Graphite Engineered Solutions
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1 1. Product and Company Identification: Product Name Product Number Brand Supplier : WonderFill : ALL Grades : Graphite Engineered Solutions Llc. : Graphite Engineered Solutions Llc. 139 Tibert Rd. Columbus, Ohio Phone : Fax : EMERGENCY Phone : Recommended Use : polymer industry filler for conductivity or shielding applications 2. Hazard(s) identification: DO NOT handle until all warnings and instructions have been read and understood! Do NOT breathe dust. WARNING! Cancer Hazard: Contains material which is known to the state of California to cause cancer! Incineration can generate airborne carbon fibers which are conductive and may cause electrical malfunctions. Primary Route(s) of Exposure: Inhalation, Skin contact, Ingestion. Effects of Overexposure: acute: In its manufactured form, this subassembly is considered to be nonhazardous. After the material is abraded, the dust released may contain carbon fibers and carbon dust. Exposures to airborne concentrations may cause irritation to the eyes, upper respiratory system or the skin. May cause coughing and pulmonary edema. Chronic: WARNING! Cancer Hazard: Contains material which is known to the state of California to cause cancer! 3. Composition/information on ingredients: Component 1: Carbon (C) Powder % by weight CAS Page 1
2 4. First-aid Measures: Inhalation: Remove the exposed person to fresh air. Seek immediate medical attention. Eye Contact: IMMEDIATELY flush eyes with running water for at least 15 minutes, keep eyelids open. Obtain medical attention if irritation persists. Skin Contact: Wash contaminated skin with soap and water. Remove contaminated clothing and wash before reuse. Avoid prolonged or repeated contact with skin. Wash thoroughly after handling. Ingestion: DO NOT INDUCE VOMITING Obtain medical attention. Provide several glasses of water to rinse mouth and give water or milk to dilute material in the stomach. 5. Fire-fighting measures: This product is: NON-FLAMMABLE. Flash Point & Method: This material does not have a flash point by conventional test methods. Health: 2 Flammability: 1 Reactivity: 0 LEL: NA UEL: NA Additional: Extinguishing Media: Powder. Special Fire Fighting Procedures: Metal powder fires should be extinguished using special powder for metal fires. As any fire, wear MSHA/NIOSH approved pressuredemand self-contained breathing apparatus or equivalent and full protective gear. Unusual Fire and Explosion Hazards: This product is normally non-explosive but may form an explosive dust-air mixture. Low hazard for usual industrial or commercial handling. Hazardous Decomposition Materials: Carbon monoxide or carbon dioxide may be generated by decomposition of graphite. Page 2
3 6. Accidental release measures: Steps to be taken in case material is spilled or released: Remove all ignition sources. Ventilate the area. Wear personal protective equipment as necessary (see Section 7). Dike or contain spill with absorbent or other available materials. Do not allow spill to discharge into storm or sanitary sewers. Shovel or scoop material back into the original container or a clean, empty container. Minimize sweeping of the material so that large amounts of dust are not generated. EPA RCRA ID Number: Not considered hazardous waste pursuant to 40 CFR 261. Waste Disposal Method: Comply with all federal, state and local laws and regulations applicable to transportation and disposal of solid waste. Material to be landfilled must not contain any free liquids, should be packaged as to minimize the generation of dust and should be disposed of at a well-managed site licensed for the disposal of solid waste. This material may also be incinerated at an EPA approved incineration facility that has proper emission controls. 7. Handling and storage: Handle to minimize formation of dust. All electrical equipment in the area where dust may be generated should be sealed to prevent invasion by conductive carbon fibers. Ventilation: When abrasion occurs to create dust, provide ventilation as necessary to maintain levels below the TLV's shown in Section 8. Respiratory: If exposures exceed the recommended time-weighted average, a NIOSH-approved N-95 respirator for dust should be worn. Eye Protection: If dust is generated, safety glasses with side shields should be worn. Protective gloves: should be worn when handling raw material Other: NA 8. Exposure controls/personal protection: Material 1. Carbon/Graphite Synonym: Carbon NIOSH #: CAS #: ACGIH (TLV) SARA Sec Symbol: C TWA:2 mg/mᶟ 8HRS (as Respirable Dust) OSHA (PEL): 1.5 mg/mᶟ 8HRS (as Total Dust) 313 Reportable: No SDS prepared by Graphite Engineered Solutions. Appropriate PPE is defined in section 7 Page 3
