Safety Data Sheet. RUST OFF 1. Identification. 2. Hazards identification

Transcription

1 Safety Data Sheet RUST OFF 1. Identification Trade name of product : RUST OFF Other Shipping Name : Corrosive Liquid N.O.S. (contains Sulphamic Acid & Glycolic Acid) Supplier Address : Total Hygiene Solutions 71 Stradbroke Street Heathwood Queensland 4110 Australia Supplier Contact Details : Phone: , sds@symbio.com.au Emergency telephone number : Poisons Information Material uses : Acidic Detergent Product dilution information : As supplied Date of issue : 1 October Hazards identification Classified as DANGEROUS GOODS by the criteria of the Australian Dangerous Goods Code (ADG Code) for Transport by Road and Rail. This material is HAZARDOUS according to Safe Work Australia s GHS Criteria. Hazard Category Corrosive to Metals - Category 1 Signal Word: WARNING Hazard Statements: May be corrosive to metals. Precautionary Statements: Prevention: Keep only in original container. Wear protective gloves. Response: Absorb spillage to prevent material damage. Storage: Store in a corrosion resistant container. Keep out of reach of children Page 1 of 6 ISSUE DATE 1 October 2016

2 3. Composition/information on ingredients Ingredient name CAS number Proportion % TWA mg/m 3 STEL mg / m 3 Sulphamic Acid Glycolic Acid <10 <10 Ingredients, determined not to be hazardous according to Safe Work Australia criteria, and not dangerous according to the ADG Code, make up the product concentration to 100%. 4. First-aid measures Eye contact Skin contact Inhalation Ingestion Notes to physician : Rinse with plenty of running water. Seek medical advice if symptoms occur. : Remove contaminated clothing (wash before re-use). Then rinse with plenty of running water. Seek medical advice if symptoms occur. : Remove to fresh air. Seek medical advice if symptoms occur. : Do NOT induce vomiting. Rinse mouth. Give water to drink. Seek medical advice if symptoms occur. : Treat symptomatically. 5. Fire-fighting measures Extinguishing media Specific Hazards arising from the chemical Special protective equipment and precautions for firefighters Hazchem Code : Use water fog, or fine spray mist to extinguish. : Fire or excessive heat may produce hazardous decomposition products such as nitrous gases and sulphur oxides : Wear full protective clothing and self-contained breathing apparatus. : 2X 6. Accidental release measures Personal precautions Environmental precautions Methods for cleaning up : Use PPE when handling any spills, including gloves, safety glasses and appropriate footwear : Contain spill using appropriate bunding or capping. : Spills may be slippery. Small spills use mop and bucket, for lager spills contain with absorbent material, collect and dispose. Ensure that any alkalis, chlorine based products or other products of incompatible classes near the spill are removed. Note: see section 8 for personal protective equipment and section 13 for waste disposal. Page 2 of 6 ISSUE DATE 1 October 2016

3 7. Handling and storage Handling Storage : Non-combustible material. Avoid contact with skin, eyes and clothing. Wash thoroughly after handling. Do not eat, drink or smoke in contaminated areas. Always use clean and dry equipment to dispense the product. Dispenser should be cleaned before and after use. All dispensers should be washed out after use. : Dangerous goods for storage. When not being used, the containers should be stored upright and secured with the original closure. If transfer to another container becomes necessary, ensure that the container is clearly labelled, is of a type suitable for the product, and is clean and free of other materials. Do not store near chlorine based chemicals 8. Exposure controls/personal protection Occupational exposure limits Engineering measures Personal Protection Eyes Hands Respiratory Skin : No information available : Use sensible work practices that reduce operator exposure to the product. Ensure that adequate ventilation is provided, and air is moving constantly in the area of use while drum is open. Avoid direct inhalation of mists. Keep containers closed when not in use. The following PPE may be considered to reduce risk of exposure. : Safety glasses : Use chemical resistant gloves, nitrile for longer term protection or PVC and neoprene for incidental splashes. : Respiratory protection should be used if there is a risk of exposure to high vapour concentrations. Respirators should comply with AS1716 or an equivalent approved by a state/territory authority. : LLong sleeve shirt and trousers may be considered to reduce risk of chemical contact. 9. Physical and chemical properties Physical state : Clear Liquid Colour : Yellow Odour : Citrus ph : Flash point ( o C) : NA Boiling point ( o C) : >100 Specific Gravity 25 C) : Solubility : Completely soluble in water 10. Stability and reactivity Reactivity Stability Possibility of Hazardous Reactions Page 3 of 6 ISSUE DATE 1 October 2016 : Do not mix with sulphites, alkaline or chlorinated products. : Stable under normal storage conditions : May release toxic chlorine gas in contact with chlorinated products.

