SUPPORTING INFORMATION. Organocatalytic asymmetric intramolecular aza-henry reaction: Facile synthesis of trans-2,3-disubstituted tetrahydroquinolines
|
|
|
- Ursula Patterson
- 6 years ago
- Views:
Transcription
1 Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2015 SUPPORTIG IFORMATIO Organocatalytic asymmetric intramolecular aza-enry reaction: Facile synthesis of trans-2,3-disubstituted tetrahydroquinolines Rajendra Maity and Subhas Chandra Pan * Department of Chemistry, Indian Institute of Technology Guwahati, orth Guwahati, Assam, span@iitg.ernet.in Table of Contents 1. General procedure of the synthesis of nitro-amine S2 2. Catalyst, solvent and temperature screening S3-S6 3. Crystal data S7-S8 4. Absolute configuration and References S9 5. MR data S10-S28 6. PLC data S29-S53 S1
2 General procedure for the synthesis of nitro-amine: R CO O 2 S 1 R= -, -5Cl, -6Cl, 1.MeO 2, 1M ao; 8M Cl 2.MsCl, DIPEA O 2-4Me 2, -5CF 3 S 2 80% R O 2 O C 2 O 100 o C, neat O OC 2 5 R O 2 2, Pd/C,MeO R O 2 O 2 2 S 3 80% S 4 75% S 2, S 4 were prepared by previously reported procedure 1, S 3 was prepared by previously reported procedure 2. S2
3 Preliminary Catalyst screening: 2 O 2 + PhCO Catalyst (10mol%) C 2 Cl 2 :pentane (1:5) 0.2 M, 3days,RT O 2 CF 3 CF 3 S S O O CF 3 75% Yield -60 ee CF 3 55% Yield 00 ee CF 3 o reaction CF 3 O O O o reaction CF 3 CF 3 Bui ibu O S 55% Yield 5% ee Bn O S o reaction O O O O S CF 3 CF 3 MeO P O O O 30% Yield o ee 70% Yield o ee o reaction MeO MeO MeO CF 3 CF 3 O O S O S TBDPSO 47% Yield 37%ee CF 3 45% Yield 30%ee CF 3 50% Yield 5%ee MeO MeO MeO O S O S 70% Yield 69% ee F 3 C CF 3 50% Yield 6% ee MeO OMe 60% Yield 5% ee S3
4 MeO O MeO S ibu S S 60% Yield 7% ee O ibu F 3C CF 3 80% Yield 67% ee F 3C CF 3 73% Yield 42% ee MeO S S S 85% Yield -60% ee F 3 C CF 3 F 3 C CF 3 80% Yield -60% ee F 3C CF 3 81% Yield 55% ee MeO S F 3C 85% Yield 74% ee CF 3 S4
5 Preliminary solvent screening using catalyst (V): O PhCO Catalyst V (10 mol%) Solvent (0.2 M), RT, 3days O 2 Ph o. Solvent Yield (%) a ee b 1. Ethanol Toluene CCl C 2 Cl Benzene PhCF Chlorobenzene Ether MTBE CCl Dichloroethane Cyclohexane:C 2 Cl 2 (5:1) n-exane:c 2 Cl 2 (5:1) Pentane:C 2 Cl 2 (5:1) eptane:c 2 Cl 2 (5:1) exane:ccl 3 (5:1) Benzene (MS 4 A o ) Benzene:CCl 3 (5:1) a Isolated yield after silica gel column chromatography. b Determined by PLC using stationary phase chiral column. S5
6 Preliminary temperature screening using the catalyst V: O 2 ΝΗ 2 + PhCO Catalyst V(10 mol%) Pentane:C 2 Cl 2 (5:1) Temp., 3 days Trans (a) O 2 + Cis (b) O 2 o Temp. Overall Yield dr(a:b) ee (a) 1 RT 85% 100:0 74% 2 0 o C 85% 1:1 80% 3-20 o C 85% 1:1 80% S6
7 CRYSTAL DATA OF COMPOUD (CCDC ) 3f: ORTEP STRUCTURE Crystal data and structure refinement for CIRAL COMPOUD 3f Identification code RM-O2-4Br-CIRAL Empirical formula C Br 2 O 2 Formula weight Temperature/K 296(2) Crystal system orthorhombic Space group P a/å 5.947(3) b/å 7.118(3) c/å (11) α/ β/ γ/ Volume/Å (10) S7
8 Z 4 ρ calc mg/mm m/mm F(000) Crystal size/mm Θ range for data collection 2.48 to Index ranges -7 h 7, -8 k 7, -36 l 40 Reflections collected Independent reflections 2607[R(int) = ] Data/restraints/parameters 2607/0/181 Goodness-of-fit on F Final R indexes [I>=2σ (I)] R 1 = , wr 2 = Final R indexes [all data] R 1 = , wr 2 = Largest diff. peak/hole / e Å /-0.51 Flack parameter (19) S8
