DANGEROUS GOODS PANEL (DGP) MEETING OF THE WORKING GROUP OF THE WHOLE

Transcription

1 18/10/06 DANGEROUS GOODS PANEL (DGP) MEETING OF THE WORKING GROUP OF THE WHOLE Beijing, China, 25 October to 3 November 2006 Agenda Item 6: Discussion of miscellaneous dangerous goods issues EXCEPTED QUANTITY PROVISIONS ADOPTED BY UNITED NATIONS (Presented by the Secretary) 1. To assist members reviewing DGP-WG/06-WP/4, two listings (one in UN number and the other in alphabetical order) of the proposed excepted quantities sorted by class or division/packing group/liquid or solid are presented in the appendices. Appendix A contains the listing in UN number order and Appendix B contains the listing in alphabetical order. (79 pages) IP.3.en.doc

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3 NUMBERICAL LISTING Appendix A Division 2.2 Air, compressed Argon, compressed Bromotrifluoromethane Refrigerant gas R 13B Carbon dioxide Carbon dioxide and nitrous oxide mixture Chlorodifluoromethane Refrigerant gas R Chloropentafluoroethane Refrigerant gas R Chloro-1,2,2,2-tetrafluoroethane Refrigerant gas R Chlorotrifluoromethane Refrigerant gas R Dichlorodifluoromethane Refrigerant gas R Dichlorofluoromethane Refrigerant gas R Helium, compressed Krypton, compressed Liquefied gases, non-flammable, charged with nitrogen, carbon dioxide or air Neon, compressed Nitrogen, compressed Refrigerant gas, n.o.s.* Sulphur hexafluoride Hexafluoropropylene Refrigerant gas R Neon, refrigerated liquid Argon, refrigerated liquid Ethylene oxide and carbon dioxide mixture, with not more than 9% ethylene oxide Compressed gas, n.o.s.* ,2-Dichloro-1,1,2,2-tetrafluoroethane Refrigerant gas R Helium, refrigerated liquid Insecticide gas, n.o.s.* Krypton, refrigerated liquid Chlorodifluoromethane and chloropentafluoroethane mixture with fixed boiling point, with approximately 49% chlorodifluoromethane Refrigerant gas R Chlorodifluorobromomethane Refrigerant gas R 12B Octafluorocyclobutane Refrigerant gas R C Nitrogen, refrigerated liquid Rare gases mixture, compressed Rare gases and oxygen mixture, compressed Rare gases and nitrogen mixture, compressed Refrigerant gas R Tetrafluoromethane Chloro-2,2,2-trifluoroethane

4 Appendix A A-2 Refrigerant gas R 133a Refrigerant gas R Trifluoromethane Xenon Carbon dioxide, refrigerated liquid Hexafluoroethane Refrigerant gas R Octafluorobut-2-ene Refrigerant gas R Octafluoropropane Refrigerant gas R Xenon, refrigerated liquid Chlorotrifluoromethane and trifluoromethane azeotropic mixture with approximately 60% chlorotrifluoromethane Refrigerant gas R Dichlorodifluoromethane and difluoroethane azeotropic mixture with approximately 74% dichlorodifluoromethane Refrigerant gas R Ethylene oxide and dichlorodifluoromethane mixture, with not more than 12.5% ethylene oxide Trifluoromethane, refrigerated liquid Gas, refrigerated liquid, n.o.s.* Refrigerant gas R 134a ,1,1,2-Tetrafluoroethane Liquefied gas, n.o.s.* Pentafluoroethane Refrigerant gas R Heptafluoropropane Refrigerant gas R Ethylene oxide and chlorotetrafluoroethane mixture, with not more than 8.8% ethylene oxide Ethylene oxide and pentafluoroethane mixture, with not more than 7.9% ethylene oxide Ethylene oxide and tetrafluoroethane mixture, with not more than 5.6% ethylene oxide Refrigerant gas R 404A Refrigerant gas R 407A Refrigerant gas R 407B Refrigerant gas R 407C Class 3 Packing Group I n-amylene I 1-Pentene I Adhesives containing flammable liquid I Coating solution, I Crotonylene I Diethyl ether I Ethyl ether I Divinyl ether, stabilized I Printing ink, flammable I Printing ink related material, I Isoprene, stabilized I Isopropylamine I Methyl formate I Paint I Paint related material I

5 A-3 Appendix A Pentanes I Petroleum crude oil I Petroleum distillates, n.o.s I Petroleum products, n.o.s I Propylene oxide I Trimethylamine, aqueous solution, not more than 50% trimethylamin I Vinyl ethyl ether, stabilized I Vinylidene chloride, stabilized I Fuel, aviation, turbine engine I Resin solution, flammable I Propyleneimine, stabilized I Aldehydes, n.o.s.* I Flammable liquid, n.o.s.* I Nitrocellulose solution, flammable with not more than 12.6% nitrogen, by dry mass, and not more than 55% nitrocellulose I 2-Chloropropane I Isopentenes I Furan I 2-Chloropropene I 2-Methyl-1-butene I 3-Methyl-1-butene I Amines, flammable, corrosive, n.o.s.* I Polyamines, flammable, corrosive, n.o.s.* I Flammable liquid, corrosive, n.o.s I Hydrocarbons, liquid, n.o.s I Mercaptan mixture, liquid, flammable, n.o.s.* I Mercaptans, liquid, flammable, n.o.s.* I Paint, flammable, corrosive I Paint related material, flammable, corrosive I Class 3 Packing Group II Acetal II Acetone II Acetone oils II Pentanols II Amylamine II Amyl chloride II Amyl mercaptan II Amyl nitrite II Benzene II Butanols II Butyl acetates II n-butylamine II 1-Bromobutane II Chlorobutanes II n-butyl formate II Butyraldehyde II Adhesives containing flammable liquid II Coal tar distillates, flammable II Coating solution, II Cyclohexane II Cyclopentane II

