M/s. Shiva Dye Stuff Pvt. Ltd Plot No.: A2-11/6104, GIDC Estate, Ankleshwar, Dist: Bharuch. ID:

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1 ANNEXURE-ADDITIONAL ATTACHMENTS INDEX Sr. No. Name of Enclosure 1. Name of Product with its quantity. 2. Packing, Storage and Final use of Product. 3. Name of Raw Material with its quantity. 4. Storage facility of Raw Material 5. Properties of Raw Material 6. Details of Hazardous Chemicals 7. Mass Balance with Chemical Reactions 8. Details of water consumption and waste water generation 9. Effluent Treatment Plant Details 10. Details of Flue gas emission and process gas emission with APCM system 11. Details of hazardous waste generation with its management. 12. Name & Address of Partners. 13. Land Supporting documents 14. Site Plan & Layout Plan of Unit. 15. CA certificate 16. Membership certificate

2 ENCLOSURE: 01 NAME OF PRODUCT WITH ITS QTY Sr. No. Product Name CAS No. Existing Proposed Total Quantity (MT/Month) 1. C.P.C. Blue Alpha Blue Ammonium Sulphate Total:

3 ENCLOSURE: 02 PACKING & FINAL USE OF PRODUCTS Name of Product CAS No. Type of Packing Final Application of Product CPC Blue (Copper Phthalo cyanine Blue) HDPE Bag Dye/ Pigment industries Alpha Blue HDPE Bag Ammonium Sulphate HDPE Bag In Chemical Industries and in textile industries for printing and dyeing. Ammonium sulphate will be used for fertilizer

4 ENCLOSURE: 03 NAME OF RAW MATERIAL WITH ITS QUANTITY Overall Raw material details: Sr. No. Name of Raw Material MT/Month 1 Ammonium Molybdate Caustic lye Copper Phthalo Cyanine Cuprous Chloride Emulsifier Ortho nitro Toluene / DCT Phthalic Anhydride Spent Sulphuric Acid 20 % Urea Sulphuric Acid 98 % Sulphuric Acid 67% 133.2

5 Product Wise Raw Material Details: Sr. Name of Qty. Raw material CAS No. MT/MT Qty (MT/M) No. Product MT/M name Ex. Pro. Total 1 CPC Blue 300 Urea Phthalic Anhydride Alpha Blue Ammonium Molybdate Spent Sulphuric Acid 50 Copper Phthalo Cyanine Sulphuric Acid (98 %) Cuprous Chloride Ortho nitro Toluene / DCT Emulsifier Caustic lye

6 ENCLOSURE: 04 CHEMICAL NAME & PHYSICAL FORM OF RAW MATERIALS WITH ITS STORAGE FACILITY Sr. No. Raw Material Chemical Name/ Other Name CAS No. Physical Form Storage Maximum Storage at a time (MT) 1. Ortho Nitro 2-Nitrotoluene Liquid Drum 25 Toluene 2. Caustic Lye Sodium hydroxide Liquid HDPE Drum 3 3. Sulphuric Acid 67 Sulphuric Acid Liquid MS Tank 50 % 4. DCT 2, Liquid MS Tank 25 Dichlorotoluene 5. Sulphuric Acid Sulphuric Acid Liquid MSRL Tank Phthalic 1,3-Dioxophthalan Powder HDPE Bag 50 Anhydride 7. Urea Carbonyldiamide Solid HDPE Bag Cuprous Chloride Copper(I) chloride Solid HDPE Bag Ammonium Molybdic acid Solid 0.3 HDPE Bag Molybdate Copper Phthalo Aqualine Blue Solid 15 HDPE Bag Cyanine 11. Emulsifier Solid HDPE Bag 0.2

7 ENCLOSURE: 05 PROPERTIES OF THE RAW MATERIAL Sr. No Product Physical & Chemical Composition B.P F.P. LEL TLV, LD 50 mg/kg Sp.Gr. (Water=1) at V.D. at (air=1) Odour Thre shold, Solubility in Water Chemical Formula State MW o C o C ppm or mg/nm 3 ppm, mg/ Nm 3 Raw Materials 1. Caustic lye NaOH Liquid NA NA STEL: 2 NA 2.13 NA NA soluble Sulphuric Acid Ortho Nitro Toluene DCT H 2 SO 4 Liquid 98 NA Not Pertinent Not Pertinent TWA: gm/cm Odorless Fully Miscible with water C 7 H 7 NO 2 Liquid NA TWA: NA 0.54 g/liter of Water CH 3 C 6 H 3 Cl 2 Liquid NA NA NA NA NA NA NA