9 (2R, 3S)-1,2,3,4-tetrahydro-3-nitro-2-phenylquinoline (3a): O 2 Absolute configuration: The optical rotation of 3a was [α] D 23 = (c 0.17, CCl 3 ). As, it was opposite to the reported compound 3, the absolute configuration was determined to be (2R, 3S). References: 1. J. C. Anderson, A. oble, P. R. Torres, Tetrahedron Lett., 2012, 53, P. Chauhan, K. Kaur,. Bala, V. Kumar, S. S. Chimni, Indian J. Chem., Sect B, 2011, 50B, X.-F. Cai, M.-W. Chen, Z.-S. Ye, R.-. Guo, L. Shi, Y.-Q. Li, Y.-G. Zhou, Chem. Asian J., 2013, 8, S9
10 MR Data of the Products: O 2 3a O 2 3a S10
11 O 2 3b Me O 2 3b Me S11
12 O 2 3c O 2 3c S12
13 O 2 3d O 2 3d S13
14 O 2 3e Cl O 2 3e Cl S14
15 O 2 3f Br O 2 3f Br S15
16 O 2 3g F O 2 3g F S16
17 O 2 3h OMe O 2 3h OMe S17
18 O 2 3i O 2 3i S18
19 O 2 3j Cl O 2 3j Cl S19
20 O 2 3k Br O 2 3k Br S20
21 O 2 3l Me Me O 2 3l Me Me S21
22 O 2 3m O 2 3m S22
23 O 2 3n O 2 3n S23
24 O 2 3o O 2 3o S24
25 Cl O 2 3p Cl O 2 3p S25
26 Cl O 2 3q Cl O 2 3q S26
27 O 2 3r O 2 3r S27
28 F 3 C O 2 3s F 3 C O 2 3s S28
29 PLC data of the Products: O 2 3a O 2 3a S29
30 O 2 3a O 2 3b Me S30
31 O 2 3b Me O 2 3b Me S31
32 O O 2 2 3c O 2 3c S32
33 O 2 3d O 2 3d S33
34 O 2 3e Cl O 2 3e Cl S34
35 O 2 3e Cl O 2 3f Br S35
36 O 2 3f Br O 2 3f Br S36
37 O 2 3g F O 2 3g F S37
38 O 2 3g F O 2 3h OMe S38
39 O 2 3h OMe O 2 3i S39
40 O 2 3i O 2 3i S40
41 O 2 3j Cl O 2 3j Cl S41
42 O 2 3j Cl O 2 3k Br S42
43 O 2 3k Br O 2 3l Me Me S43
44 O 2 3l Me Me O 2 3l Me Me S44
45 O 2 3m O 2 3m S45
46 O 2 3n O 2 3n S46
47 O 2 3o O 2 3o S47
48 Cl O 2 3p Cl O 2 3p S48
49 Cl O 2 3p Cl O 2 3q S49
50 Cl O 2 3q Cl O 2 3q S50
51 O 2 3r O 2 3r S51
52 O 2 3r F 3 C O 2 3s S52
53 F 3 C O 2 3s F 3 C O 2 3s S53
Generation of cocrystals of Tavaborole (AN2690): opportunities for boron-containing APIs
Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 2017 Electronic Supplementary Information (ESI) Generation of cocrystals of Tavaborole (AN2690):
The effect of metal distribution on the luminescence properties of mixedlanthanide metal-organic frameworks
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2018 The effect of metal distribution on the luminescence properties of mixedlanthanide metal-organic
Acceptorless Dehydrogenation and Dehydrogenative Coupling of Alcohols. by Protic NHC Ruthenium Complexes
Electronic Supplementary Material (ESI) for rganic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2017 Supporting Information for Acceptorless Dehydrogenation and Dehydrogenative
Supporting Information. Unprecedented reactions: from epichlorohydrin to epoxyglycidyl substituted
Supporting Information Unprecedented reactions: from epichlorohydrin to epoxyglycidyl substituted divinyl ether and its conversion into epoxyglycidyl propargyl ether Yiwu Yao 1, Zheng Li 2, Yatao Qiu 1,
SUPPLEMENTARY INFORMATION
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2014 SUPPLEMENTARY INFORMATION NO-binding in {Ru(NO) 2 } 8 -type [Ru(NO) 2 (PR 3 ) 2 X]BF
Electronic Supporting Information For Structural and reactivity insights into covalently linked Cu(I) complex- Anderson polyoxometalates
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2017 Electronic Supporting Information For Structural and reactivity insights into covalently
Nucleophilic Trifluoromethylation of Unactivated Arenes Jack A Pike, James W Walton
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 07 Nucleophilic Trifluoromethylation of Unactivated Arenes Jack A Pike, James W Walton Table of contents:.
