25 Toxic if swallowed. R26 Very toxic by inhalation. R34 Causes burns. R42/43 May cause sensitization by inhalation and skin contact. R45 May cause cancer. R46 May cause heritable genetic damage. R48/23 Toxic: danger of serious damage to health by prolonged exposure through inhalation. R50 Very toxic to aquatic organisms. R53 May cause long-term adverse effects in the aquatic environment. R60 May impair fertility. R61 May cause harm to the unborn child. R8 Contact with combustible material may cause fire. Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties.