Newpark Drilling Fluids, LLC 1311 Broadfield, Suite 600, Houston TX Hour Health/Environmental Emergency Phone:

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2 MATERIAL SAFETY DATA SHEET (All Grades) MSDS No. CA1004 Date Created: 11/27/03 Revised: 00/00/00 SECTION 1. GENERAL PRODUCT INFORMATION Trade Name: Chemical Name: Anhydrous Chemical Formula: NaOH Synonyms: Sodium Hydroxide - Dry NFPA Properties: Health: 3: Flammability: 0 Reactivity: 2 SECTION 2. COMPOSITION / INFORMATION ON INGREDIENTS OSHA CAS# Chemical Identity Exposure Limits Carcinogen Status ACGIH OSHA IARC NTP OSHA TWA PEL TWA * Sodium Hydroxide 2 mg/m 3 2 mg/m 3 2 mg/m 3 NO NO NO Sodium Chloride NE NE NE NC NC NC Sodium Carbonate NE NE NE NC NC NC NE = Not Established NR = Not Reviewed * = OSHA Hazardous Ingredient NC = Not Classified SECTION 3. HAZARDS IDENTIFICATION Description: White, odorless free flowing flakes, granules or beads. Statement of Hazards: May cause burns to the respiratory tract, skin, eyes and gastrointestinal tract. May cause permanent eye damage. Precautionary Measures: Do not get in eyes, on skin or clothing. Wash thoroughly after handling. Keep a gallon jug of vinegar (within arms reach) at all times when handling this product. Vinegar is Acetic Acid and it will neutralize the caustic soda if you become contaminated. is a slip hazard when wet. Signs and Symptoms of Exposure: Exposed area will produce a burning sensation and the skin will become irritated. SECTION 4. FIRST AID MEASURES Ingestion: Never give anything by mouth to an unconscious or convulsive person. If swallowed, do not induce vomiting. Give large amounts of water. If vomiting occurs spontaneously, keep airway clear. Give more water when vomiting stops. GET MEDICAL ATTENTION IMMEDIATELY. Skin: Immediately flush contaminated areas with water. Remove contaminated clothing, jewelry and shoes immediately. Wash contaminated areas with soap and water. If necessary, pour vinegar on the contaminated areas to neutralize the. Thoroughly clean and dry contaminated clothing and shoes before reuse. Discard footwear which cannot be decontaminated. GET MEDICAL ATTENTION IMMEDIATELY. Inhalation: Remove to uncontaminated area. If breathing is difficult, administer oxygen. If respiration or pulse has stopped, apply CPR. CALL FOR EMERGENCY SERVICES IMMEDIATELY. Eyes: Immediately flush eyes with a directed stream of water for at least 15 minutes, forcibly holding eyelids apart to ensure complete irrigation of all the eye and lid tissues. Washing eyes within several seconds is essential to achieve maximum effectiveness. GET MEDICAL ATTENTION IMMEDIATELY. Note to Physician: The absence of visible signs or symptoms of burns does NOT reliably exclude the presence of actual tissue damage. SECTION 5. FIRE FIGHTING MEASURES Flash Point: Not Applicable Sensitivity to Mechanical Impact: None Fire Fighting Extinguishing Media: DO NOT USE WATER. Use extinguishing agents appropriate for the surrounding fire. Direct contact of water and can cause a violent exothermic reaction. Page 1 of 4

3 Fire Fighting Equipment: Wear appropriate Personal Protection Equipment, including a NIOSH approved respirator. Fire Fighting Hazard: Direct contact of water and can cause a violent exothermic reaction. SECTION 6. ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Product becomes slippery when wet. Wear appropriate Personal Protection Equipment, including a NIOSH approved respirator. Shovel product into a suitable container for reuse or disposal. Keep the waste out of water supplies and sewers. is alkaline and may raise the ph of surface waters. Releases should be reported, if required, to appropriate agencies. If the product cannot be reused, dispose of it in accordance with federal, state and local regulations. SECTION 7. HANDLING AND STORAGE Storage: Store and handle in accordance with all current regulations and standards. Keep container tightly closed and properly labeled. is very hygroscopic. DO NOT STORE IN ALUMINUM CONTAINER OR USE ALUMINUM FITTINGS OR TRANSFER LINES BECAUSE CAUSTIC SODA IS INCOMPATIBLE WITH ALUMINUM AND FLAMMABLE HYDROGEN GAS MAY BE GENERATED. Keep separated from incompatible substances. (See Section 10) Handling: Wear appropriate Personal Protection Equipment, including a NIOSH approved respirator, if necessary. Avoid breathing dust. Do not get in eyes, on skin or on clothing. When mixing, slowly add water to minimize heat generation and spattering. Wash thoroughly after handling. Apply vinegar to skin, if necessary. SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Skin Protection: Wear appropriate protective clothing, including a face shield, apron, Tyvex suit and rubber gloves. Respiratory Protection: Use NIOSH approved respirator, if necessary. Eye Protection: Wear chemical resistant safety goggles and a face shield. Provide eye wash station and quick drench shower in the immediate work area. Engineering Controls: Provide mechanical ventilation to prevent dust concentrations and to reduce potential exposure. When mixing, stand up-wind to minimize the blow-back from dust. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Physical Form: Flakes, Granules or beads. Color: White Odor: None Physical State: Solid Solubility in Water: 100% ph: Not Applicable Specific Gravity: 20 0 C / 68 0 F Boiling Point: Not Applicable Melting Point: C / F Freezing Point: Not Applicable Molecular Weight: Percent Volatile: 0% SECTION 10. STABILITY AND REACTIVITY Stability: Stable at normal temperature and pressure. Hazardous polymerization: Will not occur Hazardous Decomposition Products: None known. Incompatibility: Acids, halogenated compounds, prolonged contact with aluminum, brass, bronze, copper, lead, tin, zinc or other alkali sensitive metals or alloys. Conditions to Avoid: Avoid contact with water. Carbon Monoxide gas may form upon contact with reducing sugars, food and beverage products in enclosed spaces. Page 2 of 4

