Al. Mickiewicza 30, Krakow, A-0 pavilion tel. (12) , Secretariat KHGI (12) , fax (012) ELABORAT # 8 page 1/pages 4
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1 GÓRNICZO HUTNICZA ACADEMY IN KRAKOW GEOLOGY, GEOPHYSICS AND ENVIRONMENTAL PROTECTION FACULTY HYDROLOGY AND ENGINEERING GEOLOGY DEPARTMENT HYDROGEOCHEMICAL LABORATORY Al. Mickiewicza 30, Krakow, A-0 pavilion tel. (12) , Secretariat KHGI (12) , fax (012) Krakow, date ELABORAT # 8 page 1/pages 4 Major physico-chemical analysis of groundwater from borehole S1 in Humniska, Brzozów district, Carpathian duchy Abstraction date Sample code 1022/H Abstraction place abstraction of groundwater from borehole S1 in Humniska Sample abstraction done sample taken by the District sanitary epidemiological station /polish- Powiatowa Stacja Sanitarno Epidemiologiczna/ in Brzozow (abstraction protocol test number 40/11/Ż) 1. General Analysis Parameter Laboratory measurements External Appearance clear Color [mg Pt/dm³] 9,4 Mist [mg SiO 2 /dm³] 0 Odor Without odor Taste No specific taste ph value 9,18 Redox potential Eh [Mv] -6 Conductivity γ25 [ms/cm] 1,053 Water temperature [ C] 10,2 Air temperature [ C] General hardness H o 26,5 [mg CaCo 3 /dm³] Carbonate hardness H w 26,5 [mg CaCo 3 /dm³] Non-carbonate hardness H N 0,00 [mval/dm³] ChZT Mn ChZT Mn * 1,28 [mg O 2 /dm³] General organic carbon * 1,1 TOC [mg C/dm³] Dissolved oxygen [mg O 2 /dm³]
2 ELABORAT # 8 page 2/pages 4 2. Detailed analysis mineral components dissociated Quality indicator mg/dm³ mval/dm³ %mval Cations Sodium Na + 254,55 ± 1,15 11,067 94,730 Potassium K + 0,91 ± 0,03 0,023 0,199 Lithium Li + 0,079 ± 0,000 0,011 0,098 Ammonium NH4 + * 0,793 0,044 0,377 Beryllium Be 2+ < 0,0005 0,000 0,000 Calcium Ca 2+ 10,00 ± 0,02 0,499 4,271 Magnesium Mg 2+ 0,371 ± 0,002 0,031 0,261 Baryllium Ba 2+ 0,0099 ± 0,0000 0,000 0,001 Strontium Sr 2+ 0,0344 ± 0,0001 0,001 0,007 Ferrum Fe 2+ 0,09 ± 0,01 0,003 0,028 Manganese Mn 2+ 0,009 ± 0,000 0,000 0,000 Silver Ag + < 0,001 0,000 0,000 Zinc Zn 2+ 0,016 ± 0,004 0,000 0,000 Copper Cu 2+ 0,017 ± 0,002 0,001 0,004 Nickel Ni 2+ < 0,001 0,000 0,000 Cobalt Co 2+ < 0,0002 0,000 0,000 Lead Pb 2+ 0,0009 ± 0,0000 0,000 0,000 Mercury Hg 2+ < 0,0001 0,000 0,000 Cadmium Cd 2+ < 0,0003 0,000 0,000 Selenium Se 2+ < 0,01 0,000 0,000 Antimony Sb 3+ 0,0011 ± 0,0000 0,000 0,000 Aluminum Al 3+ 0,010 ± 0,003 0,001 0,010 Chrome Cr 3+ < 0,005 0,000 0,000 Molybdenum Mo 6+ 0,0011 ± 0,0000 0,000 0,000 Vanadium V 5+ < 0,001 0,000 0,000 Zircon Zr 4+ 0,010 ± 0,0090 0,000 0,000 Titanium Ti 4+ < 0,02 0,000 0,000 Arsenic As 3+ 0,005 ± 0,001 0,000 0,000 Thallium Tl 4+ < 0,0001 0,000 0,000 Tungsten W 6+ 0,0013 ± 0,0000 0,000 0,000 Total cations 266,9 11, ,0 Anions Fluorides F * 1,280 0,067 0,547 Chlorides Cl 26,4 0,743 6,035 Bromides Br < 0,1 0,000 0,000 Iodide J 0,24 0,000 0,000 Sulfates 2 SO 4 7,81 ± 0,59 0,163 1,322 Bicarbonates HCO 3 357,8 5,866 47,621 Carbonates 2 CO 3 163,50 5,450 44,247 Nitrites NO 2 * < 0,003 0,000 0,000 Nitrates NO 3 * 0,24 0,004 0,031 Cyanides CN * < 0,002 0,000 0,000 phosphates 3 PO 4 0,7647 0,024 0,196 Total anions: 558,10 12, ,0 Total analysis: 825,0 Analysis characteristics: Ʃ rk- ƩrA B= 100% B = - 2,64% ƩrK+ ƩrA