6 Appendix A A-4 Diacetone alcohol II 1,2-Dichloroethylene II Ethylene glycol diethyl ether II Diethylamine II Diethyl ketone II Diisopropylamine II Diisopropyl ether II Dimethylamine, aqueous solution II Dimethyl carbonate II Dimethyldichlorosilane II Dimethyl sulphide II Dioxane II Dioxolane II Extracts, aromatic, liquid II Ethanol II Ethanol solution II Ethyl alcohol II Ethyl alcohol solution II Ethyl acetate II Ethylbenzene II Ethyl borate II 2-Ethylbutyraldehyde II Ethyl butyl ether II Ethylene dichloride II Ethyl formate II Ethyl methyl ketone II Methyl ethyl ketone II Ethyl propionate II Ethyltrichlorosilane II Extracts, flavouring, liquid II Fusel oil II Gasoline II Motor spirit II Petrol II Nitroglycerin solution in alcohol with not more than 1% nitroglycerin II Heptanes II Hexanes II Printing ink, flammable II Printing ink related material, flammable II Isobutyl acetate II Isobutylamine II Isooctene II Isopropanol II Isopropyl alcohol II Isopropyl acetate II Isopropyl nitrate II Ketones, liquid, n.o.s.* II Methanol II Methyl acetate II Methylal II Methylamine, aqueous solution II

7 A-5 Appendix A Methyl butyrate II Methyl isobutyl ketone II Methyl isopropenyl ketone, stabilized II Methyl methacrylate monomer, stabilized II Methyl propionate II Methyl propyl ketone II Octanes II Paint II Paint related material II Pentanes II Perfumery products with flammable solvents II Petroleum crude oil II Petroleum distillates, n.o.s II Petroleum products, n.o.s II n-propanol II Propyl alcohol, normal II Propionaldehyde II n-propyl acetate II Propylamine II 1,2-Dichloropropane II Propyl formates II Pyridine II Rosin oil II Rubber solution II Shale oil II Sodium methylate solution in alcohol II Tinctures, medicinal II Toluene II Triethylamine II Trimethylamine, aqueous solution, not more than 50% trimethylamin II Trimethylchlorosilane II Turpentine substitute II Vinyl acetate, stabilized II Vinyl isobutyl ether, stabilized II Wood preservatives, liquid II Xylenes II Zirconium suspended in a flammable liquid II Acetonitrile II Acetyl chloride II Allyl iodide II Propionyl chloride II Ethyl crotonate II Fuel, aviation, turbine engine II n-propyl nitrate II Resin solution, flammable II Ethyl acrylate, stabilized II Methyl acrylate, stabilized II Pyrrolidine II Alcohols, flammable, toxic, n.o.s.* II Alcohols, n.o.s.* II Aldehydes, flammable, toxic, n.o.s.* II

8 Appendix A A-6 Aldehydes, n.o.s.* II Flammable liquid, toxic, n.o.s.* II Flammable liquid, n.o.s.* II Tars, liquid, including road asphalt and oils, bitumen and cut ba II Isobutyl aldehyde II Isobutyraldehyde II Dichloropropenes II Diisobutylene, isomeric compounds II Tetrahydrofuran II Tripropylene II Valeraldehyde II Nitrocellulose solution, flammable with not more than 12.6% nitrogen, by dry mass, and not more than 55% nitrocellulose II Cycloheptane II Cycloheptene II Cyclopentene II Bicyclo [2.2.1] hepta-2-5-diene, stabilized II 2,5-Norbornadiene, stabilized II 1,2-Dimethoxyethane II Cyclohexene II Dimethylcyclohexanes II Dimethyl-N-propylamine II Ethylamine, aqueous solution with not less than 50% but not more than 70% ethylamine II Ethyl methacrylate, stabilized II n-heptene II Isobutyronitrile II Isoheptene II Isohexene II Methylcyclohexane II Methylcyclopentane II 2-Methylfuran II Octadiene II Allyl acetate II Allyl ethyl ether II Benzotrifluoride II 2-Bromobutane II 2-Bromoethyl ethyl ether II Bromomethylpropanes II 2-Bromopentane II Bromopropanes II 3-Bromopropyne II Butanedione II Butyl mercaptan II Butyl methyl ether II Butyl nitrites II Butyl vinyl ether, stabilized II Butyryl chloride II Chloromethyl ethyl ether II Cyclooctatetraene II Diallylamine II Diallylamine II

9 A-7 Appendix A Diallyl ether II 1,1-Dichloroethane II alpha-methylvaleraldehyde II 1-Hexene II 1,2-Di-(dimethylamino) ethane II Diethoxymethane II 3,3-Diethoxypropene II Diethyl sulphide II 2,3-Dihydropyran II 1,1-Dimethoxyethane II 2-Dimethylaminoacetonitrile II 1,3-Dimethylbutylamine II Dimethyldiethoxysilane II Dimethyl disulphide II Dipropylamine II Di-n-propyl ether II Ethyl isobutyrate II 1-Ethylpiperidine II Fluorobenzene II Fluorotoluenes II 2-Iodobutane II Iodomethylpropanes II Isobutyl formate II Isobutyryl chloride II Methacrylaldehyde, stabilized II 3-Methylbutan-2-one II Methyl tert-butyl ether II 1-Methylpiperidine II Methyl isovalerate II Propanethiols II Isopropenyl acetate II Isopropyl isobutyrate II Isopropyl propionate II 1,2,3,6-Tetrahydropyridine II Butyronitrile II Tetrahydrothiophene II Thiophene II Trimethyl borate II Thioacetic acid II 2,3-Dimethylbutane II Hexadiene II 2-Methyl-2-butene II Methylpentadiene II Isocyanates, flammable, toxic, n.o.s.* II Isocyanate solution, flammable, toxic, n.o.s.* II Isobutyl isocyanate II Hexamethyleneimine II 4-Methylmorpholine II N-Methylmorpholine II Methyltetrahydrofuran II Methylallyl chloride II