4 SECTION 11. TOXICOLOGICAL INFORMATION Toxicity Data: Sodium Hydroxide: 1350 mg/kg Dermal-Rabbit LD-50. As a solid, this material interacts with moist tissue to cause damage. When in solution, this material will affect all tissues with which it comes in contact. The severity of the tissue damage is a function of its concentration, the length of tissue contact time, and local tissue conditions. After exposure, there may be a time delay before irritation and other effects occur. This material is a strong irritant and is corrosive to the skin, eyes, and mucous membranes. This material may cause severe burns and permanent damage to any tissue with which it comes into contact. Inhalation will cause severe irritation, possible burns with pulmonary edema, which may lead to pneumonitis. Skin contact with this material may cause severe irritation and corrosion of tissue. Eye contact can cause severe irritation, corrosion with possible corneal damage and blindness. In general, chronic effects are due to long term irritation. This material may cause dermatitis on the skin, or recurrent corneal ulceration and visual disturbances of vision. In rare cases, reports noted long-term inhalation causes bronchial inflammatory reaction or obstructive airway dysfunction. SECTION 12. ECOLOGICAL INFORMATION Fish toxicity: This material has exhibited moderate toxicity to aquatic organisms. Biodegradation: This material is inorganic and not subject to biodegradation. Persistence: This material will exist in the disassociated state. Bioconcentration: This material is believed not to bioaccumulate. Other Ecological Information: This material has exhibited slight toxicity to terrestrial organisms. SECTION 13. DISPOSAL CONSIDERATIONS Waste Disposal Method: Disposal must be in accordance with federal, state and local regulations. Care must be taken to prevent environmental contamination from the disposal of material, residues and containers. SECTION 14. TRANSPORT INFORMATION US DOT 49 CFR : DOT Shipping Name: Sodium Hydroxide, solid ID Number: UN1823 Hazard Class or Division: 8 Packing Group: ΙΙ Labeling Requirements: 8 DOT Hazardous Substance: Sodium Hydroxide 1000 lb(s) (454kg(s)) Canadian Transportation of Dangerous Goods: Shipping Name: Sodium Hydroxide, solid UN Number: UN1823 Class: 8 Packing Group/Risk Group: ΙΙ SECTION 15. REGULATORY INFORMATION U.S. Regulations: CERCLA Sections 102a/103 Hazardous Substances (40 CFR 302.4): Sodium Hydroxide: 1000 lbs RQ SARA Title ΙΙΙ Section 302 Extremely Hazardous Substances (40 CFR ): Not regulated. SARA Title ΙΙΙ Sections 311/312 Hazardous Categories (40 CFR ): Acute: Yes Chronic: No Fire: No Reactive: Yes Sudden Release: No SARA Title ΙΙΙ Section 313 (40 CFR ): Not regulated OSHA Process Safety (29 CFR ): Not regulated State Regulations: California Proposition 65: Not regulated New Jersey Worker and Community Right to Know: Reporting Requirements: Page 3 of 4

5 Sodium Hydroxide % Sodium Chloride % Sodium Carbonate % Right to Know Hazardous Substance List: Sodium Hydroxide % Special Health Hazard Substance List: Sodium Hydroxide % Pennsylvania Right to Know: Reporting Requirement: Sodium Hydroxide % Hazardous Substance List: Sodium Hydroxide % Environmental Hazardous Substance List: Sodium Hydroxide % Special Hazardous Substance List: Not regulated Canadian Regulations: WHMIS Classification: E National Inventory Status: U.S. Inventory (TSCA): All the components of this substance are listed on or are exempt from the inventory. TSCA 12 (b) Export Notification: Not listed Canada Inventory (DSL/NDSL): All components of this product are listed on the DSL. SECTION 16. OTHER INFORMATION MSDS No: AL1100 Reason Issued: New Format Prepared By: Product Safety Committee Sections Modified: All Sections. Revised Format Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind, expressed or implied, and we assume no responsibility for any damage or expense. Page 4 of 4

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