Smiths Medical - Keene

Transcription

1 Worksheet 1 Env-A 1400 Emissions Compliance Worksheet - Determination of s Used Material Usage Basis: MSDS AP-42 OTHER Material Product CAS Used ID Compound Number (Y/N) Emission Point methyl acetate Methyl Acetate Y Mfg tetrachydrfuran tetrahydrofuran Y Mfg cyclohexanone cyclohexanone Y Mfg IPA IPA Y Mfg Propsol III MIBK Y Mfg Propsol III ethyl acetate Y Mfg Propsol III n-heptane Y Mfg Propsol III Ethanol Y Mfg Markem 300 Cleaner Acetone Y Mfg Markem 300 Cleaner ethyl acetate Y Mfg Markem 300 Cleaner IPA Y Mfg Black ink 1240 MEK Y Chemicals Solvent 1512 MEK Y Chemicals Duraprep IPA Y Chemicals Duraprep Ethanol Y Chemicals Duraprep Iodine Y Chemicals Screen Printing ink Isophrone Y Chemicals Screen Printing ink cyclohexanone Y Chemicals Tough Duty 2-Butoxyethanol Y Box Printer Cabinet Tough Duty IPA Y Box Printer Cabinet SilverMaster Stabilizer Triethanolamine Y Large Gray Cabinet SilverMaster Stabilizer Sodium bisulfate Y Large Gray Cabinet SilverMaster Stabilizer Potassium hydroxide Y Large Gray Cabinet SilverMaster Stabilizer Sodium hydroxide Y Large Gray Cabinet Varn Swell Methylene chloride Y Cabinet Varn Swell Methanol Y Cabinet Varn Swell Ammonia Y Cabinet Roller & Blanket Cleaner Kerosene Y Cabinet Roller & Blanket Cleaner Silica Y Cabinet Parrafin oil Parrafin Y Cabinet SD-20 degreaser 2-Butoxyethanol Y Cabinet SD-20 degreaser IPA Y Cabinet Rubber base Plus Black Carbon black Y Offset Under Countertop CML oil base plus color Carbon black Y Offset Under Countertop Kodak 3000 Fixer Acetic acid Y Darkroom Kodak 3000 Fixer Sodium bisulfate Y Darkroom Kodak 3000 Fixer Sulfuric acid Y Darkroom Envirosafe Cleaner MEK Y Yellow cabinet Envirosafe Cleaner Morpholine Y Yellow cabinet Envirosafe Cleaner Butane Y Yellow cabinet Fast & Easy 2-Butoxyethanol Y Yellow cabinet Fast & Easy IPA Y Yellow cabinet Varn Wash 253 1,2,4-Trimethyl benzene Y Yellow cabinet Varn Wash 253 Dipropylene glymethether Y Yellow cabinet Varn Wash 253 xylenes Y Yellow cabinet Varn Pronto B&R wash Dipropylene glymethether Y Yellow cabinet Ace stripper Methylene chloride Y Yellow cabinet Ace stripper Propylene Glymethether Y Yellow cabinet Ace stripper Ammonia Y Yellow cabinet Printed/Edited: 8/20/2007

2 Worksheet 1 Env-A 1400 Emissions Compliance Worksheet - Determination of s Used Material Usage Basis: MSDS AP-42 OTHER Material Product CAS Used ID Compound Number (Y/N) Emission Point Ace stripper Dipropylene glymethether Y Yellow cabinet Ace stripper Toluene Y Yellow cabinet Ace stripper Methanol Y Yellow cabinet Remover/Adhesive Dipropylene glymethether Y Yellow cabinet Remover/Adhesive IPA Y Yellow cabinet * Information is from Env-A 1400 compliance demonstration report dated February 26, 2004 Printed/Edited: 8/20/2007