Supporting Information
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2014 Supporting Information Rhodium-catalyzed olefination of aryl tetrazoles
Are gamma amino acids promising tools of crystal engineering? Multicomponent crystals of baclofen
Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 2015 Electronic Supplementary Information Are gamma amino acids promising tools of crystal engineering?
On the quantitative recycling of Raney-Nickel catalysts on a labscale
On the quantitative recycling of Raney-Nickel catalysts on a labscale Waldemar M. Czaplik, Jörg-M. Neudörfl and Axel Jacobi von Wangelin* Supporting information General Toluene was freshly dried and distilled
Supplementary Figures:
Supplementary Figures: Supplementary Figure 1. Crystal structure of ligand 4 drawn with 50% thermal ellipsoid probability. Hydrogens are omitted for clarity. Zinc atoms are dark blue; sulfur, yellow; phosphorus,
Ruthenium-catalyzed Olefin Metathesis Accelerated by Steric Effect of Backbone Substituent in Cyclic (Alkyl)(Amino)Carbenes
Electronic Supplementary Information for Ruthenium-catalyzed Olefin Metathesis Accelerated by Steric Effect of Backbone Substituent in Cyclic (Alkyl)(Amino)Carbenes Jun Zhang,* a Shangfei Song, a Xiao
Supplementary Material
ARKIVC 212 (viii) S1-S Supplementary Material An efficient method for the preparation of 2,2,4- trisubstituted 1,2- dihydroquinolines using catalytic amount Bi(Tf) as catalyst Zeynep Gültekin, a* Wolfgang
Regioselective (thio)carbamoylation of 2,7-di-tertbutylpyrene at the 1-position with iso(thio)cyanates
Supporting Information Regioselective (thio)carbamoylation of 2,7-di-tertbutylpyrene at the 1-position with iso(thio)cyanates for Anna Wrona-Piotrowicz *,1, Marzena Witalewska 1, Janusz Zakrzewski *1 and
Supporting Information
Supporting Information Access to Hexahydrocarbazoles: The Thorpe Ingold Effects of the Ligand on Enantioselectivity Hao Chen, Lijia Wang, Feng Wang, Liu-Peng Zhao, Pan Wang, and Yong Tang* anie_201700042_sm_miscellaneous_information.pdf
Chiral Structure of Thiolate-Protected 28-Gold-Atom Nanocluster Determined by X-ray Crystallography
Supporting information Chiral Structure of Thiolate-Protected 28-Gold-Atom Nanocluster Determined by X-ray Crystallography Chenjie Zeng, Tao Li, Anindita Das, Nathaniel L. Rosi, and Rongchao Jin *, Department
Generation Response. (Supporting Information: 14 pages)
Cs 4 Mo 5 P 2 O 22 : A First Strandberg-Type POM with 1D straight chains of polymerized [Mo 5 P 2 O 23 ] 6- units and Moderate Second Harmonic Generation Response (Supporting Information: 14 pages) Ying
Supporting Information. Deformation twinning of ferrocene crystals assisted by the rotational mobility of cyclopentadienyl rings
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2015 Supporting Information Deformation twinning of ferrocene crystals assisted by the rotational
Supporting Information for. Nitric Oxide Reactivity of Copper(II) Complexes of Bidentate Amine Ligands: Effect of. Substitution on Ligand Nitrosation
1 Supporting Information for Nitric Oxide Reactivity of Copper(II) Complexes of Bidentate Amine Ligands: Effect of Substitution on Ligand Nitrosation Moushumi Sarma and Biplab Mondal Department of Chemistry,
M. Toufiqur Rahman, Jeffrey R. Deschamps, Gregory H. Imler, Alan W. Schwabacher and James M. Cook *
SUPPORTING INFORMATION TOTAL SYNTHESIS OF MACROCARPINE D AND E VIA AN ENOLATE-DRIVEN COPPER- MEDIATED CROSS-COUPLING PROCESS: REPLACEMENT OF CATALYTIC PALLADIUM WITH COPPER IODIDE M. Toufiqur Rahman, Jeffrey
Syntheses of Bipyricorroles and their meso-meso coupled dimers
SUPPORTING INFORMATION Syntheses of Bipyricorroles and their meso-meso coupled dimers B. Adinarayana, Ajesh P. Thomas, Pardhasaradhi Satha and A. Srinivasan* School of Chemical Sciences, National Institute
Transformative route to nanoporous manganese oxides of controlled oxidation states with identical textural properties
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information (ESI) for Transformative route to
Supporting Information
