SAFETY DATA SHEET. Creation Date 24-Aug-1997 Revision Date 25-May-2017 Revision Number Identification

Transcription

1 SAFETY DATA SHEET Creation Date 24-Aug-1997 Revision Number 2 Product Name Cat No. : Synonyms Recommended Use Uses advised against 1. Identification VANADIUM AC ; AC ; AC ; AC Vanadium pentoxide Laboratory chemicals. Not for food, drug, pesticide or biocidal product use Details of the supplier of the safety data sheet Company Fisher Scientific One Reagent Lane Fair Lawn, NJ Tel: (201) Acros Organics One Reagent Lane Fair Lawn, NJ Emergency Telephone Number For information US call: ACROS-01 / Europe call: Emergency Number US: / Europe: CHEMTREC Tel. No.US: / Europe: Hazard(s) identification Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR ) Acute oral toxicity Category 4 Acute Inhalation Toxicity - Dusts and Mists Category 4 Serious Eye Damage/Eye Irritation Category 1 Germ Cell Mutagenicity Category 2 Carcinogenicity Category 2 Reproductive Toxicity Category 2 Specific target organ toxicity (single exposure) Category 3 Target Organs - Respiratory system. Specific target organ toxicity - (repeated exposure) Category 1 Label Elements Signal Word Danger Hazard Statements Harmful if swallowed Causes serious eye damage Harmful if inhaled May cause respiratory irritation Suspected of causing genetic defects Suspected of causing cancer Suspected of damaging the unborn child Page 1 / 7

2 Causes damage to organs through prolonged or repeated exposure Precautionary Statements Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Use only outdoors or in a well-ventilated area Do not breathe dust/fume/gas/mist/vapors/spray Response IF exposed or concerned: Get medical attention/advice Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor/physician Ingestion IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Rinse mouth Storage Store locked up Store in a well-ventilated place. Keep container tightly closed Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Toxic to aquatic life with long lasting effects WARNING! This product contains a chemical known in the State of California to cause cancer. 3. Composition / information on ingredients Component CAS-No Weight % Vanadium pentoxide >95 4. First-aid measures Eye Contact Skin Contact Inhalation Ingestion Most important symptoms/effects Notes to Physician Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Obtain medical attention. Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Obtain medical attention. Remove from exposure, lie down. Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Immediate medical attention is required. Call a physician immediately. Clean mouth with water. Causes eye burns. Treat symptomatically Page 2 / 7

3 Suitable Extinguishing Media Unsuitable Extinguishing Media Flash Point Method - 5. Fire-fighting measures Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Autoignition Temperature Explosion Limits Upper Lower Sensitivity to Mechanical Impact Sensitivity to Static Discharge Specific Hazards Arising from the Chemical Non-combustible. Hazardous Combustion Products Thermal decomposition can lead to release of irritating gases and vapors Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA Health 3 Flammability 0 Instability 0 Physical hazards N/A Personal Precautions Environmental Precautions 6. Accidental release measures Avoid contact with skin, eyes and clothing. Use personal protective equipment. Avoid dust formation. Ensure adequate ventilation. Do not flush into surface water or sanitary sewer system. Methods for Containment and Clean Sweep up or vacuum up spillage and collect in suitable container for disposal. Up Handling Storage Exposure Guidelines 7. Handling and storage Do not breathe dust. Do not get in eyes, on skin, or on clothing. Use only in area provided with appropriate exhaust ventilation. Keep in a dry, cool and well-ventilated place. Keep container tightly closed. Keep locked-up. 8. Exposure controls / personal protection Component ACGIH TLV OSHA PEL NIOSH IDLH Mexico OEL (TWA) Vanadium pentoxide TWA: 0.05 mg/m 3 IDLH: 35 mg/m 3 TWA: 0.5 mg/m 3 Ceiling: 0.05 mg/m 3 Legend ACGIH - American Conference of Governmental Industrial Hygienists NIOSH IDLH: The National Institute for Occupational Safety and Health Immediately Dangerous to Life or Health Page 3 / 7

