Caf. Jump into your silicone solutions. Bluesil. for Industrial Assembly.

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1 Caf Jump into your silicone solutions Bluesil for Industrial Assembly

2 General introduction Why choose Bluestar Silicones? Our experience and expertise at your service Bluestar Silicones has been active in the silicone industry for over 60 years. We believe that making quality silicone products begins by carefully listening to our customers and understanding their requirements. We then manufacture the right products, supplying them with customized formulations and unique silicone technology solutions. We also provide them with technical and regulatory support so that they can comply with the highest national and international standards. We create agile innovation Since 1944, we have continuously developed new technologies, processes and solutions to address our customers' needs. In a changing environment, we question the status quo, we generate new ideas and constantly progress, in close cooperation with our customers. Our bonding, sealing and lubrication solutions for Industrial Assembly are designed to create and build technologies that make our lives better and safer 14 Si Combining the best features of minerals and plastics Silicones are different from other organic polymers, and notably plastics, due to the presence of silicon, a semi-mineral element, and their Si-O- bond. The bonds that the silicon creates with the oxygen to form the backbone of macromolecules are exceptionally stable: they are much more difficult to break than carbon-carbon bonds in organic polymers. Silicones, a surprisingly versatile material Silicones have unlimited structural. Silicones have an advantage over natural silica because their silicon carry organic groups that contain carbon. According to the nature of these organic groups, as well as production and formulation conditions, the products obtained are extremely varied: their final texture can be fluid, viscous, pasty, elastomeric or rigid. Stable high-performance polymers This means that silicones outperform most other polymers: their remarkable spreadability combined with outstanding resistance to extreme temperatures, UV rays, IR radiation and a wide range of other environmental factors, place them among the best performing polymers available

3 General introduction Constantly committed to working closely with you Silicone technologies improve and facilitate industrial bonding, sealing and lubrication Access to a full range of silicones elastomers Our priorities: health, safety and the environment Our Health, Safety and Environment (HSE) policy is a key to achieving industrial excellence. Our high-performance management system takes into account HSE in all areas, including the transport of hazardous materials. This system enables us to track, monitor and improve results within Bluestar Silicones and in conjunction with our mother company, strengthening our place among the top chemical groups worldwide in HSE. A worldwide network to deliver our customers potential because we care 01 CAF : Room Temperature Vulcanizing (RTV) elastomers One-component RTV-1 CAF Accelerated RTV-1: CAF AXAD Functions Assembly/bonding Sealing Electrical insulation Lubrication Damping/ anti-vibration Thermal protection Properties Modular from adhesion through to release. Resistance to automotive oils and fluids over a wide temperature range. Easy spreading. Outstanding stability of dielectric over a wide temperature range. Over a wide range of temperatures. Damping and rebound resilience. Resistance over a wide temperature range. Our worldwide quality focus Our upstream and downstream production units, working closely with the worldwide sales network of our subsidiaries, agents and distributors, enhance our understanding of markets and enable us to satisfy the current and future needs of Bluestar Silicones customers. 02 Adhesion Primers and Additives 03 Pastes and Greases We at Bluestar Silicones apply our Quality Policy in line with the ISO 9001 standard, linked to a management system based on strong continuous Improvement programs. Lean manufacturing tools and methodologies are deployed through our EBS initiative (Elkem Business System) to enhance our product lines. Our worldwide operating centers - headquarters, laboratories, sales & development processes and manufacturing sites - are all ISO 9001 certified and specialist product ranges also comply with specific industry standards, such as the EN/AS 9100 for aerospace components. 4 A quality system certified to ISO 9001 and NF EN / AS 9100 Standard We offer technical support to serve demanding markets Our dedicated teams support you from product approval to after-sales technical services, including prototype production. With very high-performance facilities and unique know-how, our teams can validate technical solutions in the laboratory to cover all industrial applications that require bonding, sealing or lubrication. We then test on-site performance in conjunction with your teams to define and determine the optimal solution for your processes, and to obtain your final approval. Before ramping up to industrial-scale production, limited prototype series can be produced inhouse by our technical laboratories, with access to a robot manufacturing application. Our technicians provide services on demand to customers to assist and advise them throughout the production phase. We are a team of professionals At your service backed up by a specialist distributor network that is regularly trained in the latest innovations in this field. Listening to your needs, we combine talents to develop creative & added-value solutions for bonding, sealing and lubrication. 5

