CERTIFICATE OF ANALYSIS

Transcription

1 Your Project #: QUARTERLY Your C.O.C. #: G883 Attention:Simon Palmer 3567 East Road Denman Island, BC CANADA V0R T0 Report Date: 7/04/3 Report #: R Version: Final MAXXAM JOB #: B Received: 7/04/06, 2:45 Sample Matrix: Water # Samples Received: Analyses Alkalinity Water () Chloride by Automated Colourimetry () Colour (True) by Kone Lab () Total Coliforms & E.coli Potable W MF () Carbon (DOC) unfiltered/unpreserved (, 2) Fluoride () Hardness Total (calculated as CaCO3) () Na, K, Ca, Mg, S by CRC ICPMS (total) () Elements by CRC ICPMS (total) () Nitrate + Nitrite (N) () Nitrite (N) by CFA () Nitrogen Nitrate (as N) () ph Water (, 3) Sulphate by Automated Colourimetry () Total Dissolved Solids (Filt. Residue) () Tannin & Lignin (Total) () Carbon (Total Organic) (, 4) Turbidity () UV () UV () CERTIFICATE OF ANALYSIS Date Quantity Extracted Date Analyzed Laboratory Method BBY6SOP00026 N/A BBY6SOP000 N/A BBY6SOP00057 N/A BBY4SOP0000 N/A 7/04/0 BBY6SOP00003 N/A BBY6SOP00048 N/A BBY WI /04/06 BBY7SOP /04/0 BBY7SOP00003, N/A BBY6SOP0000 N/A BBY6SOP0000 N/A 7/04/08 BBY6SOP0000 N/A BBY6SOP00026 N/A BBY6SOP0007 7/04/08 7/04/0 BBY6SOP00033 N/A BBY6SOP00023 N/A 7/04/0 BBY6SOP00003 N/A BBY6SOP00027 N/A BBY6SOP00055 N/A BRN SOP00246 Analytical Method SM B m SM Cl E m SM 22 2 C m SM m SM C m SM F C m Auto Calc EPA 60A R m BCLM05,EPA60bR2m SM NO3 I m SM NO3 I m SM NO3 I m SM H+ B m SM SO42 E m SM C m SM5550B m SM C m SM B m SM B SM590 B Reference Method suffix m indicates test methods incorporate validated modifications from specific reference methods to improve performance. * s calculated using raw data. The rounding of final results may result in the apparent difference. () This test was performed by Maxxam Vancouver (2) DOC present in the sample should be considered as nonpurgeable DOC. (3) The BCMOE and APHA Standard Method require ph to be analysed within 5 minutes of sampling and therefore field analysis is required for compliance. All Laboratory ph analyses in this report are reported past the BCMOE/APHA Standard Method holding time. (4) TOC present in the sample should be considered as nonpurgeable TOC. Page of 3

2 Your Project #: QUARTERLY Your C.O.C. #: G883 Attention:Simon Palmer 3567 East Road Denman Island, BC CANADA V0R T0 Report Date: 7/04/3 Report #: R Version: Final MAXXAM JOB #: B Received: 7/04/06, 2:45 CERTIFICATE OF ANALYSIS Encryption Key Please direct all questions regarding this Certificate of Analysis to your Project Manager. BC Env Customer Service, BC Environmental Customer Service Phone# (250) ==================================================================== This report has been generated and distributed using a secure automated process. Maxxam has procedures in place to guard against improper use of the electronic signature and have the required "signatories", as per section of ISO/IEC 7025:05(E), signing the reports. For Service Group specific validation please refer to the Validation Signature Page. Total Cover Pages : 2 Page 2 of 3

