Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet Preparation Date: 01-May-2012 Revision Date: 21-Jun-2017 Revision Number: 2 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product Name Item#: Recommended use Supplier Emergency Telephone Number CAN6151 Cleaning agent DeLaval Inc. 150-B Jameson Drive Peterborough, Ontario, K9J 0B9 Tel: (705) (613) (Canutec) 2. HAZARDS IDENTIFICATION Emergency Overview Corrosive The product causes burns of eyes, skin and mucous membranes Potential Health Effects Principal Routes of Exposure Major effects of exposure Eyes Skin Ingestion Inhalation Eye contact Skin contact Ingestion Inhalation Corrosive to the eyes and may cause severe damage including blindness. Extremely corrosive and destructive to tissue. Ingestion causes burns of the upper digestive and respiratory tracts. Causes burns. Irritating to respiratory system. Immediate medical attention is required. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical name CAS No Weight % Sulfonic acids, C14-16-alkane hydroxy and C14-16-alkene, sodium salts Lactic acid Formic acid FIRST AID MEASURES General Advice Do not get in eyes, on skin, or on clothing. Take off contaminated clothing and Page 1 / 6

2 shoes immediately. Immediate medical attention is required. Eye contact Skin contact Ingestion Inhalation Notes to Physician Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get medical attention immediately. Wash off immediately with soap and plenty of water removing all contaminated clothes and shoes. Consult a physician if necessary. Do not induce vomiting. Rinse mouth. Never give anything by mouth to an unconscious person. Get medical attention immediately. Move to fresh air. Get medical attention immediately if symptoms occur. Treat symptomatically. 5. FIRE-FIGHTING MEASURES Fire Hazard Suitable Extinguishing Media The product is not flammable. The product is not flammable, Use extinguishing measures that are appropriate to local circumstances and the surrounding environment Unsuitable Extinguishing Media None known Hazardous Combustion Products Specific hazards arising from the chemical Protective Equipment and Precautions for Firefighters No information available Corrosive to metals. The product causes burns of eyes, skin and mucous membranes. As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA Health hazards 3 Flammability 0 Instability 0 6. ACCIDENTAL RELEASE MEASURES Personal precautions Avoid contact with skin, eyes and clothing. For personal protection see section 8. Environmental Precautions Methods for cleaning up Prevent further leakage or spillage if safe to do so. Soak up with inert absorbent material. Keep in suitable, closed containers for disposal. Page 2 / 6

3 7. HANDLING AND STORAGE Handling Storage Incompatible Materials Avoid contact with skin, eyes and clothing. Keep containers tightly closed in a dry, cool and well-ventilated place. Keep out of the reach of children. bases, bleach, light metals (e.g. aluminum, copper, brass, zinc galvanized). 8. EPOSURE CONTROLS / PERSONAL PROTECTION Chemical name ACGIH TLV OSHA PEL Alberta British Columbia Ontario TWAEV Formic acid TWA: 5 ppm TWA: 5 ppm TWA: 5 ppm TWA: 5 ppm TWA: 5 ppm STEL: 10 ppm TWA: 9 mg/m 3 TWA: 9.4 mg/m 3 STEL: 10 ppm STEL: 10 ppm STEL: 10 ppm STEL: 19 mg/m 3 Engineering Controls Ensure adequate ventilation, especially in confined areas. Quebec TWA: 5 ppm TWA: 9.4 mg/m 3 STEL: 10 ppm STEL: 19 mg/m 3 Personal Protective Equipment Eye/face Protection Skin Protection Tightly fitting safety goggles Protective gloves, Long sleeved clothing, Chemical resistant apron General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Appearance Blue Physical state Liquid Odor Strong Specific Gravity 1.1 ph < 2 Water Solubility soluble 9. PHYSICAL AND CHEMICAL PROPERTIES Page 3 / 6

4 10. STABILITY AND REACTIVITY Chemical Stability Conditions to Avoid Incompatible Materials Hazardous decomposition products Possibility of hazardous reactions stable when stored at temperatures not exceeding 80 F. Long-term storage at higher temps may degrade product over time. Product may degrade if exposed to long-term high temperature. bases, bleach, light metals (e.g. aluminum, copper, brass, zinc galvanized). None known May spatter and release heat if mixed with bases (alkalis). Mixing with chlorinated products may release deadly chlorine gas. May react with and cause damage to soft metals such as aluminum, copper, brass or zinc (galvanized) to produce flammable, potentially explosive, hydrogen gas. 11. TOICOLOGICAL INFORMATION Chemical name LD50 Oral LD50 Dermal LC50 Inhalation Sulfonic acids, C14-16-alkane = 2310 mg/kg ( Rat ) = 6300 mg/kg ( Rabbit ) hydroxy and C14-16-alkene, sodium salts Lactic acid = 3730 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) Formic acid = 730 mg/kg ( Rat ) = 15 g/m 3 ( Rat ) 15 min Chronic Toxicity Carcinogenicity Contains no ingredient listed as a carcinogen Page 4 / 6

5 12. ECOLOGICAL INFORMATION Ecotoxicity Chemical name Sulfonic acids, C14-16-alkane hydroxy and C14-16-alkene, sodium salts Lactic acid Formic acid Lactic acid Partition coefficient Formic acid Partition coefficient Algae/aquatic plants : 96 h Brachydanio rerio mg/l LC50 static 12.2: 96 h Brachydanio rerio mg/l LC50 semi-static 3.5: 70 h 320: 96 h Pseudokirchneri Brachydanio ella subcapitata rerio mg/l LC50 mg/l EC50 semi-static : 96 h Lepomis macrochirus mg/l LC50 static : 96 h Oncorhynchus mykiss mg/l LC50 static 25: 96 h Desmodesmus subspicatus mg/l EC : 72 h Desmodesmus subspicatus mg/l EC50 Fish Microtox Waterflea 175: 24 h Lepomis macrochirus mg/l LC50 static EC50 = 46.7 mg/l 17 h 13. DISPOSAL CONSIDERATIONS 240: 48 h Daphnia magna mg/l EC : 48 h Daphnia magna mg/l EC50 Static 120: 48 h Daphnia magna mg/l EC : 48 h Daphnia magna mg/l EC50 Static Waste Disposal Method Dispose of in accordance with local regulations. Should not be released into the environment. Contact your local waste disposal authority for advice, or pass to a chemical disposal company. 14. TRANSPORT INFORMATION DOT UN-No 3265 Proper Shipping Name Corrosive liquid, acidic, organic, n.o.s ( FORMIC ACID, LACTIC ACID ) Hazard Class 8 Packing Group II Page 5 / 6

6 15. REGULATORY INFORMATION Chemical name DSL NDSL TSCA EINECS ELINCS ENCS CHINA KECL PICCS AICS Sulfonic acids, KE C14-16-alkane hydroxy and C14-16-alkene, sodium salts Lactic acid KE Formic acid KE WHMIS Hazard Class E Corrosive material Chemical name Formic acid NPRI This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. 16. OTHER INFORMATION Preparation Date: Revision Date: 01-May May-2017 Revision Note: No information available Disclaimer The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. Page 6 / 6