Supporting Information Solvent-free synthesis of 1,4-disubstituted 1,2,3-triazoles using a low amount of Cu(PPh 3 ) 2 O 3 complex Dong Wang, a Li, Mingming Zhao, Weilin Shi, Chaowei Ma and Baohua Chen*
π-stacking Synthon Repetitivity in Coordination Compounds
Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 2016 π-stacking Synthon Repetitivity in Coordination Compounds Hamid Reza Khavasi,* Sima Kavand
Bulletin of the Chemical Society of Japan
Supporting Information Bulletin of the Chemical Society of Japan 1,4-Selective Diels Alder Reaction of 9,10-Diethynylanthracene with 3,6-Difluorobenzyne Yoshitaka Tsuchido, 1 Tomohito Ide, 2 Yuji Suzaki,
Supporting Information for
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2018 Supporting Information for Na 3 Ca 4 (TeO 3 )(PO 4 ) 3 : New Noncentrosymmetric Tellurite
Supporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2015 Supporting Information Mechanochromism and aggregation induced emission in benzothiazole substituted
Supporting Information. Photochromic, Photoelectric and Fluorescent Properties
Supporting Information Multifunctional Open-Framework Zinc Phosphate C 12 H 14 N 2 [Zn 6 (PO 4 ) 4 (HPO 4 )(H 2 O) 2 ]: Photochromic, Photoelectric and Fluorescent Properties Junbiao Wu, Yan Yan, Bingkun
Supplementary Figure S1 A comparison between the indium trimer in ITC-n and nickel trimer in ITC-n-Ni.
Supplementary Figure S1 A comparison between the indium trimer in ITC-n and nickel trimer in ITC-n-Ni. Supplementary Figure S2 Powder XRD and the simulation pattern of (a) ITC-1, (b) ITC-2, ITC-2NH 2 and
Supplementary Information
Supplementary Information Supplementary Figures Absorption (a. u.) a 1.5 1.0 0.5 PTFB-O PTFB-P Absorption (a. u.) b 0.8 0.4 PTFB-O PTFB-P 0.0 400 500 600 700 wavelength (nm) 0.0 400 500 600 700 800 wavelength
Supporting Information
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2016 Supporting Information Assembly of Inorganic [Mo2S2O2] 2+ Panels Connected by Selenite
Supporting Information
Supporting Information Synthesis and characterization of a luminescence metallosupramolecular hyperbranched polymer Bingran Yu, Shuwen Guo, Lipeng He, and Weifeng Bu* Key Laboratory of Nonferrous Metals
Supporting Information
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 14 Supporting Information A heterotrimetallic Ir (III), Au (III) and Pt (II) complex incorporating
Elissavet E. Anagnostaki, Alexandros L. Zografos*
A non-natural Elemane as the Stepping Stone for the Synthesis of Germacrane and Guaiane Sesquiterpenes Elissavet E. Anagnostaki, Alexandros L. Zografos* Contribution from the Department of Chemistry, Laboratory
Supporting Information for: Expedient Access to α,β-difunctionalized Azepenes using Alpha-Halo Eneformamides:
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2014 Beng et al; Supporting Information Supporting Information for: Expedient
On the use of phosphoramidite ligands in copper-catalyzed asymmetric transformations with trialkylaluminum reagents
Supporting information for n the use of phosphoramidite ligands in copper-catalyzed asymmetric transformations with trialkylaluminum reagents Chloée Bournaud, Caroline Falciola, Thomas Lecourt, Stéphane
Supporting Information for
Supporting Information for Direct Synthesis of Large-Scale ortho-iodinated Perylene Diimides: Key Precursors for Functional Dyes Jiajun Wu, Dezhi He, Li Zhang, Yudong Liu, Xiaogang Mo, Jianbin Lin* and
Supporting Information
Supporting Information Synthesis of 4-Ynamides and Cyclization by the Vilsmeier Reagent to Dihydrofuran-2(3H)-ones Zhaocheng Zhang, b Rapolu Kiran Kumar, a Guangzhi Li, b Dongmei Wu,* b Xihe Bi* a,b,c
Supporting Information. Copyright Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, 2009
Supporting Information Copyright Wiley-VC Verlag Gmb & Co. KGaA, 69451 Weinheim, 2009 A Stereodivergent Strategy to Both Product Enantiomers from the Same Enantiomer of a Stereoinducing Catalyst: Agelastatin
Electronic Supplementary Information. Synthesis and crystal structure of a rare square-planar Co (II) complex of a hydroxyamidinate ligand.