3 Smiths Medical - Keen Worksheet 2 Env-A 1400 Emissions Compliance Worksheet - Determination of, Fate and Emissions A B C=(A*B)/100 D E=(C*D)/100 Material / Product ID Use Location CAS Number Prod. (% by wgt) Desnity 100% Emitted? (Y / N) If NOT 100% - Fate? Proportion Emitted (% by wgt) methyl acetate Mfg Methyl Acetate % 7.70 Y 100% 7.70 tetrachydrfuran Mfg tetrahydrofuran % 7.40 Y 100% 7.40 cyclohexanone Mfg cyclohexanone % 7.87 Y 100% 7.87 IPA Mfg IPA % 5.40 Y 100% 5.40 Propsol III Mfg MIBK % 0.15 Y 100% 0.15 Propsol III Mfg ethyl acetate % 0.08 Y 100% Propsol III Mfg n-heptane % 0.07 Y 100% Propsol III Mfg Ethanol % 6.32 Y 100% 6.32 Markem 300 Cleaner Mfg Acetone % 2.05 Y 100% 2.05 Markem 300 Cleaner Mfg ethyl acetate % 2.73 Y 100% 2.73 Markem 300 Cleaner Mfg IPA % 2.73 Y 100% 2.73 Black ink 1240 Chemicals MEK % 7.50 Y 100% 7.50 Solvent 1512 Chemicals MEK % 7.50 Y 100% 7.50 Duraprep Chemicals IPA % 6.45 Y 100% 6.45 Duraprep Chemicals Ethanol % 0.36 Y 100% 0.36 Duraprep Chemicals Iodine % 0.07 Y 100% Screen Printing ink Chemicals Isophrone % 3.42 Y 100% 3.42 Screen Printing ink Chemicals cyclohexanone % 1.37 Y 100% 1.37 Tough Duty Box Printer Cabinet 2-Butoxyethanol % 0.75 Y 100% 0.75 Tough Duty Box Printer Cabinet IPA % 0.42 Y 100% 0.42 SilverMaster Stabilizer Large Gray Cabinet Triethanolamine % 0.43 Y 100% 0.43 SilverMaster Stabilizer Large Gray Cabinet Sodium bisulfate % 0.43 N not volatile 5% SilverMaster Stabilizer Large Gray Cabinet Potassium hydroxide % 0.45 N not volatile 5% SilverMaster Stabilizer Large Gray Cabinet Sodium hydroxide % 0.45 N not volatile 5% Varn Swell Varn Swell Varn Swell Cabinet Methylene chloride % 9.27 Y 100% 9.27 Cabinet Methanol % 0.52 Y 100% 0.52 Cabinet Ammonia % 0.21 Y 100% 0.21 Revised/Printed: 8/20/2007 Page 1 of 3

4 Smiths Medical - Keen Material / Product ID Use Location Roller & Blanket Cleaner Roller & Blanket Cleaner Parrafin oil SD-20 degreaser SD-20 degreaser Rubber base Plus Black CML oil base plus color Worksheet 2 Env-A 1400 Emissions Compliance Worksheet - Determination of, Fate and Emissions CAS Number A B C=(A*B)/100 D E=(C*D)/100 Prod. (% by wgt) Desnity 100% Emitted? (Y / N) If NOT 100% - Fate? Proportion Emitted (% by wgt) Cabinet Kerosene % 0.76 Y 100% 0.76 Cabinet Silica % 0.11 N solid 5% Cabinet Parrafin % 7.50 N not volatile 10% 0.75 Cabinet 2-Butoxyethanol % 0.67 Y 100% 0.67 Cabinet IPA % 0.42 Y 100% 0.42 Offset Under Countertop Carbon black % 2.19 N solid 5% 0.11 Offset Under Countertop Carbon black % 1.59 N solid 5% Kodak 3000 Fixer Darkroom Acetic acid % 0.54 N not volatile 10% Kodak 3000 Fixer Darkroom Sodium bisulfate % 0.11 N not volatile 10% Kodak 3000 Fixer Darkroom Sulfuric acid % 1.10 N not volatile 100% 1.10 Envirosafe Cleaner Yellow cabinet MEK % 0.75 Y 100% 0.75 Envirosafe Cleaner Yellow cabinet Morpholine % 0.75 Y 100% 0.75 Envirosafe Cleaner Yellow cabinet Butane % 0.75 Y 100% 0.75 Fast & Easy Yellow cabinet 2-Butoxyethanol % 0.25 Y 100% 0.25 Fast & Easy Yellow cabinet IPA % 0.82 Y 100% 0.82 Varn Wash 253 Yellow cabinet 1,2,4-Trimethyl benzene % 0.68 Y 100% 0.68 Varn Wash 253 Yellow cabinet Dipropylene glymethether % 0.34 Y 100% 0.34 Varn Wash 253 Yellow cabinet xylenes % 0.07 Y 100% Varn Pronto B&R wash Yellow cabinet Dipropylene glymethether % 0.25 Y 100% 0.25 Ace stripper Yellow cabinet Methylene chloride % 8.85 Y 100% 8.85 Ace stripper Yellow cabinet Propylene Glymethether % 1.97 Y 100% 1.97 Ace stripper Yellow cabinet Ammonia % 1.97 Y 100% 1.97 Ace stripper Yellow cabinet Dipropylene glymethether % 0.98 Y 100% 0.98 Ace stripper Yellow cabinet Toluene % 1.97 Y 100% 1.97 Revised/Printed: 8/20/2007 Page 2 of 3

5 Smiths Medical - Keen Worksheet 2 Env-A 1400 Emissions Compliance Worksheet - Determination of, Fate and Emissions A B C=(A*B)/100 D E=(C*D)/100 Material / Product ID Use Location CAS Number Prod. (% by wgt) Desnity 100% Emitted? (Y / N) If NOT 100% - Fate? Proportion Emitted (% by wgt) Ace stripper Yellow cabinet Methanol % 1.97 Y 100% 1.97 Remover/Adhesive Yellow cabinet Dipropylene glymethether % 2.02 Y 100% 2.02 Remover/Adhesive Yellow cabinet IPA % 2.70 Y 100% 2.70 Revised/Printed: 8/20/2007 Page 3 of 3