4 01 CAF products 01 CAF : a versatile product range to meet your needs CAF products (also known as RTV-1 products) are one-component, silicone elastomers that cure at room temperature at various rates. Acetoxy, oxime or alkoxy-type CAF products offer varying viscosities, ranging from fluid to thixotropic products, including a self-leveling version. Some Acetoxy CAF products (the CAF AXAD range) can be accelerated by adding an activator to provide very quick setting rates. Industrial and professional range Assembly and repair on automated industrial production lines Sealing/bonding for automated mass production applications and processing requiring high service levels (occasional or prolonged contact with chemicals and lubricants, temperature differences, etc.) Supplies for professionals (installers, assemblers, heating engineers, electricians, mechanics and other professionals, specifically in renovation) General assembly for sealing, bonding and damping, providing anti-vibration and other key. High-performance assembly and protection range Sealing, bonding and protection of assembled units subject to high constraints in terms of adhesion, temperature and/or corrosion and UV resistance. Flexible bonding and gasketing of Caf technology provide you with the highest performance levels in bonding and sealing applications Maintenance range Maintenance of industrial sites or off-shore platforms Repair/maintenance of air, rail, maritime fleets Automotive repair for professionals and consumers. Protection, coating and potting range Insulation, coating, potting and sealing of electrical and electronic assembly. The major features & benefits of CAF range are Outstanding bonding on a wide variety of surfaces: glass, metal and plastics Easy to use in substitution applications or to supplement traditional pre-formed joints Competitive price points: materials, controlled processing and storage costs, etc. Outstanding heat stability over a wide temperature range (- 70 C to C: UV, weathering, salt mist, etc.) Very good natural ageing resistance: long-lasting mechanical : sealing joints and very long-lasting flexible bonding applications High insulating and thermal protection capacities Good dielectric Very chemically inert. 6 7

