Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet NFPA HMIS Personal Protective Equipment 2 Health Hazard Fire Hazard 2 See Section 15. Section 1. Chemical Product and Company Identification Common Name/ Trade Name Manufacturer Commercial Name(s) Synonym Potassium titanium fluoride SPECTRUM LABORATORY PRODUCTS INC S. SAN PEDRO STREET GARDENA, CA 9248 Dipotassium hexfluorotitanate; Dipotassium hexfluorotitanate (2-); Titanate(2-), hexafluoro-, dipotassium (OC-6-11)-; Titanate(2-), hexafluoro-, dipotassium (8CI) Titanium potassium fluoride Catalog Number(s). CAS# RTECS TSCA CI# PO IN CASE OF EMERGENCY CHEMTREC (24hr) Page Number: 1 TSCA 8(b) inventory: Potassium titanium fluoride Chemical Name Chemical Family Chemical Formula Supplier Potassium hexafluorotitanate K2TiF6 SPECTRUM LABORATORY PRODUCTS INC S. SAN PEDRO STREET GARDENA, CA 9248 CALL (31) Section 2.Composition and Information on Ingredients Name CAS # Exposure Limits TWA (mg/m 3 ) STEL (mg/m 3 ) CEIL (mg/m 3 ) % by Weight 1) Potassium titanium fluoride Toxicological Data on Ingredients Potassium titanium fluoride LD5: LC5: Section 3. Hazards Identification Potential Acute Health Effects Potential Chronic Health Effects Hazardous in case of eye contact (irritant), of ingestion. Slightly hazardous in case of skin contact (irritant), of inhalation. CARCINOGENIC EFFECTS: MUTAGENIC EFFECTS: TERATOGENIC EFFECTS: DEVELOPMENTAL TOXICITY: Repeated or prolonged exposure is not known to aggravate medical condition.

2 Potassium titanium fluoride Page Number: 2 Section 4. First Aid Measures Eye Contact Skin Contact Serious Skin Contact Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention. Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Inhalation Serious Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Ingestion Serious Ingestion Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or waistband. Section 5. Fire and Explosion Data Flammability of the Product Auto-Ignition Temperature Flash Points Flammable Limits Products of Combustion Fire Hazards in Presence of Various Substances Non-flammable. Explosion Hazards in Presence of Various Substances Risks of explosion of the product in presence of mechanical impact: Risks of explosion of the product in presence of static discharge: Fire Fighting Media and Instructions Fire Hazards Explosion Hazards When heated to decomposition it emits highly toxic fumes of potassium oxides, fluorine, titanium/titanium oxides. Section 6. Accidental Release Measures Small Spill Large Spill Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.

3 Potassium titanium fluoride Page Number: 3 Section 7. Handling and Storage Precautions Storage Do not breathe dust. Avoid contact with eyes. Never add water to this product. Wear suitable protective clothing. If ingested, seek medical advice immediately and show the container or the label. Store in an appropriate container. Keep container tightly closed. Keep container in a cool, well-ventilated area. Section 8. Exposure Controls/Personal Protection Engineering Controls Personal Protection Personal Protection in Case of a Large Spill Exposure Limits Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. TWA: 2.5 (mg(f)/m 3 ) from OSHA (PEL) [United States] TWA: 2.5 (mg/(f)m 3 ) from ACGIH (TLV) [United States] Consult local authorities for acceptable exposure limits. Section 9. Physical and Chemical Properties Physical state and appearance Solid. Odor Molecular Weight ph (1% soln/water) g/mole Taste Color Boiling Point Melting Point Critical Temperature Specific Gravity Vapor Pressure Vapor Density Volatility Odor Threshold Water/Oil Dist. Coeff. Ionicity (in Water) Dispersion Properties Solubility Section 1. Stability and Data Stability Instability Temperature Conditions of Instability Incompatibility with various substances The product is stable. Incompatible materials Reactive with oxidizing agents.

4 Potassium titanium fluoride Page Number: 4 Corrosivity Corrosivity Polymerization Will not occur. Section 11. Toxicological Information Routes of Entry Toxicity to Animals Chronic Effects on Humans Other Toxic Effects on Humans Toxicity to Animals Chronic Effects on Humans other Toxic Effects on Humans Inhalation. Ingestion. LD5: LC5: Hazardous in case of ingestion. Slightly hazardous in case of skin contact (irritant), of inhalation. Acute Potential Health Effects: Skin: May cause skin irritation. Eyes: Causes eye irritation. Inhalation: May cause respiratory tract irritation. Ingestion: May be harmful if swallowed. Section 12. Ecological Information Ecotoxicity BOD5 and COD Products of Biodegradation Toxicity of the Products of Biodegradation the Products of Biodegradation Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. The product itself and its products of degradation are not toxic. Section 13. Disposal Considerations Waste Disposal Waste must be disposed of in accordance with federal, state and local environmental control regulations. Section 14. Transport Information DOT Classification Identification Not a DOT controlled material (United States). Special Provisions for Transport

5 Potassium titanium fluoride Page Number: 5 DOT Section 15. Other Regulatory Information and Pictograms Federal and State Regulations California Proposition 65 Warnings Other Regulations TSCA 8(b) inventory: Potassium titanium fluoride California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: No products were found. California prop. 65: This product contains the following ingredients for which the State of California has found to cause birth defects which would require a warning under the statute: No products were found. EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances (EINECS No ). Canada: Listed on Canadian Domestic Substance List (DSL). China: Listed on National Inventory. Japan: Listed on National Inventory (ENCS). Korea: Listed on National Inventory (KECI). Philippines: Listed on National Inventory (PICCS). Australia: Listed on AICS. Other Classifications WHMIS (Canada) CLASS D-2B: Material causing other toxic effects (TOXIC). DSCL (EEC) R22- Harmful if swallowed. R36- Irritating to eyes. R43- May cause sensitization by skin contact. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S46- If swallowed, seek medical advice immediately and show this container or label. HMIS (U.S.A.) Health Hazard Fire Hazard Personal Protection 2 E National Fire Protection Association (U.S.A.) Health 2 Flammability Specific hazard WHMIS (Canada) DSCL (Europe) TDG (Canada) ADR (Europe) Protective Equipment

6 Potassium titanium fluoride Page Number: 6 Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Splash goggles. Section 16. Other Information MSDS Code References Other Special Considerations P465 Validated by Sonia Owen on 9/14/27. Verified by Sonia Owen. Printed 9/27/27. CALL (31) Notice to Reader All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS) applies only to the material as packaged. If this product is combined with other materials, deteriorates, or becomes contaminated, it may pose hazards not mentioned in this MSDS. It shall be the user's responsibility to develop proper methods of handling and personal protection based on the actual conditions of use. While this MSDS is based on technical data judged to be reliable, Spectrum Quality Products, Inc. assumes no responsibility for the completeness or accuracy of the information contained herein.