HAYNES HIGH-TEMPERATURE ALLOYS

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1 HAYNES international HIGH-TEMPERATURE ALLOYS An age-hardenable Ni-Co-Cr- Mo-Ti-Al alloy that combines very good high-temperature strength with excellent ductility, formability and weldability. Contents Chemical Composition and Principal Features 3 Creep and Stress Rupture Strength 4 Typical Tensile Properties 5 Modulus of Elasticity 5 Oxidation Resistance 5 Physical Properties 6 Fabrication and Welding 7 Health and Safety Information 7 H-3047D 2000, Haynes International, Inc.

2 I PRINCIPAL FEATURES Very Good High-Temperature range for the alloy is approxi- treatment, the alloy is age- Strength Upto 1650 F(900 C), mately 1750 to F (955- hardened at 1470 F (800 C) for Excellent Ductility, and 1150 C). The alloy has excellent eight (8) hours, and air-cooled. Excellent Weldability ductility in the annealed condition, and thus may also be Available in Convenient HAYNES 263 alloy is an age- formed by cold working. Interme- Form hardenable nickel-cobalt-chro- diate annealing in the tempera- S mium-molybdenum alloy de- ture range from 1900 to 2000 F HAYNES 263 alloy is produced signed specifically to combine (1040 to 1100 C) may be needed in the form of sheet, strip, plate, very good aged strength proper- for complex component forming bar, billet and wire. ties with excellent fabrication operations. All hot- or coldcharacteristics in the annealed worked parts should be annealed Applications condition. While its strength at and rapidly cooled in order to HAYNES 263 alloy combines elevated temperature is not quite as high as materials such as restore the best balance of properties. properties which make it suitable for a variety of fabri- Waspaloy alloy or alloy R-41, it is cated component applications in far easier to form or weld than Alloy 263 can be welded by both both aircraft turbine engine and these alloys. Alloy 263 exhibits manual and automatic welding land-based turbine applications. excellent intermediate tempera- methods, including gas tungsten These include low-temperature ture tensile ductility, and is not arc (TiG), gas metal arc (MIG), combustors, transition liners, normally subject to strain age electron beam and resistance and some ring components. cracking problems common for welding. Matching composition gamma prime strengthened filler wire is available, and is Applicable Specifications alloys, generally used for welding alloy HAYNES 263 alloy is covered 263. by the following specifications: Alloy 263 is normally used for AMS 5872 (sheet, strip and applications up to about 1650 F Heat Treatment plate), and all relevant customer (900 C). Its oxidation resistance Wrought HAYNES 263 alloy is specifications for various other is comparable to that for other furnished in the solution heat- product forms. gamma-prime-strengthened treated condition unless othersuperalloys. wise specified. The alloy is normally solution heat-treated at Fabrication F±25 F (11 50 C±1 4 C) HAYNES 263 alloy has excellent and rapidly cooled or water forming and welding characteris- quenched for optimal properties. tics. The hot working temperature Following solution heat NOMINAL CHEMICAL COMPOSITION, PERCENT I Ni Co Fe Cr Mo Mn Si Al Ti C Cu 52~ * * 0.4* 0.6* 2.4* * *Maximum a As balance 3 HAYNES 263 alloy

3 [CREEP AND STRESS-RUPTURE STRENGTH I ICOLD-ROLLED Test Temperature F ( C) j SHEET, SOLUTION-TREATED AND AGED Approximate Initial Stress, Ksi (MPa) Creep to Produce Specified Creep in: % lohrs. 100Hrs. 1,000Hrs (540) Rupture (795) (690) 1100(595) Rupture (750) 95.0 (655) 82.0 (565) 1200 (650) (415) (425) Rupture 90.0 (620) 77.0 (530) 64.0 (440) 1300 (705) (380) 38.0 (260) (390) 42.0 (290) Rupture 74.0 (510) 60.0 (415) 45.0 (310) 1400 (760) (360) 340 (235) 21 0 (145) (370) 37.0 (255) 23.3 (160) Rupture 57.0 (395) 41.0 (285) 27.0 (185) 1500 (815) (220) 19.2 (130) 10.7 (74) (240) 21.0 (145) 11.4 (79) Rupture 38.0 (260) 25.0 (170) 14.5 (100) 1600 (870) (125) 9.9 (68) (140) 10.2 (70) Rupture 24.0 (165) 14.1 (97) 6.8 (47) I COMPARISON OF SHEET MATERIALS, STRESS TO RUPTURE IN 1,000 HOURS 1 HAYN ES 263 alloy has stress rupture strength between 1000 and 1600 F (540 and 870 C) which is higher than for alloy X-750, but less than that for Waspaloy alloy. Its rupture strength also exceeds that for alloy 718 above about 1300 F (705 C), and 242 alloy above about 1200 F (650 C). (I) Cl) U) I:1) S..,.4- C/) Test Temperature, C c~:i 0~ U) U) ci) S.., C/) Test Temperature, F HAYN ES 263 alloy 4

