SCHWEGO corrit. A Coating Additive Against Residual Rust. Description. Practice. Solution. Composition. Mode of action

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1 SCHWEGO corrit A Coating Additive Against Residual Rust Description SCHWEGO corrit is used in water-based systems as stand-alone corrosion protection additive. It can also be combined with zinc phosphate respectively other pigments and thus it can also be incorporated into primers as additional long term corrosion protection additive. Typical applications: DIY systems Maintenance paints One coat corrosion protection primers Corrosion protection primers Practice The effectiveness of anticorrosive coatings mainly depends on the thoroughness of substrate pretreatment. A thoroughly derusted, dry and fatfree substrate is a precondition for long term protection against corrosion. These optimum conditions are seldom available in practice: Residual rust frequently remains on the surface and in the pores The coating appears to confer satisfactory protection against rust. Result after several months: rust destroys the new coating from below Solution SCHWEGO corrit passivates existing residual rust by converting it into a very stable metal complex. The result is a long term corrosion protection. promotes substrate wetting and improves the adhesion of the coating. paints containing SCHWEGO corrit can be applied directly onto rusty surfaces after removal of loose rust particles. SCHWEGO corrit is based on a chelate forming agent and a wetting additive component. Mode of action The structure of the unstable Fe 3 formed during aerial oxidation is porous and therefore does not prevent further air and moisture having contact with the metal. The result is completely rusted metal.

2 Functions of SCHWEGO corrit: a) prevent the contact of material substances having a corrosive effect (mechanical barrier effect) and/or b) interfere into the electromechanical corrosion process to prevent it or at least to slow down (electromechanical influence). SCHWEGO corrit supports protection of the material from corrosion by activating both protection mechanisms, as the chelate forming agent of SCHWEGO corrit forms a virtually insoluble chelate complex with the present Fe-ions in the rust layer. Due to insolubility of the chelate complex, the Fe-ions are linked so tightly that the electro-mechanical corrosion is interrupted. Thus a barrier is formed that further oxygen attack to the metallic substrate is stopped. The result is a stable metal-organic layer adhered to the metal surface that will no longer oxidise. Thus a highly effective and durable corrosion protection is achieved but additionally there is also a chemical bondage between the metallic surface and the organic coating. Testing When testing a coating system containing SCHWEGO corrit, it is essential that the test specimen have residual rust (at least an oxidised surface). A rusty panel should be roughly derusted for laboratory tests. Especially if the resin is rather alkaline a predilution is recommended. SCHWEGO corrit should be added very slowly and carefully to avoid local overdose that will result in specks which are difficult to destroy. Most common solvents can be used, i. e. glycol, higher alcohols, water, etc. Wherever possible SCHWEGO corrit should be added at the beginning to the mill base. Post adding is also possible, but predilution is advisable as described above and the product should be added with high shear rate. We recommend evaluation of the SCHWEGO corrit using outdoor weathering. Accelerated weathering tests (e.g. salt spray test) give misleading practical values because of the high initial deterioration. In the can the surface of SCHWEGO corrit turns to green-grey gradually. This shift in colour is not a deterioration but a "cosmetic" problem. It does not affect the properties or the effectiveness of the product but influences only its appearance. The change in colour is caused by a very little oxidation of the air and the formation of this oxidation product is reversible. That means it will be immediately destroyed when the SCHWEGO corrit reacts with the iron surface. Unfortunately the shift in colour is visible at concentrations on the ppb level. Hereafter there are some guide formulations with SCHWEGO corrit.

3 Guide Formulations Description: Acrylic-thick film paint, white, high gloss Base: Primal HG 76, pure acrylic dispersion 1 Kronos 2190 (Kronos) 30.0% 2 SCHWEGO pur 8020 (Schwegmann) 0.5% 3 SCHWEGO pur 8050 (Schwegmann) 0.5% 4 Propylen glycol 8.0% 5 Water 5.8% 6 SCHWEGO corrit (Schwegmann) 1.0% Disperse up to a fineness of grind of 20µm, then prepare the binder and incorporate the paste slowly 7 Primal HG 76 (Rohm & Haas) 47.1% add slowly while stirring 8 BLISTER FREE 45 (Schwegmann) 0.5% 9 SCHWEGO wett 6290 (Schwegmann) 3.5% 10 SCHWEGO flow 8058 (Schwegmann) 1.0% 11 Preserving agent 0.1% 12 Texanol 2.0% stir well and slowly add Antigel 13 ANTIGEL (Schwegmann) 1.0% Total formulation amount: 100% Disperse the items 1 to 6 finely up to 20µm, then prepare item 7 and incorporate the paste slowly, then add the items 8 to 12 slowly and homogenise for 15 minutes, then add item 13 slowly.

