SAFETY DATA SHEET. Revision Date 11-Mar-2015 Revision Number Identification. Manganous sulfate aqueous solution.

Transcription

1 SAFETY DATA SHEET Revision Number 1 Product Name Cat. : Synonyms Recommended Use 1. Identification Manganese(II) sulfate solution SM20-1; SM Manganous sulfate aqueous solution. Laboratory chemicals. Uses advised against Information available Details of the supplier of the safety data sheet Company Fisher Scientific One Reagent Lane Fair Lawn, NJ Tel: (201) Emergency Telephone Number CHEMTRECÒ, Inside the USA: CHEMTRECÒ, Outside the USA: Hazard(s) identification Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR ) Corrosive to metals Category 1 Specific target organ toxicity - (repeated exposure) Category 2 Label Elements Signal Word Warning Hazard Statements May be corrosive to metals May cause damage to organs through prolonged or repeated exposure Precautionary Statements Prevention Do not breathe dust/fume/gas/mist/vapors/spray Page 1 / 7

2 Keep only in original container Response Get medical attention/advice if you feel unwell Spills Absorb spillage to prevent material damage Storage Store in corrosive resistant polypropylene container with a resistant inliner Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Toxic to aquatic life with long lasting effects May form explosive peroxides Unknown Acute Toxicity.? % of the mixture consists of ingredients of unknown toxicity. 3. Composition / information on ingredients Component CAS- Weight % Water Manganese(II) sulfate Manganese sulfate monohydrate First-aid measures Eye Contact Skin Contact Inhalation Ingestion Most important symptoms/effects tes to Physician Unsuitable Extinguishing Media Flash Point Method - Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Wash off immediately with plenty of water for at least 15 minutes. Move to fresh air. Do not induce vomiting.. Treat symptomatically 5. Fire-fighting measures Autoignition Temperature Explosion Limits Upper Lower Sensitivity to Mechanical Impact Sensitivity to Static Discharge Specific Hazards Arising from the Chemical Keep product and empty container away from heat and sources of ignition. Hazardous Combustion Products ne known Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Page 2 / 7

3 NFPA Health 2 * Flammability 0 Instability 0 Physical hazards N/A Personal Precautions Environmental Precautions 6. Accidental release measures Ensure adequate ventilation. Use personal protective equipment. See Section 12 for additional ecological information. Avoid release to the environment. Collect spillage. Methods for Containment and Clean. Up Handling Storage Exposure Guidelines 7. Handling and storage Ensure adequate ventilation. Keep containers tightly closed in a dry, cool and well-ventilated place. 8. Exposure controls / personal protection This product does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. Component ACGIH TLV OSHA PEL NIOSH IDLH Manganese(II) sulfate TWA: 0.02 mg/m 3 TWA: 0.1 mg/m 3 (Vacated) Ceiling: 5 mg/m 3 Ceiling: 5 mg/m 3 IDLH: 500 mg/m 3 TWA: 1 mg/m 3 STEL: 3 mg/m 3 Manganese sulfate monohydrate TWA: 0.02 mg/m 3 TWA: 0.1 mg/m 3 (Vacated) Ceiling: 5 mg/m 3 IDLH: 500 mg/m 3 Ceiling: 5 mg/m 3 TWA: 1 mg/m 3 STEL: 3 mg/m 3 Component Quebec Mexico OEL (TWA) Ontario TWAEV Manganese(II) sulfate TWA: 0.2 mg/m 3 TWA: 0.2 mg/m 3 TWA: 0.2 mg/m 3 Manganese sulfate monohydrate TWA: 0.2 mg/m 3 TWA: 0.2 mg/m 3 TWA: 0.2 mg/m 3 Legend ACGIH - American Conference of Governmental Industrial Hygienists OSHA - Occupational Safety and Health Administration NIOSH IDLH: The National Institute for Occupational Safety and Health Immediately Dangerous to Life or Health Engineering Measures Ensure adequate ventilation, especially in confined areas. Personal Protective Equipment Eye/face Protection Skin and body protection Respiratory Protection Hygiene Measures Physical State Appearance Odor Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR or European Standard EN166. Wear appropriate protective gloves and clothing to prevent skin exposure. Follow the OSHA respirator regulations found in 29 CFR or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Handle in accordance with good industrial hygiene and safety practice. 9. Physical and chemical properties Liquid Light red Odorless Page 3 / 7