10 Appendix A A-8 Cycloheptatriene II Methyl propyl ether II Ethyl propyl ether II Triisopropyl borate II Glycidaldehyde II Dimethyldioxanes II Amines, flammable, corrosive, n.o.s.* II Polyamines, flammable, corrosive, n.o.s.* II Carbamate pesticide, liquid, flammable, toxict less than II Arsenical pesticide, liquid, flammable, toxic*, flash point less than 23ºC II Organochlorine pesticide, liquid, flammable, toxic*, flash point less than 23 C II Triazine pesticide, liquid, flammable, toxic flash point less t II Copper based pesticide, liquid, flammable, toxic II Mercury based pesticide, liquid, flammable, toxic*, flash point less than 23 C II Substituted nitrophenol pesticide, liquid, flammable, toxic*, flash point less than 23 C II Bipyridilium pesticide, toxic, liquid, flammable} II Organophosphorus pesticide, liquid, flammable, toxic*, flash point less than 23 C II Organotin pesticide, liquid, flammable, toxic*, flash point less than 23 C II Vinyl butyrate, stabilized II Flammable liquid, corrosive, n.o.s II N-Methylbutylamine II Chlorosilanes, flammable, corrosive, n.o.s II Pesticide, liquid, flammable, toxic, n.o.s.*, flash point less than 23 C II 1,2-Butylene oxide, stabilized II Coumarin derivative pesticide, liquid, flammable, toxic, flash point less than II Alcoholic beverages containing more than 70% alcohol by volume II Medicine, liquid, flammable, toxic, n.o.s II Polyester resin kit II Ethers, n.o.s.* II Esters, n.o.s.* II Nitriles, flammable, toxic, n.o.s.* II Alcoholates solution, n.o.s.*, in alcohol II Flammable liquid, toxic, corrosive, n.o.s.* II Flammable liquid, toxic, corrosive, n.o.s.* II Hydrocarbons, liquid, n.o.s II Mercaptan mixture, liquid, flammable, n.o.s.* II Mercaptans, liquid, flammable, n.o.s.* II Phenoxyacetic acid derivative pesticide, liquid, flammable, toxic flash poi II Pyrethroid pesticide, liquid flammable, toxic*, flash point less than 23 C II 2-Methylbutanal II Paint, flammable, corrosive II Paint related material, flammable, corrosive II Class 3 Packing Group III Amyl acetates III Pentanols III Amylamine III Amyl formates III n-amyl methyl ketone III Amyl nitrate III Butanols III Butyl acetates III

11 A-9 Appendix A Camphor oil III Adhesives containing flammable liquid III Chlorobenzene III Coal tar distillates, flammable III Coating solution, III Decahydronaphthalene III Diacetone alcohol III Dibutyl ethers III Dichloropentanes III Ethylene glycol diethyl ether III Diisobutyl ketone III Extracts, aromatic, liquid III Ethanol III Ethanol solution III Ethyl alcohol III Ethyl alcohol solution III Ethylene glycol monoethyl ether III Ethylene glycol monoethyl ether acetate III 2-Ethylbutyl acetate III Ethyl butyrate III Ethylene glycol monomethyl ether III Ethylene glycol monomethyl ether acetate III Octyl aldehydes III Ethyl lactate III Extracts, flavouring, liquid III Formaldehyde solution, flammable III Fusel oil III Diesel fuel III Gas oil III Heating oil, light III Hexaldehyde III Printing ink, flammable III Printing ink related material, III Isobutanol III Isobutyl alcohol III Kerosene III Ketones, liquid, n.o.s.* III Mercaptan mixture, liquid, flammable, toxic, n.o.s.* III Mercaptans, liquid, flammable, toxic, n.o.s.* III Mesityl oxide III Methylamyl acetate III Paint III Paint related material III Paraldehyde III Perfumery products with flammable solvents III Petroleum crude oil III Petroleum distillates, n.o.s III Petroleum products, n.o.s III Pine oil III n-propanol III Propyl alcohol, normal III

12 Appendix A A-10 Rosin oil III Rubber solution III Shale oil III Sodium methylate solution in alcohol III Tetraethyl silicate III Tinctures, medicinal III Trimethylamine, aqueous solution, not more than 50% trimethylamin III Turpentine III Turpentine substitute III Wood preservatives, liquid III Xylenes III Zirconium suspended in a flammable liquid III Fuel, aviation, turbine engine III Resin solution, flammable III Butyl propionates III Cyclohexanone III Isopropylbenzene III Nonanes III Alcohols, flammable, toxic, n.o.s.* III Alcohols, n.o.s.* III Aldehydes, flammable, toxic, n.o.s.* III Aldehydes, n.o.s.* III Flammable liquid, toxic, n.o.s.* III Flammable liquid, n.o.s.* III Tars, liquid, including road asphalt and oils, bitumen and cut ba III Cymenes III Dichloropropenes III Dicyclopentadiene III Diethylbenzene III Dipentene III Methyl isobutyl carbinol III Styrene monomer, stabilized III Tripropylene III Nitrocellulose solution, flammable with not more than 12.6% nitrogen, by dry mass, and not more than 55% nitrocellulose III Allyl glycidyl ether III Anisole III n-butyl methacrylate, stabilized III Chlorobenzotrifluorides III Chlorotoluenes III Cyclohexyl acetate III Cyclopentanol III Cyclopentanone III n-decane III Tripropylamine III N,N-Dimethylformamide III Ethyl amyl ketone III 2-Ethylbutanol III 2-Ethylhexylamine III Hexanols III Isobutyl methacrylate, stabilized III

