Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet Revision Number: Issue date: 09/09/ PRODUCT AND COMPANY IDENTIFICATION Product name: 5699(TM) Grey High Performance RTV Silicone Gasket Maker Product use: Silicone rubber sealant Item number: Region: Canada Company address: Contact information: Henkel Canada Corporation 2225 Meadowpine Boulevard Mississauga, Ontario L5N 7P2 Telephone: Emergency telephone: Internet: 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Physical state: Paste WHMIS hazard class: D.2.A, D.2.B Color: Gray Odor: Mild WARNING: Relevant routes of exposure: MAY CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. Skin, Inhalation, Eyes Potential Health Effects Inhalation: Skin contact: Eye contact: Ingestion: Existing conditions aggravated by exposure: Inhalation of vapors or mists of the product may be irritating to the respiratory system. When heated to temperatures exceeding 300 F (150 C) in the presence of air, silicones may form formaldehyde vapors. Formaldehyde is a potential cancer hazard and a known skin and respiratory sensitizer. Vapors irritate the eyes, nose and throat. Safe handling conditions may be maintained by keeping formaldehyde vapor concentrations below the OSHA permissible limit. The silane is a skin and eye irritant and prolonged contact may cause eye and skin burns. The low concentration makes such overexposure unlikely and minimizes its affect on health and safety. Prolonged or repeated contact may cause irritation. Repeated or prolonged skin contact may result in allergic sensitization. Vapors may irritate eyes. Contact with eyes will cause irritation. Prolonged or repeated contact may worsen irritation. Contains material that may be slightly toxic. Not expected under normal conditions of use. Skin disorders. See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous components CAS NUMBER % Siloxanes and Silicones, di-me, hydroxy-terminated Calcium carbonate Garnet-group minerals Butan-2-one O,O',O''-(vinylsilylidyne)trioxime Silica, amorphous, treated Butanone oxime Aluminum Page 1 of 5

2 4. FIRST AID MEASURES Inhalation: Skin contact: Move to fresh air. If symptoms persist, seek medical advice. Wash with soap and water. Wipe off paste with paper towel or cloth. Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention. Ingestion: Keep individual calm. Do not induce vomiting. Get medical attention. 5. FIRE FIGHTING MEASURES Flash point: Autoignition temperature: Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Extinguishing media: Special firefighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: Sensitivity to Mechanical Impact: Sensitivity to static discharge: > 93 C (> F) Dry chemical. Carbon dioxide. Foam. Wear self contained breathing apparatus. Oxides of carbon. Oxides of silicon. Formaldehyde. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Clean-up methods: Do not allow product to enter sewer or waterways. Scrape up as much material as possible. Maintain good ventilation for large spills. Store in a partly filled, closed container until disposal. 7. HANDLING AND STORAGE Handling: Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Do not handle contact lenses until all sealant has been removed from hands. Residual sealant may transfer to lenses and cause eye irritation. Storage: Keep container closed. Store in a dry area below 90 F. For information on product shelf life contact Henkel Canada Customer Service at (905) EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Page 2 of 5

