Cambridge International Examinations Cambridge International General Certificate of Secondary Education

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1 * * ambridge International Examinations ambridge International General ertificate of Secondary Education EMISTRY 0620/22 Paper 2 Multiple hoice (Extended) October/November 2018 dditional Materials: Multiple hoice nswer Sheet Soft clean eraser Soft pencil (type or is recommended) 45 minutes RE TESE INSTRUTIONS FIRST Write in soft pencil. o not use staples, paper clips, glue or correction fluid. Write your name, entre number and candidate number on the nswer Sheet in the spaces provided unless this has been done for you. O NOT WRITE IN NY ROES. There are forty questions on this paper. nswer all questions. For each question there are four possible answers,, and. hoose the one you consider correct and record your choice in soft pencil on the separate nswer Sheet. Read the instructions on the nswer Sheet very carefully. Each correct answer will score one mark. mark will not be deducted for a wrong answer. ny rough working should be done in this booklet. copy of the Periodic Table is printed on page 16. Electronic calculators may be used. The syllabus is approved for use in England, Wales and Northern Ireland as a ambridge International Level 1/Level 2 ertificate. This document consists of 16 printed pages. I18 11_0620_22/4RP ULES 2018 [Turn over

2 1 Oxygen and fluorine are gaseous elements next to each other in the Periodic Table. 2 Under the same conditions of temperature and pressure, oxygen diffuses than fluorine because its is less than that of fluorine. Which words correctly complete gaps 1 and 2? 1 2 faster molecular mass faster reactivity slower molecular mass slower reactivity 2 The diagrams show four pieces of laboratory equipment. balance pipette stop-clock thermometer Which equipment is essential to find out if dissolving a salt in water is an exothermic process? balance pipette stop-clock thermometer 45 3 ow many neutrons are present in the atom 21 X?

3 4 Two naturally occurring isotopes of oxygen are 16 O and 17 O. Which statement is correct? 3 oth isotopes react with iron to form rust. Neither isotope reacts with iron to form rust. Only 16 O reacts with iron to form rust. Only 17 O reacts with iron to form rust. 5 ow many electrons are used to form covalent bonds in a molecule of methanol, 3 O? Potassium bromide and methanol are both compounds. Their melting points are different. Which row is correct? substance with the higher melting point reason why the melting points are different methanol the attractive forces between oppositely charged ions is greater than the attractive forces between molecules methanol the attractive forces between molecules is greater than the attractive forces between oppositely charged ions potassium bromide the attractive forces between oppositely charged ions is greater than the attractive forces between molecules potassium bromide the attractive forces between molecules is greater than the attractive forces between oppositely charged ions 7 Which gas sample contains the smallest number of molecules? 4 g of helium 16 g of oxygen 28 g of carbon monoxide 28 g of nitrogen [Turn over

4 8 The equation for the reaction between calcium carbonate and dilute nitric acid is shown. 4 ao 3 (s) + 2NO 3 (aq) a(no 3 ) 2 (aq) + O 2 (g) + 2 O(l) 25 g of calcium carbonate is reacted with an excess of dilute nitric acid. Which mass of calcium nitrate and which volume of carbon dioxide is produced at room temperature and pressure? mass of calcium nitrate / g volume of carbon dioxide / dm The formulae of some ions are shown. positive ion negative ion Ti 4+ 3 PO 4 l 3+ 2 SO 4 Mg 2+ NO 3 K + l Which formula is not correct? l 3(SO 4 ) 2 K 3 PO 4 Mg(NO 3 ) 2 Til 4

5 10 oncentrated aqueous copper(ii) chloride is electrolysed using copper electrodes as shown. 5 power supply copper electrodes + aqueous copper(ii) chloride What happens to the mass of each electrode during this process? positive electrode negative electrode decreases decreases decreases increases increases decreases increases increases [Turn over

6 11 The diagram shows a circuit used to electrolyse aqueous copper(ii) sulfate. 6 power supply copper electrodes aqueous copper(ii) sulfate Which arrows indicate the movement of the copper ions in the electrolyte and of the electrons in the external circuit? copper ions electrons ydrogen peroxide, OO, decomposes to form water and oxygen. 2 2 O 2 (g) 2 2 O(g) + O 2 (g) The bond energies are shown in the table. The reaction is exothermic. bond bond energy in kj / mol O +460 OO +150 O=O +496 What is the energy change for the reaction? 346 kj / mol 196 kj / mol +196 kj / mol +346 kj / mol

7 13 The equation for the formation of ammonia is shown. 7 N N 3 The energy level diagram for the reaction is shown. energy activation energy = +250 kj / mol N energy change total energy released = 342 kj / mol 2N 3 progress of reaction What is the energy change for the reaction? 592 kj / mol 92 kj / mol +92 kj / mol +592 kj / mol 14 The rate of reaction between magnesium ribbon and 2 mol / dm 3 hydrochloric acid at 25 to produce hydrogen gas is measured. In another experiment, either the concentration of the hydrochloric acid or the temperature is changed. ll other conditions are kept the same. Which conditions increase the rate of reaction? 1 mol / dm 3 hydrochloric acid at 25 2 mol / dm 3 hydrochloric acid at 10 2 mol / dm 3 hydrochloric acid at 20 3 mol / dm 3 hydrochloric acid at 25 [Turn over