Electronic Supplementary Information Synthesis and crystal structure of a rare square-planar Co (II) complex of a hydroxyamidinate ligand. Mihaela Cibian, a Sofia Derossi, a and Garry S. Hanan* a Département
Supporting Information
Supporting Information Radical Cyclizations terminated by Ir-catalyzed AT Andreas Gansäuer,* Matthias Otte, Lei Shi Kekulé-Institut für Organische Chemie und Biochemie der Universität Bonn, Gerhard Domagk
Electronic Supplementary Material (ESI)
Electronic Supplementary Material (ESI) for hemical Science. This journal is The Royal Society of hemistry 2017 Electronic Supplementary Material (ESI) Rapid Reversible orane to oryl ydride Exchange by
Supporting Information
Supporting Information A Unique Pair: Ag 40 and Ag 46 Nanoclusters with the Same Surface but Different Cores for Structure-Property Correlation Jinsong Chai, Sha Yang, Ying Lv, Tao Chen, Shuxin Wang, Haizhu
Supporting Information for:
Supporting Information for: Capture of Ni II, Cu I and Zn II by Thiolate Sulfurs of an N 2 S 2 Ni Complex: A Role for a Metallothiolate Ligand in the Acetyl-coenzyme A Synthase Active Site Melissa L. Golden,
* solvent and impurities
* solvent and impurities upplementary Figure 1. 1 H MR spectrum of 3b in CDCl 3 (1.3 mm). upplementary Figure 2. 13 C MR spectrum of 3b in CDCl 3 (1.3 mm). upplementary Figure 3. 1 H MR spectrum of 4a
Electronic Supplementary Information (ESI)
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2018 Electronic Supplementary Information (ESI) Palladium(II) and platinum(ii) saccharinate
labeled bacteria was analyzed on a glass slide using a Cy5 HYQ (Nikon 96324; Exc /Em ) filter.
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Materials and Methods Materials. All peptide related reagents (resin, coupling reagent, deprotection
Supporting Information
Supporting Information Two-Dimensional Organic Single Crystals with Scale Regulated, Phase Switchable, Polymorphism-Dependent and Amplified Spontaneous Emission Properties Zhenyu Zhang, Xiaoxian Song,
Electronic Supplementary Information (ESI) Structure-charge transport relationship of 5,15-Dialkylated porphyrins
Electronic Supplementary Information (ESI) Structure-charge transport relationship of 5,15-Dialkylated porphyrins Li Zhou, a Zong-Xiang Xu, b Ye Zhou, b Yan Feng, a Xiang-Ge Zhou, a Hai-Feng Xiang, a*
Characterization and strong piezoelectric response of an. organometallic nonlinear optical crystal: CdHg(SCN) 4 (C 2 H 6 SO) 2
Supplementary Information Characterization and strong piezoelectric response of an organometallic nonlinear optical crystal: CdHg(SCN) 4 (C 2 H 6 SO) 2 Xitao Liu, Xinqiang Wang *, Xin Yin, Shaojun Zhang,
Supporting Information
Supporting Information Synthesis of pincer hydrido ruthenium olefin complexes for catalytic alkane dehydrogenation Yuxuan Zhang, Huaquan Fang, Wubing Yao, Xuebing Leng and Zheng Huang* State Key Laboratory
Supporting Information. Template-assisted photodimerization of N-unprotected uracil derivatives - Selective formation of the cis-syn photodimer
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2017 Supporting Information Template-assisted photodimerization of -unprotected uracil derivatives -
SUPPORTING INFORMATION
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 24 SUPPORTIG IFORMATIO Polymethylhydrosiloxane Derived Palladium anoparticles for Chemo- and Regioselective
Appendix A. X-ray Crystal Structure of methyl 3-chlorothiophene-2-carboxylate
120 Appendix A X-ray Crystal Structure of methyl 3-chlorothiophene-2-carboxylate X-ray crystallographic diffraction, data collection and data work-up run by Dr. Michael W. Day at the X-Ray Crystallography
Fluorescent-based detection of nitric oxide in aqueous and methanol media using copper(ii) complex
Supporting Information for Fluorescent-based detection of nitric oxide in aqueous and methanol media using copper(ii) complex Biplab Mondal, * Pankaj Kumar, Pokhraj Ghosh and Apurba Kalita. Department
Electronic Supplementary Information. Jian-Rong Wang, Junjie Bao, Xiaowu Fan, Wenjuan Dai and Xuefeng Mei *
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information ph-switchable vitamin B 9 gels for stoichiometry-controlled