5 01 CAF products CAF Properties before curing Product category (1) CAF 22 MF CAF 30 self- Main characteristics Elongation Quick-setting Color Trans-black Industrial and professional range CAF 1 Extra fluid Flowable Fluid heat stability, quick-setting Red CAF 4 CAF 33 CAF 44 Self-levelling, Mechanical Off-white Heat stability, chemical resistances Whitetrans-black Whitetrans-black Non-flowing High mechanical and fluid resistance CAF 5661 CAF 5662 High hardness and heat stability CAF 520 self-, Fast kinetics and good adhesion Grey Ivory-black Trans-white Cure-type Oxime Meko free Acetoxy Acetoxy Acetoxy Acetoxy Acetoxy Acetoxy Alkoxy Specific gravity at 25 C (2) / Viscosity (MPa.s) (3) Extrusion (g/min) (4) / Flowability (5) < 2 mm < 2 mm - 4 mm < 2 mm < 1 mm < 5 mm < 3 mm High-performance assembly and protection CAF 510 CAF 530 CAF 50 CAF 8 CAF 36 CAF FR 55 CAF 5552 MF self-, High elongation self-, Quick-curing and high mechanical self-, Good adhesion and mechanical Flowing High heat stability High heat stability self-, Fire-stop, good adhesion self-, Good adhesion, oil resistance Grey Black-white Black Red Red Grey Black Alkoxy Alkoxy Alkoxy Acetoxy Acetoxy Oxime Oxime Meko* free < 3 mm < 2 mm 1 mm 30 sec 5 mm < 1 mm < 5 mm Cured compound Skin formation time (min) Setting time for a 2 mm thickness (h) Cured thickness after 24 h (mm) to Mechanical after curing (7 days) (6) Shore A hardness for 6 mm thick section (points) (7) Secant modulus for 100% elongation / (MPa) (8) Tensile strength (MPa) (8) /5 1.1 Elongation at break (%) (8) / Tear strength (kn/m) (9) Lap shear strength (MPa) (10) Type of failure CF (cohesive failure)/ AF ( failure) (10) CF CF AF CF CF AF CF CF ** CF CF CF CF CF - CF Physical after curing Lower service temperature ( C) Maximum continuous service temperature, 1000 h ( C) Maximum peak service temperature, 72 h ( C) (black) (black) *** 300*** Storage Shelf life from the production date (months) 6**** **** (1) Adhesive: Adhesion without primer on aluminium, glass, enamel, ceramics. Other surfaces require a primer Self-: Adhesion without primer on most of the substrates including plastics (2) ISO R 1183, DIN 53479, NM 703 (3) Brookfield NFT 76105, ASTM D445 (4) NM 495 A 3 mm / 3 bars (5) Non-flowing: Boeing S 7502 NM 459 (mm), flowing: MIL S 880 2D, NM 458 (sec or min) (6) Temp. 23 C, relative humidity 50% (7) ISO R 868, DIN 53505, ASTM D2240, BS 903 (A7), NFT 46003, NM 471 (8) ISO R 37 (H2), DIN 53504, ASTM D 412, BS 903 (A2), NFT (H2), NM 470 (9) ASTM D624 specimen A, NM492 (10) Aluminum AG-03 specimen, 1 mm thick joint, NM748, measurement made after 7 days for acetoxy products and after 14 days for oximic and alkoxy products * Methylethyl Ketoxime (MEKO) ** 7 days at RT + 1 h at 240 C *** 15 h 320 C, 15 min 350 C **** Under development 8 9

6 01 CAF products CAF High performance assembly activated CAF (bi component) Protection, coating and potting Maintenance, servicing, repair Product category (1) CAF 8 AXAD CAF 33 AXAD CAF 99 AXAD Self-levelling, self- self- self- CAF 5751 AXAD Self-levelling, self- CAF 2 Self-, CAF 4 dispersion Flowable, CAF 7037 Flowable, non-, CAF 1 CAF 3 CAF 730 CAF 731 Self-levelling Flowable, self-, Main characteristics Accelerated curing, heat stability Accelerated curing, high elongation Accelerated curing, good mechanical Fast cure, mechanical, injectable Self-levelling Sprayable Release coating Heat stability Non-slip High extrusion, mechanical Mechanical Properties before curing Cured compound Mechanical after curing (7 days) (6) Color Brick red Black Black Off-white Transluscent Off-white Red Cure-type Activated acetoxy Activated acetoxy Activated acetoxy Activated acetoxy Oxime Acetoxy Oxime Specific gravity at 25 C (2) 1.14/ / / / Viscosity (MPa.s) (3) /- -/- -/ / Extrusion (g/min) (4) Flowability (5) - 5 mm 5 mm < 5 mm Skin formation time (min) Setting time for a 2 mm thickness (h) Cured thickness after 24 h (mm) Shore A hardness for 6 mm thick section (points) (7) Secant modulus for 100% elongation (MPa) (8) Red Translucent White White Acetoxy Acetoxy Oxime Alkoxy > min 2 to 12 min 2 mm < 2 mm Tensile strength (MPa) (8) Elongation at break (%) (8) Tear strength (kn/m) (9) UL 94 Homologation: CAF 30, CAF 8, CAF 520, CAF 530, CAF 99 AXAD Lap shear strength (MPa) (10) Physical after curing Type of failure CF (cohesive failure)/ CF CF CF CF CF CF AF AF ( failure) (10) Lower service temperature ( C) Maximum continuous service temperature, 1000 h ( C) Maximum peak service temperature, 72 h ( C) CF CF AF CF CAF products are sold in various packs including 100 g tubes, 22 or 223 liters drums and 260 ml to 310 ml cartridges. As for all of our products, our direct sales network, backed up by our local specialist distributors, provides high-performance services. Storage Shelf life from the production date (months) (1) Adhesive: Adhesion without primer on aluminium, glass, enamel, ceramics. Other surfaces require a primer Self-: Adhesion without primer on most of the substrates including plastics (2) ISO R 1183, DIN 53479, NM 703 (3) Brookfield NFT 76105, ASTM D445 (4) NM 495 A 3 mm / 3 bars (5) Non-flowing: Boeing S 7502 NM 459 (mm), flowing: MIL S 880 2D, NM 458 (sec or min) (6) Temp. 23 C, relative humidity 50% (7) ISO R 868, DIN 53505, ASTM D2240, BS 903 (A7), NFT 46003, NM 471 (8) ISO R 37 (H2), DIN 53504, ASTM D 412, BS 903 (A2), NFT (H2), NM 470 (9) ASTM D624 specimen A, NM492 (10) Aluminum AG-03 specimen, 1 mm thick joint, NM748, measurement made after 7 days for acetoxy products and after 14 days for oximic and alkoxy products * Methylethyl Ketoxime (MEKO) ** 7 days at RT + 1 h at 240 C *** 15 h 320 C, 15 min 350 C **** Under development 10 11

