Material Safety Data Sheet ICE Zirconia - Prettau Zirconia

Transcription

1 SI0003 Date of issue: In Conformity with: EG-No.1907/2006 Material Safety Data Sheet ICE Zirconia - Prettau Zirconia 1. COMMERCIAL PRODUCT NAME AND SUPPLIER 1.1 COMMERCIAL PRODUCT NAME ICE ZIRCONIA - PRETTAU ZIRCONIA 1.2 APPLICATION/USE Production of dentures. 1.3 PRODUCER Zirkonzahn GmbH, An der Ahr 7, IT Gais 1.4 SUPPLIER Zirkonzahn GmbH, An der Ahr 7, IT Gais 1.5 TOX EMERGENCY NUMBER COMPOSITION 2.1 CHEMICAL CHARACTERIZATION/PRODUCT Designation Proportion (% weight) CAS - number EG-EC - number Zirconium oxide 70-97% Aluminium oxide <1% Yttrium oxide <6% Hafnium oxide <5% DESCRIPTION Porous ZrO 2 blank 2.3 ADDITIONAL INFORMATION None. 3. HAZARD IDENTIFICATION 3.1 HAZARD DENOMINATION Not applicable. 3.2 SPECIAL HAZARD WARNINGS FOR HUMAN BEINGS AND ENVIRONMENT Not hazardous if used correctly. Avoid dust when grinding (see item ). 3.3 CLASSIFICATION SYSTEM Classification corresponds to current EC lists, but is completed by instructions taken from specialist literature and provided by the producer. 3.4 ADDITIONAL INFORMATION None. 1

2 4. FIRST AID MEASURES 4.1 EYE CONTACT Open eyes as wide as possible and rinse with large quantities of running water. 4.2 SKIN CONTACT Wash thoroughly with warm water. 4.3 INGESTION If troubles persist, contact a physician. 4.4 INHALATION Provide sufficient ventilation. If troubles persist, contact a physician. 4.5 ADDITIONAL INFORMATION None. 5. FIRE FIGHTING MEASURES 5.1 SUITABLE EXTINGUISHING DEVICES Suitable extinguishing device depend on environment. No special measures required. Not combustible. 5.2 UNSUITABLE EXTINGUISHING DEVICES None. 5.3 ADDITIONAL INFORMATION None. 6. ACCIDENTAL RELEASE MEASURES 6.1 INDIVIDUAL PROTECTION Not required. 6.2 MEASURES FOR ENVIRONMENTAL PROTECTION Do not empty into sewage or waterways. 6.3 MEASURES FOR CLEANING Pick up mechanically. 6.1 ADDITIONAL INFORMATION No hazardous substances are released. 7. HANDLING AND STORAGE 7.1 HANDLING Only adequately trained personnel should handle this product. Keep out of the reach of children. 7.2 INDUSTRIAL HYGIENE Usual hygienic measures are necessary. When using, do not eat; drink or smoke. 7.3 STORAGE No special requirements for place of storage and containers. 7.4 INFORMATION ABOUT STORAGE IN ONE COMMON STORAGE FACILITY Not required. 7.5 FIRE AND EXPLOSION PROTECTION No special measures required. 7.6 INDICATIONS FOR SAFE HANDLING Provide for sufficient ventilation/suction at work place. In case of dust exposure, provide suction unit. 7.7 ADDITIONAL INFORMATION None. 2

3 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 TECHNICAL EQUIPMENT No further information required. 8.2 CONTROL OF THRESHOLD LIMITS Components are to be monitored with limit values referred to work place. Provide adequate air suction in order to keep longterm safe compliance of work place limit values. 8.3 PERSONAL PROTECTIVE EQUIPMENT Yes RESPIRATORY PROTECTION Respiratory protection if dust is generated HAND PROTECTION Not required EYE PROTECTION Safety goggles GENERAL MEASURES Observe usual precautionary measures in handling with chemical products. 8.4 DIRECTIVES OF EXPOSURE / THRESHOLD Zirconium oxide (CAS: ) MAK: 6 mg/m 3 (TRGS900). 8.5 ADDITIONAL INFORMATION None. 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1 FORM Solid. 9.2 COLOUR White. 9.3 ODOUR Odourless. 9.4 CHANGES IN PHYSICAL STATE FREEZING POINT/SPHERE Not applicable MELTING POINT/SPHERE Undetermined BOILING POINT/SPHERE Undetermined. 9.5 DENSITY 3,0 g/cm SOLUBILITY Insoluble in water. Organic solvents 0,0 % 9.7 PH-VALUE Undetermined. 9.8 FLASH POINT Not applicable. 9.9 IGNITION POINT The product is not self-igniting EXPLOSION LIMITS The product is not explosive SOLIDS CONTENT/VISCOSITY 100% solid body ADDITIONAL INFORMATION None. 10. STABILITY AND REACTIVITY 10.1 THERMAL DECOMPOSITION No decomposition if used according to specifications HAZARDOUS DECOMPOSITION No dangerous decomposition products known. 3

4 10.3 DANGEROUS REACTIONS No dangerous reactions known ADDITIONAL INFORMATION None. 11. TOXICOLOGICAL INFORMATION 11.1 ACUTE TOXICITY Primary irritating effect SKIN Mild irritating effect EYES Mild irritating effect SENSITIZATION No sensitizing effects known ADDITIONAL TOXICOLOGICAL INFORMATION The product has to be labelled due to the calculation procedure of the "General classification guideline for preparations of the EU" in the latest valid version. Based in our experience and the information at our disposal, the product causes no harmful effects if handled correctly and used according to regulations. 12. ECOLOGICAL INFORMATION No toxicological information on environment at our disposal. Avoid discharge into drains or surface other water. 13. DISPOSAL CONSIDERATIONS 13.1 PRODUCT Dispose of in conformity with local official regulations EC-WASTE KEY Not known CONTAINER Dispose of soiled packaging in conformity with local official regulations ADDITIONAL INFORMATION None. 14. TRANSPORT INFORMATION 14.1 TRANSPORT AT LAND (ADR/RIG/GGVSE) CLASSIFICATION HAZARD LABLE UN-NO KEMLER NUMBER PACKING GROUP CLASSIFICATION CODE WARNING SIGN PACKING CODE VOLUME OR MASS - 4

5 CORRECT TECHNICAL TERM LIMITED QUANTITY TRANSPORT AT SEA (IMDG-CODE/GGVSEE) CLASSIFICATION UN-NO PACKING GROUP EMS MARINE POLLUTANT ADDITIONAL DANGER AIR TRANSPORT (ICAO-CODE/GGVSEE) CLASSIFICATION UN-NO PACKING GROUP SUBSIDIARY RISK ADDITIONAL INFORMATION Not classed as hazardous good under transport regulations. 15. REGULATORY INFORMATION 15.1 REGULATIONS ACCORDING TO EC REGULATIONS The product is a medical device according to the EC-directive 93/ DANGER SYMBOL Not applicable HAZARD DECLARATION Not applicable R-PHRASES S-PHRASES S29: Do not empty into drains SPECIAL LABELLING None ADDITIONAL INFORMATION None. 16. ADDITIONAL INFORMATION No further information The above mentioned data correspond to our present state of knowledge and experience. The material safety data sheet serves as description of the products with regards to necessary safety measures. The indications do not have the meaning of guarantees on properties. 5