Supporting Information. for. Group-assisted purification (GAP) chemistry for the synthesis of Velcade via asymmetric borylation of N- phosphinylimines
Supporting Information for Group-assisted purification (GAP) chemistry for the synthesis of Velcade via asymmetric borylation of N- phosphinylimines Jian-bo Xie 1, Jian Luo 1, Timothy R. Winn 1, David
Supporting Information
Supporting Information Electrochemical Tandem Synthesis of Oximes from Alcohols Using KNO 3 as Nitrogen Source Mediated by Tin Microspheres in Aqueous Medium Li Zhang, He Chen, Zhenggen Zha*, Zhiyong Wang*
Configuration of Polymorphic Single Crystal Er 2 Si 2 O 7 and Its Comparison with C-type & D-type Single Crystals
International Journal of Sciences: Basic and Applied Research (IJSBAR) ISSN 2307-4531 (Print & Online) http://gssrr.org/index.php?journal=journalofbasicandapplied ---------------------------------------------------------------------------------------------------------------------------
N-Alkylated and N,N-Dialkylated 1,6-Diaminoperylene Diimides via Copper Catalyzed Direct Aromatic Amination. Table of Contents:
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supporting Information for: N-Alkylated and N,N-Dialkylated 1,6-Diaminoperylene Diimides via Copper
Zhao-gang Wang, Yong Jin, Xiao-hua Cao, Ming Lu* School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing , China.
Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2014 New Journal of Chemistry Dynamic
Supporting Information
Supporting Information Wiley-VC 2007 69451 Weinheim, Germany A Truly Practical Synthesis of a Phytosiderophore 2 -Deoxymugineic Acid. A Key to the Mechanistic Study of Iron Acquisition by Graminaceous
Copper(II)- Catalyzed Electrophilic Amination of Quinoline
Electronic Supplementary Material (ESI) for rganic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 215 Copper(II)- Catalyzed Electrophilic Amination of Quinoline xides with Benzoyl
Supporting Information
Supporting nformation A Toolbox Approach to the Search for Effective Ligands for Catalytic Asymmetric Cr-diated Coupling Reactions aibing Guo, Cheng-Guo Dong, Dae-Shik Kim, Daisuke Urabe, Jiashi Wang,
Facile Catalytic Transfer Hydrogenation of Imines to Secondary Amines Using Inexpensive Commercial Zinc Dust and Ammonium Formate
Chapter 4 Facile Catalytic Transfer ydrogenation of Imines to Secondary Amines Using Inexpensive Commercial Zinc Dust and Ammonium Formate 4.1 ITRODUCTIO The conversion of carbonyl derivatives to secondary
A Colorimetric and Ratiometric Fluorescent Chemosensor. with a Large Red-shift in Emission: Cu(II)-only Sensing by
Supporting Information For A Colorimetric and Ratiometric Fluorescent Chemosensor with a Large Red-shift in Emission: Cu(II)-only Sensing by Deprotonation of Secondary Amines as Receptor Conjugated to
Supporting information. Synthesis of pyrimido[1,6-a]quinoxalines via intermolecular trapping of thermally
![Supporting information. Synthesis of pyrimido[1,6-a]quinoxalines via intermolecular trapping of thermally](/thumbs/95/125821392.jpg "Supporting information. Synthesis of pyrimido[1,6-a]quinoxalines via intermolecular trapping of thermally")
Supporting information for Synthesis of pyrimido[1,6-a]quinoxalines via intermolecular trapping of thermally generated acyl(quinoxalin-2-yl)ketenes by Schiff bases Svetlana. Kasatkina, Ekaterina E. Stepanova*,
Supporting Information for
Supporting Information for Regioselective Cis Insertion of DMAD into Au-P Bonds: Effect of Auxiliary Ligands on Reaction Mechanism Hitoshi Kuniyasu, * Takuya Nakajima, Takashi Tamaki, Takanori Iwasaki,
Catalysis and kinetics David Fox (Warwick) Catalysis is 1) important, 2) complicated and 3) often un-optimized
Catalysis and kinetics David Fox (Warwick) Catalysis is 1) important, 2) complicated and 3) often un-optimized R Ts N Ru N Cl formic acid / triethylamine R high yields and e.e.s Noyori 1996 Catalysis and
Multi-step and multi-component organometallic synthesis in one pot using orthogonal mechanochemical reactions
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2014 Supporting Information Multi-step and multi-component organometallic synthesis in one pot
