Right material for the right application. Laurent Pascal/Total

Transcription

1 Right material for the right application Laurent Pascal/Total

2 CONTENTS 1 TOTAL- AN OVERVIEW 2 TECHNOLOGY EVOLUTION OF POLYETHYLENE 3 TOTAL - AN INVINCIBLE PLAYER IN TECHNOLOGICAL EVOLUTION 4 ROTOMOULDING INDUSTRY CURRENT SCENARIO 5 PRODUCT UP GRADATION BY TOTAL 6 PRODUCTS FOR CUSTOMIZED APPLICATIONS 6 CONDUCTIVE ALLOYS CANBON NANO TECHNOLOGY (CNT) 8 CONCLUSIONS 2

3 TOTAL IN BRIEF 3

4 REFINING AND HEART OF TOTAL 4

5 OUR KEY INDICATORS IN 2016 $210.1 bn* REVENUE * 190.7bn $3.96 bn* ADJUSTED NET INCOME * 3.6bn $8.8 bn ALLOCATED TO R&D between 2015 and 2019 $26.4 bn* ORGANIC INVESTMENT * 19.9bn 97,126 EMPLOYEES MORE THAN 700 PRODUCTION FACILITIES 5

6 REFINING & CHEMICALS KEY INDICATORS IN 2016 No. 1 REFINER IN WESTERN EUROPE A TOP 10 GLOBAL REFINING AND PETROCHEMICALS COMPANY 26 PETROCHEMICALS FACILITIES 3.8 MT OF ETHYLENE PRODUCTION CAPACITY 49,967 EMPLOYEES * 2 SPECIALITY CHEMICALS AFFILIATES*, HUTCHINSON AND ATOTECH WITH NEARLY 100 SITES WORLDWIDE 2.2 MB/DAY OF REFINING CAPACITY WORLDWIDE * Employees present as of Dec. 31, 2016 * Bostik sold in early

7 TOTAL S INTEGRATED PLATFORMS Refinery Refinery + Petrochemicals complex Petrochemicals Plant La Porte, Texas Bayport, Texas Carville, Louisiana Dalian China Foshan China Port Arthur Normandy Antwerp Jubail Qatar Daesan 7 7

8 TECHNOLOGICAL ADVANCEMENT OF POLYETHYLENE THREE CORNER STONES Created by right combination of process and catalyst Determines Processing parameter, Properties, and Applications 1 Polymerization process and technology harvests products 3 Product Technological Advancement Proces Catalyst 2 Determines and controls molecular weight and structure of polymer 8

9 Technological Evolution THE TECHNOLOGICAL EVOLUTION CURVE OF PE REVOLUTION breakthrough innovation EVOLUTION incremental innovation Metallocene Bimodal Materials Science -Nano -Bio -Organic -Smart Linear PE/PP Cr, Z-N Gas phase LDPE

10 TOTAL - GLOBAL TECHNICAL APPROACH FOR THE ROTOMOLDING APPLICATIONS Powder Quality TP-Picture technology Sintering Densification analysis Processing window determination Rotomol ded part Polymers and Compounds Formulation Rotomou lding machine TP-Picture technology 3D scans/overall shrinkage + Structural calculations Process conditio ns TP-Picture technology Polymer «sagging» studies 10

11 PERFORMANCES PERFORMANCE DRIVEN DEVELOPMENTS BIO-TPSEAL BIOTP-SEAL CONDUCTIVE AND HFFR ALLOYS ROTOCOMPOSITE TP-SEAL mipp/pla/eva TAILORMADE COMPOUNDS 3rd GENERATION PE s 2d GENERATION mpe s TIME 11

12 ROTOMOULDING INDUSTRY - CURRENT SCENARIO Ethos Pathos More than 95 % of the rotomolding market is based on Polyethylene MFI range is from 2.0 to 4.0 gm/10 min. Density range is from to g./cc Almost all available rotomoulding products are made out of conventional ZN catalyst Rotomoulding industries are not able to adequately expand application bases Finding limitations in product substitution Logos Limitations in availability of high density products Inadequacy in rendering required long term properties 12

13 ROTOMOULDING INDUSTRY - CURRENT SCENARIO Typical Applications Water Tank Road dividers Heating Oil tank Manhole Chambers Playing equipment Pallets Ice Boxes Floats... Do all the above applications demand same product performance? 13

14 SHORT-TERM AND LONG-TERM PROPERTIES Stiffness Fatigue/Creep Short-term Properties Tensile Impact at room temp Long-term Properties Swelling/Bulging HDT Fit Products made by ZN Catalyst Not Fit TOTAL s Metallocene catalyst based resins offer excellent short term and long term properties. These are designed to combine the excellent mechanical properties with a trouble free processing. These new resins are able to enter applications which have generally been restricted previously to engineering polymers 14