8 15 Methanol is prepared by the reversible reaction shown. 8 O(g) (g) 3 O(g) The forward reaction is exothermic. Which conditions produce the highest equilibrium yield of methanol? temperature pressure high high high low low high low low 16 The thermite reaction can be used to produce iron from iron(iii) oxide. The equation for the reaction is shown. 2l + Fe 2 O 3 2Fe + l 2O 3 Which statements about this reaction are correct? 1 luminium is the oxidising agent. 2 luminium is less reactive than iron. 3 Electrons are transferred from aluminium to iron. 4 The iron in the iron(iii) oxide is reduced. 1 and 3 1 and 4 2 and 3 3 and 4 17 In which row are the oxides correctly identified? acidic basic magnesium oxide, calcium oxide sulfur dioxide, carbon dioxide magnesium oxide, sulfur dioxide carbon dioxide, calcium oxide sulfur dioxide, carbon dioxide calcium oxide, magnesium oxide sulfur dioxide, magnesium oxide calcium oxide, carbon dioxide

9 9 18 When dilute sulfuric acid is added to solid X, a colourless solution is formed and a gas is produced. What is X? copper(ii) oxide sodium oxide copper(ii) carbonate sodium carbonate 19 few drops of methyl orange are added to a reaction mixture. uring the reaction, a gas is produced and the methyl orange turns from red to orange. What are the reactants? aqueous sodium hydroxide and ammonium chloride aqueous sodium hydroxide and calcium carbonate dilute hydrochloric acid and magnesium dilute hydrochloric acid and aqueous sodium hydroxide 20 Some general rules for the solubility of salts in water are listed. arbonates are insoluble (except ammonium carbonate, potassium carbonate and sodium carbonate). hlorides are soluble (except lead(ii) chloride and silver chloride). Nitrates are soluble. Sulfates are soluble (except barium sulfate, calcium sulfate and lead(ii) sulfate). Which substances produce an insoluble salt when aqueous solutions of them are mixed? barium chloride and magnesium nitrate calcium chloride and ammonium nitrate silver nitrate and zinc chloride sodium carbonate and potassium sulfate [Turn over

10 10 21 Elements in Group I of the Periodic Table react with water. Which row describes the products made in the reaction and the trend in reactivity of the elements? products trend in reactivity metal hydroxide and hydrogen less reactive down the group metal hydroxide and hydrogen more reactive down the group metal oxide and hydrogen less reactive down the group metal oxide and hydrogen more reactive down the group 22 The equation shows the reaction between a halogen and aqueous bromide ions. X 2 + 2r 2X + r Which words complete gaps 1, 2 and 3? chlorine brown colourless chlorine colourless brown iodine brown colourless iodine colourless brown 23 n inert gas R is used to fill weather balloons. Which descriptions of R are correct? number of outer shell electrons in atoms of R structure of gas R 2 diatomic molecules 2 single atoms 8 diatomic molecules 8 single atoms

11 11 24 eating copper(ii) carbonate produces copper(ii) oxide and carbon dioxide. eating the copper(ii) oxide formed with carbon produces copper. Which processes are involved in this conversion of copper(ii) carbonate to copper? sublimation followed by oxidation sublimation followed by reduction thermal decomposition followed by oxidation thermal decomposition followed by reduction 25 Four metals, W, X, Y and Z, are separately reacted with water and dilute hydrochloric acid. The results are shown. metal W X Y Z reaction with water fizzes no reaction fizzes vigorously no reaction reaction with dilute hydrochloric acid fizzes no reaction fizzes violently fizzes What is the order of reactivity of the four metals starting with the least reactive? least reactive most reactive X W Z Y X Z W Y Y W Z X Y Z W X 26 Which statement about the uses of metals is not correct? luminium is used in aircraft because of its strength and good electrical conductivity. opper is used in electrical wiring because of its good electrical conductivity. Stainless steel resists corrosion and is used to make cutlery. Transition elements are often used as catalysts. [Turn over

12 12 27 auxite contains aluminium oxide. luminium is extracted from aluminium oxide by electrolysis. Why is cryolite added to the electrolytic cell used to extract aluminium? ryolite prevents the carbon anodes being burned away. ryolite removes impurities from the bauxite. ryolite increases the rate at which aluminium ions are discharged. Molten cryolite dissolves the aluminium oxide. 28 Which statement about the aber process is correct? The hydrogen used is obtained from the air. The nitrogen used is obtained from nitrates in the soil. Nitrogen reacts with hydrogen to make ammonia. The reaction takes place at room temperature and pressure. 29 Which statements about sulfur dioxide pollution are correct? 1 It increases the p of rivers. 2 It damages limestone buildings. 3 It causes respiratory problems. 1 only 2 only 1 and 3 2 and 3 30 rgon is a noble gas used to fill light bulbs. What is the approximate percentage of argon in air? 1% 20% 79% 99%

