TABLE OF CONTENTS. 5 KOLON PLASTICS at a glance 7 KOPEL (TPC-ET) 8 CHARACTERISTIC OF KOPEL 9 APPLICATIONS 10 OVERVIEW PRODUCT PORTFOLIO
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2 TABLE F CNTENTS 5 KLN PLASTICS at a glance 7 KPEL (TPC-ET) 8 CHARACTERISTIC F KPEL 9 APPLICATINS 1 VERVIEW PRDUCT PRTFLI 13 NMENCLATURE 14 THE PRPERTIES F KPEL 18 INJECTIN CNDITINS & HANDLING PRECAUTINS
3 KLN PLASTICS at a glance KLN PLASTICS always offer the best solution to customers. KLN PLASTICS creates a better world based on the DNA of KLN Group, the dream of becoming 'Lifestyle Innovator'. KLN PLASTICS is the only engineering plastics specialist in Korea, producing and selling the highest-quality Base and Compound products in the world. From PM, PA, PBT to Composite, we are building a wide range of product portfolios around the world to 9 countries, including Europe, America, and Japan. KLN PLASTICS, through the world's best technology and sustainable research and development, will present differentiated value to customers and continues to strengthen its global competitiveness through expansion of overseas markets. ESTABLISHMENT March 15, 1996 HEAD FFICE Gimcheon, Korea SALES 25 bil. USD (216) PRDUCTS 8 Brands, 4 Grades 4 5
4 KPEL (TPC-ET) KPEL is first national TPEE produced by KLN PLASTICS. Thermoplastic Polyester elastomer, which is a TPE based engineering plastic, has rubber-like properties with greater properties, thermal stability, chemical resistance and UV stability. KPEL Thermoplastic Polyester Elastomer KPEL consists of hard segmented and soft segmented block copolymer. Hard segment is crystalline polymer Polybutylene terephthalate (PBT), and soft segment is amorphous polyether. Due to these structures, KPEL has the same properties and stability of engineering plastic, along with rubber-like flexibility. (CH2CH2CH2CH2)X m n [ KPEL Molecular Formula ] 7
5 CHARACTERISTIC F KPEL APPLICATINS KPEL has the following strengths. CVJ BTS (KP3942BM) Long-term durability Heat resistance Excellent repeat fatigue resistance TPEE vs TPV Abrasion resistance TPEE vs SEBS Abrasion resistance SIDE AIRBAG GUIDE (KP3855FB, KP3855FBBL) Long-term durability il resistance Weatherability il resistance SEBS Weatherability TPV AIRBAG CVER (KP3855FB, KP3855FBBL) Tensile strength Tear resistance Tensile strength Tear resistance Long-term durability TPEE vs TPU Abrasion resistance TPEE vs TPA Abrasion resistance CABLES (KP3363, KP3768EX, KP3372) il resistance Weatherability il resistance Weatherability Excellent heat resistance Excellent repetitive fatigue characteristic Tensile strength TPU Tear resistance Tensile strength [ Comparing general & engineering properties of TPE and TPEE ] TPA Tear resistance ARTIFICIAL LEATHER (KP3226, KP3328) Wear resistance Weather resistance Fatigue resistance Great emotional touch 8 9
6 VERVIEW PRDUCT PRTFLI LW HARDNESS GRADE NAME APPLICATIN MIDDLE HARDNESS GRADE NAME APPLICATIN HIGH HARDNESS GRADE NAME APPLICATIN KP3225 Artificial Leather Automatic Gear Lever Slider Artificial Leather KP334 Low Noise Gear Conveyor Belt With Various Profile KP3328 Air Ventilation for Backpack Rail Roda Pad (General) Ski/Snowboard Equipment Golf Ball(Core) Draft Gear KP3335HR Air Ventilation for Backpack Golf Ball(Core) Roller for Semi-Conduct Process Line Bed Spring / Support Equipment Brush / Broom Door Latch Catch KP3335W Wiper Spoiler KP334HR KP3363 Parts For Cosmetic Container KP3335WB Wiper Spoiler Brush / Broom Low Noise Gear House Roofing Membrane Damper Coupling Cable Inner Liner(Charge/Data) Golf Ball(Core) Grommet / Plug KP3942BM Blow Molding Components Snow Chain Parts Automatic Gear Lever Slider Cable/Tubing for Robot System Rail Roda Pad (General) House Roofing Membrane Roller for Semi-Conduct Process Line KP3339UM KP3355 Brush / Broom Bed Spring / Support Equipment Brush / Broom Door Latch Catch Cable Inner Liner(Charge/Data) Low Noise Gear KP3363HR Draft Gear Air Ventilation for Backpack Grommet / Plug Snow Chain Parts Damper Coupling KP3355CB Roller for Semi-Conduct Process Line Cable/Tubing for Robot System Golf Ball(Skin) Rail Roda Pad (General) Rail Roda Pad (Um) Roller for Semi-Conduct Process Line KP3768 