3 Report Date: 7/04/3 RESULTS OF CHEMICAL ANALYSES OF WATER Maxxam ID Sampling Date COC Number UNITS MAC AO OG QV653 7/04/06 :30 G883 COMPREHENSIVE ST QTR 7 RDL QC Batch CONVENTIONALS Transmittance at 254nm Misc. Inorganics T/cm 66.6 N/A UV absorbance (254nm) ANIONS AU/cm Nitrite (N) Calculated Parameters < Nitrate (N) Misc. Inorganics Fluoride (F) Dissolved Organic Carbon (C) Alkalinity (Total as CaCO3) Total Organic Carbon (C) Alkalinity (PP as CaCO3) Bicarbonate (HCO3) Carbonate (CO3) Hydroxide (OH) Anions () Dissolved Sulphate (SO4) Dissolved Chloride (Cl) MISCELLANEOUS True Colour Tannins and Lignins Nutrients Col. Unit Nitrate plus Nitrite (N) Physical Properties ph Physical Properties ph 7.0: Total Dissolved Solids Turbidity NTU see remark 500 see remark see remark No Fill No Exceedance Grey Exceeds criteria policy/level Black Exceeds both criteria/levels RDL = Reportable Detection Limit N/A = Not Applicable () Sample preserved to extend hold time. Page 3 of 3

4 Report Date: 7/04/3 MICROBIOLOGY (WATER) Maxxam ID Sampling Date COC Number UNITS MAC Microbiological Param. Total Coliforms CFU/00mL 0 E. coli CFU/00mL 0 No Fill No Exceedance Grey Exceeds criteria policy/level Black Exceeds both criteria/levels QV653 7/04/06 :30 G883 COMPREHENSIVE ST QTR QC Batch Page 4 of 3

5 Report Date: 7/04/3 CSR TOTAL METALS IN WATER (WATER) Maxxam ID Sampling Date COC Number UNITS MAC AO OG QV653 7/04/06 :30 G883 COMPREHENSIVE ST QTR 7 RDL QC Batch Calculated Parameters Total Hardness (CaCO3) Total Metals by ICPMS Total Aluminum (Al) Total Antimony (Sb) Total Arsenic (As) Total Barium (Ba) Total Beryllium (Be) Total Bismuth (Bi) Total Boron (B) Total Cadmium (Cd) Total Chromium (Cr) Total Cobalt (Co) Total Copper (Cu) Total Iron (Fe) Total Lead (Pb) Total Lithium (Li) Total Manganese (Mn) Total Molybdenum (Mo) Total Nickel (Ni) Total Selenium (Se) Total Silicon (Si) Total Silver (Ag) Total Strontium (Sr) Total Thallium (Tl) Total Tin (Sn) Total Titanium (Ti) Total Uranium (U) Total Vanadium (V) Total Zinc (Zn) Total Zirconium (Zr) Total Calcium (Ca) Total Magnesium (Mg) <0.0 <.0 <50 <0.00 <.0 < <0. < <.0 <.0 < < <0.00 < < No Fill No Exceedance Grey Exceeds criteria policy/level Black Exceeds both criteria/levels RDL = Reportable Detection Limit Page 5 of 3

6 Report Date: 7/04/3 CSR TOTAL METALS IN WATER (WATER) Maxxam ID Sampling Date COC Number UNITS MAC AO OG QV653 7/04/06 :30 G883 COMPREHENSIVE ST QTR 7 RDL QC Batch Total Potassium (K) Total Sodium (Na) Total Sulphur (S) < No Fill No Exceedance Grey Exceeds criteria policy/level Black Exceeds both criteria/levels RDL = Reportable Detection Limit Page 6 of 3