4 Conditions to avoid Incompatible Materials : Store away from food stuffs. : Sulphites, alkaline and chlorinated products. May be corrosive to aluminium and alloys. 11. Toxicological information Potential health effects Ingestion Skin Eye Inhalation: Chronic : May irritate intestinal tract and mouth causing minor discomfort and/or burns. : May cause irritation. Prolonged contact may cause chemical burns. : May cause severe irritation and reddening. Prolonged contact may cause permanent damage. : Inhalation of vapour may cause irritation and/or chemical burns to the respiratory tract and nasal passages. : Prolonged contact with concentrated product may cause dermatitis and defatting of skin. 12. Ecological information Ecotoxicity data Persistence/degradability Mobility in Soil Other adverse effects : No known significant effects : No known significant effects : Concentrated solutions are expected to be harmful to aquatic organisms with long term effects. 13. Disposal considerations Methods of disposal : Containers should be emptied as completely as practical before disposal. If possible, recycle containers either in-house or send to recycle company. If this is not practical, send to a commercial waste disposal site. 14. Transport information Regulation UN Number Proper shipping name Class Packing group Additional information ADG 3264 Corrosive Liquid N.O.S. (contains Sulphamic Acid & Glycolic Acid) 8 III Hazchem 2X 15. Regulatory information Hazard Category : Hazard Category Corrosive to Metals - Category 1 Page 4 of 6 ISSUE DATE 1 October 2016

5 Poisons Schedule : Schedule 5 Signal Word: WARNING Hazard Statements: May be corrosive to metals. Precautionary Statements: Prevention: Keep only in original container. Wear protective gloves. Response: Absorb spillage to prevent material damage. Storage: Store in a corrosion resistant container. AICS (Australia) : All ingredients listed Page 5 of 6 ISSUE DATE 1 October 2016

6 16. Other information Literature References : Preparation of Safety Data Sheets for Hazardous Chemicals Code of Practice. Standard for the Uniform Scheduling of Medicines and Poisons. Australian Code for the Transport of Dangerous Goods by Road & Rail. Workplace exposure standards, Safe Work Australia. Hazardous Sunstances/Chemicals Information System, Safe Work Australia. Globally Harmonised System of classification and labelling of chemicals. Raw material suppliers SDS Symbio Traffic Light System Classified as Dangerous Goods according to the Australian Code for the Traffic Light Transport of Dangerous Goods by Road and Rail (7th edition) (ADG7) Classified as Hazardous according to the Globally Harmonised System of Classification and labelling of Chemicals (GHS) as adopted by Work, Health and Safety regulations, Australia. RED AMBER GREEN Notes PLUS products that are NOT Classified as Dangerous Goods according to ADG7, but classified as Corrosive to eyes and skin and/or Aspiration Hazard Category 1 and/or Toxic to humans according to the GHS as adopted by Work, Health and Safety regulations, Australia EXCLUDING products that are classified as Corrosive to eyes and skin and/or Aspiration Hazard Category 1 and/or Toxic to humans according to the GHS as adopted by Work, Health and Safety regulations, Australia Prepared by : Australian Chemical Services ( ) This Safety Data Sheet is the first issue under the direction of the PREPARATION OF SAFETY DATA SHEETS FOR HAZARDOUS CHEMICALS of December The information sourced for the preparation of this document was correct and complete at the time or writing to the best of the writer s knowledge. The document represents the commitment to the company s responsibilities surrounding the supply of this product, undertaken in good faith. This document should be taken as a safety guide for the product and its recommended uses but is in no way an absolute authority. Please consult the relevant legislation and regulations governing the use and storage of this type of product. END OF SAFETY DATA SHEET Page 6 of 6 ISSUE DATE 1 October 2016