Brammer Standard Company, Inc.

Transcription

1 Brammer Stadard Compay, Ic. Certificate of Aalysis BS 690B Certified Referece Material for Icoel UNS Number N06690 Certified Estimate of Certified Values 3 Certified Estimate of Value 1 Ucertaity 2 Value 1 Ucertaity 2 Al Ni C O Cr S Fe Si M Ti N Iformatioal Values 3,4 As (0.0004) B (0.0004) Ca (0.0005) Co (0.003) Cu (0.007) Mg (0.0006) Mo (0.005) Nb (0.003) P (0.003) S (0.0006) V (0.008) W (0.002) Zr (0.002) 1 For each elemet, the certified value listed is the preset best estimate of the true value based o the mea of the weighted results of a iterlaboratory testig program. See page 3 for more iformatio o its calculatio. 2 For each elemet, the ucertaity listed is based o a statistical evaluatio of the cotributios of homogeeity ad the iterlaboratory testig program. See page 3 for more iformatio o its calculatio. 3 Values are give i weight percet. Values i brackets are reported by differece. 4 Values i paretheses are ot certified ad are provided for iformatio oly. Trace elemet iformatio values for Bi, Ga, Ge, Pb, Sb, U, ad Z are show o page 3. The requiremets of ISO Guides 30, 31, ad 35 were followed for the preparatio of this Certified Referece Material ad certificate of aalysis. Certificate Number 690B Page 1/6

2 BS 690B * Code for method Certified values listed as weight percet Certificate Number 690B Page 2/6

3 BS 690B * Code for method Iformatioal values listed as weight percet For each elemet, i accordace with the requiremets of ISO ad Guide 35, a effort must be made to accout for the effects o the certified value of the ucertaity estimate from homogeeity testig (H) ad the ucertaities of the cotributig laboratories. The average (A) is calculated usig a weighted mea where the reciprocal of the square of each laboratory s combied ucertaity (C ), calculated from its stadard deviatio (S ) ad its ucertaity estimate (U ), is used as the weight (W ) for it s mea (M ). The stadard deviatio (S) is calculated as the square root of the reciprocal of the sum of the weights. U 1 is the combied ucertaity from homogeeity ad labs. U 2 is U 1 multiplied by the coverage factor (95 % t-statistic). U 3 is U 2 divided by the square root of the umber of determiatios (). Thus: W 2 2 C S U 1 C 2 A i 1 W i1 W M S 1 i1 W 2 2 U H S U t U U U 2 All but the fial reported values are take to two sigificat figures as determied by each quatity s ucertaity estimate. The fial reported Ucertaity is U 3 rouded to oe sigificat figure ad represets the half width of the 95 % cofidece iterval for the Certified value. The fial reported Certified value is A rouded to the same decimal place as the Ucertaity. The Ucertaity is a measure of the quality of the Certified value. The Tolerace is a measure of the expected performace of a aalysis. This ivolves further expadig the sample ucertaity to iclude istrumet ad operator ucertaity, for those without access to such calculatios. For further iformatio regardig the cofidece iterval for the certified value see ISO Guide 35:2006 sectio 6. BS 690B * Code for aalytical method Trace aalysis listed as mg/kg (ppm) Certificate Number 690B Page 3/6

4 Aalytical Method Codes: 1 Combustio (ASTM E1019) 7 Photometric 13 Titrimetric 2 Fusio (ASTM E1019) 8 Flame Atomic Absorptio 14 DCP Atomic Emissio 3 Spark Atomic Emissio 9 GF Atomic Absorptio 15 HG Atomic Fluorescece 4 ICP Atomic Emissio 10 X-Ray Fluorescece 16 Differece 5 ICP Mass Spectrometry 11 GD Atomic Emissio 17 AAS 6 Gravimetric 12 GD Mass Spectrometry 18 Wet 19 PIXE ICP = Iductively Coupled Plasma GF = Graphite Furace GD = Glow Discharge DCP = Direct Curret Plasma HG = Hydride Geeratio AAS = Atomic Absorptio Spectrometry A2A = America Associatio for aboratory Accreditatio ANAB = ANSI-ASQ Natioal Accreditatio Board CNAS = Chia Natioal Accreditatio Service NAB = Natioal Accreditatio Board for Testig ad Calibratio aboratories PCA = Polish Ceter For Accreditatio PRI =Performace Review Istitute Aalysis: Chemical aalyses were made o solid pieces ad chips prepared by a ed mill from represetative samples for the certified portio of the lot i accordace with ASTM Stadard Practice E1806. The laboratories participatig i the testig followed the requiremets of ISO Stadard Traceability: The followig Certified Referece Materials were used to validate the aalytical data: AR 612B, 654, 670, 875, 882, 892, 1648, 1650, 1652, 1653; BAS 4/94, 387; BS H2C, H2D, H3C, H8, HON-U, 200-1, 200-4, 200A, 351, 600-2, 600-3, 600-5, 600-6, 600C, 690, 690A, 750A, 750C, 750D; ECRM 385; IARM 53C, 53F, 54B, 56C, 56D, 56G, 57B, 57C, 59A, 63E, 68C, 100B, 189A, 190A, 201, 201A, 338A; ECO , , , , , , , , ; NCS NS20035b; SRM 166B, 349, 864, 865, 866, 867, 1244, 1249, Homogeeity: This Certified Referece Material (CRM) was tested for homogeeity usig ASTM Stadard Method E826 ad foud acceptable. It was also examied by spark atomic emissio spectrometry ad foud to be compatible with the followig Referece Materials BAS 4/94; BS HON-U, 200-1, 200-4, 200A, 351, 600-2, 600-3, 600-5, 600-6, 600C, 690, 690A, 750A, 750C, 750D; IARM 189A, 338A; ECO , ; NCS NS20035B; SRM Validity statemet: ISO Guide 31 states that the certificatio should cotai a expiratio date for all materials where istability has bee demostrated or is cosidered possible, after which the certified value is o loger guarateed by the certifyig body. The certificatio of BS 690B is valid idefiitely. The certificatio is ullified if this CRM is damaged, cotamiated, or otherwise modified. Storage: This CRM must be stored i a cool, dry, o-corrosive eviromet. Certificate Number 690B Page 4/6

