Open new market opportunities with BioPBS TM /PLA. InnoBioPlast 2016 September 15, 2016

Transcription

1 Open new market opportunities with BioPBS TM /PLA InnoBioPlast 2016 September 15, 2016

2 Agenda Introduction to BioPBS TM BioPBS TM /PLA compound Takeaway Points Acknowledgement

3 More People, More Plastics

4 We produce more waste, and most of it isn t disposed in the most environmentally-friendly method.

5 Bioplastics PBAT, PCL Petro-based Conventional Plastics: PE, PP, PS, PET, ABS, PC, PMMA, Nylon, etc. Biodegradable Non-biodegradable BioPBS Starch blends with PE PHA PLA Bio-based Bio-PE Bio-PP Bio-PA PTT

6 Who are we?

7 Renewable content Continuous process More efficient purification Higher drying capability More uniform products Very low moisture Very low impurity Longer shelf-life

8 Introduction to BioPBS produced by batch process in Japan O m n p Petro-Succinic Acid 1,4-butanediol Polybutylene Succinate, PBS O O O X produced by continuous process in Thailand O m n p Bio-Succinic Acid 1,4-butanediol Polybutylene Succinate, PBS O O O X

9 Injection Molding Properties Properties Unit FZ71 FZ91 FD92 Melt Flow Rate (190ºC/2.16kg f ) g/10min Density g/cm Glass Transition Temperature ºC Melting Point ºC Yield Stress MPa Tensile Strength at Break MPa Tensile Strain at Break % Flexural Modulus MPa Flexural Strength MPa Izod Impact Strength (23ºC) kj/m Heat Deflection Temperature (0.45 MPa) ºC Vicat Softening Point ºC Rockwell Hardness (R-scale) kj/mm Note: These values are typical and not to be construed as specifications.

10 Film Properties Properties Unit FZ91 (20 µm) FD92 (20 µm) Melt Flow Rate (190ºC/2.16kg f ) g/10min 5 4 Density g/cm Tensile Modulus MD MPa TD MPa Yield Stress MD MPa TD MPa Stress at break MD MPa TD MPa Strain at break MD % TD % Elmendorf Tear Strength MD N/mm 2 2 TD N/mm 4 5 WVTR 20 / 50 µm g/m 2 d 510 / 210 1,050 / 510 OTR 20 / 50 µm cm 3 /m 2 d bar 490 / 140 2,040 / 760 Puncture Impact Strength kj/mm 4 6 Haze (25 µm) Note: These values are typical and not to be construed as specifications.

11 Certified Compostable CEDAR GROVE

12 Biodegradation in SOIL % biodegradation Days Cellulose BioPBS FZ71PB BioPBS FZ91PB BioPBS FD92PB

13 Excellent heat seal strength even at low temp. Heat Seal Condition: Pressure 0.2 MPa Time 1 sec Seal width 5 mm Strength Measurement Condition: Specimen: Film 15 mm width with 20µm thickness Chuck Interval: 60 mm Test Speed: 300 mm/min

14 BioPBS Heat Seal Property Heat seal strength(n/15mm) Heat seal temperature (deg.c) Paper Coating conditions : Structure: Kraft/resin (20 μm) Processing temperature: PBS 270ºC LDPE* 320ºC Corona treatment Heat seal conditions : Seal surface: Resin/paper Seal bar width : 5 mm Pressure / time : 0.2 MPa/1.0sec Film * MFR 8.2 g/10min Density g/cm 3 GS PBS Pla LDPE LDPE+corona

15 Food Contact Safety Complies with EU directives 10/2011 All raw materials on positive list Migration test passed OM-6 (100 C, 4 hours) FCN No and 1643 FZ-grade: Condition of Use B-H FD-grade: Condition of Use C-G All food types except alcoholic foods Listed in JHOSPA Positive List

16 BioPBS for Paper Coating Excellent process as fast as LDPE Stable and narrow neck-in Excellent adhesion and seal strength Compostable at room temperature Recyclable in paper mill BioPBS BioPBS BioPBS Source: MCC s internal laboratory

17 BioPBS as Sealing Layer in Flexible Packaging Excellent process in existing LDPE extrusion coating machine Excellent seal strength Compostable without composting facility Excellent printability without pre-treatment Good to retain aroma such as limonene Suitable for food packaging Example of a film structure Utilizing BioPBS as a sealing layer Cellulose Metallized Cellulose BioPBS TM