3 Hazardous components ACGIH TLV OSHA PEL AIHA WEEL OTHER Siloxanes and Silicones, di-me, hydroxy-terminated 5 mg/m3 TWA 10 mg/m3 TWA Respirable fraction. Calcium carbonate Total dust. 15 mg/m3 TWA Total dust. Garnet-group minerals Butan-2-one O,O',O''-(vinylsilylidyne)trioxime Silica, amorphous, treated 10 mg/m3 TWA Inhalable dust. Butanone oxime Aluminum 1 mg/m3 TWA Respirable fraction. 6 mg/m3 TWA 15 mg/m3 TWA (as Al) Total dust. 5 mg/m3 TWA (as Al) Respirable dust. 10 ppm (36 mg/m3) TWA (Skin sensitizer) Engineering controls: Respiratory protection: Eye/face protection: Skin protection: Provide adequate local exhaust ventilation to maintain worker exposure below exposure limits. Use a NIOSH approved air-purifying respirator if the potential to exceed established exposure limits exists. Safety goggles or safety glasses with side shields. Nitrile gloves. Use impermeable gloves and protective clothing as necessary to prevent skin contact. Recommend using 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Color: Odor: Odor threshold: ph: Vapor pressure: Boiling point/range: Melting point/ range: Specific gravity: Vapor density: Flash point: Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Autoignition temperature: Evaporation rate: Solubility in water: Partition coefficient (n-octanol/water): VOC content: Paste Gray Mild 1.5 at 20 C (68 F) Heavier than air. > 93 C (> F) Polymerises in presence of water %; g/l 10. STABILITY AND REACTIVITY Stability: Hazardous reactions: Hazardous decomposition products: Incompatible materials: Conditions to avoid: Stable Will not occur. Oxides of silicon. Oxides of carbon. Methyl ethyl ketoxime formed during cure. Formaldehyde. Acids and bases. Oxidizing agents. Polymerizes on contact with water. Avoid contact with acids and oxidizing agents. High temperatures. Moisture. Page 3 of 5

4 11. TOXICOLOGICAL INFORMATION Toxicologically synergistic products: Refer to the following for Irritancy of Product, Sensitization to Product, Carcinogenicity, Reproductive Toxicity, Teratogenicity, and Mutagenicity. Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) ACGIH Carcinogen Siloxanes and Silicones, di-me, hydroxyterminated No No No No Calcium carbonate No No No No Garnet-group minerals No No No No Butan-2-one O,O',O''- (vinylsilylidyne)trioxime No No No No Silica, amorphous, treated No No No No Butanone oxime No No No No Aluminum No No No Group A4 Hazardous components LD50s and LC50s Health Effects/Target Organs Siloxanes and Silicones, di-me, hydroxyterminated No Target Organs Calcium carbonate Oral LD50 (RAT) = 6,450 mg/kg Nuisance dust Garnet-group minerals No Records Butan-2-one O,O',O''- Irritant, Allergen (vinylsilylidyne)trioxime Silica, amorphous, treated No Target Organs Allergen, Blood, Central nervous system, Butanone oxime Eyes, Irritant, Some evidence of carcinogenicity Aluminum Central nervous system, Irritant, Lung 12. ECOLOGICAL INFORMATION Ecological information: No specific studies have been conducted by Henkel on the ecotoxicity or environmental fate of this material; however, commonly available data on the material indicate that uncontrolled releases to soil, ground water, or surface waters could entail acute and/or chronic ecological effects, depending on the quantity and concentration of such releases. Releases of volatile components to the atmosphere are not believed to entail significant ecological consequences provided such releases are within the exposure levels set forth in this document. Accordingly, all appropriate measures should be taken to avoid uncontrolled releases to the environment, and any spills or other uncontrolled releases which may occur should be contained and cleaned up immediately in accordance with Section DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Cured rubber can be incinerated or landfilled following EPA and local regulations. Canada Transportation of Dangerous Goods - Ground 14. TRANSPORT INFORMATION Page 4 of 5

5 International Air Transportation (ICAO/IATA) Water Transportation (IMO/IMDG) Exceptions: 15. REGULATORY INFORMATION Canada Regulatory Information CEPA DSL/NDSL Status: One or more components are not listed on, and are not exempt from listing on either the Domestic Substances List or the Non-Domestic Substances List. United States Regulatory Information TSCA 8 (b) Inventory Status: One or more components of this product are not listed on the U.S. Toxic Substances Control Act (TSCA) inventory. As such, this product may only be used for research and development purposes as described in 40 CFR All other components of this product are listed or are exempt from listing. 16. OTHER INFORMATION This material safety data sheet contains changes from the previous version in sections: New Material Safety Data Sheet format. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulation (CPR), and the MSDS contains all the information required by the CPR. Prepared by: Lou Fabrizio, Regulatory Affairs Specialist DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Page 5 of 5