15 TOTAL PUSHING THE BOUNDARIES WITH PRODUCT UPGRADATION TOTAL is pushing the boundaries toward stiffer materials/alloys with superior functionality and surface properties MFI 2.5 MFI 4.0 to 6.0 MFI 3.0 to 10.0 Density 0.935, Modulus ~850 MPa Density to Modulus ~950 to 1000 MPa Modulus MPa M3581UV M4041UV M3421UV MFI Density TOTAL has overcome the conventional challenges with high density Rotomoulding products (High Shrinkage, Low ESCR, Low Impact, Low Durability) with its proprietary Metallocene technology 15

16 GRADE SLATE Specialty Compound HDPE Compound PP Compound Foam Compound (4-5 AND 6-7 Expansion factor) TPSeal /BioTPSeal PLA Compound (Modulus 3500 MPa) EVA Compound Roto lining Compound 16

17 FOAM COMPOUND: BASED ON TOTAL METALLOCENE POLYOLEFINS (LUMICENE PRODUCT RANGE) 17

18 FOAMED STRUCTURES :TP-SEAL AND BIO-TPSEAL STIFFNESS «BOOSTERS» Skin/Foam/Skin samples have been compared to monolayer parts in compression test. Total Bottle mould used for this purpose. - First test: single skin part compared to skin/foam/skin TP-SEAL part produced with the same shot weight Single skin part = 7.0 mm thickness S/F/S part = mm foam, 3 mm outer skin, 2 mm inner skin. - Second test: foam layer was increased to 17 mm. This was done with TP-SEAL and BIO-TPSEAL parts. A 20mm slice of the part was cut and tested 18

19 TP-SEAL AND BIOTPSEAL ROTOMOULDING TECHNOLOGIES: BASED ON TOTAL METALLOCENE POLYOLEFINS (LUMICENE PRODUCT RANGE) TP-SEAL BioTPSeal Skin/Skin mpe / PA11 Low fuel permeation Fuel tanks (CARB/EPA USA) Skin/Foam/Skin mpe / mpe / mpe Boats Structural parts Buoys mpe-pla alloys Monolayers Multilayers Skin/Foam/Skin, Skin/Skin Structural parts. Low warpage parts. Very high stiffness parts Surface properties Paintable parts Design parts (courtesy Elkamet Germany) (courtesy Sealver (France) From Polyolefin to new Material 19

20 TP-SEAL AND BIOTPSEAL SOME APPLICATIONS A project with unique material properties for each component of the structure: Excellent Surface finish for exterior/interior walls - BIO-TPSEAL Low Warpage and Shrinkage for wall panels - BIO-TPSEAL Roof and floors produced from TPSEAL and HDPE for rigidity TPSEAL foam used for insulation purposes 20

21 TP-SEAL AND BIOTPSEAL SOME APPLICATIONS A projects requiring Low Warpage/Shrinkage to produce a 2.4 meter panel: This panel was produced using BIO-TPSEAL with 1100 MPa modulus No post production jigging 21

22 CONDUCTIVE ALLOYS TOTAL S CARBON NANO TECHNOLOGY (CNT): The need for conductive materials has been globally identified in different segments: Packaging : Sheets, Trays, Crates etc Dangerous good transport: IBC s, Fuel pumps, rotomolding potential For the rotomolding market, only carbon black compounds are available. These carbon black compounds are generally very weak in mechanical performances It is almost impossible to get an ADR approval for a rotomolded IBC s (Aluminum is now one of the preferred materials for this market) Total introduced Nanotechnology based solution to overcome existing product s limitations 22

23 BENEFITS OF CARBON NANO TECHNOLOGY (CNT) BASED ALLOYS High Cleanliness Low particle generation Low volatile emmission Fast transition & easy cleaning Over alternative compounds (carbon black, carbon fibers) CB in commercial PS-CB Improved ESD performances Lower conductive filler loading CB aspect ratio ~ 1 TOTAL s CNT Higher processability (lower viscosity) Cycle time reduction Improved conservation of mechanical properties Recyclability Not sensitive to humidity CNT aspect ratio ~

24 TOTAL S CNT ALLOYS FOR ROTOMOLDING : Alloys have been produced based on Lumicene mpe s : MI2 : 4 to 8 g./10 Tensile Modulus : 600 to 800 Mpa Rotomolding : PIAT ~225 C Recorded resistivity: 3.5 to E+04 Ω EASY PROCESSING DUCTILE AT LOW TEMPERATURE 24

25 CONCLUSIONS TOTAL has very rich experience (over 20 years) in rotomoulding industry TOTAL is fully committed to rotomoulding industry with its global, independent and dedicated team comprising of in house R&D and testing facilities in line with the needs of an increasingly global industry Fully owned production assets in Europe and the US offering more freedom for strategic decisions 25

26 26