13 13 31 The diagrams show experiments involving the rusting of iron. tube P tube Q tube R iron nails oil water student predicted the following results. 1 In tube P, the iron nails rust. water boiled to remove the air anhydrous calcium chloride to dry the air 2 In tube Q, the iron nails do not rust. 3 In tube R, the iron nails do not rust. Which predictions are correct? 1, 2 and 3 1 and 2 only 1 and 3 only 2 and 3 only 32 In the carbon cycle, which two processes add carbon dioxide to the atmosphere? combustion and carbonate formation combustion and photosynthesis combustion and respiration respiration and photosynthesis 33 Which statement about sulfur or one of its compounds is correct? Sulfur occurs naturally as the element sulfur. Sulfur dioxide is used to kill bacteria in drinking water. Sulfuric acid is a weak acid. ilute sulfuric acid is a dehydrating agent. [Turn over

14 14 34 What is not a use of lime? It is used as a bleach in the manufacture of wood pulp. It is used to desulfurise flue gases. It is used to neutralise acidic industrial waste. It is used to treat acidic soil. 35 Which equation representing a reaction of methane is correct? 4 + l 2 3 l + l 4 + l 2 4 l l 2 2 l l l + l Which two compounds are molecules which both contain a double bond? ethane and ethanoic acid ethane and ethanol ethene and ethanoic acid ethene and ethanol 37 Ethanol can be formed by: 1 fermentation 2 reaction between steam and ethene. Which of these processes use a catalyst? 1 2

15 15 38 Ethanol is manufactured from ethene. What is an advantage of this process? It is a continuous process. It has high labour costs. It needs high temperature and pressure. It uses non-renewable materials. 39 Which reaction can be used to make ethanoic acid? oxidation of ethanol oxidation of ethene reduction of ethanol reduction of ethene 40 The structure of an addition polymer is shown. O O O Which monomer is used to make this polymer? O O O O O O Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every reasonable effort has been made by the publisher (ULES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the publisher will be pleased to make amends at the earliest possible opportunity. To avoid the issue of disclosure of answer-related information to candidates, all copyright acknowledgements are reproduced online in the ambridge International Examinations opyright cknowledgements ooklet. This is produced for each series of examinations and is freely available to download at after the live examination series. ambridge International Examinations is part of the ambridge ssessment Group. ambridge ssessment is the brand name of University of ambridge Local Examinations Syndicate (ULES), which is itself a department of the University of ambridge.

16 16 Group The Periodic Table of Elements 1 hydrogen 1 2 e helium 4 I II III IV V VI VII VIII 3 Li lithium 7 4 e beryllium 9 atomic number atomic symbol Key name relative atomic mass 11 Na sodium Mg magnesium K potassium a calcium Rb rubidium Sr strontium s caesium a barium Fr francium 88 Ra radium 5 boron l aluminium Ga gallium In indium Tl thallium carbon Si silicon Ge germanium Sn tin Pb lead Ti titanium Zr zirconium f hafnium Rf rutherfordium 23 V vanadium Nb niobium Ta tantalum b dubnium 24 r chromium Mo molybdenum W tungsten Sg seaborgium 25 Mn manganese Tc technetium 75 Re rhenium h bohrium 26 Fe iron Ru ruthenium Os osmium s hassium 27 o cobalt Rh rhodium Ir iridium Mt meitnerium 28 Ni nickel Pd palladium Pt platinum s darmstadtium 29 u copper g silver u gold Rg roentgenium 30 Zn zinc d cadmium g mercury n copernicium 114 Fl flerovium 116 Lv livermorium 7 N nitrogen P phosphorus s arsenic Sb antimony i bismuth O oxygen S sulfur Se selenium Te tellurium Po polonium 9 F fluorine l chlorine r bromine I iodine t astatine 10 Ne neon r argon Kr krypton Xe xenon Rn radon 21 Sc scandium Y yttrium lanthanoids actinoids 57 La lanthanum c lanthanoids actinoids The volume of one mole of any gas is 24 dm 3 at room temperature and pressure (r.t.p.). actinium 58 e cerium Th thorium Pr praseodymium Pa protactinium Nd neodymium U uranium Pm promethium 93 Np neptunium 62 Sm samarium Pu plutonium 63 Eu europium m americium 64 Gd gadolinium m curium 65 Tb terbium k berkelium 66 y dysprosium f californium 67 o holmium Es einsteinium 68 Er erbium Fm fermium 69 Tm thulium Md mendelevium 70 Yb ytterbium No nobelium 71 Lu lutetium Lr lawrencium