13 A-11 Appendix A Pentamethylheptane III 4-Methoxy-4-methylpentan-2-one III Methylcyclohexanone III 5-Methylhexan-2-one III Isopropenylbenzene III Pentane-2,4-dione III Picolines III Terpene hydrocarbons, n.o.s III Triethyl phosphite III Triisobutylene III 1,3,5-Trimethylbenzene III Trimethyl phosphite III Undecane III Acetaldehyde oxime III 1-Bromo-3-methylbutane III Bromopropanes III Butyl acrylates, stabilized III Butyl nitrites III Diisobutylamine III n-propylbenzene III Diethyl carbonate III alpha-pinene III Iodopropanes III Isobutyl propionate III Isopropyl butyrate III Tetrapropyl orthotitanate III Isocyanates, flammable, toxic, n.o.s.* III Isocyanate solution, flammable, toxic, n.o.s.* III 1,2,3,6-Tetrahydrobenzaldehyde III Bromobenzene III Cyclooctadienes III Ethyl orthoformate III Furfurylamine III Isobutyl acrylate, stabilized III Isobutyl isobutyrate III Isobutyric acid III Terpinolene III 2-Methylpentan-2-ol III Acrolein dimer, stabilized III Nitropropanes III Triallylamine III Methallyl alcohol III Triisopropyl borate III Methylcyclohexanols, flammable III Vinyltoluenes, stabilized III Amyl butyrates III Acetyl methyl carbinol III 3-Diethylaminopropylamine III Dimethyldioxanes III Butylbenzenes III Dipropyl ketone III

14 Appendix A A-12 Amines, flammable, corrosive, n.o.s.* III Polyamines, flammable, corrosive, n.o.s.* III 1,2-Epoxy-3-ethoxypropane III Butyraldoxime III Di-n-amylamine III Nitroethane III Propylene tetramer III Flammable liquid, corrosive, n.o.s.* III Methyl 2-chloropropionate III Isopropyl 2-chloropropionate III Ethyl 2-chloropropionate III Tetrahydrofurfurylamine III Isopropyl chloroacetate III Cyclohexyl mercaptan III n-heptaldehyde III Alcoholic beverages containing more than 24% but not more than 70% alcohol by volume III 1-Methoxy-2-propanol III Medicine, liquid, flammable, toxic, n.o.s III Polyester resin kit III Ethers, n.o.s.* III Esters, n.o.s.* III Hydrocarbons, liquid, n.o.s III Mercaptan mixture, liquid, flammable, n.o.s.* III Mercaptans, liquid, flammable, n.o.s.* III Paint, flammable, corrosive III Paint related material, flammable, corrosive III Division 4.1 Packing Group II Aluminium powder, coated II Ferrocerium II Flammable solid, organic, n.o.s.* II Hafnium powder, wetted not less than 25% water (a visible excess of water must be present) II Cerium, slabs, ingots or rods II Phosphorus heptasulphide, free from yellow and white phosphorus II Phosphorus sesquisulphide, free from yellow and white phosphorus II Phosphorus trisulphide, free from yellow and white phosphorus II Rubber scrap, powdered or granulated, not exceeding 840 microns and rubber content exceeding 45% II Rubber shoddy, powdered or granulated, not exceeding 840 microns and rubber content exceeding 45% II Zirconium hydride II Titanium hydride II Nitrocellulose with water, not less than 25% water by mass II Nitrocellulose with alcohol, not less than 25% alcohol, by mass, and not more than 12.6% nitrogen, by dry mass II Nitrocellulose not more than 12.6% nitrogen, by dry mass, \ II Nitrocellulose, with not more than 12.6% nitrogen, by dry mass, \ II Nitrocellulose with not more than 12.6% nitrogen, by dry mass, \ II Nitrocellulose, with not more than 12.6% nitrogen, by dry mass, \ II Isosorbide dinitrate mixture with not less than 60% lactose, mannose, starch or calcium hydrogen phosphate II Flammable solid, corrosive, organic, n.o.s.* II

15 A-13 Appendix A Flammable solid, toxic, organic, n.o.s.* II Lead phosphite, dibasic II Metal powder, flammable, n.o.s II Solids containing flammable liquid, n.o.s.* II Flammable solid, inorganic, n.o.s.* II Flammable solid, toxic, inorganic, n.o.s.* II Flammable solid, corrosive, inorganic, n.o.s.* II Metal salts of organic compounds, flammable, n.o.s.* II Metal hydrides, flammable, n.o.s.* II Nitrocellulose membrane filters with not more than 12.6% nitrogen, by dry mass II Division 4.1 Packing Group III Aluminium powder, coated III Borneol III Calcium resinate III Calcium resinate, fused III Cobalt resinate, precipitated III Films, nitrocellulose base, gelatin coated, except scrap III Flammable solid, organic, n.o.s.* III Hexamethylenetetramine III Manganese resinate III Metaldehyde III Naphthalene, crude III Naphthalene, refined III Phosphorus, amorphous III Silicon powder, amorphous III Sulphur III Fabrics impregnated with weakly nitrated nitrocellulose, n.o.s III Fibres impregnated with weakly nitrated nitrocellulose, n.o.s III Magnesium in pellets, turnings or ribbons III Magnesium alloys with more than 50% magnesium in pellets, turnings or ribbons III Matches, safety (book, card or strike on box) III Matches, wax vesta III Celluloid, in blocks, rods, rolls, sheets, tubes, etc. (except scrap) III Cobalt naphthenates, powder III Paraformaldehyde III Nitronaphthalene III Firelighters, solid with flammable liquid III Dicyclohexylammonium nitrite III Zinc resinate III Aluminium resinate III Camphor, synthetic III Zirconium, dry, coiled wire, finished metal sheets, strip (thinne III Titanium sponge granules III Titanium sponge powders III Flammable solid, corrosive, organic, n.o.s.* III Flammable solid, toxic, organic, n.o.s.* III Lead phosphite, dibasic III Metal powder, flammable, n.o.s III Flammable solid, inorganic, n.o.s.* III Flammable solid, toxic, inorganic, n.o.s.* III Flammable solid, corrosive, inorganic, n.o.s.* III