7 01 CAF applications CAF applications Industrial and professional range High-performance assembly and protection Protection, coating and potting Maintenance, servicing and repair Sealing bonding CAF 22 MF CAF 30 CAF 1 extra fluid CAF 4 CAF 33 CAF 44 CAF 5661 CAF 5662 CAF 520 CAF 510 CAF 530 CAF 50 CAF 8 CAF 36 CAF FR 55 CAF 5552 MF CAF 8 AXAD CAF 33 AXAD CAF 99 AXAD CAF 5751 AXAD CAF 2 CAF 4 dispersion CAF 7037 CAF 1 CAF 3 CAF 730 CAF 731 Rheology* NF NF F NF NF NF NF NF NF NF NF F NF NF NF F NF NF F F F F F F NF NF Adhesive Self- High-temperature adhesion Non-corrosive Quick-setting Electrical protection Insulation Coating Potting Sealing Coating Non-slip Release coating Thermal protection Maintenance Automotive Electricity Aeronautics - marine - rail * NF : Non Flowable / F : Flowable 12 13

8 02 Adhesion Primers and Additives 02 The BLUESIL Primer range The Bluestar Silicones Primer range offers a series of surface treatments designed so that Bluestar Silicones elastomers achieve optimal adhesion between different surfaces. Bluestar Silicones Primers are solutions that dry in air, using a siloxane that reacts with atmospheric humidity. Bluestar Silicones means benefits When used with Bluestar Silicones elastomers, our primers optimize RTV adhesion on a wide variety of surfaces: Polar plastics, including polyamide, polycarbonate, ABS, etc. Composite materials, glass fibers, epoxy resins Aluminum Polished or unpolished stainless steel Painted, zinc-plated or chrome-plated steel. To quickly and efficiently develop good surface adhesion, all surfaces must to be clean, dry and free from any contaminants before applying a primer or an RTV. Specially-designed primer solutions to provide the best adhesion on specific substrates Getting the best results Processing is particularly easy since Bluestar Silicones Primers are delivered in ready-to-use formulations. In all cases they must be applied to perfectly clean and dry surfaces. Bluestar Silicones Primers are applied with a dry cloth or a fiber pad in a thin and uniform coat. After application, it is best to allow the required drying time before spreading the elastomer on the primed surface (see table overleaf on the technical data sheet). To avoid any problems with hydrolysis, it is best not to allow the tin of primer to come into contact with ambient humidity by closing the container following each application