4 I TYPICAL TENSILE PROPERTIES I I COLD-ROLLED SHEET, SOLUTION-TREATED AND AGED ] Ultimate Test Tensile 0.2% Yield Elongation Temperature Strength Strength in 2 in. (51 mm) F ( C) Ksi MPa Ksi MPa % Room (540) (650) (760) (870) (980) (1095) I DYNAMIC MODULUS OF ELASTICITY I Dynamic Dynamic Modulus of Modulus of Elasticity Elasticity Temp., F 106 psi Temp., C GPa Room 32.1 Room I COMPARATIVE OXIDATION RESISTANCE IN FLOWING AIR* I Average Metal Affected in 1008 Hours** 1800 F (980 C) 2000 F (1095 C) 2100 F (1150 C) Material Mils pm Mils p.m Mils p.m 230 alloy HASTELLOY alloy X Waspaloy alloy Alloy Alloy R * Flowing air at a velocity of 7.0 ft/mm. (213.4 cm/mm.) past the samples. Samples cycled to room temperature once-a-week. ** Metal Loss + Average Internal Penetration. 5 HAYN ES 263 alloy

5 I TYPICAL PHYSICAL PROPERTIES 1 Temp., F British Units Temp., C Metric Units Density Room lb/in 3 Room 8.36g/cm 3 Melting Range Electrical Resistivity Room 45.3 p.ohm-in Room 115 p.ohm-cm p.ohm-in p.ohm-cm p.ohm-in p.ohm-cm p.ohm-in p.ohm-cm p.ohm-in p.ohm-cm p.ohm-in p.ohm-cm p.ohm-in p.ohm-cm p.ohm-in p.ohm-cm p.ohm-in p.ohm-cm p.ohm-in p.ohm-cm pohm-cm Thermal Conductivity Room 81 BTU-in/ft 2 hr- F Room 11.7 W/m-K BTU-in/ft 2 hr- F W/m-K BTU-in/ft 2 hr- F W/m-K BTU-in/ft 2 hr- F W/m-K BTU-in/ft 2 hr- F W/m-K BTU-in/ft 2 hr- F W/m-K BTU-in/ft 2 hr- F W/m-K Mean Coefficient of Thermal Expansion BTU-in/ft 2 hr- F W/m-K BTU-in/ft 2 hr- F W/m-K BTU-in/ft 2 hr- F W/m-K W/m-K microinches/in- F p.m/m- C microinches/in- F llm/m- C microinches/in- F p.m/m- C microinches/in- F p.m/m- C microinches/in- F p.m/m- C microinches/in- F p.m/m- C microinches/in- F p.m/m- C microinches/in- F p.m/m- C microinches/in- F p.m/m- C p.m/m- C HAYNES 263 alloy 6

