Material Safety Data Sheet

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1 ITW Permatex 10 Columbus Blvd. Hartford, CT USA Telephone: 1-87-Permatex (877) Emergency: (ChemTel) International Emergency: Material Safety Data Sheet 1. PRODUCT IDENTIFICATION Product Name: (HARDENER) Item No: 1007A Product Type: Epoxy hardener 2. COMPOSITION/INFORMATION ON INGREDIENTS Component: Weight% ACGIH; TLV-TWA OSHA PEL POLYAMINE-POLYMERCAPTAN >80 Not listed Not listed BLEND Mixture _ 2,2-OXYBIS (N,N- < ppm Not listed DIMETHYLETHANAMINE) SUBSTITUTED AMIDINE <5 Not listed Not listed 3. HAZARDS IDENTIFICATION Toxicity: Primary Routes of Entry: Signs and Symptoms of Exposure: Corrosive. The product causes burns of eyes, skin and mucous membranes. Eye and skin contact, ingestion, inhalation Eye irritation may be severe and result in injury. Contact causes severe skin irritation and possible burns. Inhalation of vapours is irritating to the respiratory system, may cause throat pain and cough. Ingestion can cause damage to the mucous membranes or other tissues with which contact is made. Aggravated Medical Condition: Preexisting eye, skin and respiratory disorders may be aggravated by overexposure to this product. WHMIS E CORROSIVE MATERIAL 4. FIRST AID MEASURES Ingestion: Inhalation: Skin Contact: Eye Contact: Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek medical attention. Never give anything by mouth to an unconscious person. Move to fresh air in case of accidental inhalation of vapours. Oxygen or artificial respiration if needed. If symptoms persist, call a physician. Rinse immediately with plenty of water for at least 15 minutes. Obtain medical attention. Wash contaminated clothing before re-use. Discard contaminated shoes. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Immediate medical attention is required. 5. FIRE FIGHTING MEASURES Flash Point F(C ): Recommended Extinguishing Media: Special Fire-Fighting Procedures: Unusual Fire/Explosion Hazards: Lower Explosive Limit: Upper Explosive Limit: >200 F (>93 C) Dry chemical, Carbon dioxide, Foam Firefighters shoud wear self-contained breathing apparatus and protective clothing to prevent all skin and eye contact Oxides of carbon, Oxides of nitrogen, Oxides of sulfur, Hydrogen sulfide Irritating or toxic gases or fumes may be generated by thermal decomposition or combustion. 6. ACCIDENTAL RELEASE MEASURES Spill Procedures: Maintain good ventilation. Take up with an inert absorbent. Store in a closed waste container until disposal. Wear appropriate protective and respiratory equipment. 1 of 3

2 (HARDENER) Item No. 1007A 7. HANDLING AND STORAGE Storage: Handling: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eyes: Skin: Ventilation: Respiratory Protection: 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Amber liquid Odor: Mercaptan Boiling Point: ph: Not applicable Solubility in Water: Dispersable Specific Gravity: 1.12 VOC(Wt.%): 0 Vapor Pressure: Vapor Density (Air=1): >1 Evaporation Rate: <1 (butyl acetate = 1) Store in a cool, dry area. Keep away from acids and oxidizers. Do not inhale vapors. Avoid contact with skin and eyes. Avoid contact with clothing. Wash thoroughly after handling. Discard contaminated leather gloves and shoes. Safety glasses with side shields or chemical goggles. Neoprene or nitrile gloves recommended. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. An approved organic vapor respirator should be worn when exposures are expected to exceed the applicable limits. 10. STABILITY AND REACTIVITY Chemical Stability: Hazardous Polymerization: Incompatabilities: Conditions to Avoid: Stable Will not occur Strong oxidizers, Amines, Acids Excessive heat Oxides of carbon, Oxides of nitrogen, Oxides of sulfur, Hydrogen sulfide 11. TOXICOLOGICAL INFORMATION Oral LD50 (rat) = >2000 mg/kg Skin irritation: 6.62/8 (Severe) 12. ECOLOGICAL INFORMATION No data available 13. DISPOSAL CONSIDERATIONS Recommended Method of Disposal: US EPA Waste Number: 14. TRANSPORTATION INFORMATION DOT (49CFR 172) U.S. Department of Transportation - DOT - 49 CFR (Ground) Disposal should be made in accordance with federal, state and local regulations NH - Not a RCRA Hazardous Waste Material DOT Shipping Name: Corrosive liquid, basic, organic, n.o.s.(mercaptan/amine blend), Limited Quantity Class 8 PGIII UN/ID Number: UN 3267 IATA (Air) Proper Shipping Name: Consumer Commodity Class or Division: Class 9 UN/ID Number: ID 8000 IMDG (Vessel) Proper Shipping Name: UN Number: UN 3267 Corrosive liquid, basic, organic, n.o.s.(mercaptan/amine blend), Limited Quantity Class 8 PGIII Marine Pollutant:

3 (HARDENER) Item No. 1007A SARA 313 Chemicals: The following component(s) is listed as a SARA Section 313 Toxic Chemical. California Proposition 65: No California Prop 65 chemicals are known to be present. TSCA Inventory Status: All components of this product are listed (or exempt) on the EPA TSCA inventory. 16. OTHER INFORMATION Estimated NFPA Rating: HEALTH 3, FLAMMABILITY 1, REACTIVITY 0. Estimated HMIS Classification: HEALTH 3, FLAMMABILITY 1, PHYSICAL HAZARD 0 (NFPA is a registered trademark of the National Fire Protection Association) (HMIS is a registered trademark of the National Paint and Coatings Association) Prepared By: Denise Boyd, Manager-Environmental, Health & Safety Revision Date: April 02, 2014 Company: ITW Permatex 10 Columbus Blvd. Hartford, CT USA Revision Number: 1 Telephone No.: 1-87-Permatex (877)