Toothbrush House Roofing Membrane Bed Spring / Support Equipment KP3768EX Cable Inner Liner(Charge/Data) Flexible ptical Fiber (General) Brush / Broom KP3355HR Draft Gear Coolant Hose for Airconditioner KP3769EX Cable Inner Liner (Charge/Data) Flexible ptical Fiber (General) KP3339UMHR Cable Inner Liner(Charge/Data) Mesh Chair / Slim Seat (General) Ski/Snowboard Equipment Air Ventilation for Backpack Golf Ball (Skin) Parts for Cosmetic Container Damper Coupling Car Sheet Monofilament (General) KP3372 Low Noise Gear Golf Ball(Skin) KP3355HS Coolant Hose for Air-Conditioner Cable Inner Liner(Charge/Data) Rail Roda Pad (Um) KP3355MF (UV-stabilized) Car Sheet Monofilament Mesh Chair / Slim Seat Toothbrush KP3355UM Grommet / Plug KP3355WB (UV-stabilized) Automatic Gear Lever Slider Car Sheet Monofilament Mesh Chair / Slim Seat KP3855FB Airbag Cover KP3855FBBL Airbag Cover KP3956BM Blow Molding Components KP3358HR Draft Gear 1 11
7 NMENCLATURE The name of KPEL commercial products generally follows the scheme below: RESIN K P PRCESS RESIN CLR/CHARACTERISTIC KP3 BL GR GN HR HS UM FB, PB, LV BM MF EX RA MP W PRCESS Alloy Injection Flame retardant Extrusion Airbag cover Blow molding HARDNESS HARDNESS CLR/CHARACTERISTICS H R Black Gray Green High resilience Heat stabilized Upper molecular weight Airbag cover Blow molding Monofilament Extrusion Low melting point Moisture permeable Weather resistant (Shore D) 13
8 THE PRPERTIES F KPEL KPEL FR AIRBAG CVER LW-TEMPERATURE FLEXIBILITY KPEL FR BLW MLDING MELT VISCSITY CMPARISN Air Bag Module cover made of KPEL boasts superior deployment stability and sensitivity quality. Due to the vehicle crash caused by a collision, it does not cause any debris that may endanger the safety of the occupants, protecting the customer's safety from a wide range of temperatures range from 4 C to 12 C. And we achieved the top durability among product lines that withstand persisting period of the car. In addition, KPEL for airbag cover features the aesthetic surface quality, providing the highest sensitivity quality for passengers to drive in comfort TPU: 4D - KPEL : 4D KPEL blow molded products are used in applications such as CVJ boots or bellows, which are used under harsh environments due to their high melt viscosity and excellent durability. Superior bending resistance and hinge fatigue properties show excellent material retention even when the blow molded moldings are deformed by torsion. It is also excellent in heat resistance and chemical resistance, so it can be used even when used with various types of grease and oils. Melt viscosity (Pa. s) 5, - KP3942BM - Competitor A - Competitor B 5 1 1, 1, As shown in the right figure, the KPEL glass transition temperature is shown to be at -5 C where TPU shows C. These low glass transition temperatures maintain high resiliency at low temperatures, allowing applications to such as ski boots. [ Glass transition temperature test of KPEL and TPU using DMA analysis ] KPEL FR DAMPING APPLICATIN V ibration absorbing, fatigue resistance and impact resistance are key properties for damping applications. Stress (MPa) FATIGUE RESISTANCE Share rate (1/s) As shown in the right figure, the energy loss factor was measured by hysteresis analysis. Compared with TPU, KPEL shows lower energy loss. Low energy loss can be an advantage for applications such as shoe soles, rail pad and draft gear. KPEL Low energy loss Strain (%) Stress (MPa) TPU High energy loss Strain (%) [ Fatigue resistance Comparison Data (KPEL vs. TPU) ] 14 15
9 THE PRPERTIES F KPEL KPEL FR AUTMATIC GEAR LEVER SLIDER Gear lever slider which is always held while driving, made of KPEL enhances handling which helps better pleasant driving. Automatic gear lever slider made from KPEL makes it possible to maintain consistent, continuous gear operation with wear resistant and durability. Static Friction coefficient FRICTIN CEFFICIENT CMPARED WITH TPE TPU KPEL PVC KPEL FR LIVING & LEISURE KPEL is applied to various life products. It has excellent overmolding, eco-friendliness and soft feeling quality, so it offers differentiated value from other materials. It also contributes to the enjoyment of skiing and