MATERIAL SAFETY DATA SHEET

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1 PAGE: 1/7 PRODUCT NAME : <See separate section> MANUFACTURER NAME: ADDRESS: RISO KAGAKU CORPORATION SHIBA, MINATO-KU, TOKYO, , JAPAN TELEPHONE NUMBER: 81 (3) DISTRIBUTOR NAME: ADDRESS: RISO LATIN AMERICA, INC. 3 S.W. 129th Avenue, Suite 100, Pembroke Pines, FL U.S.A. TELEPHONE NUMBER: (954) SUBSTANCE / MIXTURE: CHEMICAL NATURE: Mixture (Preparation) Water-in-Oil-type emulsion <See separate section> Section 3 - HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS: EYE: SKIN: INHALATION: INGESTION: EYE: SKIN: INHALATION: INGESTION: FLASH POINT: AUTOIGNITION TEMPERATURE: EXPLOSION PROPERTIES: EXTINGUISHING MEDIA: Vapour or mist in unusually high concentrations generated from heating this ink, or as from exposure in poorly ventilated areas, may cause irritation of the nose and throat, headache, and nausea. May cause abdominal discomfort, nausea. Section 4 - FIRST-AID MEASURES In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of water using a mild soap. If you feel unwell, move from the contamination immediately to fresh air and seek medical advice. If swallowed, do not induce vomiting and seek medical advice. Section 5 - FIRE-FIGHTING MEASURES None(Closed Cup) > 400 o C Water, CO 2, foam, dry chemical powder, dry sand SPECIFIC HAZARDS WITH REGARD TO FIRE-FIGHTING MEASURES: This ink does not act as a source of ignition, but might burn if involved in a fire. HAZARDOUS COMBUSTION PRODUCTS: CO, CO 2, smoke

2 PAGE: 2/7 PERSONAL PRECAUTIONS: Section 6 - ACCIDENTAL RELEASE MEASURES Ventilate the area until material is completely picked up. ENVIRONMENTAL PRECAUTIONS: Do not empty into the drains. METHOD OF CLEANING UP: Shovel up, then wipe up with cloth or paper. Section 7 - HANDLING AND STORAGE HANDLING: TECHNICAL MEASURES: SAFE HANDLING ADVICE: Use only in the well-ventilated areas. Avoid contact with skin. Use only with cartridge (bottle). STORAGE: STORAGE CONDITIONS: PACKAGING MATERIAL: ENGINEERING MEASURES: EXPOSURE GUIDELINES: Store at 5-35 o C and protect from sunlight. Keep the ink out of reach of children. Only original cartridge (bottle). PERSONAL PROTECTIVE EQUIPMENT: RESPIRATORY PROTECTION : HAND PROTECTION: EYE PROTECTION: SKIN AND BODY PROTECTION : PHYSICAL STATE: ODOR: PH: BOILING POINT: MELTING POINT: OXIDISING PROPERTIES: Good general ventilation should be sufficient for most conditions. <See separate section> Not normally required Recommend the use of gloves in case of contact with skin. Not normally required Not normally required Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Paste Slight petroleum odor > 100 o C < 0 o C DENSITY: WATER SOLUBILITY: STABILITY: CONDITION TO AVOID: MATERIALS TO AVOID: HAZARDOUS DECOMPOSITION PRODUCTS: Negligible Section 10 - STABILITY AND REACTIVITY This product is considered a stable material under normal storage and handling conditions. Avoid exposure to high temperatures. Strong oxidising agents None

3 PAGE: 3/7 ACUTE ORAL TOXICITY: ACUTE EYE IRRITATION: ACUTE SKIN IRRITATION: MUTAGENICITY: Section 11 - TOXICOLOGICAL INFORMATION LD50 >= 2500mg/kg (rat) Negative in the Ames test CARCINOGENICITY: Carbon black is listed as a Class 2B (Possible human carcinogen) by IARC. (However, IARC Monograph 65 also indicates exposures to carbon black in the use of printing ink, rubber or paint are negligible. ) None of the other ingredients in this product are listed by IARC,NTP,MAK, OSHA or ACGIH as a carcinogen. None of the other ingredients have been classified as carcinogens according to EU, IARC, MAK, NTP or OSHA. *These information are based on toxicity data for similar materials and ingredients. Section 12 - ECOLOGICAL INFORMATION No data available Section 13 - DISPOSAL CONSIDERATIONS METHOD OF DISPOSAL: Burn in an adequate incinerator or bury in landfill in accordance with all applicable regulations. Any disposal practice must be in compliance with local, state and federal laws and regulations. Ink Cartridge (bottle) material is plastic (polypropylene/polyethylene). Label material is plastic (metal included). Section 14 - TRANSPORT INFORMATION RID/ADR: ADNR: IMDG CODE: ICAO/IATA-DGR: UN NUMBER: Section 15 - REGULATORY INFORMATION OSHA Hazard Communication Standard, 29CFR : This product is not considered hazardous under this standard. TSCA (Toxic Substance Control Act) : All chemical substances in these products are listed in TSCA chemical substance inventory. ACGIH (American Conference of Governmental Industrial Hygienists) : This product contains no chemical substances classed carcinogenicity. WHMIS (Workplace Hazardous Materials Information System) This product is not considered a controlled product under this System. Section 16 - OTHER INFORMATION NFPA RATING (U.S.A.): Health = 0 Flammability = 1 Reactivity = 0 The information herein is given in good faith, but no warranty, express or implies, is made. Please consult RISO LATIN AMERICA, INC. for further information.

4 PAGE: 4/7 PRODUCT NAMES (ITEM CODE): RED (S-4275/U) BLUE (S-4257/U) GREEN (S-4259/U) YELLOW (S-4279) BRIGHT RED (S-4263/U) MEDIUM BLUE (S-4261/U) RISO-FEDERAL BLUE (S-4265/U) PURPLE (S-4267/U) BURGUNDY (S-4255/U) ORANGE (S-4283/U) CRIMSON (S-4285) FLUORESCENT PINK (S-4287) FLUORESCENT ORANGE (S-4289)

5 PAGE: 5/7 Section 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAMES (ITEM CODE): BROWN (S-4277/U) RISO-MARINE RED (S-4281/U) TEAL (S-4269/U) FLAT GOLD (S-4271/U) Carbon black (pigment) < 1 Carbon black (pigment) mg/m mg/m 3

6 PAGE: 6/7 PRODUCT NAME (ITEM CODE): HUNTER GREEN (S-4273) Carbon black (pigment) < 10 Carbon black (pigment) mg/m mg/m 3

7 PAGE: 7/7 PRODUCT NAMES (ITEM CODE): GREY (S-4293) LIGHT GREY (S-4291) Carbon black (pigment) < 1 Titanium dioxide (pigment) < 20 Carbon black (pigment) mg/m mg/m 3 Titanium dioxide (pigment) mg/m 3 15 mg/m 3

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