4 ITW Permatex 10 Columbus Blvd. Hartford, CT USA Telephone: 1-87-Permatex (877) Emergency: (ChemTel) International Emergency: Material Safety Data Sheet 1. PRODUCT IDENTIFICATION Product Name: (RESIN) Item No: Z Product Type: Epoxy resin 2. COMPOSITION/INFORMATION ON INGREDIENTS Component: Weight% ACGIH; TLV-TWA OSHA PEL BISPHENOL A/EPICHLOROHYDRIN Not listed Not listed BASED EPOXY RESIN TREATED SILICON DIOXIDE, SYNTHETIC, CRYSTALLINE-FREE mg/m 3 Not listed 3. HAZARDS IDENTIFICATION Toxicity: Primary Routes of Entry: Signs and Symptoms of Exposure: This material is irritating to skin, eyes and respiratory tract. May cause skin sensitization. Eye and skin contact, ingestion, inhalation May cause pain, redness or swelling of the eyes and excessive blinking and tear production. Eye irritation may be severe and result in injury. Skin redness. Repeated skin contact may cause allergic skin reactions. Ingestion may cause cramps or diarrhea. Aggravated Medical Condition: 4. FIRST AID MEASURES Ingestion: Inhalation: Skin Contact: Eye Contact: Preexisting pulmonary and dermatological disorders. If swallowed, do not induce vomiting - seek medical advice. Never give anything by mouth to an unconscious person. Move to fresh air in case of accidental inhalation of vapours. If symptoms persist, call a physician. In case of contact, immediately flush skin with plenty of soap and water for at least 15 minutes. Get medical attention. Remove contaminated clothing and launder before reuse. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Immediate medical attention is required. 5. FIRE FIGHTING MEASURES Flash Point F(C ): Recommended Extinguishing Media: Special Fire-Fighting Procedures: Unusual Fire/Explosion Hazards: Lower Explosive Limit: Upper Explosive Limit: >400 F (>204 C) Dry chemical, Carbon dioxide, Foam Firefighters shoud wear self-contained breathing apparatus and protective clothing to prevent all skin and eye contact Oxides of carbon, Phenolics Heating above 149 C (300 F) in the presence of air may cause slow oxidation decomposition and above 260 C (500 F) may cause polymerization. 6. ACCIDENTAL RELEASE MEASURES Spill Procedures: Maintain good ventilation. Take up with an inert absorbent. Store in a closed waste container until disposal. 7. HANDLING AND STORAGE Storage: Handling: Store in a cool, dry area. Store away from heat. Avoid contact with skin and eyes. Use in a well ventilated area. Wash thoroughly after handling. Discard contaminated leather gloves and shoes. 1 of 3

5 (RESIN) Item No Z 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eyes: Skin: Ventilation: Respiratory Protection: 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Viscous liquid Odor: Little odor Boiling Point: >500 F (260 C) ph: Not applicable Solubility in Water: Negligible Specific Gravity: 1.16 VOC(Wt.%): 0 Vapor Pressure: F Vapor Density (Air=1): >1 Evaporation Rate: <1 (butyl acetate = 1) Safety glasses Neoprene or nitrile gloves recommended Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. An approved organic vapor respirator should be worn when exposures are expected to exceed the applicable limits. 10. STABILITY AND REACTIVITY Chemical Stability: Hazardous Polymerization: Incompatabilities: Conditions to Avoid: Stable Will not occur Strong Lewis or mineral acids, strong oxidizing agents, strong mineral and organic bases (especially primary and secondary aliphatic amines) Excessive heat Oxides of carbon, Phenolics 11. TOXICOLOGICAL INFORMATION See Section ECOLOGICAL INFORMATION No data available 13. DISPOSAL CONSIDERATIONS Recommended Method of Disposal: US EPA Waste Number: 14. TRANSPORTATION INFORMATION DOT (49CFR 172) U.S. Department of Transportation - DOT - 49 CFR (Ground) DOT Shipping Name: UN/ID Number: IATA (Air) Proper Shipping Name: Class or Division: UN/ID Number: Disposal should be made in accordance with federal, state and local regulations NH - Not a RCRA Hazardous Waste Material Not regulated Not regulated IMDG (Vessel) Proper Shipping Name: UN Number: Not regulated SARA 313 Chemicals: The following component(s) is listed as a SARA Section 313 Toxic Chemical. California Proposition 65: No California Prop 65 chemicals are known to be present. TSCA Inventory Status: All components of this product are listed (or exempt) on the EPA TSCA inventory.

6 (RESIN) Item No Z 16. OTHER INFORMATION Estimated NFPA Rating: HEALTH 2, FLAMMABILITY 1, REACTIVITY 0. Estimated HMIS Classification: HEALTH 2, FLAMMABILITY 1, PHYSICAL HAZARD 0 (NFPA is a registered trademark of the National Fire Protection Association) (HMIS is a registered trademark of the National Paint and Coatings Association) Prepared By: Denise Boyd, Manager-Environmental, Health & Safety Company: ITW Permatex 10 Columbus Blvd. Hartford, CT USA Telephone No.: 1-87-Permatex (877) Revision Date: April 17, 2014 Revision Number: 2

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