4 Description: Acrylic matt to silk finish paints, black Base: Liocryl AM 912, pure acrylic, without solvents and plasticisers 1 Water 10.0% 2 Propylen glycol 8.0% 3 SCHWEGO pur 8050 (Schwegmann) 1.0% 4 SCHWEGO pur 8020 (Schwegmann) 0.3% 5 SCHWEGO corrit (Schwegmann) 1.0% premix well, then add: 6 Liocryl AM 912 (Synthopol) 68.9% 7 Colanylblack N131 (Clariant) 8.0% 8 Texanol (Eastman) 2.0% 9 BLISTER FREE 56 (Schwegmann) 1.0% 10 Matting Agent OK 500 (Degussa) 0.8% Total formulation amount: 100% Thoroughly premix the items 1-5, then incorporate the items 6-10 under agitation.

5 Description: Aqueous metal primer, grey, RAL7000 Base: Neocryl XK 62, styrene-acrylic dispersion 1 Butyldiglycol 5.00% 2 SCHWEGO wett 8075 (Schwegmann) 2.50% 3 SCHWEGO flow 8058 (Schwegmann) 2.50% 4 BLISTER FREE 56 (Schwegmann) 1.50% 5 SCHWEGO pur 8050 (Schwegmann) 2.00% 6 SCHWEGO pur 8020 (Schwegmann) 0.50% 7 SCHWEGO corrit (Schwegmann) 1.00 % premix 8 Kronos 2190 (Kronos) 6.00% 9 Silicic Acid HDK N20 (Wacker) 0.50% 10 Halox BW 191 (Lawrence Industries) 4.00% 11 Microdol extra (Omya) 11.00% Disperse up to a fineness of grind of µm, around 20min then prepare the following items and add the above mentioned paste slowly and stir 12 Neocryl XK 62 (Zeneca) 61.29% 13 Texanol (Eastman) 2.0% 14 Colanylblack N131 (Clariant) 0.20% 15 Colanylblue B2G100 (Clariant) 0.01% Total formulation amount : 100.0% Weigh the items 1 up 7 and mix them well, then add the items 8 to 11 and mix them, then disperse them with a pearl mill up to a fineness of 15 to 20 µm. Prepare item 12 and slowly add the white paste, then slowly add the items 13 to 15 while stirring.

6 Description: Acrylic-thick film paint, light grey, high gloss Base: Primal HG 76, pure acrylic dispersion 1 Kronos 2310 (Kronos) 30.0% 2 SCHWEGO pur 8020 (Schwegmann) 0.5% 3 SCHWEGO pur 8050 (Schwegmann) 0.5% 4 Propylen glycol 8.0% 5 SCHWEGO wett 6290 (Schwegmann) 3.5% 6 Water 5.8% 7 SCHWEGO foam 8325 (Schwegmann) 0.4% 8 SCHWEGO corrit (Schwegmann) 1.0% Disperse up to a fineness of grind 20µm then prepare the binder and incorporate the paste slowly 9 Primal HG 76 (Rohm & Haas) 47.1% add slowly while stirring 10 SCHWEGO flow 8058 (Schwegmann) 1.0% 11 Preserving agent 0.1% 12 Texanol 2.0% 13 SCHWEGO fluor 6536 (Schwegmann) 0.1% 14 Colanyl black N131 (Clariant) 1.0% Total formulation amount: 100 % Disperse the items 1-8 finely up to 20µm, then prepare item 9 and incorporate the paste slowly. Then add the items slowly and stir well at least 15 minutes.

7 Description: Aqueous metal primer, red oxide Base: Alberdingk AS 2681, styrene-acrylic copolymer dispersion : 1 Dest. water 10.40% 2 Dowanol DPM 3.80% 3 SCHWEGO foam 8013 (Schwegmann) 0.60% 4 Talkum AT extra (Norwegian Talc) 5.00% 5 Microdol Extra (Omya) 8.00% 6 Zinkphosphat ZP 10 (Heubach) 10.00% 7 Zinkwhite Harzsiegel (Heubach) 0.50% 8 Bayferrox 130 M (Bayer) 8.50% 9 SCHWEGO pur 8050 (Schwegmann) 1.20% 10 Propylen glycol 11.00% 11 SCHWEGO corrit (Schwegmann) 3.00% Mixing and then disperse up to a fineness of grind of µm, for about 20 minutes then prepare the following items and add the above mentioned paste slowly stirring constantly 12 Alberdingk AS 2681 (Alberdingk&Boley) 30.00% 13 Adhesion Resin EP-DS 1300 (Degussa-Hüls) 3.00% 14 Synthetic Resin EP-DS 50 (Degussa-Hüls) 5.00% Total of formulation: 100% Weigh the items 1 up to 10 and dissolve them, then add item 11 and disperse them with the aid of a dissolver up to a fineness of 25 30µm. Prepare the items 12 to 14 and incorporate the colour paste. Homogenize for about 5 minutes. Adjustment of viscosity: propylene glycol Additional hints: SCHWEGO corrit has been incorporated into this corrosion protection primer, because this product converts existing rust and prevents from the rust underneath the paint. Therefore this corrosion protection primer has an improved adhesion and shows excellent protection against rust.

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