4 Engineering Measures Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location. Personal Protective Equipment Eye/face Protection Skin and body protection Respiratory Protection Hygiene Measures Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR or European Standard EN166. Wear appropriate protective gloves and clothing to prevent skin exposure. Follow the OSHA respirator regulations found in 29 CFR or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Handle in accordance with good industrial hygiene and safety practice. 9. Physical and chemical properties Physical State Powder Solid Appearance Amber Odor Odorless Odor Threshold ph 4 (5 %) Melting Point/Range 690 C / 1274 F Boiling Point/Range 1750 C / 3182 F Flash Point Evaporation Rate Flammability (solid,gas) Flammability or explosive limits Upper Lower Vapor Pressure C Vapor Density Specific Gravity Solubility 8 g/l Partition coefficient; n-octanol/water Autoignition Temperature Decomposition Temperature 1750 C Viscosity Molecular Formula O5 V2 Molecular Weight Stability and reactivity Reactive Hazard Stability Conditions to Avoid Incompatible Materials None known, based on information available Stable under normal conditions. Incompatible products. Combustible material. Strong acids, Reducing agents Hazardous Decomposition Products Thermal decomposition can lead to release of irritating gases and vapors Hazardous Polymerization Hazardous Reactions Hazardous polymerization does not occur. None under normal processing. 11. Toxicological information Page 4 / 7

5 Acute Toxicity Product Information Component Information Component LD50 Oral LD50 Dermal LC50 Inhalation Vanadium pentoxide 474 mg/kg ( Rat, male ) 467 mg/kg ( Rat, female ) 314 mg/kg ( Rat, male ) 221 mg/kg ( Rat, female ) LD50 = 50 mg/kg ( Rabbit ) LC50 = 4.29 mg/l ( Rat ) 4 h Toxicologically Synergistic Products Delayed and immediate effects as well as chronic effects from short and long-term exposure Irritation Sensitization Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Component CAS-No IARC NTP ACGIH OSHA Mexico Vanadium pentoxide Group 2B Not listed A3 X Not listed Mutagenic Effects Reproductive Effects Developmental Effects Teratogenicity STOT - single exposure STOT - repeated exposure Aspiration hazard Symptoms / effects,both acute and delayed Endocrine Disruptor Information Other Adverse Effects... Respiratory system None known The toxicological properties have not been fully investigated. 12. Ecological information Ecotoxicity Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Persistence and Degradability Bioaccumulation/ Accumulation Mobility Waste Disposal Methods DOT Soluble in water Persistence is unlikely based on information available.. Will likely be mobile in the environment due to its water solubility. 13. Disposal considerations Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification. 14. Transport information Page 5 / 7

6 TDG IATA IMDG/IMO International Inventories 15. Regulatory information Component TSCA DSL NDSL EINECS ELINCS NLP PICCS ENCS AICS IECSC KECL Vanadium pentoxide X X X X X X X Legend: X - Listed E - Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA. F - Indicates a substance that is the subject of a Section 5(f) Rule under TSCA. N - Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designated polymer made with any free-radical initiator regardless of the amount used. P - Indicates a commenced PMN substance R - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA. S - Indicates a substance that is identified in a proposed or final Significant New Use Rule T - Indicates a substance that is the subject of a Section 4 test rule under TSCA. XU - Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40 CFR 710(B). Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater. Y2 - Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactants that comprises one of the eligibility criteria for the exemption rule. U.S. Federal Regulations TSCA 12(b) SARA 313 Component CAS-No Weight % SARA Threshold Values % Vanadium pentoxide > SARA 311/312 Hazard Categories Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Yes Yes No No No CWA (Clean Water Act) Component CWA - Hazardous CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants Substances Quantities Vanadium pentoxide X 1000 lb - - Page 6 / 7

7 Clean Air Act OSHA Occupational Safety and Health Administration CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Component Hazardous Substances RQs CERCLA EHS RQs Vanadium pentoxide 1000 lb 1000 lb California Proposition 65 This product contains the following proposition 65 chemicals Component CAS-No California Prop. 65 Prop 65 NSRL Category Vanadium pentoxide Carcinogen - Carcinogen U.S. State Right-to-Know Regulations Component Massachusetts New Jersey Pennsylvania Illinois Rhode Island Vanadium pentoxide X X X X X U.S. Department of Transportation Reportable Quantity (RQ): DOT Marine Pollutant DOT Severe Marine Pollutant N N N U.S. Department of Homeland Security This product does not contain any DHS chemicals. Other International Regulations Mexico - Grade Prepared By Creation Date Revision Date Print Date Revision Summary 16. Other information Regulatory Affairs Thermo Fisher Scientific EMSDS.RA@thermofisher.com 24-Aug May May-2017 This document has been updated to comply with the US OSHA HazCom 2012 Standard replacing the current legislation under 29 CFR to align with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS). Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of SDS Page 7 / 7