SAFETY DATA SHEET. Revision Date 19-Jan-2018 Revision Number 3 AC ; AC ; AC ; AC

Transcription

1 SAFETY DATA SHEET Revision Number 3 Product Name Cat No. : 1. Identification AC ; AC ; AC ; AC CAS-No Synonyms Recommended Use Uses advised against Laboratory chemicals. Not for food, drug, pesticide or biocidal product use Details of the supplier of the safety data sheet Company Fisher Scientific One Reagent Lane Fair Lawn, NJ Tel: (201) Acros Organics One Reagent Lane Fair Lawn, NJ Emergency Telephone Number For information US call: ACROS-01 / Europe call: Emergency Number US: / Europe: CHEMTREC Tel. No.US: / Europe: Hazard(s) identification Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR ) Flammable solids Category 2 Combustible dust Yes Label Elements Signal Word Warning Hazard Statements Flammable solid May form combustible dust concentrations in air Page 1 / 6

2 Precautionary Statements Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking Ground/bond container and receiving equipment Use explosion-proof electrical/ventilating/lighting/equipment Wear protective gloves/protective clothing/eye protection/face protection Fire In case of fire: Use CO2, dry chemical, or foam for extinction Storage Store in a well-ventilated place. Keep container tightly closed Hazards not otherwise classified (HNOC) None identified 3. Composition/Information on Ingredients Component CAS-No Weight % Ruthenium First-aid measures Eye Contact Skin Contact Inhalation Ingestion Most important symptoms and effects Notes to Physician Suitable Extinguishing Media Unsuitable Extinguishing Media Flash Point Method - Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention. Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Obtain medical attention. Remove from exposure, lie down. Move to fresh air. If not breathing, give artificial respiration. Obtain medical attention. Clean mouth with water. Get medical attention.. Treat symptomatically 5. Fire-fighting measures Dry chemical. Autoignition Temperature Explosion Limits Upper Lower Sensitivity to Mechanical Impact Sensitivity to Static Discharge Specific Hazards Arising from the Chemical Flammable. Dust can form an explosive mixture in air. Combustible material. Fine dust dispersed in air may ignite. Hazardous Combustion Products None known Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full Page 2 / 6

3 protective gear. NFPA Health 0 Flammability 2 Instability 0 Physical hazards N/A Personal Precautions Environmental Precautions 6. Accidental release measures Ensure adequate ventilation. Use personal protective equipment. See Section 12 for additional ecological information. Methods for Containment and Clean Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Up Sweep up or vacuum up spillage and collect in suitable container for disposal. Handling Storage Exposure Guidelines 7. Handling and storage Avoid contact with skin and eyes. Do not breathe dust. Use explosion-proof equipment. Use only non-sparking tools. Keep in a dry, cool and well-ventilated place. Keep container tightly closed. Keep away from heat and sources of ignition. Flammables area. 8. Exposure controls / personal protection This product does not contain any hazardous materials with occupational exposure limitsestablished by the region specific regulatory bodies. Engineering Measures Use explosion-proof electrical/ventilating/lighting/equipment. Personal Protective Equipment Eye/face Protection Skin and body protection Respiratory Protection Hygiene Measures Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR or European Standard EN166. Wear appropriate protective gloves and clothing to prevent skin exposure. No protective equipment is needed under normal use conditions. Handle in accordance with good industrial hygiene and safety practice. 9. Physical and chemical properties Physical State Powder Solid Appearance Grey Odor Odorless Odor Threshold ph Melting Point/Range 2310 C / 4190 F Boiling Point/Range 3900 C / mmhg Flash Point Evaporation Rate Flammability (solid,gas) Flammability or explosive limits Upper Lower Vapor Pressure Vapor Density Specific Gravity Page 3 / 6

4 Solubility Partition coefficient; n-octanol/water Autoignition Temperature Decomposition Temperature Viscosity Molecular Formula Ru Molecular Weight Stability and reactivity Reactive Hazard Stability Conditions to Avoid Incompatible Materials None known, based on information available Stable under normal conditions. Keep away from open flames, hot surfaces and sources of ignition. Incompatible products. Strong oxidizing agents Hazardous Decomposition Products None under normal use conditions Hazardous Polymerization Hazardous Reactions Acute Toxicity Hazardous polymerization does not occur. None under normal processing. 11. Toxicological information Product Information No acute toxicity information is available for this product Component Information Toxicologically Synergistic Products Delayed and immediate effects as well as chronic effects from short and long-term exposure Irritation Sensitization Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Component CAS-No IARC NTP ACGIH OSHA Mexico Ruthenium Not listed Not listed Not listed Not listed Not listed Mutagenic Effects Reproductive Effects Developmental Effects Teratogenicity STOT - single exposure STOT - repeated exposure Aspiration hazard Symptoms / effects,both acute and delayed Endocrine Disruptor Information Other Adverse Effects... None known None known The toxicological properties have not been fully investigated. Page 4 / 6

5 Ecotoxicity. Persistence and Degradability Bioaccumulation/ Accumulation Mobility Waste Disposal Methods 12. Ecological information Insoluble in water. Is not likely mobile in the environment due its low water solubility. 13. Disposal considerations Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification. 14. Transport information DOT Not regulated TDG Not regulated IATA UN-No 3089 Proper Shipping Name METAL POWDER, FLAMMABLE, N.O.S. Hazard Class 4.1 Packing Group III IMDG/IMO UN-No 3089 Proper Shipping Name METAL POWDER, FLAMMABLE, N.O.S. Hazard Class 4.1 Packing Group III International Inventories 15. Regulatory information Component TSCA DSL NDSL EINECS ELINCS NLP PICCS ENCS AICS IECSC KECL Ruthenium X X X - X X X Legend: X - Listed E - Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA. F - Indicates a substance that is the subject of a Section 5(f) Rule under TSCA. N - Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designated polymer made with any free-radical initiator regardless of the amount used. P - Indicates a commenced PMN substance R - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA. S - Indicates a substance that is identified in a proposed or final Significant New Use Rule T - Indicates a substance that is the subject of a Section 4 test rule under TSCA. XU - Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40 CFR 710(B). Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater. Y2 - Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactants that comprises one of the eligibility criteria for the exemption rule. U.S. Federal Regulations TSCA 12(b) SARA 313 SARA 311/312 Hazard Categories See section 2 for more information Page 5 / 6

6 CWA (Clean Water Act) Clean Air Act OSHA Occupational Safety and Health Administration CERCLA California Proposition 65 U.S. State Right-to-Know Regulations This product does not contain any Proposition 65 chemicals U.S. Department of Transportation Reportable Quantity (RQ): DOT Marine Pollutant DOT Severe Marine Pollutant N N N U.S. Department of Homeland Security This product does not contain any DHS chemicals. Other International Regulations Mexico - Grade Prepared By Revision Date Print Date Revision Summary 16. Other information Regulatory Affairs Thermo Fisher Scientific EMSDS.RA@thermofisher.com 19-Jan Jan-2018 This document has been updated to comply with the US OSHA HazCom 2012 Standard replacing the current legislation under 29 CFR to align with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS). Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of SDS Page 6 / 6