SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Silsoft* ETS

Transcription

1 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 Product identifier Trade name : CAS : Chemical name : Heptamethyl ethyl trisiloxane ELINCS No. : REACH Registration No. : XXXX 1.2 Relevant identified uses of the substance or mixture and uses advised against Usage : Industrial use, Component in personal care products Uses advised against : 1.3 Details of the supplier of the safety data sheet Company: : Momentive Performance Materials GmbH Chempark Leverkusen Gebaeude V7 DE Leverkusen Telephone : Information contact: : MomentiveEMEA.productsteward@momentive.com 1.4 Emergency telephone 24 Hour Emergency Telephone : Europe, Israel & All other: +44 (0) ; Middle East:+44 (0) HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture: Classification according to Regulation (EC) No 1272/2008 as amended Flammable liquids Category 3; H226; Classification according to Directive 67/548/EEC or 1999/45/EC as amended: R10; 2.2 Label elements GHS-Labelling Regulation (EC) No. 1272/2008: Hazard pictograms Signal words: warning 1/11

2 Hazard statements H226 Flammable liquid and vapor. Precautionary Statement - Prevention: P233 Keep container tightly closed. Precautionary Statement - Response: P381 Eliminate all ignition sources if safe to do so. Labelling according to EC Directives Hazardous components which must be listed on the label: R-phrase(s) : R10 Flammable. S-phrase(s) : S7 Keep container tightly closed. S16 Keep away from sources of ignition - No smoking. 2.3 Other hazards 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Component(s) Chemical name CAS-No.; EC No.; REACH Registration No ; ; XXXX; Concentration % > 98, ,000 EU Classification F;R10; Regulation (EC) No. 1272/2008 Category 3; Flam. Liq.; H226; 4. FIRST AID MEASURES 4.1 Description of first aid measures Inhalation : Move to fresh air. Consult a physician after significant exposure. 2/11

3 Skin contact : Wash area with soap and water. Get medical attention if symptoms occur. Eye contact : Rinse the eye with water immediately. Get medical attention if symptoms persist. Ingestion : Drink plenty of water. Do NOT induce vomiting. 4.2 Most important symptoms and effects, both acute and delayed 4.3 Indication of any immediate medical attention and special treatment needed 5. FIRE-FIGHTING MEASURES 5.1 Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : All standard extinguishing agents are suitable. : Avoid water in straight hose stream; will scatter and spread fire. 5.2 Special hazards arising from the substance or mixture: Vapors are heavier than air and may spread near ground to sources of ignition. 5.3 Advice for firefighters: Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. 6. ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures: Avoid contact with eyes, skin, and clothing. Avoid contact with liquid and vapors. Use personal protective equipment. 6.2 Environmental precautions: Do not allow runoff to sewer, waterway or ground. 6.3 Methods and material for containment and cleaning up: Remove sources of ignition. Take up with an absorbent for chemicals or, otherwise use dry sand. 3/11

4 7. HANDLING AND STORAGE 7.1 Precautions for safe handling Handling : Do not taste or swallow. Avoid contact with eyes, skin, and clothing. Avoid breathing mists or vapors. Wash hands after handling. Advice on protection against fire and explosion : Keep away from sources of ignition - No smoking. Do not empty into drains. 7.2 Conditions for safe storage, including any incompatibilities Requirements for storage areas and containers Advice on common storage : Keep away from acids. Other data : Stable : Keep away from sources of ignition - No smoking. Keep container tightly closed in a cool, well-ventilated place. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 Control parameters Occupational exposure limits Contains no substances with occupational exposure limit values. DNEL-Values: No data available PNEC-Values: No data available 8.2 Exposure controls Personal protective equipment (ppe) Respiratory Protection : Respirator with a vapour filter (EN 141) Hand protection : Advice: This recommendation is valid only for our Product as delivered. If this product will be mixed with other substances you need to contact a supplier of CE approved protective gloves (e.g. KCL GmbH, D Eichenzell, Tel (0) , Fax (0) , vertrieb@kcl.de). Material: 730 Camatril Minimum break through time: 480 min Glove thickness: 0,4 mm 4/11

5 Producer: KCL GmbH, D Eichenzell, Tel (0) , Fax (0) , Eye protection : Safety glasses with side shields 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties Appearance : Liquid Color Odor Odor Threshold ph Melting Point Boiling point/boiling range : Colorless : Faint : Pour Point < -60 C : 172 C at hpa Flash Point : 45 C Method: ASTM D 93 Evaporation Rate : <1 Lower explosion limit Upper explosion limit Vapour pressure : 1,15 hpa at 20 C Vapor Density : >1 Density Solubility(ies) : 0,828 g/cm3 at 20 C (1,013 hpa) : Insoluble Solubility in Water : 0,001 g/l at 22 C Method: OECD Test Guideline 105 0,0016 g/l at 25 C Partition Coefficient: n- octanol/water Autoignition Temperature Thermal decomposition 5/11