7 Report Date: 7/04/3 GENERAL COMMENTS MAC,AO,OG: The guidelines that have been included in this report have been taken from the Canadian Drinking Water Quality Summary Table, February 7. Criteria A = Maximum Acceptable Concentration (MAC) / Criteria B = Aesthetic Objectives (AO) / Criteria C = Operational Guidance Values (OG) It is recommended to consult these guidelines when interpreting your data since there are nonnumerical guidelines that are not included on this report. Turbidity Guidelines:. Chemically assisted filtration: less than or equal to 0.3 NTU in 95 of the measurements or 95 of the time each month. Shall not exceed.0 NTU at any time. 2. Slow sand / diatomaceous earth filtration: less than or equal to.0 NTU in 95 of the measurements or 95 of the time each month. Shall not exceed 3.0 NTU at any time. 3. Membrane filtration: less than or equal to 0. NTU in 99 of the measurements made or at least 99 of the time each calendar month. Shall not exceed 0.3 NTU at any time. Results relate only to the items tested. Page 7 of 3

8 Report Date: 7/04/3 QUALITY ASSURAE REPORT QA/QC Batch Init MM3 MM3 MM3 MM3 MM3 MM3 WAY WAY WAY DC6 DC6 JSG JSG IW IW IW IW IW IW IW IW AA QC Type [QV6530] [QV65302] Parameter ph ph Alkalinity (Total as CaCO3) Alkalinity (Total as CaCO3) Alkalinity (Total as CaCO3) Alkalinity (PP as CaCO3) Bicarbonate (HCO3) Carbonate (CO3) Hydroxide (OH) Alkalinity (Total as CaCO3) Alkalinity (PP as CaCO3) Bicarbonate (HCO3) Carbonate (CO3) Hydroxide (OH) True Colour True Colour True Colour Turbidity Turbidity Turbidity Fluoride (F) Fluoride (F) UV absorbance (254nm) UV absorbance (254nm) Total Dissolved Solids Total Dissolved Solids Total Dissolved Solids Total Dissolved Solids Dissolved Organic Carbon (C) Dissolved Organic Carbon (C) Dissolved Organic Carbon (C) Dissolved Organic Carbon (C) Nitrate plus Nitrite (N) Nitrate plus Nitrite (N) Nitrate plus Nitrite (N) Nitrate plus Nitrite (N) Nitrite (N) Nitrite (N) Nitrite (N) Nitrite (N) Dissolved Chloride (Cl) Dissolved Chloride (Cl) Dissolved Chloride (Cl) Dissolved Chloride (Cl) Dissolved Sulphate (SO4) Dissolved Sulphate (SO4) Dissolved Sulphate (SO4) Dissolved Sulphate (SO4) Total Aluminum (Al) Total Antimony (Sb) Total Arsenic (As) Total Barium (Ba) Total Beryllium (Be) Total Bismuth (Bi) Date Analyzed 7/04/0 7/04/0 7/04/0 7/04/0 7/04/0 7/04/0 7/04/0 7/04/0 Value < , RDL=0.00 < < <0.0.7 < Recovery UNITS QC Limits N/A Col. Unit 80 NTU 80 AU/cm Page 8 of 3

9 Report Date: 7/04/3 QUALITY ASSURAE REPORT(CONT'D) QA/QC Batch Init AA AA QC Type Parameter Total Boron (B) Total Cadmium (Cd) Total Chromium (Cr) Total Cobalt (Co) Total Copper (Cu) Total Iron (Fe) Total Lead (Pb) Total Lithium (Li) Total Manganese (Mn) Total Molybdenum (Mo) Total Nickel (Ni) Total Selenium (Se) Total Silver (Ag) Total Strontium (Sr) Total Thallium (Tl) Total Tin (Sn) Total Titanium (Ti) Total Uranium (U) Total Vanadium (V) Total Zinc (Zn) Total Aluminum (Al) Total Antimony (Sb) Total Arsenic (As) Total Barium (Ba) Total Beryllium (Be) Total Bismuth (Bi) Total Boron (B) Total Cadmium (Cd) Total Chromium (Cr) Total Cobalt (Co) Total Copper (Cu) Total Iron (Fe) Total Lead (Pb) Total Lithium (Li) Total Manganese (Mn) Total Molybdenum (Mo) Total Nickel (Ni) Total Selenium (Se) Total Silver (Ag) Total Strontium (Sr) Total Thallium (Tl) Total Tin (Sn) Total Titanium (Ti) Total Uranium (U) Total Vanadium (V) Total Zinc (Zn) Total Aluminum (Al) Total Antimony (Sb) Total Arsenic (As) Total Barium (Ba) Total Beryllium (Be) Total Bismuth (Bi) Total Boron (B) Total Cadmium (Cd) Total Chromium (Cr) Date Analyzed Value <3.0 <0.0 <.0 <0.0 <.0 <50 <0.00 <.0 Recovery UNITS QC Limits Page 9 of 3