Rh(III)-Catalysed Solvent-Free Hydrodehalogenation of Alkyl Halides by Tertiary Silanes
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2018 Supplementary Material (ESI) for Dalton Trans. Supporting Information for: Rh(III)-Catalysed
Supporting Information
Supporting Information Cyclization of Ketones with Nitriles under Base: A General and Economical Synthesis of Pyrimidines Lebin Su, Kang Sun, Neng Pan, Long Liu, Mengli Sun, Jianyu Dong,* Yongbo Zhou,*
Electronic Supplementary Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C. Electronic Supplementary Information A terbium(iii) lanthanide organic framework as a platform for recyclable multi-responsive
Supporting Information
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2014 Supporting Information Efficient Synthesis of Diverse Well-defined Functional Polypropylenes
Supplementary Material (ESI) for Chemical Communications. Solid-state single-crystal-to-single-crystal transformation from a 2D
Supplementary Material (ESI) for Chemical Communications Solid-state single-crystal-to-single-crystal transformation from a 2D layer to a 3D framework mediated by lattice iodine release Yuan-Chun He, a
films for organic field-effect transistor applications
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information for Control of consistent ordering in -conjugated polymer
Ambi-Valence Taken Literally: Ru vs. Fe Oxidation in 1,1'- Diphosphinoferroceneruthenium(II) Hydride and Chloride Complexes as
1 Ambi-Valence Taken Literally: Ru vs. Fe Oxidation in 1,1'- Diphosphinoferroceneruthenium(II) Hydride and Chloride Complexes as Deduced from Spectroelectrochemistry of the Heterodimetallic Mixed-Valent
A7.1 CRYSTAL STRUCTURE ANALYSIS OF
Appendix 7 X-ray Crystallography Reports Relevant to Chapter 2 326 APPENDIX 7 X-ray Crystallography Reports Relevant to Chapter 2 A7.1 CRYSTAL STRUCTURE ANALYSIS OF 240 240 Note: The crystallographic data
Copper-Catalyzed Alkene Aziridination with N-Tosyloxycarbamates
Copper-Catalyzed Alkene Aziridination with -Tosyloxycarbamates élène Lebel,* Sylvain Lectard and Michaël Parmentier Département de chimie, Université de Montréal, Montréal, Québec, Canada, 3C 3J7 Supporting
Supplementary Document: Si-Based Earth Abundant Clathrates for Solar Energy Conversion
Electronic Supplementary Material (ESI) for Energy. This journal is The Royal Society of Chemistry 2014 Supplementary Document: Si-Based Earth Abundant Clathrates for Solar Energy Conversion Yuping He,
Electronic Supplementary Information
Electronic Supplementary Information Cu(0) nanoparticle catalyzed efficient reductive cleavage of isoxazoline, carbonyl azide and domino cyclization in water medium Krishnanka S. Gayen, a Tista Sengupta,
Supporting Information. Metal-coordination-driven Mixed Ligand Binding in Supramolecular Bisporphyrin Tweezers
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Supporting Information Metal-coordination-driven Mixed Ligand Binding in Supramolecular Bisporphyrin
Supplementary Material. Synthesis and Characterization of L, 1,2, 3 and 4
Zinc(II) and Copper(I) Mediated Large Two-Photon Absorption Cross Sections in a bis-cinnamaldiminato Schiff Base Sanjib Das, Amit Nag, Debabrata Goswami * and Parimal K. Bharadwaj * Department of Chemistry,
A new Method for the Preparation of 1, 3, 5-Triarylbenzenes Catalyzed by
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2015 A new Method for the Preparation of 1, 3, 5-Triarylbenzenes Catalyzed by Nanoclinoptilolite/HDTMA
Color polymorphs of aldose reductase inhibitor Epalrestat: configurational, conformational and synthon differences
Electronic Supplementary Material (ESI) for Chemical Communications. This journal is The Royal Society of Chemistry 2016 Color polymorphs of aldose reductase inhibitor Epalrestat: configurational, conformational
Supporting Information. Visible Light Mediated Photopolymerization in Single Crystals: Photomechanical Bending and Thermomechanical Unbending
Supporting Information Visible Light Mediated Photopolymerization in Single Crystals: Photomechanical Bending and Thermomechanical Unbending Ranita Samanta, a Subhrokoli Ghosh, b Ramesh Devarapalli, a