8 Phthallic Anhydride Urea Cuprous chloride Ammonium Molyblate CPC Blue Crude M/s. Shiva Dye Stuff Pvt. Ltd C 8 H 4 O 3 Solid C NA TWA: 6.1 NH 2 CONH 2 Solid 60 NA NA NA NA NA 20 0 C NA 0.62 gm /100 gm of water NA NA 119 gm/100 gm of 25 0 C CuCl2 Solid NA NA TWA: NA NA Very Slightly Soluble in cold water. (NH 4 ) 6 Mo H 2 O Solid NA NA NA TWA: NA NA 4.3 gm/liter of water C 32 H 16 CuN 8 Solid 576 NA NA NA NA NA 1.5 NA NA Insoluble

9 ENCLOSURE: 06 DETAILS OF HAZARDOUS CHEMICALS The Raw Materials, which are termed as Hazardous Chemicals as per the "Manufacturing, Storage and Import of Hazardous Chemicals Rules, 1989", are as listed in below Table: Sr. No. 1 Name of Hazardous chemicals Cuprous Chloride (Copper & its Compound) 2 Ortho Nitro Toluene 3 Phthalic Anhydride 4 Sulphuric Acid Reference in MSIHC Maximum Storage Capacity (MT) Threshold Quantity (MT) Sr. No. 146 (Part II, Schedule 1 of MSIHCR, No listed Sr. No. 440(Part II, Sch. 1 of MSIHCR, 1989) Sr. No. 508 (Part II, Schedule 1 of MSIHCR, 1989 Sr. No. 591(Part II, Sch. 1 of MSIHCR, 1989) 25 Not Listed 50 No listed 50 No listed

10 ENCLOSURE: 07 Mass balance and chemical reaction of the product 1. Copper Phthalo Cyanine Blue: Manufacturing Process: Charge ortho nitro toluene (solvent) in glass lined vessel. Charge required quantity of Phthalic Anhydride, Urea in a Glass Vessel and give the desire temperature. Heating the content to higher temperature and then add of catalyst(ammonium Molybdate) and Cuprous Chloride to it. Raise the temperature of the reaction mass at desire temperature and maintain this temperature for 5/6 hours. Scrub the ammonia and carbon dioxide gas evolved during the process to water scrubber to get the solution of ammonium carbonate. After reaction is over, draw the sample and check for complete conversion of Phthalic Anhydride to CPC Blue Crude. Discharge the batch into Horizontal Rotary Vacuum Dryer (HRVD) and remove the solvent under vacuum. After complete removal of solvent add water to the Horizontal Rotary Vacuum Dryer (HRVD) and transfer the material to treatment tank. Add Spent Sulphuric Acid and Water and raise the temperature to the total mass for Acid treatment. Filter the material through filter press and wash the wet Cake by Water. Dry the material using Spin Flash Dryer (SFD) and collect the dried powder in bags. Chemical Reaction

11 Mass Balance: Mass Balance of CPC Blue Crude Urea: 1000 Kg Phthalic Anhydride: 1075 Kg Cuprous Chloride: 160 Kg Solvent: 1739 Kg Ammonia Molybdate: 4 Kg Total: 3978 Kg Reaction Vessel 3978 Kg Ammonia : 230 kg, Carbon Dioxide: 593 kg. which is scrub by cold water 4000 kg (MEE Plant Water) to collect ammonium Carbonate in solution and used for Amm. Sulphate recovery kg (15 % Amm. Carbonate Sol. Vacuum Distillation 3155 Kg Solvent Recovery: 1704 Kg Spent Sulfuric Acid: 2583 Kg (20 %) (Used from Alpha Blue MEE Water : 3000 Kg Vessel 6999 Kg Used in Mfg. of Ammonium Sulphate RO Water: 2750 L MEE Water :1750 L Filtration Kg Spent Acid: 5264 Kg (7%) Effluent to ETP: 3000 L Spin Flash Dryer 3235 Kg Drying Loss: 2270 Kg Final Product 1000Kg of CPC Blue