3 ELABORAT # 8 page 3/pages 4 3. Nondissociated minerals: Metasilicic acid H 2 SiO 3 [mg/dm³] Metaboric acid HBO 2 [mg/dm³] 8,68 (Silica SiO2 6,68 mg/dm³) 3,25 (Bor B 0,80 mg/dm³) The sum of solids [mg/dm³] 836,9 4. Gaseous compoments: 5. Organic compounds*: Surfactants SPC (anionic) [mg/dm³] <0,02 Volatile phenols <0,002 Clorophene [mg/dm³] <0,0002 Polyaromatic hydrocarbons (WWA): Benzo (a) pyrene [ng/dm³] <5 Benzo (k) fluoranthene [ng/dm³] <5 Benzo (b) fluoranthene [ng/dm³] <5 Benzo (g, h, i) perylene [ng/dm³] <5 indeno 1,2,3 CD pyrene [ng/dm³] <10 Acenaphtene [ng/dm³] <5 Anthracene [ng/dm³] <5 Benzo (a) anthracene [ng/dm³] <5 Chrysen [ng/dm³] <5 Dibenzo(a.h) anthracene [ng/dm³] <5 Phenanthrene [ng/dm³] <5 Fluoranthene [ng/dm³] <5 Fluorene [ng/dm³] 10 Naphthalene [ng/dm³] <5 Pyrene [ng/dm³] 10 Pesticides: 4,4ʾ- DDT [ng/dm³] <1 4,4ʾ- DDE [ng/dm³] <1 4,4ʾ- DDD [ng/dm³] <1 Sum WWA: <30ng/dm³ = 0ng/dm³ [according Commission Directive 2009/90/ES] Sum DDT and its metabolites <3,0 ng/dm³ = 0 ng/dm³ [according Commission Directive 2009/90/ES]
4 ELABORAT # 8 page 4/pages 4 Aldrin [ng/dm³] <1 Dieldrin [ng/dm³] <1 Endrin [ng/dm³] <1 Heptachlor [ng/dm³] <1 Lindane gamma HcH [ng/dm³] <1 Matoxychlor [ng/dm³] <1 * - research has been conducted by WIOŚ Krakow accreditation certificate PCA# AB 176 Characteristics: 0,08% moderately mineralized water (according to the criteria set out in the Regulation of the Minister of Health Z.z. from year 2011, number 85, pol. 466) of the bicarbonate-carbonatesodium nature Resolution: Groundwater from borehole S1 in Humniska, collected for research of chemical composition on , contains 0.84 g / dm solids. Dominants among anions: bicarbonate ion HCO ,6% mval and carbonic CO ,2% mval. Among the cations prevails sodium ion Na ,7% mval. Studied groundwater is classified as 0.08% moderately-mineralized water on this basis. (according to the criteria set out in the Minister of Health Regulation Z.z. from year 2011, number 85, pol. 466 aj Z.z. from year 2006, number 80, pol. 565) of the bicarbonatecarbonate-sodium nature [HCO 3 -CO 3 -Na] Appendix: 1. Tests report 8/2012 (Lab. KHGI) 2. Tests report number /2012 (Lab. WIOŚ) Head of the Department of Hydrogeology and engineering geology prof. dr hab. inż. Jadwiga Szczepańska -Plewa /-/ unreadable signature
5 Notary office Liliana Roman notary Krosno, Czajkowskiwego street 1 tel./fax Notary journal A number 388 / 2015 Notary Lilianna Roman, heading Notary office in Krosno at Czajkowskiego street 1, hereby certifies that a copy literally agrees with the submission of the original document which was submitted by Lucjanom Langerom, residing at in Krosno at Korczyńskiej street 40 B, Notary fee has been paid for completion according to 13 point 2 of the Minister of Justice from 28 June 2004 on the maximum rates of notary fees /Z.z. 148 pol / -1,00 PLN as well as value added tax according to paragraph 41 from 11. march 2004 about value added tax / Z.z from year 2011, number 177, pol with subsequent changes in the rate 23% - 0,23 PLN Krosno, dated Fourth of February, Two Thousand and Fifteen ( ) Round stamp with text: Lilianna Roman Notary in Krosno, national emblem of Republic of Poland in the middle mgr. Lilianna Roman Notary, /-/ unreadable signature
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