9 02 Primer range BLUESIL Prim 131 BLUESIL Prim PM 820/PM 820 UVT* BLUESIL Prim PM 824 BLUESIL Prim General characteristics Metallic powder coating & substrates, stainless steel, aluminium, Zn or Cr-plated steel Metallic substrates Plastic substrates (ABS, PA, PC ) Painted steel, epoxy/pes powder coatings, metallic substrates Aluminium, stainless steel, zinc and alloys, PES powder coating, fluorinated resin based substrates Product category Liquid Liquid Liquid Liquid Color Transparent Light yellow, transparent Transparent Transparent Specific gravity at 25 C approx. Viscosity at 25 C, mm 2 /s, approx. Flash point, C, approx < Diluent Aliphatic hydrocarbons Aliphatic hydrocarbons Aliphatic hydrocarbons Isopropyl alcohol Solvent Isopropyl alcohol Hydrotreated light Naphtha Octamethyltrisiloxane Isopropyl alcohol Minimum drying time Maximum drying time before elastomer appl. 1 min 6 hours 1-3 min 6 hours 15 min 6 hours 15 min 3 hours Shelf life/packaging 24 months/0.8 kg 12 months/0.75 kg 18 months/0.4 kg 18 months/0.8 kg * PM820 UVT: adhesion promoter PM820 is available with a UV tracer (UVT) to visualize areas where primer has been applied. Primers are sold in 0.4 kg to 0.8 kg cans. As is the case for all of our products, our direct sales network works closely with our local specialist distributors, to ensure the best possible service for our customers. For specific technical recommendations, please contact your Sealing and Bonding Customer Service Laboratory. Additive range BLUESIL Silicone Remover is a cleaning agent that eliminates all cured silicones. The liquid product is very convenient for cleaning tools: nozzles, screws, spatulas, etc. by immersion in BLUESIL Silicone Remover. This product can also be used on substrates to replace or remove silicone beads, as well as on glass, enamel and metals (stainless steel, anodized aluminum, etc.). Main benefits and precautions Removes all type of cured RTV Silicone. Available ready to use. Usable on several substrates. Check TDS before application. It is necessary to verify the compatibility with substrates. Main substrates Physical state Color BLUESIL Silicone Remover Glass, enamel, metals, stainless steel, anodized aluminium, PC, PP, PE Liquid Light brown Specific gravity at 20 C approx. 0.9 Flash point, C, approx. > 70 Minimum application time Packaging Shelf life 20 min 1 l, 40 l 24 months 16 17

10 03 Pastes and Greases 03 A wide range of Pastes and Greases for your applications Covering a very wide range of viscosities, Bluestar Silicones Pastes and Greases are ideal for a variety of technical applications: from extreme temperature lubrication or lubrication that comes in contact with oxygen, e.g. for the protection of oil rig probes, including high-voltage electrical insulation. Bluestar Silicones Pastes and Greases: choosing performance On the strength of their mixed mineral and organic components, Bluestar Silicones Pastes and Greases feature a range of outstanding : Stability over time and over a wide range of operating temperatures: from - 60 C to C Outstanding chemical inertness - resistance to oxidation, chemical agents and ageing (UV, weathering, ozone, etc.) Very hydrophobic, providing added resistance to weathering. Pastes for robust protection Excellent dielectric characteristics providing outstanding electrical insulation Robust protection against corrosive atmospheres and conductive or abrasive dusts High levels of release. Greases for reliable lubrication Good lubricating power in a wide range of temperatures High resistance to oxidation and corrosion and wash-out Very high drip point. Pastes and Greases offer you the best performance stability in a wide range of temperatures Bluestar Silicones Pastes and Greases are sold in various formats, including tubes, 1 kg - 5 kg - 25 kg tins and 200 kg drums. As is the case for all of our products, our direct sales network works closely with our local specialist distributors, to ensure the best possible service for our customers