18 Agenda PTTMCC and BioPBS TM BioPBS TM /PLA Compound Take Away Points Acknowledgement

19 Properties comparison of BioPBS vs PLA Flexible Flexibility Rigid Higher Impact strength Lower Faster Biodegradability* Slower BioPBS Higher Heat resistance Lower PLA Lower Process temp. Higher Lower Heat-seal temp. Higher Translucent Transparency Transparent * in soil at 30 C (86 F), 50%RH

20 Potential of PBS/PLA Compound Potential PBS-PLA Compound PBS Compound BioPBS

21 Compatible to PLA Compound resin of PBS with PLA showed good dispersion 75 / / / 75 PBS / PLA 1μm

22 Improve thermal stability Degradation Temperature HDT %crystallinity %BioPBS FZ71

23 BioPBS can improve service temperature PLA 0% PLA 30% PLA 60% PLA 75% PLA 90% PLA 100% 60ºC for 1 hour 70ºC for 1 hour 80ºC for 1 hour

24 Tensile Properties Tensile Strength, MPa Elongation, % Tensile Modulus, MPa %BioPBS FZ71 Tensile Strength Elongation Tensile Modulus 0

25 Flexural Properties Flexural Modulus, MPa Flexural Modulus Yield Stress Yield Stress, MPa %BioPBS FZ71

26 Izod Impact Strength 25 Izod Impact Strength, ft lb/ft Notched %BioPBS FZ71

27 Opportunities are endless

28 How can you use BioPBS?

29 Takeaway Points Properties alike LDPE plus biodegradable at ambient Food contact safety in USA and EU Improve flexibility, impact, and thermal properties of PLA

30 Acknowledgement PTT Research Institute of Technology Dr. Narin Kaabbuathong and his team Dr. Jirawut Junkasem Mitsubishi Chemical Corporation Dr. Uyeda Tadashi

31 Mr. Chinnawat Srirojpinyo Marketing Technical Service Manager

32 Test Condition Material: PLA Ingeo 4032D PBS BioPBS FZ71PM Sample Preparation: 1. Compounded by twin-screw extruder at 320 F 2. Injected specimen at 375 F 3. Conditioned at 73.4±3.6 F, 50±5%RH for 40 hours before evaluation

33 Bio-based Certificates Certificates FZ71 FZ91 FD92 Din Certco 50-85% (51%) 50-85% (51%) 20-50% (35%) BiomassPla 48.5% 48.5% 33.5%

34 Compostable Certificates Certificates Standard FZ71 FZ91 FD92 BPI (USA) ASTM D µm 68µm On process (Q2/2016) OK Compost (EU) EN µm 69µm 87µm OK Compost HOME (EU) EN13432 at 28±2 C µm OK Biodegradable Soil (EU) EN13432 at 25 C 2-year test Up to Feb year test Up to Feb year test Up to Feb 2018 GreenPla (JBPA) JBPA On process (Q3/2016) On process (Q3/2016) On process (Q3/2016) ABA (Australia) AS 4736 On process (Q3/2016) On process (Q3/2016) On process (Q3/2016)

35 EU 10/2011 BioPBS FZ-grade (PBS) 50µm: BioPBS FD-grade (PBSA) 50µm: OM-6 condition, simulant A, B, D1, D2 OM-3 condition, simulant A, B, D1, D2 Raw materials including chain extenders are in positive list Overall migration limit < 10 mg/dm 2 Specific migration limit are met 1,4-BDO < 5 mg/kg SML(T) Grade Condition 1,4-BDO FZ71PM 50 µm OM-6 < mg/kg FZ91PM 50 µm OM-6 <0.1 mg/kg FD92PM 50 µm OM-3 < mg/kg

36 MFR 190 C, 2.16 kg f MFR, g/10min %BioPBS FZ71 in PLA

37 Viscosity 190 C 10,000 Viscosity, Pa-s 1, :100 10:90 20:80 40:60 60:40 80:20 100: ,000 10,000 Shear Rate, s-1

38 Summary FZ71PM Ingeo 4032D MFR Crystallinity HDT Thermal Degradation Temperature g/10min Tc, C % C C FZ71PM Ingeo 4032D Tensile Flexural Izod Impact Modulus, MPa Strength, MPa Elongation, % Modulus, MPa Stress, MPa Notched, ft lb/ft , , , , , , , , , , ,