6 Viscosity, dynamic : ca. 1,095 mpa.s at 20 C Viscosity, kinematic Explosive properties Oxidizing properties 10. STABILITY AND REACTIVITY 10.1 Reactivity: No data available 10.2 Chemical stability: No data available 10.3 Possibility of hazardous reactions: In use, may form flammable/explosive vapour-air mixture.; Apply the following regulations and datasheets of the German BG Chemie.; M 050 "Handling harmful substances".; M 053 "General industrial protective measures for handling dangerous substances" Conditions to avoid: 10.5 Incompatible materials: Acids Hazardous decomposition products: No decomposition if stored and applied as directed. 11. TOXICOLOGICAL INFORMATION 11.1 Information on toxicological effects Acute oral toxicity : LD50 Rat Dose: > mg/kg Method: OECD-Guideline 423 (Acute Oral Toxicity - Acute Toxic Class Method) Acute inhalation toxicity : Rat 6/11

7 Dose: >10 mg/l Exposure time: 4 h Method: OECD Test Guideline 403 Acute dermal toxicity Skin irritation. : Rabbit Exposure time: 4 h Result: No skin irritation Method: OECD Test Guideline 404 Eye irritation : Rabbit Result: No eye irritation Method: OECD Test Guideline 405 Sensitization : Guinea Pig Result: negative Method: OECD Test Guideline 406 Mutagenicity : In Vivo comet Assay: Result: Negative. Did not show any mutagenic effects. Genetic Toxicity in vitro : Test type: Ames-Test Result: negative (not mutagenic) Method: OECD-Guideline 471 (Genetic Toxicology: Salmonella typhimurium, Reverse Mutation Assay) : Test type: Chromosomal aberration Metabolic activation: with or without metabolic activation Result: negative Method: OECD 473 Genetic toxicity in vivo : Test type: Micronucleus test Result: negative (not mutagenic) Method: OECD-Guideline 474 (Genetic Toxicology: Micronucleus Test) 12. ECOLOGICAL INFORMATION 12.1 Toxicity Ecotoxicity effects Toxicity to fish : LC50 Species: Rainbow Trout Dose: > 100 mg/l Exposure time: 96 h Method: OECD Test Guideline 203 Toxicity to other organisms : EC50 Species: Daphnia magna Dose: > 100 mg/l 7/11

8 Exposure time: 48 h Method: OECD Test Guideline 202 Toxicity to algae : EC50 Species: Desmodesmus subspicatus (green algae) Dose: > 100 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Toxicity to microorganisms : Respiration inhibition test. EC50 Species: activated sludge (adaptation not specified) Dose: > mg/l Exposure time: 3 h Method: OECD-Guideline No Persistence and degradability Elimination information (persistence and degradability) Persistence and degradability : Biological degradability Exposure time: 28 d < 60 % Method: OECD-Guideline 301 F (Manometric Respirometry Test) The product is not readily biodegradable Bioaccumulation Product: No data available 12.4 Mobility in soil No data available 12.5 Results of PBT and vpvb assessment Product: No data available 12.6 Other adverse effects 13. DISPOSAL CONSIDERATIONS 13.1 Waste treatment methods Product : According to local regulations, can be taken to an appropriate incinerator equipped with exhaust gas cleaning. Contaminated packaging : Dispose of as unused product. 8/11

9 14. TRANSPORT INFORMATION Land transport ADR: UN-Number 1993 Class 3 Packing group III Classification Code F1 Hazard identification No 30 ADR/RID-Labels 3 Proper Shipping Name FLAMMABLE LIQUID, N.O.S. Contains RID Class No.: UN-Number 1993 Class 3 Packing group III Classification Code F1 Hazard identification No 30 ADR/RID-Labels 3 Proper Shipping Name FLAMMABLE LIQUID, N.O.S. Contains Inland waterway transport ADNR: UN-Number 1993 Class 3 Packing group III Classification Code F1 Hazard identification No 33 ADNR-Labels 3 Proper Shipping Name Flammable liquids, n.o.s. Contains Sea transport IMDG: UN-Number 1993 Class 3 Packing group III IMDG-Labels 3 EmS F-E, S-E Proper Shipping Name FLAMMABLE LIQUID, N.O.S. Contains Air transport ICAO/IATA: UN-Number /11

10 Class 3 Packing group III ICAO-Labels 3 Proper Shipping Name Flammable liquid, n.o.s. Contains Further Information : Combustible Keep away from food, foodstuff, acids and bases. 15. REGULATORY INFORMATION 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture 15.2 Chemical safety assessment Inventories Australia Inventory of y (positive listing) Chemical Substances (AICS) EU list of new chemical y (positive listing) substances Japan Inventory of Existing & y (positive listing) New Chemical Substances (ENCS) China Inventory of Existing n (Negative listing) Chemical Substances Korea Existing Chemicals y (positive listing) Inventory (KECI) Canada DSL Inventory q (quantity restricted) Canada NDSL Inventory n (Negative listing) Philippines Inventory of n (Negative listing) Chemicals and Chemical Substances (PICCS) TSCA list e (special case) This product is intended only for personal care applications. It is not intended for industrial use; therefore, it is not subject to TSCA. For inventories that are marked as quantity restricted or special cases, please contact Momentive. 10/11

11 16. OTHER INFORMATION Wording of the R-phrases and H-statements in section 2 and 3 H226: Flammable liquid and vapor. H226: Flammable liquid and vapor. R10 Flammable. Unless otherwise specified in section 1.2.1, Momentive Products are intended for industrial application only. They are not intended for specific medical applications, neither for long-lasting (> 30 days) implantation into the human body, injected or directly ingested, nor for the manufacture of multiple usable contraceptives. Further Information The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. 11/11