4 9. Physical and chemical properties Appearance: Powdered solid; Black color. Melt Point: Graphite 3500 C Vapor Density: NA. Material Density: <1.76/2.0 g/cc Vapor Pressure: NA Odor: NA Boiling Point: NA Volatiles by Weight: Not Volatile ph: NA Solubility: graphite is insoluble. 10. Stability and reactivity: This product is normally non-explosive but may form an explosive dust-air mixture. Low hazard for usual industrial or commercial handling. Hazardous Decomposition Materials: Carbon monoxide or carbon dioxide may be generated by decomposition of graphite. 11. Toxicological information: Primary Route(s) of Exposure: Inhalation, Skin contact, Ingestion. Effects of Overexposure acute: In its manufactured form, this subassembly is considered to be non-hazardous. After the material is abraded, the dust released may contain carbon fibers and carbon dust. Exposures to airborne concentrations may cause irritation to the eyes, upper respiratory system or the skin. May also cause coughing and pulmonary edema. Chronic: WARNING! Cancer Hazard: Contains material which is known to the state of California to cause cancer! Page 4
5 12. Ecological information: Steps to be taken in case material is spilled or released: Remove all ignition sources. Ventilate the area. Wear personal protective equipment as necessary (see Section 7). Dike or contain spill with absorbent or other available materials. Do not allow spill to discharge into storm or sanitary sewers. Shovel or scoop material back into the original container or a clean, empty container. Minimize sweeping of the material so that large amounts of dust are not generated. EPA RCRA ID Number: This material is considered hazardous by the OSHA Hazard Communication Standard. (29 CFR ) 13. Disposal considerations: Recycle first when possible. Waste Disposal Method: Comply with all federal, state and local laws and regulations applicable to transportation and disposal of solid waste. Material to be landfilled must not contain any free liquids, should be packaged as to minimize the generation of dust and should be disposed of at a well-managed site licensed for the disposal of solid waste. This material may also be incinerated at an EPA approved incineration facility that has proper emission controls. 14. Transport information: Not currently regulated under DOT. DOT Shipping Name: NA Technical Shipping Name: Synthetic Graphite DOT Hazard Classification (Primary): NA (Secondary): NA Freight Classification: Carbon / graphite dust Number: NA IMO Hazard Class: NA DOT Labels Required: NA EPA/DOT Hazardous substances RQ: NA Canadian Transportation of Dangerous Foods Act (TDG): Not regulated International Maritime Dangerous Goods Code: Not regulated International Civil Aviation Organization Technical Instructions for the Carriage of Dangerous Good by Air: Not regulated European Agreement Concerning the International Carriage of Dangerous Goods by Road: Not regulated Page 5
6 15. Regulatory information: OSHA Hazardous by definition of Hazard Communication Standard CFR TSCA Inventory: component included in the Toxic Substances Control Act (TSCA) Health-2 Fire-1 Reactivity-0 HMIS Classification Other: WHMIS Class D-2B Material causing other toxic effects (TOXIC) 16. Definitions / Warranty: NE - NOT ESTABLISHED NA - NOT APPLICABLE This health and accident hazard information is made available to the Buyer only on the express condition that the Buyer release Graphite Engineered Solutions, Llc. from any liability or responsibility. As the information was obtained, in part, from independent research laboratories not under the direction or supervision of Graphite Engineered Solutions Llc.. No warranty or representation is made that the information contained in this document is accurate, reliable, complete or representative. Graphite Engineered Solutions Llc. warrants only that it has made no effort to censor other than trade secret information or to conceal deleterious aspects of its products. The data shown above in no way modifies, amends or enlarges any specification or warranty. It is the user s responsibility to determine safe use and handling of this product. Graphite Engineered Solutions Llc. Does not warrant the fitness of this material for any particular use and assumes no responsibility for injury, illness or damage caused directly or indirectly by or related to the use of the material. Page 6
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