12 2. Ammonium Sulphate Manufacturing Process Take 4323 kgs. Ammonium Carbonate Scrubber water in neutralization Tank and neutralize with sulphuric acid (67%)- 444 kgs and 5264 kg Spent Sulphuric Acid form CPC Plant. Then Filter Neutralize solution and collect the filtrate in copper recovery tank. Then add Sodium Sulphide 1 kg and stire. Then filter and send the Ammonium Sulphate filtrate to MEE Plant. Then condensate from MEE Plant collect in Tank for use in process. The Solid mass coming out of the MEE Plant send to Crystallizer to get final product Ammonium Sulphate. Mass Balance 5264 Kg : 7% Spent Sulphuric acid from CPC Plant Kg: 15% Ammo. Carbonate solution. 444 Kg: 67% Sulphuric Acid fresh. Sodium Sulphide : 1 kg. Neutralization Tank 9734 kgs. (Ammonia Sulphate solution.) Filtration : 9484 Kgs. Copper Recovery Tank : 9485 Kgs. Filtrate to MEE Plant : Kgs. Carbon dioxide: 297 kgs. Sludge : 250 kgs. Sent to TSDF. Copper Sulphide wet cake: 1.2 Kgs. After drying sent to TSDF or sell to authorized user. MEE Condensate Water: 8373 kgs. Used in process. AMMONIUM SULPHATE: kgs. Passed through Crystalizer. Ammo. Sulphate water to be added in Neutralization Tank : kgs. AMMONIUM SULPHATE: 1000 KGS.

13 3. Alpha Blue/ Pigment Alpha Blue 15: Manufacturing Process Copper Phthalo cyanine blue is charge in reactor. Then add 98% sulphuric acid and thoroughly mixed in a vessel to obtain a homogenous paste. The temperature of the vessel is cooled to 50 C. The contents are dumped into another vessel containing water. This is done to reduce sulphuric acid concentration. The concentrate liquor obtained from the previous step is Filter and wash with water and collect the Cake. The Cake tanke in another vessel and make slurry with water and neutralize with Caustic Lye and add Emulsifier then heat to desire temperature and filter and wash. The wet cake of finished product is finally sent down for SFD. Chemical Reaction: CPC Crude Polymorphic form ALPHA BLUE

14 Mass Balance: Mass Balance of Alpha Blue CPC: 1050 Kg Fresh Water: 2000 L Sulphuric Acid: 3500 Kg Total: 6550 Kg Reactor 6550 Kg MEE Water: 3500 L Drawning Vessel kg MEE Water: L MEE Water: 2000 L Emulsifier: 1 Kg Caustic Lye: 100 Kg Total: 2101 Kg Filtration 4550 Kg Reaction Vessel 6651 Kg Kg - Spent Dilute Sulphuric Acid (18-20 %)(to be reused in CPC BLUE) Fresh Water: 1662 L MEE Water: 6238 L Filter Press Kg Effluent to ETP PLANT: L Spin Flash Dryer 4030 kg Drying Loss: 3030 Kg Finished Product 1000 Kg of Alpha Blue

15 ENCLOSURE: 8 DETAILS OF WATER CONSUMPTION & WASTEWATER GENERATION Source of Water- GIDC water supply Water Consumption (KL/Day) Effluent generation (KL/Day) Existing Proposed Total Existing Proposed Total (A) Domestic (B) Gardening (C )Industrial Process Boiler Cooling Washing Scrubber (C )Industrial Total Total Domestic water 5.0 KLPD and sewage generated will be disposed to soak pit via septic 3.0KLPD. Gardening water 2 KLPD. Industrial water KLPD and effluent KLPD. Industrial KLPD will be treated in primary and secondary and tertiary treatment followed by RO system. RO KLPD will be reused in process manufacturing. RO 26 KLPD will be send to ETL, Ankleshwar.

16 Water Balance Diagram-

17 Sr. No. 1 2 M/s. Shiva Dye Stuff Pvt. Ltd Product wise Water Consumption & Waste water generation details Product C.P.C. Blue Alpha Blue/ Pigment Alpha Blue 15 Batch Size (in Kg) Production in MT/Month No. of Batches/Month Water Consumption in KL/Batch Effluent Generation in KL/Batch Water Consumption in KL/Day Effluent generation in KL/Day Total MEE Condensate effluent management: Product Name Generated MEE Condensate water in KL/D Used in Product Stage Reused MEE Condensate water in KL/D Ammonium Sulphate CPC Blue Reaction 36 Vessel Filtration 21 Alpha Blue Drowing 7 Vessel Filtration 20 Reaction 4 Vessel Filter press Total Total RO permeate effluent management: 33 KL/D Product Name Stage Reused RO permeate CPC Blue Filtration 33 Total 33

18 Solvent Details: Sr. No. Product Name Product Quantity per Month Name of Solvent Quantity In MT/Batch Quantity In MT/M Recovered Quantity Fresh Solvent To Be Used/Month 1 CPC Blue 300 Ortho Nitro Toluene / DCT Product wise Spent acid Management Sr. No Name of Product Producti on Qty. % of Spent Spent Acid Consumption % of Spent Spent Acid generation Management MT/M Sulphuric MT/ MT/M Sulphuric MT/M MT/M Acid MT Acid T 01 CPC Blue % % Spent acid of CPC Blue used in recovery of ammonium sulphate. 02 Alpha Blue % % Spent Acid of (Fresh) Alpha blue used in purification of 03 Ammoniu m Sulphate % CPC Blue

