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1 1 (7) CWA Nerve Blister Library specified agents GA, GB, GD, GF VX HD L Low mg/m Library unspecified agents/cases Nerve precursors Vesicant precursor - - s in hazardous concentration Blood AC, CK 20 - Nerve: Nerve agents -Tabun (GA), Sarin (GB), Soman (GD), Cyclo-Sarin (GF) and VX. Blister: Blister agents- Sulphur mustard (HD) and Lewisite (L). Blood: Blood agents- Hydrogen cyanide (AC) and Cyanogen chloride (CK).
2 2 (7) TIC Acid Library specified agents Low (1) ppm Hydrogen Chloride (HCl) 50 (2) Hydrogen Fluoride (HF) 30 (2) Nitric Acid (HNO 3 ) 25 (2) Toxic Ammonia (NH 3 ) Carbon disulfide (CS 2 ) Hydrogen sulfide H 2 S) Chlorine Cyanogen chloride (CK) Hydrogen Cyanide (AC) Arsine (AsH 3 ) Ethylene oxide (ETOX) Phosphorous trichloride (PH 3 ) (2) (1): Low = Alarm limit (IDLH-level). Note: Alarm may occur also below this concentration limit. (2): Valid in < 16 g (H 2 O)/m 3. Acid: Toxic: Library unspecified agents/cases Acetic Acid Acrylonitrile - - Agent in hazardous concentration Hydrogen Chloride (HCl), Hydrogen Fluoride (HF) and Nitric Acid (HNO 3 ) from IDLH level (Immediate Danger for Life and Health). may occur in high acid concentrations. Ammonia (NH 3 ), Carbon disulfide (CS 2 ), Hydrogen sulphide (H 2 S), Hydrogen cyanide (AC), Cyanogen Chloride (CK), Ethylene Oxide (ETOX), Arsine (AsH 3 ), Chlorine (Cl 2 ) and Phosphorous trichloride (PH 3 ) from about IDLH level. appears often preceding or following Toxic alarm.
3 3 (7) Precursor Nerve precursor Vesicant precursor Library specified agents Low (1) mg/m 3 Dimethyl methyl phosphonate / Di methyl phosphite / Methyl phosphonic dichloride / Pinacolyl alcohol 0.5 / 0.5 / 0.2 / 150 Thiodiglycol 0.1 (1): Low = Alarm limit. Note: Alarm may occur also below this concentration limit. Library unspecified agents/cases CWA nerve agents - - Agent in hazardous concentration Nerve precursor: Dimethyl methyl phosphonate (DMMP), Dimethyl phosphite, Methyl phosphonic dichloride and Pinacolyl alcohol. may occur in high nerve precursor concentrations. Vesicant precursor: Thiodiglycol. may also occur.
4 4 (7) First Responder Toxic Detected Library Specified Agents Alarm Limit (1) ppm Ethylene Oxide Acrylonitrile Hydrogen Sulfide 10 Arsine 5 Ammonia 300 Phosphorous 25 Trichloride Carbon Disulfide 500 Allyl Alcohol 40 Hydrogen Cyanide 50 Cyanogen Chloride 50 G type Nerve 0.2 mg/m3 HD type Blister - Any measurable agent 5 mg/m3 - (1): Operation in cold (< 5 C) and hot environments (>35 C) may lead to increased alarm limits. Operation in conditions where background air is slightly contaminated can also lead to increased alarm limits. Toxic: Toxic Industrial Compounds like Ethylene Oxide (ETOX), Acrylonitrile, Arsine (AsH 3 ), Hydrogen Sulfide (H 2 S), Ammonia (NH 3 ), Phosphorous Trichloride (PCl 3 ), Carbon Disulfide (CS 2 ), Allyl Alcohol, Hydrogen Cyanide (AC) and Cyanogen Chloride (CK) as well as Warfare Agents like G-type Nerve agents and HD-Blister agent. Detected: Library specified agents in concentrations lower than Alarm Limit. detected alarm often precedes and follows Toxic alarm indication. Indication may occur also due to several other compounds.
5 5 (7) VOC Library specified Low (1) Library unspecified agents ppm agents/cases Flammable Acetone Ethanol 2000 Solvents and fuel vapours Methanol n-hexane Isopropanol Diethyl ether Ethyl acetate Methyl methacrylate Organic acid Acetic acid Agent in hazardous concentration (1): Low = Alarm limit. Note: Alarm may occur also below this concentration limit. Flammable: Acetone, Ethanol, Methanol, n-hexane, Isopropanol, Diethyl ether, Ethyl acetate and Methyl methacrylate. may occur in high concentration and humidity. Organic acid: Acetic acid. may occur in high concentration.
6 6 (7) First Responder-9.2.3E Toxic Library Specified Agents Alarm Limit (1) ppm Ethylene Oxide Acrylonitrile Hydrogen Sulfide 10 Arsine 5 Ammonia 300 Phosphorous 25 Trichloride Carbon Disulfide 500 Allyl Alcohol 40 Hydrogen Cyanide 50 Cyanogen Chloride 50 G type Nerve 0.2 mg/m3 HD type Blister 5 mg/m3 (1): Operation in cold (< 5 C) and hot environments (>35 C) may lead to increased alarm limits. Operation in conditions where background air is slightly contaminated can also lead to increased alarm limits. Toxic: Detected: Toxic Industrial Compounds like Ethylene Oxide (ETOX), Acrylonitrile, Arsine (AsH 3 ), Hydrogen Sulfide (H 2 S), Ammonia (NH 3 ), Phosphorous Trichloride (PCl 3 ), Carbon Disulfide (CS 2 ), Allyl Alcohol, Hydrogen Cyanide (AC) and Cyanogen Chloride (CK) as well as Warfare Agents such as G-type Nerve agents and HD-Blister agent. Library specified agents in concentrations lower than Alarm Limit. Often precedes and follows indication of Toxic. Indication may occur also due to several other compounds.
7 7 (7) H.T.C s and semi-quantitative concentration limit: Alarm Indication Library specified Agents Alarm Limit (1) Library unspecified agents/causes TDI Toluene di-isocyanate pm Alkanes and diesel vapor in low concentration. Acetonitrile Acetonitrile 30- ppm Inorganic acid Hydrogen Chloride 5-10 ppm Inorganic acid Hydrogen Fluoride 2-5ppm(RH<40) >>5ppm(RH>40) Toxic Toxic Not specified G type nerve agents, Lewisite, inorganic acids in high concentration possible. VOC VOC Not specified Alcohols, alkanes, ketones, fuel and solvent vapors. (1): Low = Alarm level. Note: Alarm may occur also below this concentration limit.
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