6 Worksheet 3 Env-A 1400 Emissions Compliance Worksheet - Deminimum Emission Level Method Compliance Basis: POTENTIAL 1 hrs/day: 24 days/yr: 365 Hr/yr: 8,760 3 times Corrected 2003 Use Rate Maximum Deminimus Exceeds Use Rates 2003 (lbs/gal) Emissions 24-hr Annual Deminimus CAS # (gal/hr) (gal/yr) (From Wrksht 2) (lbs/day) (lbs/yr) (lbs/day) (lbs/yr) (Y/N) Triethanolamine NO Butane ,164 NO Propylene Glymethether ,741 NO MIBK ,942 NO Toluene ,927 NO cyclohexanone cyclohexanone ,444 NO tetrahydrofuran ,519 NO Morpholine ,025 NO 2-Butoxyethanol Butoxyethanol Butoxyethanol ,318 NO Potassium hydroxide NO Sodium hydroxide NO xylenes ,449 NO Carbon black Carbon black NO ethyl acetate ethyl acetate ,111 NO n-heptane ,681 NO Silica NO Dipropylene glymethether Dipropylene glymethether Dipropylene glymethether Dipropylene glymethether ,750 NO Ethanol Ethanol ,147 NO Acetic acid NO Methanol E Methanol ,783 NO IPA IPA IPA IPA IPA IPA IPA ,194 NO Acetone ,180 NO Methylene chloride E Methylene chloride ,783 NO Edited/Printed: 8/20/2007

7 Worksheet 3 Env-A 1400 Emissions Compliance Worksheet - Deminimum Emission Level Method Compliance Basis: POTENTIAL 1 hrs/day: 24 days/yr: 365 Hr/yr: 8,760 3 times Corrected 2003 Use Rate Maximum Deminimus Exceeds Use Rates 2003 (lbs/gal) Emissions 24-hr Annual Deminimus CAS # (gal/hr) (gal/yr) (From Wrksht 2) (lbs/day) (lbs/yr) (lbs/day) (lbs/yr) (Y/N) Iodine NO Edited/Printed: 8/20/2007

8 Worksheet 3 Env-A 1400 Emissions Compliance Worksheet - Deminimum Emission Level Method Compliance Basis: POTENTIAL 1 hrs/day: 24 days/yr: 365 Hr/yr: 8,760 3 times Corrected 2003 Use Rate Maximum Deminimus Exceeds Use Rates 2003 (lbs/gal) Emissions 24-hr Annual Deminimus CAS # (gal/hr) (gal/yr) (From Wrksht 2) (lbs/day) (lbs/yr) (lbs/day) (lbs/yr) (Y/N) Sodium bisulfate Sodium bisulfate NO Ammonia E Ammonia NO Sulfuric acid NO Isophrone NO MEK MEK MEK ,871 NO Methyl Acetate ,887 NO Kerosene ,444 NO Parrafin NO 1,2,4-Trimethyl benzene ,776 NO Emissions are based on potential hours of operation, assuming 24hr/day, 365 days/yr. Maximum use rate (gal/hr) = Use Rate for 2003 * 3 / 8760hr/yr Maximum emissions (lb/day) = Max use rate (gal/hr * 24hr/day) Maximum emissions (lb/yr) = maximum emissions (lb/day) * 365 days/yr Edited/Printed: 8/20/2007

9 Potential VOC and HAP Emission Calculations Compound CAS VOC HAP lb/hr lb/yr tpy Butane x MIBK x x Toluene x x cyclohexanone x tetrahydrofuran x , Morpholine x Butoxyethanol x xylenes x x ethyl acetate x n-heptane x Ethanol x , Methanol x x IPA x , Methylene chloride x Isophrone x x MEK x x ,2,4-Trimethyl benzene x TOTAL VOC tpy 14 Potential emissions based on 3 times the 2003 lb/yr use rates. TOTAL HAP tpy 0.39 Actual VOC and HAP Emission Calculations Compound CAS VOC HAP lb/hr lb/yr tpy Butane x MIBK x x Toluene x x cyclohexanone x tetrahydrofuran x , Morpholine x Butoxyethanol x xylenes x x ethyl acetate x n-heptane x Ethanol x , Methanol x x IPA x , Methylene chloride x Isophrone x x MEK x x ,2,4-Trimethyl benzene x TOTAL VOC tpy 4.7 Potential emissions based on the 2003 lb/yr use rates. TOTAL HAP tpy 0.13 Edited/Printed: 8/20/2007 DRAFT