16 Appendix A A-14 Metal salts of organic compounds, flammable, n.o.s.* III Metal hydrides, flammable, n.o.s.* III 2-Bromo-2-nitropropane-1,3-diol III Division 4.2 Packing Group II Liquids Self-heating liquid, organic, n.o.s.* II Self-heating liquid, toxic, organic, n.o.s.* II Self-heating liquid, corrosive, organic, n.o.s.* II Self-heating liquid, inorganic, n.o.s.* II Self-heating liquid, toxic, inorganic, n.o.s.* II Self-heating liquid, corrosive, inorganic, n.o.s.* II Division 4.2 Packing Group III Liquids Self-heating liquid, organic, n.o.s.* III Self-heating liquid, toxic, organic, n.o.s.* III Self-heating liquid, corrosive, organic, n.o.s.* III Self-heating liquid, inorganic, n.o.s.* III Self-heating liquid, toxic, inorganic, n.o.s.* III Self-heating liquid, corrosive, inorganic, n.o.s.* III Division 4.2 Packing Group II Solids p-nitrosodimethylaniline II Potassium sulphide with less than 30% water of crystallization II Potassium sulphide, anhydrous II Sodium dithionite II Sodium hydrosulphite II Sodium sulphide with less than 30% water of crystallization II Sodium sulphide, anhydrous II Sodium methylate II Calcium dithionite II Calcium hydrosulphite II Potassium dithionite II Potassium hydrosulphite II Magnesium diamide II Zirconium powder, dry II Sodium hydrosulphide with less than 25% water of crystallization II Hafnium powder, dry II Titanium powder, dry II Cyclooctadiene phosphines II 9-Phosphabicyclononanes II Self-heating solid, organic, n.o.s.* II Self-heating solid, corrosive, organic, n.o.s.* II Self-heating solid, toxic, organic, n.o.s.* II Metal powder, self-heating, n.o.s.* II Self-heating solid, inorganic, n.o.s.* II Self-heating solid, toxic, inorganic, n.o.s.* II Self-heating solid, corrosive, inorganic, n.o.s.* II Alkaline earth metal alcoholates, n.o.s.* II Alkali metal alcoholates, self-heating, corrosive, n.o.s.* II Organic pigments, self-heating II Thiourea dioxide II Xanthates II Organometallic substance, solid, self-heating* II Division 4.2 Packing Group III Solids

17 A-15 Appendix A Carbon, activated III Zirconium powder, dry III Zirconium, dry, finished sheets, strip or coiled wire III Maneb III Maneb preparation with not less than 60% maneb III Hafnium powder, dry III Titanium powder, dry III Ferrous metal borings in a form liable to self-heating III Ferrous metal cuttings in a form liable to self-heating III Ferrous metal shavings in a form liable to self-heating III Ferrous metal turnings in a form liable to self-heating III Metal catalyst, dry III Self-heating solid, organic, n.o.s.* III Self-heating solid, corrosive, organic, n.o.s.* III Self-heating solid, toxic, organic, n.o.s.* III Titanium disulphide III Metal powder, self-heating, n.o.s.* III Self-heating solid, inorganic, n.o.s.* III Self-heating solid, toxic, inorganic, n.o.s.* III Self-heating solid, corrosive, inorganic, n.o.s.* III Alkaline earth metal alcoholates, n.o.s.* III Alkali metal alcoholates, self-heating, corrosive, n.o.s.* III Organic pigments, self-heating III Thiourea dioxide III Xanthates III Organometallic substance, solid, self-heating* III Division 4.3 Packing Group II Liquids Water-reactive liquid, corrosive, n.o.s.* II Water-reactive liquid, toxic, n.o.s.* II Water-reactive liquid, n.o.s.* II Organometallic substance, liquid, water reactive* II Organometallic substance, liquid, water reactive, flammable* II Division 4.3 Packing Group III Liquids Water-reactive liquid, corrosive, n.o.s.* III Water-reactive liquid, toxic, n.o.s.* III Water-reactive liquid, n.o.s.* III Organometallic substance, liquid, water reactive* III Organometallic substance, liquid, water reactive, flammable* III Division 4.3 Packing Group II Solids Phosphorus pentasulphide, free from yellow and white phosphorus II Alkali metal amides II Alkaline earth metal alloy, n.o.s II Aluminium carbide II Aluminium ferrosilicon powder II Aluminium powder, uncoated II Barium II Calcium II Calcium carbide II Calcium silicide II Metal hydrides, water-reactive, n.o.s.* II Lithium silicon II

18 Appendix A A-16 Magnesium alloys powder II Magnesium powder II Zinc dust II Zinc powder II Magnesium silicide II Lithium hydride, fused solid II Water-reactive solid, n.o.s.* II Lithium ferrosilicon II Cerium, turnings or gritty powder II Water-reactive solid, corrosive, n.o.s.* II Water-reactive solid, flammable, n.o.s.* II Water-reactive solid, toxic, n.o.s.* II Water-reactive solid, self-heating, n.o.s.* II Aluminium remelting by-products II Aluminium smelting by-products II Metallic substance, water-reactive, n.o.s.* II Metallic substance, water-reactive, self-heating, n.o.s.* II Organometallic substance, solid, water reactive* II Organometallic substance, solid, water reactive, flammable* II Organometallic substance, solid, water reactive, self-heating* II Division 4.3 Packing Group III Solids Aluminium powder, uncoated III Aluminium silicon powder, uncoated III Calcium cyanamide with more than 0.1% of calcium carbide III Calcium silicide III Ferrosilicon with 30% or more but less than 90% silicon III Magnesium alloys powder III Magnesium powder III Zinc ashes III Zinc dust III Zinc powder III Water-reactive solid, n.o.s.* III Calcium manganese silicon III Magnesium granules, coated, particle size not less than 149 microns III Maneb preparation, stabilized against self-heating III Maneb stabilized against self-heating III Water-reactive solid, corrosive, n.o.s.* III Water-reactive solid, flammable, n.o.s.* III Water-reactive solid, toxic, n.o.s.* III Water-reactive solid, self-heating, n.o.s.* III Aluminium remelting by-products III Aluminium smelting by-products III Metallic substance, water-reactive, n.o.s.* III Metallic substance, water-reactive, self-heating, n.o.s.* III Organometallic substance, solid, water reactive* III Organometallic substance, solid, water reactive, flammable* III Organometallic substance, solid, water reactive, self-heating* III Division 5.1 Packing II Solids Ammonium dichromate II Ammonium perchlorate II Barium chlorate, solid II

