Section 1: PRODUCT AND COMPANY IDENTIFICATION. Section 2: HAZARDS IDENTIFICATION

Transcription

1 PreparedinaccordancewithGB/T ,GB/TGB/T ,GB ,GB/T Globally Harmonized System (GHS) Print Date: 20/Aug/2016 Page 1 of 7 Section 1: PRODUCT AND COMPANY IDENTIFICATION Product Name: Product use Uses advised against Chemical Name Company: Thickener Synthetic Amorphous Silica J.M. Huber Corporation 3100 Cumberland Boulevard, Suite 600 Atlanta, GA USA Tel: Telephone CHEMTREC: or International Internet Registration Number hubermaterials@huber.com Section 2: HAZARDS IDENTIFICATION GHS Classification Physical Hazard Health Hazard Environmental Hazard GHS Label Elements, including precautionary statements Symbols/Pictogram Signal Word Hazard Statement The substance does not meet the criteria for classification. Precautionary Statements Prevention Observe good industrial hygiene practices. Avoid breathing dust. Use mechanical ventilation (dilution and local exhaust) to control exposure

2 Print Date: 20/Aug/2016 Page 2 of 7 Response Spills and Leaks Storage Disposal Wash hands and face before breaks and immediately after handling the product. Collect spillage Store away from incompatible materials. Store in a dry place Dispose of contents/containers in accordance with local regulations Hazards not otherwise classified (HNOC) Section 3: COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS Number China (IECSC) Synthetic amorphous silica TSCA: United States Y REACH China registratio classification n number Not dangerous goods. Weight-% 100 Section 4: FIRST AID MEASURES General Advice Eye Contact Skin Contact Inhalation Ingestion Notes to Physician Personal Protective Equipment For First Aid Responders Expected acute symptoms and delayed symptoms Hold eyelids apart and flush eyes with a steady, gentle stream of water for several minutes. Wash skin with soap and water Move person to fresh air Rinse mouth with water. Do not induce vomiting. Treat symptomatically Wear suitable protective clothing Section 5: FIRE FIGHTING MEASURES Flammable Properties Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media: Specific Hazards Arising from the Chemical

3 Print Date: 20/Aug/2016 Page 3 of 7 Unusual fire & explosion hazards: Protective measures: Protective Equipment and Precautions for Firefighters Use protective equipment that is appropriate for surrounding materials. Wear self-contained breathing apparatus and protective suit Section 6: SPILLAGE, ACCIDENTAL RELEASE MEASURES Personal Precautions Environmental Precautions Methods for cleaning up Other Information: Ensure adequate ventilation. Avoid dust formation. Avoid inhalation of dust. Refer to Section 8 for personal protective equipment. Prevent entry into waterways, sewers, basements or confined areas. Do not flush into surface water or sanitary sewer system. Pick up mechanically and / or by rinsing with water. Avoid dry sweeping and use a sprinkler system or exhaust ventilation to prevent dust formation. Section 7: HANDLING AND STORAGE Handling Storage Avoid dust formation. Avoid breathing dust. Handle in accordance with good industrial hygiene and safety practice. Keep container tightly closed in a dry and well-ventilated place Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Chemical Name China China TWA China STEL ACGIH OSHA Japan ISHL ACL Japan JSOH TWA TWA: 5 mg/m 3 total dust STEL: 10 mg/m 3 total dust 5 mg/m 3 TWA (total dust) 10 mg/m 3 STEL (total dust) TWA: 10 mg/m 3 (total dust) TWA: 15 mg/m 3 (total dust) 5 mg/m 3 (respirable dust) (vacated) TWA: 6 mg/m 3 Not established Not established Synthetic amorphous silica Engineering Measures Personal Protective Equipment Eye/Face Protection Skin and Body Protection Hand Protection Respiratory Protection Ensure adequate ventilation, especially in confined areas Tightly fitting safety goggles Wear body protection appropriate to handling activities Protective gloves. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators.

4 Print Date: 20/Aug/2016 Page 4 of 7 Hygiene Measures Handle in accordance with good industrial hygiene and safety practice Section 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Physical State Color Odor Odor Threshold ph: Solid Powder White Odorless 6.8 5% Water suspension Melting Point / Melting Range > 3092 F (> 1700 C) 101,3 kpa Initial Boiling Point Freezing Point Flash Point: Evaporation Rate Flammability (solid, gas) Upper flammability limit: Lower flammability limit: Vapor Pressure Vapor Density No data available No data available Density 2.0 g/cm3, 20 C Water Solubility g/l Water 20ºC Partition coefficient <0.5 Autoignition Temperature Decomposition Temperature Viscosity Viscosity, kinematic No data available No data available. Explosive Properties Oxidizing Properties

5 Print Date: 20/Aug/2016 Page 5 of Other information Section 10: STABILITY AND REACTIVITY Stability Conditions to avoid: Incompatible Products: Hazardous decomposition products Hazardous Reactions Hazardous polymerization: Stable under normal conditions No materials to be especially mentioned under normal processing under normal processing Product Information Section 11: TOXICOLOGICAL INFORMATION Inhalation Eye Contact Skin Contact Acute Toxicity Dust contact with the eyes can lead to mechanical irritation. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Synthetic amorphous silica >3300 mg/kg Rat >5000, mg/kg, Rabbit >2.06 mg/l 4-hr Rat Chronic Toxicity Carcinogenicity Irritation Corrosivity Sensitization Neurological Effects Mutagenic effects Reproductive Toxicity Developmental Toxicity IARC Group 3 - Not Classifiable as to Carcinogenicity in Humans Did not cause sensitization on laboratory animals

6 Print Date: 20/Aug/2016 Page 6 of 7 Target Organ Effects Section 12: ECOLOGICAL INFORMATION Ecotoxicity Persistence / Degradability Bioaccumulation Mobility Not biodegradable Section 13: DISPOSAL CONSIDERATIONS Waste from Residues/Unused Products Contaminated Packaging: Dispose of in accordance with local regulations Empty containers should be taken to an approved waste handling site for recycling or disposal. Section 14: TRANSPORT INFORMATION Mode of Transportation (Road, Water, Air, Rail) DOT ADR RID ADN IATA IMDG/IMO ICAO UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards No Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

7 Print Date: 20/Aug/2016 Page 7 of 7 Section 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture Global Inventories Chemical Name CAS Number Synthetic amorphous silica Legend Y: Yes N: No Exempt EC No REACH registration number Australia (AICS) Canada (DSL) China (IECSC ) Japan Y Y Y (1)-548 (ENCS) South Korea (KECL) Mexico New Philippin Zealand es (PICCS) Taiwan TSCA: United States KE Y Y Y Y Section 16: OTHER INFORMATION Prepared by Huber Engineered Materials Global Regulatory Affairs regulatory.affairs@huber.com Reason for Revision GB/T GB/T GB GB/T Physical Hazard Health Hazard Environmental Hazard GHS Label Elements, including precautionary statements Symbols/Pictogram Signal Word Hazard Statement Training Advice Sources of key data: The substance does not meet the criteria for classification. Do not handle until all safety precautions have been read and understood. Literature data and/or investigative reports are available through the manufacturer. Disclaimer The information provided in this is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of