11 03 Automotive Lubricating devices and vehicles exposed to cold and hot conditions: gearboxes, starter units, etc. Heat protection and evacuation: high thermal conductivity pastes, alternators, etc. Domestic appliances Lubricating moving metal parts. Electrical distribution Protective paste for high voltage glass and ceramic insulators and lightning surge arresters Protection of circuit breakers, cable ends and electrical distribution accessories in industrial atmospheres or harsh climatic conditions. Oil extraction Protection of oil rig probes Lubrication of valves, gears and mechanical assembly processes. Aeronautics Lubrication of devices subjected to mechanical stress and extreme condition. General industry Lubrication of water distribution circuit valves Lubrication of domestic and industrial taps Lubrication of smaller assembly units or mechanisms (plastic/plastic, plastic/metal): plastic gears, pins, etc. Anti-seizing protection (production line and maintenance). Optical fiber protection 20 21

12 03 Pastes and Greases Properties Physical Thermal Dielectric Storage Bluesil Silbione Paste 4 Paste 5 Paste 7 Paste 340 Paste 408 Paste B431 Paste 90 Paste Color Translucent to whitish White Translucent to whitish Specific gravity at 25 C Worked preparation (mm/10) (1) < 260 < 250 < Rested preparation (mm/10) (1) Exudation (%) (2) < 6 < 7 < 10 < 1.5 < < 1 < 0.5 Evaporation (%) (2) < 2 < 3 < 5 < 1.5 < 3 < 3 < 1 < 3 Drip point ( C) (3) > Service temperatures ( C) - 40 to to to to to to to to Thermal conductivity at 25 C (W/mK) Dielectric strength (kv/mm) (4) > 20 > 20 - > 15 > 20 > 20 - > 20 Dielectric constant at 1 khz (5) Dissipation factor at 1 khz (5) Volume resistivity (Ω.cm) (6) > > > > > Shelf life from the production date (months) Bluesil Vacuum Tap GRS GRS 33 GRS 55 GRS Translucent to whitish Brown < 8 < 0.5 < 4 to 150 C < 5 to 100 C < 3 < 2 < 3 to 150 C < 2.5 to 100 C to to to to (1) NFT 6012, ASTM D 217, DIN (2) After 24 h at 200 C (3) astm d566 (4) NFC 26225, ASTM D419, IEC 243 (5) NFC 26230, ASTM D150, IEC 250 (6) NFC, ASTM D257, IEC 93 Applications Bluesil Silbione Paste 4 Paste 5 Paste 7 Paste 340 Paste 408 Paste B431 Paste 90 Paste Electrical insulation Thermal dissipation Demolding Food contact Protection Humidity Corrosion Lubrication General purpose Extreme temperatures Tap release applications Vacuum Rubber swelling Potable water Industrial water Sealing Casings Recommended product Other possible usage Optic cables: land Tap GRS Vacuum GRS Bluesil GRS 33 GRS 55 For detailled commercial contacts please visit our website:

13 Elkem Group Bluestar Silicones Bluestar Silicones is one of the world s leading fully integrated silicone manufacturers with applications and research laboratories, production sites and sales offices located around the globe. We focus on developing state-of-the-art application expertise to help our customers challenge their boundaries. At Bluestar Silicones, we re more than just high quality silicone products. We are dedicated people located around the globe committed to your success. From technical support to customized formulations and regulatory support, Bluestar Silicones has the people in place when and where you need them. The information contained in this document is given in good faith based on our current knowledge. It is only an indication and is in no way binding, particularly as regards infringement of or prejudice to third party rights through the use of our products. Bluestar Silicones guarantees that its products comply with its sales specifications. This information must on no account be used as a substitute for necessary prior tests which alone can ensure that a product is suitable for given use. Determination of the suitability of product for the uses and applications contemplated by users and others shall be the sole responsibility of users. Users are responsible for ensuring compliance with local legislation and for obtaining the necessary certifications and authorisations. Users are requested to check that they are in possession of the latest version of this document and Bluestar Silicones is at their disposal to supply any additional information. For detailed commercial contacts please visit our website : SIL Bluestar Silicones France SAS 21, avenue Georges Pompidou F Lyon Cedex 03 - France Tel : +33 (0) Fax : +33 (0) Elkem Group Art direction & graphic design: Day on mars Font: Synthese BSS rounded Photography: Stephane Cande, Sebastien Secchi, Christian Chaize Image bank: Shutterstock

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