19 A-17 Appendix A Barium nitrate II Barium perchlorate, solid II Barium permanganate II Barium peroxide II Bromates, inorganic, n.o.s II Calcium chlorate II Calcium chlorite II Calcium perchlorate II Calcium permanganate II Calcium peroxide II Chlorate and borate mixture II Chlorate and magnesium chloride mixture, solid II Chlorates, inorganic, n.o.s II Chlorites, inorganic, n.o.s II Chromium trioxide, anhydrous II Chromium trioxide, anhydrous II Lead nitrate II Lead perchlorate, solid II Lithium hypochlorite, dry II Lithium hypochlorite mixture II Lithium peroxide II Magnesium bromate II Magnesium perchlorate II Magnesium peroxide II Nitrates, inorganic, n.o.s II Oxidizing solid, n.o.s.* II Perchlorates, inorganic, n.o.s II Permanganates, inorganic, n.o.s II Peroxides, inorganic, n.o.s II Potassium bromate II Potassium chlorate II Potassium nitrate and sodium nitrite mixture II Potassium nitrite II Potassium perchlorate II Potassium permanganate II Silver nitrate II Sodium bromate II Sodium chlorate II Sodium chlorite II Sodium perchlorate II Sodium permanganate II Strontium chlorate II Strontium perchlorate II Strontium peroxide II Zinc ammonium nitrite II Zinc chlorate II Zinc nitrate II Zinc permanganate II Zinc peroxide II Calcium hypochlorite, dry II Calcium hypochlorite mixture, dry with more than 39% available chlorine (8.8% available oxygen) II

20 Appendix A A-18 Beryllium nitrate II Dichloroisocyanuric acid, dry II Dichloroisocyanuric acid salts II Trichloroisocyanuric acid, dry II Thallium chlorate II Nitrites, inorganic, n.o.s II Barium bromate II Copper chlorate II Magnesium chlorate II Barium hypochlorite with more than 22% available chlorine II Calcium hypochlorite, hydrated with not less than 5.5% but not more than 16% water II Calcium hypochlorite, hydrated mixture with not less than 5.5% but not more than 16% water II Oxidizing solid, corrosive, n.o.s.* II Oxidizing solid, toxic, n.o.s.* II Hypochlorites, inorganic, n.o.s II Sodium peroxoborate, anhydrous II Sodium carbonate peroxyhydrate II Division 5.1 Packing III Solids Aluminium nitrate III Ammonium persulphate III Caesium nitrate III Calcium nitrate III Chlorate and borate mixture III Chlorate and magnesium chloride mixture, solid III Didymium nitrate III Ferric nitrate III Guanidine nitrate III Magnesium nitrate III Nitrates, inorganic, n.o.s III Oxidizing solid, n.o.s.* III Perchlorates, inorganic, n.o.s III Permanganates, inorganic, n.o.s III Peroxides, inorganic, n.o.s III Potassium nitrate III Potassium persulphate III Sodium nitrate III Sodium nitrate and potassium nitrate mixture III Sodium nitrite III Sodium persulphate III Strontium nitrate III Urea hydrogen peroxide III Calcium hypochlorite, dry III Calcium hypochlorite mixture, dry with more than 39% available chlorine (8.8% available oxygen) III Lead dioxide III Ammonium nitrate with not more than 0.2% combustible substances, including any organic substance calculated as carbon, to the exclusion of any other added substance III Ammonium nitrate based fertilizer III Calcium hypochlorite mixture, dry with more than 10% but not more than 39% available chlorine III Zinc bromate III Chromium nitrate III Lithium nitrate III

21 A-19 Appendix A Manganese nitrate III Nickel nitrate III Nickel nitrite III Zirconium nitrate III Calcium hypochlorite, hydrated with not less than 5.5% but not more than 16% water III Calcium hypochlorite, hydrated mixture with not less than 5.5% but not more than 16% water III Oxidizing solid, corrosive, n.o.s.* III Oxidizing solid, toxic, n.o.s.* III Persulphates, inorganic, n.o.s III Sodium perborate monohydrate III Sodium carbonate peroxyhydrate III Division 5.1 Packing Group II Liquids Hydrogen peroxide, aqueous solution with not less than 20% but not more than 40% hydrogen peroxide (stabilized as necessary) II Potassium chlorate, aqueous solution II Sodium chlorate, aqueous solution II Calcium chlorate, aqueous solution II Oxidizing liquid, corrosive, n.o.s.* II Oxidizing liquid, toxic, n.o.s.* II Oxidizing liquid, n.o.s.* II Hydrogen peroxide and peroxyacetic acid mixture with acid(s), water and not more than 5% peroxyacetic acid, stabilized II Chlorates, inorganic, aqueous solution, n.o.s II Perchlorates, inorganic, aqueous solution, n.o.s II Bromates, inorganic, aqueous solution, n.o.s II Permanganates, inorganic, aqueous solution, n.o.s II Nitrates, inorganic, aqueous solution, n.o.s II Nitrites, inorganic, aqueous solution, n.o.s II Barium chlorate solution II Barium perchlorate solution II Chlorate and magnesium chloride mixture solution II Lead perchlorate solution II Division 5.1 Packing Group III Liquids Potassium chlorate, aqueous solution III Sodium chlorate, aqueous solution III Calcium chlorate, aqueous solution III Hydrogen peroxide, aqueous solution with not less than 8% but less than 20% hydrogen peroxide (stabilized as necessary) III Oxidizing liquid, corrosive, n.o.s.* III Oxidizing liquid, toxic, n.o.s.* III Oxidizing liquid, n.o.s.* III Chlorates, inorganic, aqueous solution, n.o.s III Perchlorates, inorganic, aqueous solution, n.o.s III Bromates, inorganic, aqueous solution, n.o.s III Persulphates, inorganic, aqueous solution, n.o.s III Nitrates, inorganic, aqueous solution, n.o.s III Nitrites, inorganic, aqueous solution, n.o.s III Barium chlorate solution III Barium perchlorate solution III Chlorate and magnesium chloride mixture solution III Lead perchlorate solution III