6 I HAYN ES 263 alloy has FABRICATION AND WELDING excellent forming and welding characteristics. It may be hotworked at temperatures in the range of about F ( C) provided the entire piece is soaked for a time sufficient to bring it uniformly to temperature. Initial breakdown is normally performed at the higher end of the range, while finishing is usually done at the lower temperatures to afford grain refinement. The alloy can be welded by a variety of processes, including gas tungsten arc, gas metal arc, electron beam and resistance welding. High heat input processes such as submerged arc and oxyacetalyne welding are not recommended. Welding Procedures Welding procedures common to most high-temperature, nickelbase alloys are recommended. These include use of stringer plete penetration defects, the root opening and bevel should be sufficiently open. Filler Metals HAYNES 263 alloy should be joined using matching filler metal. For welding alloy 263 to other alloys, HASTELLOY S or W filler wires are suggested. Post-Weld Heat Treatment HAYNES 263 alloy is normally used in the fully-aged condition. beads and an interpass tem- Following forming and welding, As a consequence of its good perature less than 200 F a full solution anneal prior to ductility, alloy 263 is also (95 C). Preheat is not required. aging is often employed in order readily formed by cold-working. Cleanliness is critical, and to develop the best joint and All hot- or cold-worked parts careful attention should be given overall fabrication properties. should normally be annealed at to the removal of grease, oil, The best practice is dependent 2100 F (1150 C) and cooled by crayon marks, shop dirt, etc. upon the specific condition of air cool or faster rate before prior to welding. Because of the the fabrication prior to aging. aging at 1470 F (800 C) in alloy s high nickel content, the Contact Haynes International order to develop the best weld puddle will be somewhat Inc. for further information. balance of properties. sluggish relative to steels. To avoid lack of fusion and incorn- I_HEALTH AND SAFETY INFORMATION Welding can be a safe occupation. Those in the welding industry, however, should be aware of the potential hazards associated with welding fumes, gases, radiation, electric shock, heat, eye injuries, burns, etc. Also, local, municipal, state, and federal regulations (such as those issued by OSHA) relative to welding and cutting processes should be considered. Nickel-, cobalt-, and iron-base alloy products may contain, in varying concentrations, the following elemental constituents: aluminum, cobalt, chromium, copper, iron, manga- nese, molybdenum, nickel and tungsten. For specific concentrations of these and other elements present, refer to the Materials Safety Data Sheets (MSDS), H3095 and H1072 for the product. Inhalation of metal dust or fumes generated from welding, cutting, grinding, melting, or dross handling of these alloys may cause adverse health effects such as reduced lung function, nasal and mucous membrane irritation. Exposure to dust or fumes which may be generated in working with these alloys may also cause eye irritation, skin rash and effects on other organ systems. The operation and maintenance of welding and cutting equipment should conform to the provisions of American National Standard ANSI/AWS Z49.1, Safety in Welding and Cutting. Attention is especially called to Section 7 (Protection of Personnel) and 8 (Health Protection and Ventilation) of ANSI/AWS Z49.1. Mechanical ventilation is advisable and, under certain conditions such as a very confined space, is necessary during welding or cutting operations, or both, to prevent possible exposure to hazardous fumes, gases, or dust that may occur. 7 HAYNES 263 alloy

7 STANDARD PRODUCTS By Brand or Alloy Designation: HAYNES International HASTELLOY Family of Corrosion-Resistant Alloys B-3, C-4, C-22, C-276, C-2000, C-22HS, G-30, G-35, G-50, HYBRID-BC1, and N HASTELLOY Family of Heat-Resistant Alloys S, W, and X HAYNES Family of Heat-Resistant Alloys 25, R-41, 75, HR-120, HR-160, 188, 214, 230, 230-W, 242, 263, 282, 556, 617, 625, 65SQ, 718, X-750, MULTIMET, NS-163, and Waspaloy Corrosion-Wear Resistant Alloy ULTIMET HAYNES Titanium Alloy Tubular Wear-Resistant Alloy 6B Ti-3Al-2.5V Standard Forms: Bar, Billet, Plate, Sheet, Strip, Coils, Seamless or Welded Pipe & Tubing, Pipe Fittings, Flanges, Fittings, Welding Wire, and Coated Electrodes Properties Data: The data and information in this publication are based on work conducted principally by Haynes International, Inc. and occasionally supplemented by information from the open literature, and are believed to be reliable. However, Haynes does not make any warranty or assume any legal liability or responsibility for its accuracy, completeness, or usefulness, nor does Haynes represent that its use would not infringe upon private rights. Any suggestions as to uses and applications for specific alloys are opinions only and Haynes International, Inc. makes no warranty of results to be obtained in any particular situation. For specific concentrations of elements present in a particular product and a discussion of the potential health affects thereof, refer to the Material Safety Data Sheet supplied by Haynes International, Inc. All trademarks are owned by Haynes International, Inc. Global Headquarters 1020 West Park Avenue P.O. Box 9013 Kokomo, Indiana (USA) Phone: or (765) Fax: (765) For your local sales offfor your local sales office or service center, please call or visit our website.

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