4 Odor Threshold ph Melting Point/Range Boiling Point/Range Flash Point Evaporation Rate Flammability (solid,gas) Flammability or explosive limits Upper Lower Vapor Pressure Vapor Density Relative Density 1.27 Solubility Soluble in water Partition coefficient; n-octanol/water Autoignition Temperature Decomposition Temperature Viscosity 10. Stability and reactivity Reactive Hazard Stability Conditions to Avoid Incompatible Materials ne known, based on information available Stable under normal conditions. Incompatible products. Strong oxidizing agents Hazardous Decomposition Products ne under normal use conditions Hazardous Polymerization Hazardous Reactions Acute Toxicity Hazardous polymerization does not occur. ne under normal processing. 11. Toxicological information Oral LD50 Based on ATE data, the classification criteria are not met. ATE > 2000 mg/kg. Dermal LD50 Based on ATE data, the classification criteria are not met. ATE > 2000 mg/kg. Vapor LC50 Based on ATE data, the classification criteria are not met. ATE > 20 mg/l. Component Information Component LD50 Oral LD50 Dermal LC50 Inhalation Manganese(II) sulfate 782 mg/kg ( Rat ) t listed t listed Toxicologically Synergistic Products Delayed and immediate effects as well as chronic effects from short and long-term exposure Irritation Sensitization Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Component CAS- IARC NTP ACGIH OSHA Mexico Water t listed t listed t listed t listed t listed Manganese(II) sulfate t listed t listed t listed t listed t listed Manganese sulfate monohydrate t listed t listed t listed t listed t listed Mutagenic Effects Page 4 / 7

5 Reproductive Effects Developmental Effects Teratogenicity STOT - single exposure STOT - repeated exposure Aspiration hazard Symptoms / effects,both acute and delayed Endocrine Disruptor Information Other Adverse Effects Ecotoxicity Do not empty into drains. Persistence and Degradability Bioaccumulation/ Accumulation Mobility Waste Disposal Methods DOT TDG IATA IMDG/IMO... ne known ne known The toxicological properties have not been fully investigated. 12. Ecological information Disposal considerations Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification. 14. Transport information t regulated t regulated t regulated t regulated 15. Regulatory information International Inventories Component TSCA DSL NDSL EINECS ELINCS NLP PICCS ENCS AICS IECSC KECL Water X X X - X X X Manganese(II) sulfate X X X X X X X Manganese sulfate X X X X - monohydrate Legend: X - Listed E - Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA. F - Indicates a substance that is the subject of a Section 5(f) Rule under TSCA. N - Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designated polymer made with any free-radical initiator regardless of the amount used. P - Indicates a commenced PMN substance R - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA. S - Indicates a substance that is identified in a proposed or final Significant New Use Rule T - Indicates a substance that is the subject of a Section 4 test rule under TSCA. XU - Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40 CFR 710(B). Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater. Page 5 / 7

6 Y2 - Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactants that comprises one of the eligibility criteria for the exemption rule. U.S. Federal Regulations TSCA 12(b) SARA 313 Component CAS- Weight % SARA Threshold Values % Manganese(II) sulfate Manganese sulfate monohydrate SARA 311/312 Hazardous Categorization Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Yes Clean Water Act Clean Air Act Component HAPS Data Class 1 Ozone Depletors Class 2 Ozone Depletors Manganese(II) sulfate X - Manganese sulfate monohydrate X - OSHA Occupational Safety and Health Administration CERCLA California Proposition 65 This product does not contain any Proposition 65 chemicals State Right-to-Know Component Massachusetts New Jersey Pennsylvania Illinois Rhode Island Water - - X - - Manganese(II) sulfate - X X X - Manganese sulfate monohydrate - X X X - U.S. Department of Transportation Reportable Quantity (RQ): DOT Marine Pollutant DOT Severe Marine Pollutant N N N U.S. Department of Homeland Security This product does not contain any DHS chemicals. Other International Regulations Mexico - Grade Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR WHMIS Hazard Class E Corrosive material D2B Toxic materials Page 6 / 7

7 Prepared By 16. Other information Regulatory Affairs Thermo Fisher Scientific Revision Date Print Date Revision Summary 11-Mar Mar-2015 This document has been updated to comply with the US OSHA HazCom 2012 Standard replacing the current legislation under 29 CFR to align with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Disclaimer The information provided on this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of SDS Page 7 / 7