22 Appendix A A-20 Division 6.1 Packing Group I Solid Alkaloid salts, solid, n.o.s.* I Alkaloids, solid, n.o.s.* I Arsenic compound, solid, n.o.s I Barium cyanide I Brucine I Calcium cyanide I Cyanides, inorganic, solid, n.o.s.* I Disinfectant, solid, toxic, n.o.s.* I Mercuric potassium cyanide I Nicotine compound, solid, n.o.s I Nicotine preparation, solid, n.o.s I Potassium cyanide, solid I Sodium cyanide, solid I Strychnine I Strychnine salts I Zinc cyanide I Mercury compound, solid, n.o.s I Phenylmercuric compound, n.o.s I Sodium cuprocyanide, solid I Osmium tetroxide I Cadmium compound I Pesticide, solid, toxic, n.o.s.* I Potassium fluoroacetate I Sodium fluoroacetate I Selenates I Selenites I Fluoroacetic acid I Carbamate pesticide, solid, toxic* I Arsenical pesticide, solid, toxic* I Organochlorine pesticide, solid, toxic* I Triazine pesticide, solid, toxic* I Thiocarbamate pesticide, solid, toxic* I Copper based pesticide, solid, toxic* I Mercury based pesticide, solid, toxic* I Substituted nitrophenol pesticide, solid, toxic* I Bipyridilium pesticide, solid, toxic* I Organophosphorus pesticide, solid, toxic* I Organotin pesticide, solid, toxic* I Toxic solid, organic, n.o.s.* I Toxic solid, corrosive, organic, n.o.s.* I Toxic solid, flammable, organic, n.o.s.* I Coumarin derivative pesticide, solid, toxic* I Toxic solid, oxidizing, n.o.s.* I Toxic solid, self-heating, n.o.s.* I Toxic solid, water-reactive, n.o.s.* I Dye intermediate, solid, toxic, n.o.s.* I Dye, solid, toxic, n.o.s.* I Organotin compound, solid, n.o.s.* I Selenium compound, solid, n.o.s I Tellurium compound, n.o.s I

23 A-21 Appendix A Vanadium compound, n.o.s I Toxic solid, inorganic, n.o.s.* I Toxic solid, corrosive, inorganic, n.o.s.* I Phenoxyacetic acid derivative pesticide, solid, toxic* I Pyrethroid pesticide, solid, toxic* I Nitriles, toxic, solid, n.o.s.* I Bromobenzyl cyanides, solid I Toxins, extracted from living sources, solid, n.o.s.* I Organophosphorus compound, toxic, solid, n.o.s.* I Organoarsenic compound, solid, n.o.s.* I Metal carbonyls, solid, n.o.s.* I Organometallic compound, toxic, solid, n.o.s.* I Division 6.1 Packing Group II Solids Alkaloid salts, solid, n.o.s.* II Alkaloids, solid, n.o.s.* II Ammonium arsenate II Arsenic acid, solid II Arsenic bromide II Arsenic compound, solid, n.o.s II Arsenic II Arsenic pentoxide II Arsenic trioxide II Arsenical dust II Barium compound, n.o.s II Beryllium compound, n.o.s II Beryllium powder II Cacodylic acid II Calcium arsenate II Calcium arsenate and calcium arsenite mixture, solid II Chloronitrobenzenes, solid II Copper acetoarsenite II Copper arsenite II Copper cyanide II Cyanides, inorganic, solid, n.o.s.* II Dinitroanilines II Dinitro-o-cresol, solid II Disinfectant, solid, toxic, n.o.s.* II Ferric arsenate II Ferric arsenite II Ferrous arsenate II Hexaethyl tetraphosphate, solid II Lead arsenates II Lead arsenites II Lead cyanide II London Purple II Magnesium arsenate II Mercuric arsenate II Mercuric chloride II Mercuric nitrate II Mercurous nitrate II Mercury acetate II

24 Appendix A A-22 Mercury ammonium chloride II Mercury benzoate II Mercury bromides II Mercury cyanide II Mercury gluconate II Mercury iodide, solid II Mercury nucleate II Mercury oleate II Mercury oxide II Mercury oxycyanide, desensitized II Mercury potassium iodide II Mercury salicylate II Mercury sulphate II Mercury thiocyanate II beta-naphthylamine, solid II Naphthylthiourea II Naphthylurea II Nickel cyanide II Nicotine compound, solid, n.o.s II Nicotine preparation, solid, n.o.s II Nicotine salicylate II Nicotine tartrate II Nitroanilines (o-,m-,p-) II Phenol, solid II Phenylmercuric acetate II Potassium arsenate II Potassium arsenite II Potassium cuprocyanide II Silver arsenite II Silver cyanide II Sodium arsenate II Sodium azide II Sodium cacodylate II Strontium arsenite II Thallium compound, n.o.s II Xylidines, solid II Zinc arsenate II Zinc arsenate and zinc arsenite mixture II Zinc arsenite II Chloroacetic acid, solid II Ammonium dinitro-o-cresolate, solid II Benzidine II Phenylmercuric hydroxide II Phenylmercuric nitrate II Cyanide solution, n.o.s II Chloroanilines, solid II Mercury compound, liquid, n.o.s II Mercury compound, solid, n.o.s II Phenylmercuric compound, n.o.s II Sodium arsenite, solid II Dichlorophenyl isocyanates II