5 Source: The bar stock for this CRM was produced by Next Geeratio Metals; Boca Rato, F. Form: This CRM is machied i the form of a disc, approximately 51 mm i diameter ad 19 mm thick by Brammer Stadard Compay, Ic. Use: This CRM is iteded for use i spark atomic emissio, glow discharge, ad x-ray spectrometric methods of aalysis. Refer to ISO Guide 33 for iformatio about the use of Certified Referece Materials. Certified Area: The etire depth of the CRM may be used. Cautio: As with ay bar material, avoid spark atomic emissio spectrometric burs i the ceter of the CRM (5 mm radius), as some segregatio may be preset. Sample Preparatio: For best aalytical results, use the same method for preparig the aalytical surface o all referece materials as used for productio specimes. Avoid overheatig the sample durig surface preparatio. Cautio: CRM cotais sigificat isoluble soft metal iclusios. Surface smearig may occur. Spark atomic emissio spectrometers may require exteded preburs to compesate. Certificate Number: The uique idetificatio umber for this certificate of aalysis is 690B You may obtai iformatio o revisios of certificates from the iteret at Safety Notice: A Safety Data Sheet (SDS) is ot required for this material. This material will ot release or otherwise result i exposure to a hazardous chemical, uder ormal coditios of use. Iquiries cocerig this Referece Material should be directed to: Brammer Stadard Co., Ic. Phoe: (281) Web: Befer Road Housto, Texas USA Fax: (281) cotact@brammerstadard.com Brammer Stadard Compay, Ic., is accredited by the America Associatio For aboratory Accreditatio (A2A) to ISO Stadard as a Referece Material Producer for the productio of Certified Referece Materials ad Referece Materials (Certificate Number ) Brammer Stadard Compay's Chemical aboratory is accredited by A2A to ISO Stadard (Certificate Number ) By Certificate Number 10539, the Quality System of Brammer Stadard Compay, Ic., is registered to ISO 9001 by Natioal Quality Assurace (NQA), U.S.A. The scopes of accreditatio are listed o the website: Certificate Number 690B Page 5/6

6 Refereces: Versios used were those available at the time of testig ad characterizatio E826 E1019 E1806 Stadard Practice for Testig Homogeeity of a Metal ot or Batch i Solid Form by Spark Atomic Emissio Spectrometry Stadard Test Methods for Determiatio of Carbo, Sulfur, Nitroge, ad Oxyge i Steel, Iro, Nickel, ad Cobalt Alloys by Various Combustio ad Fusio Techiques Stadard Practice for Samplig Steel ad Iro for Determiatio of Chemical Compositio ISO Stadard 17025:2005 Geeral requiremets for the competece of testig ad calibratio laboratories ISO Stadard 9001:2015 Quality Maagemet Systems - Requiremets ISO Guide 30:2015 Terms ad defiitios used i coectio with referece materials amedmet ISO Guide 31:2015 Referece materials - Cotets of certificates ad labels ISO Guide 33:2015 Uses of certified referece materials ISO Stadard 17034:2016 Geeral requiremets for the competece of referece material producers ISO Guide 35:2006 Referece Materials - Geeral ad statistical priciples for certificatio ASTM documets available from ASTM, 100 Barr Harbor Dr., West Coshohocke, PA ISO Guides ad Stadards available from Global Egieerig - Other useful documets available from NIST, U.S. Departmet of Commerce, Gaithersburg, MD NIST Special Publicatio , Hadbook for SRM Users NIST Special Publicatio 829, Use of NIST Stadard Referece Materials for Decisios o Performace of Aalytical Chemical Methods ad aboratories Certified by: o September 21, Beau R. Brammer Presidet Certificate Number 690B Page 6/6