snowboarding more safely and comfortably. Excellent mechanical properties and low temperature stability are applied to ski straps for ski/snowboards and high backs for snowboards, enabling skiers and skiers to enjoy snowy conditions with confidence. Tensile stress Reduction (%) CHEMICAL RESISTANCE TEST UNDER VARIUS SLVENTS Acetic acid Ethanol Benzene KP3363 EG KP334 Water [ KPEL Test Result ] KPEL on SUS ASTM D1894 TYPE F KPEL STATIC DYNAMIC KP3339UM KP334HR KP Flexure Modulus Reduction (%) KP3363 KP334 KP KP KP Acetic acid Ethanol Benzene EG Water [ KPEL Test Result ] The KPEL material is extremely resistant to abrasion and has an abrasion resistance greater than twice the durability of TPU. Condition: ASTM CS-17 - TPU: 1~5mg - KPEL : 3~2mg Loss in mg WEAR RESISTANCE CMPARED WITH TPU KPEL m aterial ow ns exc ellent a d hesive characteristic with PC, PVC, ABS, PS and other polyester based products. This characteristic is due to hard segment PBT. Because of this it is possible to apply to different materials such as grips and other applied areas. As shown in the right figure, it shows excellent adhesive intensity on PBT, PC like ester group high molecules. And also certain levels of adhesive intensity on PA, PP like high molecules. Material A Sample KP3328 (28D) KP3355 (55D) Material B PA PBT PP PC TPU KPEL Note: KLN PL AS TICS has prepared this repor t based on the data obtained up to the time of writing. The figures in all tables are representative values, not quality assurance values. The figures in the table can not be used as basic data for semi-finished products and finished product designs. As product quality improves, figures in the table may change without notice
10 INJECTIN CNDITINS & HANDLING PRECAUTINS KPEL is an engineering elastomer, which has similar performance to rubber, while the processing conditions for product molding are similar to those of ordinary crystalline thermoplastic resins, making it easy to process with the usual injection molding aids used for molding crystalline resins. CNDITINS F INJECTIN MLDING PRECAUTINS IN MLDING PRCESS Injection speed can vary greatly depending on the form of the product, but KPEL has a relatively high rubber property even in the molten state compared to the polycrystalline resin. When the injection speed is set high, the melt absorbs the injection pressure It is advantageous to set it lower than other resins because the state of the melt is excited and can act as a disadvantage to the product design and condition setting. In addition, in case of thin product, the cooling rate in CAVITY The injection speed should be relatively fast. In case of a thick product, if the injection speed is fast, surface defects such as flow marks and jetting may cause the product to be a critical defect. When using a screen filter for mixing or other purposes in a barrel during extrusion, 6 or 12 mesh is suitable. INJECTIN MLDING PARAMETERS KP3335 KP334 KP3355 KP3363 KP3372 Recommeded Moisture Contents (%).4 Melting Temperature ( C) 17 ~ ~ 2 21 ~ ~ ~ 24 Nozzle 18 ~ ~ 2 21 ~ ~ ~ 24 Front 16 ~ 2 18 ~ 2 21 ~ ~ ~ 24 Cylinder Temperature ( C) Middle 15 ~ ~ 19 2 ~ ~ ~ 235 Rear 14 ~ ~ ~ 19 2 ~ 21 2 ~ 21 Mold Temperature ( C) 2 ~ 5 2 ~ 5 2 ~ 5 4 ~ 6 4 ~ 6 Holding Pressure (%) 1/3 ~ 2/3 of max. injection pressure Cushion (mm) 5 ~ In order to prevent deterioration during processing of KPEL, moisture content should be kept below.1wt%. Usually, after about 2 hours from the opening of the bag, the moisture content becomes more than.1wt% After drying for 2~4 hours at 11 C, you can get good quality products. KPEL has a very low melting point compared to other thermoplastic resins, which can cause defects on the product surface when mixed with other resins. In order to prevent this, we need clean management of the expectation, prework FEEDER and BARREL, and occasionally screen washing. Also, using SCREEN FILTER between DIE and BARREL is effective for eliminating unmelted material and impurities. PLYMER MELT It is also advantageous in terms of flow uniformity. However, in this case, care must be taken to avoid excessive pressure build-up within BARREL
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