25 A-23 Appendix A Xylenols, solid II Sodium pentachlorophenate II Cadmium compound II Benzoquinone II Pesticide, solid, toxic, n.o.s.* II Phenacyl bromide II Malononitrile II 1,3-Dichloroacetone II Selenium disulphide II Aminopyridines (o-,m-,p-) II 2-Amino-4-chlorophenol II Thallium nitrate II Carbamate pesticide, solid, toxic* II Arsenical pesticide, solid, toxic* II Organochlorine pesticide, solid, toxic* II Triazine pesticide, solid, toxic* II Thiocarbamate pesticide, solid, toxic* II Copper based pesticide, solid, toxic* II Mercury based pesticide, solid, toxic* II Substituted nitrophenol pesticide, solid, toxic* II Bipyridilium pesticide, solid, toxic* II Organophosphorus pesticide, solid, toxic* II Organotin pesticide, solid, toxic* II Toxic solid, organic, n.o.s.* II Ammonium metavanadate II Ammonium polyvanadate II Sodium ammonium vanadate II Potassium metavanadate II Toxic solid, corrosive, organic, n.o.s.* II Toxic solid, flammable, organic, n.o.s.* II Vanadyl sulphate II Coumarin derivative pesticide, solid, toxic* II Toxic solid, oxidizing, n.o.s.* II Toxic solid, self-heating, n.o.s.* II Toxic solid, water-reactive, n.o.s.* II Dye intermediate, solid, toxic, n.o.s.* II Dye, solid, toxic, n.o.s.* II Organotin compound, solid, n.o.s.* II Pentachlorophenol II Solids containing toxic liquid, n.o.s.* II Medicine, solid, toxic, n.o.s II Selenium compound, solid, n.o.s II Tellurium compound, n.o.s II Vanadium compound, n.o.s II Toxic solid, inorganic, n.o.s.* II Toxic solid, corrosive, inorganic, n.o.s.* II Phenoxyacetic acid derivative pesticide, solid, toxic* II Pyrethroid pesticide, solid, toxic* II Xylyl bromide, solid II 3-Chloro-4-methylphenyl isocyanate, solid II Nitrobenzotrifluorides, solid II

26 Appendix A A-24 Hexafluoroacetone hydrate, solid II Chlorocresols, solid II Nitriles, toxic, solid, n.o.s.* II Chlorodinitrobenzenes, solid II Dichloroanilines, solid II Dinitrobenzenes, solid II Nicotine hydrochloride, solid II Nicotine sulphate, solid II Nitrotoluenes, solid II Nitroxylenes, solid II Toluidines, solid II Xylidines, solid II Dinitrotoluenes, solid II Cresols, solid II Toxins, extracted from living sources, solid, n.o.s.* II Organophosphorus compound, toxic, solid, n.o.s.* II Organoarsenic compound, solid, n.o.s II Metal carbonyls, solid, n.o.s.* II Organometallic compound, toxic, solid, n.o.s.* II Division 6.1 Packing Group III Solids Alkaloid salts, solid, n.o.s.* III Alkaloids, solid, n.o.s.* III Aniline hydrochloride III Antimony compound, inorganic, solid, n.o.s III Antimony lactate III Antimony potassium tartrate III Arsenic compound, solid, n.o.s III Barium compound, n.o.s III Beryllium compound, n.o.s III 4-Chloro-o-toluidine hydrochloride, solid III Cyanides, inorganic, solid, n.o.s.* III Disinfectant, solid, toxic, n.o.s.* III Lead acetate III Nicotine compound, solid, n.o.s III Nicotine preparation, solid, n.o.s III Nitrophenols (o-,m-,p-) III Phenylenediamines (o-,m-,p-) III Sodium fluoride, solid III 2,4-Toluylenediamine, solid III Potassium fluoride, solid III Barium oxide III Chlorophenols, solid III Mercury compound, solid, n.o.s III Phenylmercuric compound, n.o.s III Acrylamide, solid III alpha-naphthylamine III Chloroanisidines III Chloronitroanilines III Chlorotoluidines, solid III Lead compound, soluble, n.o.s III

27 A-25 Appendix A Anisidines, solid III Nitrocresols, solid III Sodium arsanilate III Ammonium fluoride III Aminophenols (o-,m-,p-) III Carbon tetrabromide III Cadmium compound III Pesticide, solid, toxic, n.o.s.* III 4,4 -Diaminodiphenylmethane III Potassium fluorosilicate III Sodium chloroacetate III Nitrotoluidines (mono) III Hydroquinone, solid III Sodium fluorosilicate III Acridine III 1,4-Butynediol III Hexachlorobenzene III Carbamate pesticide, solid, toxic* III Arsenical pesticide, solid, toxic* III Organochlorine pesticide, solid, toxic* III Triazine pesticide, solid, toxic* III Thiocarbamate pesticide, solid, toxic* III Copper based pesticide, solid, toxic* III Mercury based pesticide, solid, toxic* III Substituted nitrophenol pesticide, solid, toxic* III Bipyridilium pesticide, solid, toxic* III Organophosphorus pesticide, solid, toxic* III Organotin pesticide, solid, toxic* III Toxic solid, organic, n.o.s.* III Magnesium fluorosilicate III Ammonium fluorosilicate III Zinc fluorosilicate III Fluorosilicates, n.o.s III Vanadium pentoxide III Antimony powder III Hexachlorophene III Resorcinol III Coumarin derivative pesticide, solid, toxic* III Dye intermediate, solid, toxic, n.o.s.* III Dye, solid, toxic, n.o.s.* III Organotin compound, solid, n.o.s.* III Medicine, solid, toxic, n.o.s III Selenium compound, solid, n.o.s III Tellurium compound, n.o.s III Vanadium compound, n.o.s III Toxic solid, inorganic, n.o.s.* III Phenoxyacetic acid derivative pesticide, solid, toxic* III Pyrethroid pesticide, solid, toxic* III Chlorobenzyl chlorides, solid III alpha-methylbenzyl alcohol, solid III Nitriles, toxic, solid, n.o.s.* III