Preparation and X-ray structure of 2-iodoxybenzenesulfonic. acid (IBS) a powerful hypervalent iodine(v) oxidant
Supporting Information for Preparation and X-ray structure of 2-iodoxybenzenesulfonic acid (IBS) a powerful hypervalent iodine(v) oxidant Irina A. Mironova 1, Pavel S. Postnikov 1, Rosa Y. Yusubova 1,
SUPPLEMENTARY INFORMATION
In the format provided by the authors and unedited. SUPPLEMENTARY INFORMATION DOI: 10.1038/NCHEM.2848 Atomic resolution of structural changes in elastic crystals of copper(ii) acetylacetonate Atomic Resolution
Electronic Supplementary Information
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2018 Electronic Supplementary Information Ba 3 B 10 O 17 Br 2 : A New Barium Borate Halide
Catalytic Enantioselective Mannich Type Reaction with β Phenylsulfonyl Acetonitrile. Supporting Information
Catalytic Enantioselective Mannich Type Reaction with β Phenylsulfonyl Acetonitrile Pedro B. González, Rosa Lopez, Claudio Palomo.* Departamento de Química Orgánica I, Facultad de Química, Universidad
Supporting Information For: Brønsted Acid-Promoted Formation of Stabilized Silylium Ions for Catalytic Friedel Crafts C H Silylation
Supporting Information For: Brønsted Acid-Promoted Formation of Stabilized Silylium Ions for Catalytic Friedel Crafts C H Silylation Qing-An Chen, Hendrik F. T. Klare, and Martin Oestreich* martin.oestreich@tu-berlin.de
Organocatalyzed Oxidative N-Annulation for Diverse and Polyfunctionalized Pyridines. Hari Datta Khanal and Yong Rok Lee* Supplementary Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Organocatalyzed Oxidative -Annulation for Diverse and Polyfunctionalized Pyridines Hari Datta Khanal
Photoreduction of Carbon Dioxide to Carbon Monoxide with Hydrogen Catalyzed by a Rhenium(I)phenanthroline-Polyoxometalate Hybrid Complex
Photoreduction of Carbon Dioxide to Carbon Monoxide with Hydrogen Catalyzed by a Rhenium(I)phenanthroline-Polyoxometalate Hybrid Complex Jessica Ettedgui, Yael Diskin-Posner, Lev Weiner and Ronny Neumann
Correlation between the Structure and Catalytic. Activity of [Cp*Rh(Substituted Bipyridine)] Complexes for NADH Regeneration
![Correlation between the Structure and Catalytic. Activity of [Cp*Rh(Substituted Bipyridine)] Complexes for NADH Regeneration](/thumbs/76/73822043.jpg "Correlation between the Structure and Catalytic. Activity of [Cp*Rh(Substituted Bipyridine)] Complexes for NADH Regeneration")
Supporting Information Correlation between the Structure and Catalytic Activity of [Cp*Rh(Substituted Bipyridine)] Complexes for NADH Regeneration Vinothkumar Ganesan, Dharmalingam Sivanesan and Sungho
Supporting Information. A Fully Synthetic and Self-Adjuvanting Globo H-Based Anticancer Vaccine Elicited Strong T Cell-Mediated Antitumor Immunity
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2015 S1 Supporting Information A Fully Synthetic and Self-Adjuvanting Globo H-Based Anticancer
Goldilocks Effect of Water in Lewis-Brønsted Acid and Base Catalysis
Supporting Information Goldilocks Effect of Water in Lewis-Brønsted Acid and Base Catalysis Benedict J. Barron, a,b Wing-Tak Wong, b Pauline Chiu b and King Kuok (Mimi) ii a * [a] Department of Chemistry,
Supporting Information
Wiley-VC 2009 69451 Weinheim, Germany Ma, an, Krishnan, Virgil and Stoltz Catalytic Enantioselective Stereoablative Alkylation of 3-alooxindoles: Facile Access to C(3) All- Carbon Quaternary Stereocenters
Temperature- and excitation wavelengthdependent emission in a manganese(ii) complex
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 218 Electronic Supplementary Information Temperature- and excitation wavelengthdependent
Concise and Efficient Syntheses of preq 1 base, Q base, and (ent)-q Base
Electronic Supplementary Material (ESI) for rganic & Biomolecular Chemistry Concise and Efficient Syntheses of preq 1 base, Q base, and (ent)-q Base Supporting Information ans-dieter Gerber and Gerhard
Simulation Studies and Sensitivity Analysis of Methyl Tert-butyl Ether Reactive Distillation
Simulation Studies and Sensitivity Analysis of Methyl Tert-butyl Ether Reactive Distillation Sudibyo, Murat, M. N. and Aziz, N. School of Chemical Engineering, Engineering Campus, Universiti Sains Malaysia,