10 Report Date: 7/04/3 QUALITY ASSURAE REPORT(CONT'D) QA/QC Batch Init AA QC Type [QV65302] Parameter Total Cobalt (Co) Total Copper (Cu) Total Iron (Fe) Total Lead (Pb) Total Lithium (Li) Total Manganese (Mn) Total Molybdenum (Mo) Total Nickel (Ni) Total Selenium (Se) Total Silicon (Si) Total Silver (Ag) Total Strontium (Sr) Total Thallium (Tl) Total Tin (Sn) Total Titanium (Ti) Total Uranium (U) Total Vanadium (V) Total Zinc (Zn) Total Zirconium (Zr) Total Aluminum (Al) Total Antimony (Sb) Total Arsenic (As) Total Barium (Ba) Total Beryllium (Be) Total Bismuth (Bi) Total Boron (B) Total Cadmium (Cd) Total Chromium (Cr) Total Cobalt (Co) Total Copper (Cu) Total Iron (Fe) Total Lead (Pb) Total Lithium (Li) Total Manganese (Mn) Total Molybdenum (Mo) Total Nickel (Ni) Total Selenium (Se) Total Silicon (Si) Total Silver (Ag) Total Strontium (Sr) Total Thallium (Tl) Total Tin (Sn) Total Titanium (Ti) Total Uranium (U) Total Vanadium (V) Total Zinc (Zn) Total Zirconium (Zr) Total Organic Carbon (C) Total Organic Carbon (C) Total Organic Carbon (C) Total Organic Carbon (C) Tannins and Lignins Tannins and Lignins Tannins and Lignins Date Analyzed 7/04/0 7/04/0 7/04/0 7/04/0 Value <0. <0 <0. <2.0 <.0 <.0 <.0 <0.0 <00 <0.0 <.0 <0.00 <0.0 < <0.0 Recovery UNITS QC Limits Page 0 of 3

11 Report Date: 7/04/3 QA/QC Batch Init N/A = Not Applicable QC Type [QV65302] QUALITY ASSURAE REPORT(CONT'D) Parameter Tannins and Lignins Date Analyzed Value 6.0 Duplicate: Paired analysis of a separate portion of the same sample. Used to evaluate the variance in the measurement. Recovery : A sample to which a known amount of the analyte of interest has been added. Used to evaluate sample matrix interference. : A blank matrix sample to which a known amount of the analyte, usually from a second source, has been added. Used to evaluate method accuracy. : A blank matrix containing all reagents used in the analytical procedure. Used to identify laboratory contamination. (Duplicate ): The duplicate was not calculated. The concentration in the sample and/or duplicate was too low to permit a reliable calculation (absolute difference <= 2x RDL). UNITS QC Limits (): The recovery in the matrix spike was not calculated. The relative difference between the concentration in the parent sample and the spike amount was too small to permit a reliable recovery calculation (matrix spike concentration was less than the native sample concentration) Page of 3

12 Report Date: 7/04/3 VALIDATION SIGNATURE PAGE The analytical data and all QC contained in this report were reviewed and validated by the following individual(s). Andy Lu, Ph.D., P.Chem., Scientific Specialist Maxxam has procedures in place to guard against improper use of the electronic signature and have the required "signatories", as per section of ISO/IEC 7025:05(E), signing the reports. For Service Group specific validation please refer to the Validation Signature Page. Page 2 of 3

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