19 ENCLOSURE: 9 DETAILS OF EFFLUENT TREATMENT PLANT Sr. No. Name of Unit No. of Unit 1. Collection Tank 2 2. Neutralization Tank 2 Size (Feet) (Each) (Each) Capacity 28.5 KL (each) 28.5 KL (each) 3. Primary Settling Tank KL 4. Aeration Tank KL 5. Secondary settling Tank KL 7. Holding Tank KL 11. Carbon Cum Sand Filter Holding Tank RO Plant lit/hr Ro Reusable Water Tank KL 10. RO Rejected Tank (Collection Tank for ETL) KL 13. Over Head Tank 2 50 KL Sludge Drying Bed

20 ETP Diagram: Collection Tank Neutralization Tank Primary Settling Tank Aeration Tank Secondary Settling Tank Sludge Drying Bed RO Permeate Tank RO Plant Holding Tank Carbon Cum Sand filter Holding Tank RO Reject Tank (Final Collection Tank) Overhead Tank Send ETL

21 ENCLOSURE: 10 DETAILS OF FLUE GAS EMISSION & PROCESS GAS EMISSION WITH APCM SYSTEM Flue gas emission: Sr. No. Stack Attached To Qty. of Fuel To be Used Type of Fuel Stack Height (m) Air Pollution Control Measure Pollutants 1 Industrial Boiler (5 MT) (Existing) Coal 2 MT/D (Exi.) MT/D (Pro.) 30 Adequate Stack PM So x NO x 2 Thermo pack boiler (15 lack Kcal) (Existing) Coal 1 MT/D (Exi.) MT/D (Pro.) 30 Adequate Stack PM So x NO x 3 4 D.G. Set (600 KVA) (Proposed) Diesel 80 lit/hr 9 Adequate Stack HOT AIR GENERATOR (SFD) KCAL/Hr. (Proposed) PM So x NO x Coal 5 MT/D 16 Adequate Stack PM Process Gas Emission Details: Sr. No. Stack attached To APCD System Stack Height Pollutants 1 Reaction vessel Two Stage water Scrubber system followed by Alkali Scrubber 11 m NH 3 <= 175 mg/nm 3 2 Spin Flash Dryer (300 KGS/Hr.) (In built HAG) Bag Filter 9 SPM <= 150 mg/nm 3

22 FUEL REQUIREMENT No. Type of Fuel Existing Proposed Quantity 1. Coal 3 MT/Day 12 MT/Day 15 MT/Day 2. Diesel lit/hr 80 lit/hr

23 ENCLOSURE: 11 DETAILS OF HAZARDOUS WASTE GENERATION WITH ITS MANAGEMENT Sr. No. Waste Category Quantity Facility Existing Proposed Total After Expansion 1. ETP Waste MT/M 140 MT/M. 150 MT/M. Collection, Storage, Transportation, Disposal to TSDF site by BEIL. 2. Discarded Containers Nos./M 440 Nos./M Bags/Liner nos./yr 5600 nos./yr 500 Nos./M Collection, Storage, Transportation and Reuse by self /given back to supplier/sold 8000 nos/yr to Registered recyclers 3. Used Oil Lit/Yr Lit/Yr. Collection, Storage, Transportation and Reuse for lubrication/ sell to registered recyclers in case of need arise Spent Sulphuric Acid (18-20 %) 4. Copper Sulphide D-2 Sch KL/Month KL/M Spent Acid(18-20%) of Alpha blue used in purification of CPC KL/M Spent acid(7 %) of CPC Blue used in recovery of ammonium sulphate MT/yr 2.5 MT/yr Collection, Storage, Transportation, Disposal to TSDF site by BEIL. Or Sell to actual user having rule 9 permission. 5. Ammonium Carbonate MT/Month 1300 MT/Month It will be reused in recovery of ammonium sulphate.

24 ENCLOSURE: 12 NAME & ADDRESS OF PARTNER Sr. No. Name Address 1 Mr. Vipulbhai V. Gajera 2 Mr. Balubhai V. Gajera 402/08/B, Alkapuri Society, G.I.D.C. Estate, Ankleshwar (M) ID: dgajera@nilkanthgroup.co.in 405/11/B, Sardar Patel Society, G.I.D.C.Estate, Ankleshwar (M) ID: balugajera@nilkanthgroup.co.in

25 ENCLOSURE: 13 LAND SUPPORTING DOCUMENT

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28 14. SITE PLAN & LAYOUT PLAN

29 15. VALUATION CERTIFICATE

30 16. EXISTING CCA

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38 17. MEMBERSHIP CERTIFICATE